CN107043255A - The manufacturing process of fin - Google Patents

The manufacturing process of fin Download PDF

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Publication number
CN107043255A
CN107043255A CN201710095575.XA CN201710095575A CN107043255A CN 107043255 A CN107043255 A CN 107043255A CN 201710095575 A CN201710095575 A CN 201710095575A CN 107043255 A CN107043255 A CN 107043255A
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Prior art keywords
kapton
parts
graphite
film
fin
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Inventor
金闯
梁豪
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Sidike New Materials Jiangsu Co Ltd
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Sidike New Materials Jiangsu Co Ltd
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Priority to CN201710095575.XA priority Critical patent/CN107043255A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09D179/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/12Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein one or more rollers exert pressure on the material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/524Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from polymer precursors, e.g. glass-like carbon material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62218Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic films, e.g. by using temporary supports
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F1/00Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
    • G06F1/16Constructional details or arrangements
    • G06F1/20Cooling means
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F1/00Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
    • G06F1/16Constructional details or arrangements
    • G06F1/20Cooling means
    • G06F1/203Cooling means for portable computers, e.g. for laptops
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K7/00Constructional details common to different types of electric apparatus
    • H05K7/20Modifications to facilitate cooling, ventilating, or heating
    • H05K7/2039Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/48Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
    • C04B2235/483Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/616Liquid infiltration of green bodies or pre-forms
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient

Abstract

A kind of manufacturing process of fin of the present invention, including:Graphite modified dose is respectively coated on the upper and lower surface of Kapton, the Kapton after processing is made up of Kapton, the first coat and the second coat;The graphite modified dose of component by following parts by weight is constituted:Benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, N methyl pyrrolidones, ethylene glycol, dimethyl silicone polymer, dibutyl phthalate;Kapton after processing is risen to after 1200 DEG C to the carbonized film for obtaining pre-burned from room temperature;Carbonized film is warming up to after 2850 DEG C ~ 2950 DEG C and cooled down, so as to obtain the graphite film of main firing.While the present invention realizes the uniformity of heat conductivility, heat dispersion stability, the reliability of product are improved.

