CN107058891A - A kind of method that utilization sea sand ore deposit produces high-strength anti-seismic building materials - Google Patents
A kind of method that utilization sea sand ore deposit produces high-strength anti-seismic building materials Download PDFInfo
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- CN107058891A CN107058891A CN201611215659.4A CN201611215659A CN107058891A CN 107058891 A CN107058891 A CN 107058891A CN 201611215659 A CN201611215659 A CN 201611215659A CN 107058891 A CN107058891 A CN 107058891A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/02—Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/5264—Manufacture of alloyed steels including ferro-alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/006—Making ferrous alloys compositions used for making ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Treatment Of Steel In Its Molten State (AREA)
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- Carbon Steel Or Casting Steel Manufacturing (AREA)
Abstract
The present invention relates to being refined after sea sand ore deposit smelting molten iron, the vanadium titanium elements wherein contained using ore lift the performance of steel.(400MPa grades of above antidetonation building materials of existing market generally add vanadium or niobium, and cost of alloy is expensive) high-strength anti-seismic building materials can be smelted according to different proportionings.Because addition of the sea sand ore deposit containing alloying components such as vanadium 0.3 0.5%, titanium 6 15%, iron 50 60%, the crystal grain of steel is refined instead of conventional a part of manganese element, the intensity, extensibility and corrosion resistance of steel is improved.Existing steel production pattern is broken, has been low cost, high-performance, high-quality upgrading steel product.And preparation technology is easy, conventional smelting iron and steel flow is easily popularized.Part iron ore is substituted using cheap sea sand ore deposit and reduce further production cost, with good economic benefit, social benefit and application prospect.
Description
Technical field
The present invention relates to field of metallurgy, and in particular to purposes of the sea sand ore deposit in production high-strength anti-seismic building materials, Yi Jili
The method that high-strength anti-seismic building materials are produced with sea sand ore deposit.
Background technology
At present, China's iron ore deposit is gradually reduced, and steel production capacity is significantly expanded, and the iron ore deposit of steel production is most of
By import.Sea sand ore deposit contains the valuable metals such as vanadium, titanium, iron, compared with iron ore deposit, and sea sand ore deposit is not only a kind of cheap iron
Source, and the also valuable metal such as vanadium titanium.Iron ore deposit is increasingly reduced at home, steel production increasingly relies on imported iron ore
In the case of, using sea sand ore deposit as a kind of new iron ore deposit, steel production is carried out, significant economic benefit will be brought.
At home, start to be taken seriously as the source of iron of steel-making using pyrometallurgical smelting laterite nickel ore and producing ferronickel in recent years, but
Lateritic nickel ore resource is also limited by Southeast Asian countries.There are the sea sand more than lateritic nickel ore reserves in Indonesia, Philippine Sea water front
Ore deposit, the low-grade and ultralow grade sea sand ore deposit of a large amount of imports is a large amount of using iron content 50%, containing vanadium 0.3%, the cheap sea sand of titanium 6%
Ore deposit (180-220 yuan/ton) will reduce iron ore and a trusted path of cost of alloy, again can be by using wherein vanadium titanium
Composition influence improves the performance of building materials.
The content of the invention
To overcome the application limitation of existing sea sand ore deposit, the invention provides sea sand ore deposit in smelting high-strength antidetonation building materials
Purposes.
The sea sand ore deposit selects iron content 50%-60%, 0.3-0.5% containing vanadium, titanium 6-15%, preferably iron content 55%, containing vanadium
0.5%th, the sea sand ore deposit of titanium 12%.
The invention provides a kind of method that utilization sea sand ore deposit produces high-strength anti-seismic building materials, comprise the following steps：
(1) using sea sand ore deposit with iron ore adapted is sintered, blast furnace process obtains the molten iron containing vanadium, titanium composition；
(2) molten iron enters the steel that steel-making obtains meeting performance requirement by using refining, trimming (addition alloy material)
Water；
(3) need to enter continuous casting by kind, casting meets the steel billet of steel rolling process needs；
(4) high line, screw thread, valve snail etc. are rolled.
