CN107033753A - A kind of safety cap protection paint vehicle and preparation method thereof - Google Patents

A kind of safety cap protection paint vehicle and preparation method thereof Download PDF

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Publication number
CN107033753A
CN107033753A CN201710303992.9A CN201710303992A CN107033753A CN 107033753 A CN107033753 A CN 107033753A CN 201710303992 A CN201710303992 A CN 201710303992A CN 107033753 A CN107033753 A CN 107033753A
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Prior art keywords
parts
paint vehicle
aqueous
added
safety cap
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CN201710303992.9A
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Chinese (zh)
Inventor
邰文思
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Funan County Wei Tai Shiyu Sports Equipment Co Ltd
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Funan County Wei Tai Shiyu Sports Equipment Co Ltd
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Priority to CN201710303992.9A priority Critical patent/CN107033753A/en
Publication of CN107033753A publication Critical patent/CN107033753A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • C09D7/44Combinations of two or more thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/325Calcium, strontium or barium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of safety cap protection paint vehicle and preparation method thereof, is related to paint vehicle technical field, is prepared from the following components, aqueous saturated polyester resin, ammonia nertralizer, milky white adhesive, beeswax, defoamer, thickener, petroleum coke powder, aqueous white slurry, deionized water;Thickener includes hydroxylmethyl cellulose, bentonite, apatite, sepiolite powder and cornstarch by weight.1) 24 25 parts of aqueous saturated polyester resins are added into container, be then stirred with high speed dispersor, ammonia nertralizer is progressively added dropwise while stirring;2) the whole millings of solid material are handled, then all solid materials is added in container and are sufficiently mixed carry out emulsification treatment;3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 10 15 minutes, test pH value is made paint vehicle between 7.5 8.5.Environmental Safety of the present invention, pollution-free, hardness is high, be not easy to scratch, and is easy to production, and service life is long.

Description

A kind of safety cap protection paint vehicle and preparation method thereof
Technical field:
The present invention relates to paint vehicle technical field, and in particular to a kind of safety cap protection paint vehicle and preparation method thereof.
Background technology:
In recent years, environment for human survival is increasingly severe, and atmosphere pollution is also on the rise.With the earth be faced with it is more and more tighter High atmosphere pollution, control of the Overseas Government to paint vehicle product Volatile organic emissions is also increasingly strict.China is locomotory apparatus Material big producer, the requirement of particularly safety cap protective paint is very high, still, and presently commercially available paint vehicle volatility is stronger, taste compared with Greatly, indices are unsatisfactory for the relevant laws and regulations of American-European countries, also do not meet the current development prospect of China.
The content of the invention:
The technical problems to be solved by the invention are to overcome existing technological deficiency that there is provided a kind of Environmental Safety, no dirt Dye, hardness height, the safety cap for being not easy to scratch protect paint vehicle and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of safety cap protects paint vehicle, it is characterised in that:It is prepared from by the component of following parts by weight meter:30~40 parts of water Property saturated polyester resin, 1~2 part of ammonia nertralizer, 4~5 parts of milky white adhesives, 0.2~0.4 part of beeswax, 0.2~0.3 part of defoamer, 0.3~0.4 part of thickener, 0.1~0.2 part of petroleum coke powder, 40~50 parts of aqueous white slurries, 18~25 parts of deionized waters;It is described Thickener by weight include 6-8 parts of hydroxylmethyl cellulose, 2~4 parts of bentonite, 3~4 parts of apatite, 3~4 parts of sepiolite powder With 1~2 part of cornstarch.
A kind of safety cap protects the preparation method of paint vehicle, it is characterised in that:
1) 24-25 parts of aqueous saturated polyester resins are added into container, be then stirred with high speed dispersor, while stirring Ammonia nertralizer is progressively added dropwise, after mixing speed is 500r/min-900r/min, 3-5min, test mixing liquid pH value is in 7.5- Between 8.5, stop stirring, carry out next step operation;
2) the whole millings of solid material are handled, then all solid materials is added progress breast is sufficiently mixed in container Change is handled, 60 DEG C of emulsifying temperature during emulsification, emulsification stirring speed 2000r/min, emulsification times 15min;
3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 10-15 points Clock, test pH value is made paint vehicle between 7.5-8.5.
The aqueous white slurry is to be prepared from according to the following steps:
1) titanium dioxide, dispersant, defoamer, cosolvent, deionized water, ammonia nertralizer are mixed by proportioning, mixed Liquid;
2) mixed liquor is stirred into mixing under high speed dispersion agent, mixing speed is 1000r/min-1500r/min, during stirring Between 0.3-0.7h, obtain stir liquid;
3) stirring liquid is inserted in horizontal sand mill, bead mill is handled 3-5 times, aqueous white slurry is made.