Description

The manufacturing process of fin
Technical field
The present invention relates to a kind of manufacturing process of fin, belong to graphite flake technical field.
Background technology
As modern microelectronic technology high-speed develops, electronic equipment(Such as notebook computer, mobile phone, tablet personal computer)Increasingly Become ultra-thin, light, this structure causes electronic equipment internal power density to significantly improve, the heat produced by operation is difficult Discharge, be easy to rapid accumulation and form high temperature.On the other hand, high temperature can reduce the performance of electronic equipment, reliability and use the longevity Life.Therefore, Current electronic industry proposes higher and higher requirement for the heat sink material as heat control system core component, urgently Need a kind of high-efficiency heat conduction, light material to transfer heat away from rapidly, ensure that electronic equipment is normally run.
Kapton is mostly used for flexible PCB in the prior art, although has and is obtained using polyimide film sintered Graphite heat radiation fin, so as to be covered on thermal source, but be constrained to Kapton product quality and performances the good and the bad not Together, the performance of the two-sided pad pasting heat dispersion of radiating has been had influence on, there is following technical problem:Radiating is uneven, adhesive tape easily occurs Hot-spot, the heat dispersion that improves product is unstable, reliability performance is poor, is unfavorable for product quality management control, influences product Competitiveness.
The content of the invention
Objects of the present invention are to provide a kind of manufacturing process of fin, and the fin that the manufacturing process is obtained is vertical Direction and horizontal direction improve heat conductivility, it is to avoid hot-spot, while realizing the uniformity of heat conductivility, improve Heat dispersion stability, the reliability of product, greatly reduces the cost of product.
To achieve the above object of the invention, the technical solution adopted by the present invention is:A kind of manufacturing process of fin, the stone Black fin is obtained by following steps:
Step 1: be respectively coated on the upper and lower surface of Kapton graphite modified dose handled after polyimides it is thin Film, the Kapton after processing is made up of Kapton, the first coat and the second coat;
The graphite modified dose of component by following parts by weight is constituted:
22 parts of benzophenone tetracarboxylic dianhydride,
15 parts of pyromellitic acid anhydride,
20 parts of MDA,
21 parts of dimethylformamide,
8.5 parts of 1-METHYLPYRROLIDONE,
2.2 parts of ethylene glycol,
2.4 parts of dimethyl silicone polymer,
0.8 part of dibutyl phthalate;
Step 2: by the Kapton after processing under inert gas shielding, 240 DEG C ~ 260 DEG C, insulation are risen to from room temperature After rise to 480 DEG C ~ 500 DEG C, 780 DEG C ~ 820 DEG C are warming up to after insulation again, risen to after insulation after 1200 DEG C cool down, so as to obtain pre- The carbonized film of firing;
Step 3: carbonized film is warming up into 2350 DEG C ~ 2450 DEG C, it is incubated, then is warming up to cooling after 2850 DEG C ~ 2950 DEG C, so that Obtain the graphite film of main firing;
Step 4: then the graphite film of the main firing obtained by step 3 is carried out calendering to obtain the heat conduction graphite patch.
Because above-mentioned technical proposal is used, the present invention has following advantages and effect compared with prior art:
1st, graphite linings are coated with one layer graphite modified dose by upper and lower surface in the manufacturing process of fin of the present invention, its structure Kapton is prepared from, and is improved in heat conductivility both vertically and horizontally, it is to avoid adhesive tape hot-spot, real The uniformity of adhesive tape heat conductivility is showed;Next, it is located at graphite modified dose of Kapton surface by benzophenone four Acid dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, ethylene glycol, dimethyl silicone polymer composition, It is coated on Kapton, is filled with the pin hole in heating process, improves crystallinity simultaneously, also overcome thermal contraction It is uneven caused by big, improve graphite linings biaxial tension performance.
2nd, the manufacturing process of fin of the present invention, it is located at graphite modified dose of Kapton surface by benzophenone It is tetracarboxylic dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, 1-METHYLPYRROLIDONE, ethylene glycol, poly- Dimethyl siloxane is constituted, and reduces azeotropic point using dimethylformamide, 1-METHYLPYRROLIDONE and smooth boiling point area, Improve the flatness and pliability of final products film forming;;Secondly, dimethylformamide, 1-METHYLPYRROLIDONE and adjacent benzene two Formic acid dibutyl ester Kapton surface, prevents bubble from producing, and is more beneficial for the small pin hole of filled polyimide film, changes It has been apt to the uniformity of radiating paster heat conductivility.
