CN107034729A - 一种阳离子松香施胶剂 - Google Patents

一种阳离子松香施胶剂 Download PDF

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Publication number
CN107034729A
CN107034729A CN201710095913.XA CN201710095913A CN107034729A CN 107034729 A CN107034729 A CN 107034729A CN 201710095913 A CN201710095913 A CN 201710095913A CN 107034729 A CN107034729 A CN 107034729A
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parts
rosin
cation colophony
styrene
pocl3
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朱红兵
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Zhenjiang Tianyi Chemical Industry Research And Design Institute Co Ltd
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Zhenjiang Tianyi Chemical Industry Research And Design Institute Co Ltd
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62—Rosin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

本发明公开了一种造纸用施胶剂，具体地说是一种阳离子松香施胶剂。它包括以下重量份的原料组成：松香120～150份、苯乙烯15～20份、丁基苯乙烯5～10份、丙烯酸丁酯6～9份、三氯氧磷7～9份、二甲基硅25～35份、聚乙二醇12～15份、丙烯酰胺4～7份。采用上述的方法后，由于采用了合理的选用各种配方并限定了配方比例，各种成分之间混合后不会产生任何有害物质，因此使其环保安全，保证了人体的健康，另外，其合理的配方使得稳定性能得到大幅度提高，延长了保质期。

Description

一种阳离子松香施胶剂
技术领域
本发明涉及一种造纸用施胶剂，具体地说是一种阳离子松香施胶剂。
背景技术
施胶剂是一种造纸的添加剂，主要分为浆内施胶和表面施胶，在纸上施胶可提高纸张抗水、抗油、抗印刷油墨等性能，同时可提高光滑性、憎水性、印刷适应性，从而提高纸的平滑度、强度和使用期，其中松香施胶剂属于造纸助剂浆内施胶剂的一种，由于松香施胶剂具有优越的特性，因此广泛被使用，现有技术中常见的松香施胶剂种类繁多，但是由于配方不合理，现有的松香施胶剂不但存在容易污染环境，危害人体健康问题，还存在稳定性能较差、保质期过短的缺陷。
发明内容
本发明要解决的技术问题是提供一种安全环保、稳定性好且保质期长的阳离子松香施胶剂。
为了解决上述技术问题，本发明的阳离子松香施胶剂，包括以下重量份的原料组成：松香120～150份、苯乙烯15～20份、丁基苯乙烯5～10份、丙烯酸丁酯6～9份、三氯氧磷7～9份、二甲基硅25～35份、聚乙二醇12～15份、丙烯酰胺4～7份。
上述的阳离子松香施胶剂，包括以下重量份的原料组成：松香135份、苯乙烯17份、丁基苯乙烯7份、丙烯酸丁酯8份、三氯氧磷8份、二甲基硅30份、聚乙二醇13份、丙烯酰胺6份。
所述松香包括松香、松香甘油酯。
采用上述的方法后，由于采用了合理的选用各种配方并限定了配方比例，各种成分之间混合后不会产生任何有害物质，因此使其环保安全，保证了人体的健康，另外，其合理的配方使得稳定性能得到大幅度提高，延长了保质期。
具体实施方式
下面结合具体实施方式，对本发明的阳离子松香施胶剂作进一步详细说明。
实施例一：
本发明的阳离子松香施胶剂，包括以下重量份的原料组成：松香120份、苯乙烯15份、丁基苯乙烯5份、丙烯酸丁酯6份、三氯氧磷7份、二甲基硅25份、聚乙二醇12份、丙烯酰胺4份。
实施例二：
本发明的阳离子松香施胶剂，包括以下重量份的原料组成：松香甘油酯135份、苯乙烯17份、丁基苯乙烯7份、丙烯酸丁酯8份、三氯氧磷8份、二甲基硅30份、聚乙二醇13份、丙烯酰胺6份。
实施例三：
本发明的阳离子松香施胶剂，包括以下重量份的原料组成：松香和松香甘油酯150份、苯乙烯20份、丁基苯乙烯10份、丙烯酸丁酯9份、三氯氧磷9份、二甲基硅35份、聚乙二醇15份、丙烯酰胺7份。

Claims (3)

1.一种阳离子松香施胶剂，包括以下重量份的原料组成：松香120～150份、苯乙烯15～20份、丁基苯乙烯5～10份、丙烯酸丁酯6～9份、三氯氧磷7～9份、二甲基硅25～35份、聚乙二醇12～15份、丙烯酰胺4～7份。
2.按照权利要求1所述的阳离子松香施胶剂，包括以下重量份的原料组成：松香135份、苯乙烯17份、丁基苯乙烯7份、丙烯酸丁酯8份、三氯氧磷8份、二甲基硅30份、聚乙二醇13份、丙烯酰胺6份。
3.按照权利要求1或2所述的阳离子松香施胶剂，其特征在于：所述松香包括松香、松香甘油酯。
CN201710095913.XA 2017-02-22 2017-02-22 一种阳离子松香施胶剂 Pending CN107034729A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1692976A (zh) * 2005-05-23 2005-11-09 山东轻工业学院 一种阳离子分散松香胶
CN101649580A (zh) * 2009-09-01 2010-02-17 陕西科技大学 一种阳离子松香/akd中性施胶剂的制备方法
CN102268115A (zh) * 2010-06-02 2011-12-07 武汉强力荷新材料有限公司 免加热法生产聚合物乳液

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1692976A (zh) * 2005-05-23 2005-11-09 山东轻工业学院 一种阳离子分散松香胶
CN101649580A (zh) * 2009-09-01 2010-02-17 陕西科技大学 一种阳离子松香/akd中性施胶剂的制备方法
CN102268115A (zh) * 2010-06-02 2011-12-07 武汉强力荷新材料有限公司 免加热法生产聚合物乳液

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