Described defoamer includes wooden 2~4 parts of triethanolamine, 2~4 parts of triisopropanolamine and ethylene glycol 3~7 by weight Part.
The ammonia nertralizer is formic acid or acetic acid.
Described defoamer by weight include 2~4 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, have 1-3 parts of silicone emulsion and 2~4 parts of high-carbon polyol fatty acid.
Viscosity foot of the invention, intensity is high, and rate of drying is fast, it is not easy to drop.The defoamer of the present invention not only has efficient Froth breaking effect, improve the uniformity, and play paint vehicle rapid draing and meanwhile strengthen paint vehicle dry after intensity and hardness purpose, Thickener in the present invention can also strengthen paint vehicle bond and the intensity of itself, be encounter hard object also will not be broken It is rotten.The preparation method of the present invention makes by milling, emulsification and under specific temperature, time, and paint vehicle fineness, the uniformity are high, Be conducive to improving the performance of product.
1st, aqueous paint vehicle economy of the invention, durable, especially this aqueous paint vehicle uses water as solvent and decentralized medium, It is diluted with water and can be used, almost pollution-free to air, it is to avoid the poisonous and harmful property of organic solvent, environmental protection, energy-conservation is strong Health;
2nd, aqueous paint vehicle of the invention is by the use of aqueous saturated polyester resin as matrix resin, the paint film have hardness height, The advantages of flexible, impact resistance, UV resistant;Aqueous white slurry in aqueous paint vehicle can be used for the paint for preparing different colours Material, the paint vehicle gloss made is bright-coloured, and service life is long;
3rd, the preparation method step of paint vehicle of the invention is simple, short the time required to preparation process, is given birth to beneficial to large-scale industry Production, application, and the aqueous paint vehicle environmental protection that the preparation method is prepared, can promote the steady of China's sports equipment industry Step, sound development, strengthen the competitiveness of China's sports equipment.
The beneficial effects of the invention are as follows:Environmental Safety of the present invention, pollution-free, hardness is high, be not easy to scratch, and is easy to life Production, service life is long.
Embodiment:
In order that technological means, creation new feature, reached purpose and effect that the present invention is realized are easy to understand, below With reference to instantiation, the present invention is expanded on further.
Embodiment 1
A kind of safety cap protects paint vehicle, is prepared from by the component of following parts by weight meter:30 parts of aqueous saturated polyester resins, 1 part of ammonia nertralizer, 4 parts of milky white adhesives, 0.2 part of beeswax, 0.2 part of defoamer, 0.3 part of thickener, 0.1 part of petroleum coke powder, 40 parts of water Property stock white, 18 parts of deionized waters;Thickener includes 6 parts of hydroxylmethyl cellulose, 2 parts of bentonite, 3 parts of apatite, sea by weight 1 part of 3 parts of afrodite powder and cornstarch.
A kind of safety cap protects the preparation method of paint vehicle
1) aqueous saturated polyester resin is added into container, is then stirred, progressively dripped while stirring with high speed dispersor Ammonification nertralizer, after mixing speed is 500r/min, 3min, test mixing liquid pH value stops stirring between 7.5, carries out Next step is operated;
2) the whole millings of solid material are handled, then all solid materials is added progress breast is sufficiently mixed in container Change is handled, 60 DEG C of emulsifying temperature during emulsification, emulsification stirring speed 2000r/min, emulsification times 15min;
3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 10 minutes, surveys PH value is tried between 7.5, that is, paint vehicle is made.
Aqueous white slurry is to be prepared from according to the following steps:
1) titanium dioxide, dispersant, defoamer, cosolvent, deionized water, ammonia nertralizer are mixed by proportioning, mixed Liquid;
2) mixed liquor is stirred into mixing under high speed dispersion agent, mixing speed is 1000r/min, mixing time 0.3h, is obtained To stirring liquid;
3) stirring liquid is inserted in horizontal sand mill, bead mill is handled 3 times, aqueous white slurry is made.
Defoamer includes 3 parts of wooden 2 parts of triethanolamine, 2 parts of triisopropanolamine and ethylene glycol by weight.
Ammonia nertralizer is formic acid.
Defoamer includes 2 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, has 1 part of silicone emulsion and high-carbon polyol fatty acid by weight 2 parts.