3rd, the manufacturing process of fin of the present invention, calendaring processes are increased between the carbonized film and graphitization of pre-burned, with And re-form and roll again after heat conduction graphite patch, it is to avoid the volume contraction in fold and graphitization sintering process, improve Compactness and crystallinity, are further increased in heat conductivility both vertically and horizontally.
Embodiment
With reference to embodiment, the invention will be further described:
Embodiment:A kind of manufacturing process of fin, the graphite heat radiation fin is obtained by following steps:
Step 1: be respectively coated on the upper and lower surface of Kapton graphite modified dose handled after polyimides it is thin Film, the Kapton after processing is made up of Kapton, the first coat and the second coat;
The graphite modified dose of component by following parts by weight is constituted:
22 parts of benzophenone tetracarboxylic dianhydride,
15 parts of pyromellitic acid anhydride,
20 parts of MDA,
21 parts of dimethylformamide,
8.5 parts of 1-METHYLPYRROLIDONE,
2.2 parts of ethylene glycol,
2.4 parts of dimethyl silicone polymer,
0.8 part of dibutyl phthalate;
Step 2: by the Kapton after processing under inert gas shielding, 240 DEG C ~ 260 DEG C, insulation are risen to from room temperature After rise to 480 DEG C ~ 500 DEG C, 780 DEG C ~ 820 DEG C are warming up to after insulation again, risen to after insulation after 1200 DEG C cool down, so as to obtain pre- The carbonized film of firing;
Step 3: carbonized film is warming up into 2350 DEG C ~ 2450 DEG C, it is incubated, then is warming up to cooling after 2850 DEG C ~ 2950 DEG C, so that Obtain the graphite film of main firing;
Step 4: then the graphite film of the main firing obtained by step 3 is carried out calendering to obtain the heat conduction graphite patch.
Above-mentioned graphite modified dose of viscosity is 30000 ~ 48000CP.
A kind of manufacturing process of above-mentioned graphite heat radiation fin, comprises the following steps:
Step 1: be respectively coated on the upper and lower surface of Kapton graphite modified dose handled after polyimides it is thin Film, the Kapton after processing is made up of Kapton, the first coat and the second coat, described graphite modified The viscosity of agent is 30000 ~ 48000CP;
The graphite modified dose of component by following parts by weight is constituted:
22 parts of benzophenone tetracarboxylic dianhydride,
15 parts of pyromellitic acid anhydride,
20 parts of MDA,
21 parts of dimethylformamide,
8.5 parts of 1-METHYLPYRROLIDONE,
2.2 parts of ethylene glycol,
2.4 parts of dimethyl silicone polymer,
0.8 part of dibutyl phthalate;
Step 2: by the Kapton after processing under inert gas shielding, 240 DEG C ~ 260 DEG C, insulation are risen to from room temperature After rise to 480 DEG C ~ 500 DEG C, 780 DEG C ~ 820 DEG C are warming up to after insulation again, risen to after insulation after 1200 DEG C cool down, so as to obtain pre- The carbonized film of firing;
Step 3: carbonized film is warming up into 2350 DEG C ~ 2450 DEG C, it is incubated, then is warming up to cooling after 2850 DEG C ~ 2950 DEG C, so that Obtain the graphite film of main firing;
Step 4: then the graphite film of the main firing obtained by step 3 is carried out calendering to obtain the heat conduction graphite patch.
During using above-mentioned manufacturing process, obtain and be coated with for graphite linings in graphite heat radiation fin its structure by upper and lower surface One layer graphite modified dose of Kapton is prepared from, and is improved in heat conductivility both vertically and horizontally, is kept away Exempt from adhesive tape hot-spot, realize the uniformity of adhesive tape heat conductivility;Secondly, its graphite for being located at Kapton surface changes Property agent is by benzophenone tetracarboxylic dianhydride, pyromellitic acid anhydride, MDA, dimethylformamide, ethylene glycol, poly- two Methylsiloxane is constituted, and is coated on Kapton, is filled with the pin hole in heating process, improves crystallinity simultaneously, Also overcome thermal contraction excessive caused uneven, improve graphite linings biaxial tension performance, also reduce azeotropic point and put down Sliding boiling point area, improves the flatness and pliability of final products film forming;Again, there is graphite to change on Kapton surface Property agent, improve graphite linings and heat conduction adhesive layer heat conductivility in two-sided pad pasting, and the pre-burned is rolled using calender Carbonized film, it is to avoid the volume contraction in fold and graphitization sintering process, improves compactness and crystallinity, further improves In heat conductivility both vertically and horizontally.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all according to the present invention The equivalent change or modification that Spirit Essence is made, should all be included within the scope of the present invention.