Sea sand ore deposit and iron ore adapted described in step (1), refer to, according to vanadium titanium composition requirement in molten steel, carry out iron ore
Stone and the proportioning of sea sand ore deposit；Sintering, blast fumance are existing current conventional production process；
Step (2) refining can be completed by converter or electric furnace；Composition in fine tuning molten steel can pass through electric furnace
Smelt to complete；
The performance that meets is according to national standard；Or particular/special requirement, produced as a trial through laboratory, check feature reaches specificity
The nickel chromium triangle new material product that can be required；
Step (3) described continuous casting process is existing current conventional production process；
Step (4) described rolling mill practice is existing current common process, is not required to add particular device.
Above-mentioned sea sand ore deposit selects iron content 50%-60%, 0.3-0.5% containing vanadium, titanium 6-15%, preferably iron content 55%, containing vanadium
0.5%th, the sea sand ore deposit of titanium 12%.
Technical scheme regard sea sand ore deposit as a part of source of iron of high-strength anti-shock production of construction materials or whole sources of iron, profit
The high-strength anti-seismic building materials of titanium containing vanadium are obtained with steel-making and steel rolling process.
Fig. 1 is shown in technological process.Detailed step is as follows：
(1) to the composition tracing detection of sea sand ore deposit, result is produced as a trial according to laboratory and formulates rational sea sand ore deposit, iron ore
Proportioning；
Firstth, according to required steel grade national standard requirement, control alloy content is not more than national standard, makes full use of sea sand
Iron in ore deposit；
Secondth, according to laboratory results, by reaching the trial production composition proportion of performance requirement material, formulate suitable
Proportioning and select corresponding sea sand ore deposit kind；
3rd, produce product and possess notable feature and be：Contain vanadium titanium composition in steel product ingredient, (because at present on vanadium
Titanium new material does not have specific national standard, using sea sand ore deposit smelting molten iron, the vanadium titanium member that vanadium Ti content is depended in sea sand ore deposit
Cellulose content and the proportioning with iron ore, but material overall performance after tested, hence it is evident that higher than the material for being not added with vanadium titanium composition), institute
To be referred to as nickel chromium triangle new material；
(2) it is sintered using sea sand ore deposit and iron ore adapted, blast furnace process obtains the molten iron of the composition of titanium containing vanadium；
Sintering, blast furnace are existing common process；
(3) steel-making is entered, refining can be completed by converter or electric furnace；Composition in fine tuning molten steel can pass through electric furnace
Smelt to complete；
When producing national standard steel grade, the vanadium Ti content in molten iron can be strictly controlled by dispensing in allowed band, profit
Can produce molten steel with converter, make full use of the iron in sea sand ore deposit, micro vanadium titanium can be obviously improved steel yield strength,
Tensile strength；
, can be according to performance requirement when producing property and requiring steel grade, laboratory trial production adds that necessary other are micro-
Secondary element, according to the corresponding sea sand ore deposit of laboratory data formulation and iron ore, (particular/special requirement can add other ore deposits after performance is up to standard
Sinter together, example：Need to add nickel chromium triangle in the weather-proof steel bar of 500MPa, 700MPa grades of antidetonations of production, so in sintering deposit matching somebody with somebody
Enter a certain proportion of lateritic nickel ore) proportioning, obtain meeting the composition of performance requirement, by electric furnace refining and finely tune composition and obtain
Preferable nickel chromium.
(4) need to enter continuous casting by kind, casting meets the steel billet of steel rolling process needs；
The continuous casting process is existing current common process, is not required to add particular device；
(5) rolled wire, bar etc..
The building materials bar and wire rod rolling process technique is existing current common process, is not required to add particular device
Technical solutions according to the invention are coordinated with iron ore with sea sand ore deposit or all entered using sea sand ore deposit production sintering deposit
Row is smelted, refining, reduces the cost of manufacture of steel, improves the application of lateritic nickel ore, can be obtained according to different consumptions
To the steel of Multiple Type, and due to the addition of the elements such as vanadium, titanium, the performance of steel, and preparation technology letter are also improved
Just, with good economic benefit and application prospect.
Brief description of the drawings
Fig. 1 is the process chart that the inventive method refines high-strength anti-seismic building materials using sea sand mining and metallurgy.
Embodiment
Following examples are used to illustrate the present invention, but are not limited to the scope of the present invention.