Embodiment two
A kind of safety cap protects paint vehicle, is prepared from by the component of following parts by weight meter:35 parts of aqueous saturated polyester resins, 1.5 parts of ammonia nertralizers, 4.5 parts of milky white adhesives, 0.3 part of beeswax, 0.25 part of defoamer, 0.35 part of thickener, 0.15 part of petroleum coke powder, 45 parts of aqueous white slurries, 21 parts of deionized waters;Thickener includes 7 parts of hydroxylmethyl cellulose, 3 parts of bentonite, apatite by weight 1.5 parts of 3.5 parts, 3.5 parts of sepiolite powder and cornstarch.
A kind of safety cap protects the preparation method of paint vehicle,
1) aqueous saturated polyester resin is added into container, is then stirred, progressively dripped while stirring with high speed dispersor Ammonification nertralizer, after mixing speed is 700r/min, 4min, test mixing liquid pH value stops stirring, under progress between 8 Single stepping;
2) the whole millings of solid material are handled, then all solid materials is added progress breast is sufficiently mixed in container Change is handled, 60 DEG C of emulsifying temperature during emulsification, emulsification stirring speed 2000r/min, emulsification times 15min;
3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 13 minutes, surveys PH value is tried between 8, that is, paint vehicle is made.
Aqueous white slurry is to be prepared from according to the following steps:
1) titanium dioxide, dispersant, defoamer, cosolvent, deionized water, ammonia nertralizer are mixed by proportioning, mixed Liquid;
2) mixed liquor is stirred into mixing under high speed dispersion agent, mixing speed is 1250r/min, mixing time 0.5h, is obtained To stirring liquid;
3) stirring liquid is inserted in horizontal sand mill, bead mill is handled 4 times, aqueous white slurry is made.
Defoamer includes 5 parts of wooden 3 parts of triethanolamine, 3 parts of triisopropanolamine and ethylene glycol by weight.
Ammonia nertralizer is acetic acid.
Defoamer includes 3 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, has 2 parts of silicone emulsion and high-carbon polyol fatty acid by weight 3 parts.
Embodiment 3
A kind of safety cap protects paint vehicle, is prepared from by the component of following parts by weight meter:40 parts of aqueous saturated polyester resins, 2 parts of ammonia nertralizers, 5 parts of milky white adhesives, 0.4 part of beeswax, 0.3 part of defoamer, 0.4 part of thickener, 0.2 part of petroleum coke powder, 50 parts of water Property stock white, 25 parts of deionized waters;Thickener includes 8 parts of hydroxylmethyl cellulose, 4 parts of bentonite, 4 parts of apatite, sea by weight 2 parts of 4 parts of afrodite powder and cornstarch.
A kind of safety cap protects the preparation method of paint vehicle,
1) 25 parts of aqueous saturated polyester resins are added into containers, are then stirred with high speed dispersor, while stirring by Ammonia nertralizer is added dropwise in step, after mixing speed is 900r/min, 5min, and test mixing liquid pH value stops stirring between 8.5, Carry out next step operation;
2) the whole millings of solid material are handled, then all solid materials is added progress breast is sufficiently mixed in container Change is handled, 60 DEG C of emulsifying temperature during emulsification, emulsification stirring speed 2000r/min, emulsification times 15min;
3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 15 minutes, surveys PH value is tried between 8.5, that is, paint vehicle is made.
Aqueous white slurry is to be prepared from according to the following steps:
1) titanium dioxide, dispersant, defoamer, cosolvent, deionized water, ammonia nertralizer are mixed by proportioning, mixed Liquid;
2) mixed liquor is stirred into mixing under high speed dispersion agent, mixing speed is 1500r/min, mixing time 0.3- 0.7h, obtains stirring liquid;
3) stirring liquid is inserted in horizontal sand mill, bead mill is handled 5 times, aqueous white slurry is made.
Defoamer includes 7 parts of wooden 4 parts of triethanolamine, 4 parts of triisopropanolamine and ethylene glycol by weight.
Ammonia nertralizer is formic acid or acetic acid.
Defoamer includes 4 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, has 3 parts of silicone emulsion and high-carbon polyol fatty acid by weight 4 parts.