Claims (1)

1. a kind of manufacturing process of fin, it is characterised in that:The fin is obtained by following steps:
Step 1: be respectively coated on the upper and lower surface of Kapton graphite modified dose handled after polyimides it is thin Film, the Kapton after processing is made up of Kapton, the first coat and the second coat;
The graphite modified dose of component by following parts by weight is constituted:
22 parts of benzophenone tetracarboxylic dianhydride,
15 parts of pyromellitic acid anhydride,
20 parts of MDA,
21 parts of dimethylformamide,
8.5 parts of 1-METHYLPYRROLIDONE,
2.2 parts of ethylene glycol,
2.4 parts of dimethyl silicone polymer,
0.8 part of dibutyl phthalate;
Step 2: by the Kapton after processing under inert gas shielding, 240 DEG C ~ 260 DEG C, insulation are risen to from room temperature After rise to 480 DEG C ~ 500 DEG C, 780 DEG C ~ 820 DEG C are warming up to after insulation again, risen to after insulation after 1200 DEG C cool down, so as to obtain pre- The carbonized film of firing;
Step 3: carbonized film is warming up into 2350 DEG C ~ 2450 DEG C, it is incubated, then is warming up to cooling after 2850 DEG C ~ 2950 DEG C, so that Obtain the graphite film of main firing;
Step 4: then the graphite film of the main firing obtained by step 3 is carried out calendering to obtain the heat conduction graphite patch.
CN201710095575.XA 2014-01-26 2014-01-26 The manufacturing process of fin Pending CN107043255A (en)

Priority Applications (1)

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CN201410036320.2A CN104812204B (en) 2014-01-26 2014-01-26 Manufacturing process for graphite heat radiation fin
CN201710095575.XA CN107043255A (en) 2014-01-26 2014-01-26 The manufacturing process of fin

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Family Applications (11)

Application Number Title Priority Date Filing Date
CN201710665183.2A Pending CN107986789A (en) 2014-01-26 2014-01-26 Smart mobile phone heat dissipation film
CN201710095544.4A Pending CN107043256A (en) 2014-01-26 2014-01-26 Manufacturing process for the paster that radiates
CN201710095543.XA Active CN107043108B (en) 2014-01-26 2014-01-26 Cooling fin manufacturing process for smart phone
CN201710095545.9A Pending CN107043257A (en) 2014-01-26 2014-01-26 Manufacture method for the fin of computer radiator
CN201710095581.5A Pending CN107043258A (en) 2014-01-26 2014-01-26 The manufacture method of notebook computer fin
CN201710665185.1A Pending CN108206164A (en) 2014-01-26 2014-01-26 For the cooling fin of microelectronics heat dissipation
CN201710665184.7A Pending CN108218428A (en) 2014-01-26 2014-01-26 For the manufacturing method of tablet computer soaking patch
CN201710665192.1A Pending CN108646885A (en) 2014-01-26 2014-01-26 Cooling fin for laptop
CN201710665173.9A Pending CN107573072A (en) 2014-01-26 2014-01-26 The production method of high compactness fin
CN201410036320.2A Active CN104812204B (en) 2014-01-26 2014-01-26 Manufacturing process for graphite heat radiation fin
CN201710095575.XA Pending CN107043255A (en) 2014-01-26 2014-01-26 The manufacturing process of fin

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Application Number Title Priority Date Filing Date
CN201710665183.2A Pending CN107986789A (en) 2014-01-26 2014-01-26 Smart mobile phone heat dissipation film
CN201710095544.4A Pending CN107043256A (en) 2014-01-26 2014-01-26 Manufacturing process for the paster that radiates
CN201710095543.XA Active CN107043108B (en) 2014-01-26 2014-01-26 Cooling fin manufacturing process for smart phone
CN201710095545.9A Pending CN107043257A (en) 2014-01-26 2014-01-26 Manufacture method for the fin of computer radiator
CN201710095581.5A Pending CN107043258A (en) 2014-01-26 2014-01-26 The manufacture method of notebook computer fin
CN201710665185.1A Pending CN108206164A (en) 2014-01-26 2014-01-26 For the cooling fin of microelectronics heat dissipation
CN201710665184.7A Pending CN108218428A (en) 2014-01-26 2014-01-26 For the manufacturing method of tablet computer soaking patch
CN201710665192.1A Pending CN108646885A (en) 2014-01-26 2014-01-26 Cooling fin for laptop
CN201710665173.9A Pending CN107573072A (en) 2014-01-26 2014-01-26 The production method of high compactness fin
CN201410036320.2A Active CN104812204B (en) 2014-01-26 2014-01-26 Manufacturing process for graphite heat radiation fin