Embodiment 1
Produce common hot calendering round bar (low-alloy steel)：
Select containing vanadium 0.3%, titanium 6%, iron 50% sea sand ore deposit；
Sea sand ore deposit and the iron ore ratio 1 of iron content 61%:9 are sintered, ironmaking, and containing vanadium 0.21%, (80% receives molten iron
Rate), titanium 0.2%-0.25% (do not stay titanium as special process, only remain), molten iron enters steel-making and refines, and vanadium titanium is into split-phase in molten steel
Plus keep≤0.4%；Molten steel casting blank, steel billet rolls out hot rolling plain bar into steel rolling.
Through pilot production repeatedly, draw and a part of manganese constituent reduction manganese alloy consumption, its overall mechanical property are replaced with vanadium titanium
Can, processing performance is apparently higher than the steel without vanadium titanium.And cheap sea sand ore deposit steel per ton reduces about 25 yuan of iron ore
Cost, with the addition of vanadium titanium elements in sea sand ore deposit, steel per ton can also saving 5kg silicomangans per ton, about ton steel saving alloy
Expect 30 yuan or so of cost.
Embodiment 2
The common hot-rolled ribbed 400E grades reinforcing bar (low-alloy steel) of production：
Select containing vanadium 0.3%, titanium 6%, iron 50% sea sand ore deposit；
Containing containing vanadium 0.3%, titanium 6%, the sea sand ore deposit of iron 50% and the iron ore ratio 2 of iron content 61%:8 are sintered, ironmaking,
Molten iron reduces silicomangan amount at 5kg/ tons containing vanadium 0.43%, titanium 0.2%-0.25% (not staying titanium as special process, only remain)
Steel；
Strand, rolls out hot rolled ribbed bars.
Through pilot production repeatedly, show that its overall mechanical properties, processing performance are same apparently higher than alone Manganese alloy production
The steel of carbon equivalent.And sea sand ore deposit steel per ton reduces about 50 yuan of iron ore cost, with nickel in lateritic nickel ore, chromium
Add, steel per ton can also saving 5kg silicomangans per ton, about 30 yuan or so of ton steel saving alloy material cost.
It is that company brings considerable economic benefit through volume production.
Embodiment 3
The common hot-rolled ribbed 500E grades reinforcing bar (low-alloy steel) of production：
Select containing vanadium 0.5%, titanium 12%, iron 60% sea sand ore deposit；
Containing containing vanadium 0.5%, titanium 12%, the sea sand ore deposit of iron 60% and the iron ore ratio 2 of iron content 61%:8 are sintered, refining
Iron, molten iron reduces silicomangan amount and existed containing vanadium 0.66%, titanium 0.2%-0.25% (not staying titanium as special process, only remain)
6kg/ tons of steel；
Strand, rolls out hot rolled ribbed bars.
Through pilot production repeatedly, show that its overall mechanical properties, processing performance are same apparently higher than alone Manganese alloy production
The steel of carbon equivalent.And sea sand ore deposit steel per ton reduces about 50 yuan of iron ore cost, with nickel in lateritic nickel ore, chromium
Add, steel per ton can also saving 6kg silicomangans per ton, about 36 yuan or so of ton steel saving alloy material cost.
It is that company brings considerable economic benefit through volume production.
Although above having used general explanation, embodiment and experiment, the present invention is described in detail,
But on the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.
Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed model
Enclose.
Claims (10)
1. utilizing sea sand ore deposit sintering deposit, blast fumance contains vanadium titanium iron, then steel-making, strand, rolling.
2. purposes according to claim 1, it is characterised in that the sea sand ore deposit selects iron content 50%-60%, 0.3- containing vanadium
0.5%th, titanium 6-15%, preferably iron content 55%, the sea sand ore deposit containing vanadium 0.5%, titanium 12%.
3. a kind of method that utilization sea sand mining and metallurgy refines high-strength anti-seismic building materials, it is characterised in that comprise the following steps：
(1) it is sintered using sea sand ore deposit and iron ore dispensing, the pig iron of the titanium containing vanadium is obtained through blast furnace reducing and smelting；
(2) the charging link for converter or the electric furnace refining for passing through steel making working procedure containing vanadium titanium iron obtains meeting the steel of performance requirement
Water；
(3) need to enter continuous casting by kind, casting meets the steel billet of steel rolling process needs；
(4) become a useful person by rolling.