Experimental data is obtained to embodiments of the invention progress experiment detection as shown in the table:
Inspection content Embodiment 1 Embodiment 2 Embodiment 3
Amount of solid content (%) 68 72 65
Paint vehicle viscosity (s) 149 150 152
PH value 7.9 7.8 7.8
Coating dry film thickness (μm) 25 26 23
Fineness (μm) 18 20 19
Surface gloss 91 95 89
Aberration 0.3 0.2 0.4
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of safety cap protects paint vehicle, it is characterised in that:It is prepared from by the component of following parts by weight meter:30~40 parts aqueous Saturated polyester resin, 1~2 part of ammonia nertralizer, 4~5 parts of milky white adhesives, 0.2~0.4 part of beeswax, 0.2~0.3 part of defoamer, 0.3 ~0.4 part of thickener, 0.1~0.2 part of petroleum coke powder, 40~50 parts of aqueous white slurries, 18~25 parts of deionized waters;Described increasing Thick dose includes 6-8 parts of hydroxylmethyl cellulose, 2~4 parts of bentonite, 3~4 parts of apatite, 3~4 parts of sepiolite powder and jade by weight 1~2 part of rice starch.
2. a kind of safety cap protection paint vehicle according to claim 1, it is characterised in that:
1) aqueous saturated polyester resin is added into container, is then stirred with high speed dispersor, ammonia is progressively added dropwise while stirring Nertralizer, after mixing speed is 500r/min-900r/min, 3-5min, test mixing liquid pH value stops between 7.5-8.5 Only stir, carry out next step operation;
2) the whole millings of solid material are handled, then all solid materials is added and are sufficiently mixed in container at progress emulsification Reason, 60 DEG C of emulsifying temperature during emulsification, emulsification stirring speed 2000r/min, emulsification times 15min;
3) aqueous white slurry and milky white adhesive are added into container again, deionized water is eventually adding, continues scattered 10-15 minutes, surveys PH value is tried between 7.5-8.5, that is, paint vehicle is made.
3. a kind of paint vehicle for sports equipment according to claim 1, it is characterised in that the aqueous white slurry be by Following steps are prepared from:
1) titanium dioxide, dispersant, defoamer, cosolvent, deionized water, ammonia nertralizer are mixed by proportioning, obtains mixed liquor;
2) mixed liquor is stirred into mixing under high speed dispersion agent, mixing speed is 1000r/min-1500r/min, mixing time 0.3-0.7h, obtains stirring liquid;
3) stirring liquid is inserted in horizontal sand mill, bead mill is handled 3-5 times, aqueous white slurry is made.
4. a kind of safety cap protection paint vehicle according to claim 1, it is characterised in that:Described defoamer is wrapped by weight Include 3~7 parts of wooden 2~4 parts of triethanolamine, 2~4 parts of triisopropanolamine and ethylene glycol.
5. a kind of safety cap protection paint vehicle according to claim 1, it is characterised in that:The ammonia nertralizer be formic acid or Acetic acid.
6. a kind of safety cap protection paint vehicle according to claim 1, it is characterised in that:Described defoamer is wrapped by weight Include 2~4 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether, have 2~4 parts of 1-3 parts of silicone emulsion and high-carbon polyol fatty acid.
CN201710303992.9A 2017-05-03 2017-05-03 A kind of safety cap protection paint vehicle and preparation method thereof Pending CN107033753A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107325696A (en) * 2017-08-22 2017-11-07 安徽杰可森木业科技有限公司 A kind of poplar pencil protection paint vehicle and preparation method thereof
CN107495525A (en) * 2017-09-06 2017-12-22 阜南县邰氏宇崴运动器材有限公司 A kind of children's skidding crash helmet
CN107518489A (en) * 2017-09-06 2017-12-29 阜南县邰氏宇崴运动器材有限公司 A kind of skidding permeable helmet

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04120183A (en) * 1990-09-07 1992-04-21 Shimadzu Corp Coating composition
CN102952436A (en) * 2012-11-29 2013-03-06 益阳祥瑞科技有限公司 Water-based white fluorocarbon coating
CN105907269A (en) * 2016-05-26 2016-08-31 广州产协高分子有限公司 Water-based coating for sports equipment and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04120183A (en) * 1990-09-07 1992-04-21 Shimadzu Corp Coating composition
CN102952436A (en) * 2012-11-29 2013-03-06 益阳祥瑞科技有限公司 Water-based white fluorocarbon coating
CN105907269A (en) * 2016-05-26 2016-08-31 广州产协高分子有限公司 Water-based coating for sports equipment and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107325696A (en) * 2017-08-22 2017-11-07 安徽杰可森木业科技有限公司 A kind of poplar pencil protection paint vehicle and preparation method thereof
CN107495525A (en) * 2017-09-06 2017-12-22 阜南县邰氏宇崴运动器材有限公司 A kind of children's skidding crash helmet
CN107518489A (en) * 2017-09-06 2017-12-29 阜南县邰氏宇崴运动器材有限公司 A kind of skidding permeable helmet

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Application publication date: 20170811