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CN107551392A (en) * 2017-08-29 2018-01-09 成都三乙医疗科技有限公司 A kind of thermal conducting piece for thermotherapy
WO2022198661A1 (en) * 2021-03-26 2022-09-29 浙江华熔科技有限公司 Ultrathin thermally-conductive graphite film and manufacturing method therefor
CN114714687B (en) * 2022-03-30 2023-09-29 安徽碳华新材料科技有限公司 Preparation method of graphite heat dissipation film without halogen residues

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120141758A1 (en) * 2010-12-07 2012-06-07 E.I. Du Pont De Nemours And Company Filled polyimide films and coverlays comprising such films
CN102560453A (en) * 2012-03-08 2012-07-11 哈尔滨工业大学 Method for preparing carbide film by carbonizing graphene reinforced polyimide resin
CN103045119A (en) * 2012-12-28 2013-04-17 苏州斯迪克新材料科技股份有限公司 Heat-dissipating double-sided adhesive tape with ultrahigh heat conductivity coefficient
CN103144387A (en) * 2007-05-17 2013-06-12 株式会社钟化 Graphite film and graphite composite film

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9814835D0 (en) * 1998-07-08 1998-09-09 Europ Org For Nuclear Research A thermal management board
AU2003261889A1 (en) * 2003-09-02 2005-03-29 Kaneka Corporation Filmy graphite and process for producing the same
JP2005119887A (en) * 2003-10-14 2005-05-12 Matsushita Electric Ind Co Ltd High thermal conductivity member, its producing method, and heat dissipation system using the member
JP5069860B2 (en) * 2006-01-31 2012-11-07 株式会社カネカ Graphite film
JP5707039B2 (en) * 2007-06-07 2015-04-22 株式会社カネカ Graphite composite film
JP2010003981A (en) * 2008-06-23 2010-01-07 Kaneka Corp Heat-conducting sheet with graphite oriented in thickness direction
TWI405667B (en) * 2010-12-15 2013-08-21 Ind Tech Res Inst Polyimide film laminate and metal laminate employing the same
CN103415467B (en) * 2011-03-28 2015-04-22 株式会社钟化 Process for producing graphite film
CN102757736A (en) * 2011-04-29 2012-10-31 苏州沛德导热材料有限公司 Graphite heat conducting adhesive tape and production process thereof
WO2013008437A1 (en) * 2011-07-08 2013-01-17 三井化学株式会社 Polyimide resin composition and laminate including same
TWM446318U (en) * 2012-08-09 2013-02-01 Hugetemp Energy Ltd Material stacked structure of flexible graphite paper
CN103043657B (en) * 2012-12-28 2014-10-15 苏州斯迪克新材料科技股份有限公司 Graphite radiation fin for adhesive tapes
CN103059761B (en) * 2012-12-28 2014-09-03 斯迪克新型材料(江苏)有限公司 High-heat conductivity coefficient graphite heat-radiation adhesive tape

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103144387A (en) * 2007-05-17 2013-06-12 株式会社钟化 Graphite film and graphite composite film
US20120141758A1 (en) * 2010-12-07 2012-06-07 E.I. Du Pont De Nemours And Company Filled polyimide films and coverlays comprising such films
CN102560453A (en) * 2012-03-08 2012-07-11 哈尔滨工业大学 Method for preparing carbide film by carbonizing graphene reinforced polyimide resin
CN103045119A (en) * 2012-12-28 2013-04-17 苏州斯迪克新材料科技股份有限公司 Heat-dissipating double-sided adhesive tape with ultrahigh heat conductivity coefficient

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CN107043258A (en) 2017-08-15
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Application publication date: 20170815