4. method according to claim 3, it is characterised in that described in step (1) by controlling sea sand ore deposit and iron ore
Proportioning by sinter, blast furnace process obtain the alloy containing vanadium, titanium composition, using converter or electric furnace refining, reach lifting intensity
And anti-seismic performance, save the purpose of manganese alloy.
5. method according to claim 3, it is characterised in that the refining equipment described in step (2) contains electric furnace, converter, steel
Plant and contain (vanadium titanium) steel alloy.
6. method according to claim 3, it is characterised in that the mill described in step (4), according to produce high line,
Screw thread needs to enter corresponding rolling line.
7. method according to claim 3, it is characterised in that the performance requirement described in step (2) is：
(1) component requirements in existing each steel grade national standard, strict control vanadium titanium composition addition；
(2) national standard has supplementary notes：Example：Extraneous copper, chromium, nickel composition are not more than 0.3% in steel, and supplier such as can guarantee that quality
It can not analyze (see the 7.1.2 of page six in GB1499.2-2007)；
Embodiment：
8. the method according to claim any one of 3-7, it is characterised in that the sea sand ore deposit is iron content 50-60%, containing vanadium
0.3-5%, titanium 6-15% sea sand ore deposit, preferably iron content 55%, the sea sand ore deposit containing vanadium 0.5%, titanium 12%.
9. measure：The present invention key component and percentage by weight be：
Note：Remaining is Fe and inevitable impurity, because the present invention uses sea sand ore deposit for primary raw material, the highest containing vanadium in molten iron
Up to 0.1%, titanium 3%, it is generally acknowledged that vanadium, titanium improve influence to the performance of material, but its is expensive.
10. the main points of the present invention：
1st, using cheap sea sand ore resources, replacement iron ore resource is main metallurgical ore；
2nd, influence to improve the performance of building materials using beneficial elements such as the vanadium in alloy, titaniums, product is possessed the property such as high intensity, antivibration
Energy.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611215659.4A CN107058891A (en) | 2016-12-26 | 2016-12-26 | A kind of method that utilization sea sand ore deposit produces high-strength anti-seismic building materials |
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| CN201611215659.4A CN107058891A (en) | 2016-12-26 | 2016-12-26 | A kind of method that utilization sea sand ore deposit produces high-strength anti-seismic building materials |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108193124A (en) * | 2017-12-29 | 2018-06-22 | 钢研晟华科技股份有限公司 | A kind of high-strength air corrosion-resistant steel muscle and preparation method thereof |
| CN112080682A (en) * | 2020-09-23 | 2020-12-15 | 宁夏建龙龙祥钢铁有限公司 | Method for increasing vanadium content of molten deformed steel bar by using vanadium-containing titanium-containing pig iron block |
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| CN104911339A (en) * | 2015-04-24 | 2015-09-16 | 攀钢集团攀枝花钢铁研究院有限公司 | Vanadium titanium sinter and preparation method thereof |
| CN105441668A (en) * | 2015-11-25 | 2016-03-30 | 攀钢集团攀枝花钢铁研究院有限公司 | Sintering method for sea sand vanadium-titanium-iron concentrate |
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2016
- 2016-12-26 CN CN201611215659.4A patent/CN107058891A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104911339A (en) * | 2015-04-24 | 2015-09-16 | 攀钢集团攀枝花钢铁研究院有限公司 | Vanadium titanium sinter and preparation method thereof |
| CN104911338A (en) * | 2015-04-28 | 2015-09-16 | 攀钢集团攀枝花钢铁研究院有限公司 | Sintering raw material composition and acid vanadium titanium sinter and preparation method and application thereof |
| CN105441668A (en) * | 2015-11-25 | 2016-03-30 | 攀钢集团攀枝花钢铁研究院有限公司 | Sintering method for sea sand vanadium-titanium-iron concentrate |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108193124A (en) * | 2017-12-29 | 2018-06-22 | 钢研晟华科技股份有限公司 | A kind of high-strength air corrosion-resistant steel muscle and preparation method thereof |
| CN112080682A (en) * | 2020-09-23 | 2020-12-15 | 宁夏建龙龙祥钢铁有限公司 | Method for increasing vanadium content of molten deformed steel bar by using vanadium-containing titanium-containing pig iron block |
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