CN106966635A - A kind of acrylic diamond of strong hardness - Google Patents
A kind of acrylic diamond of strong hardness Download PDFInfo
- Publication number
- CN106966635A CN106966635A CN201710293226.9A CN201710293226A CN106966635A CN 106966635 A CN106966635 A CN 106966635A CN 201710293226 A CN201710293226 A CN 201710293226A CN 106966635 A CN106966635 A CN 106966635A
- Authority
- CN
- China
- Prior art keywords
- acrylic
- strong hardness
- diamond
- styrene
- acrylic diamond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
Abstract
The acrylic diamond of a kind of strong hardness, by weight including following components：Acryl resin monomer 10 30%；Thickener 0.25 1%；Curing agent 0.001 0.1%；Unsaturated-resin 0.1 2%；Inorganic filler is to 100%, and the acryl resin monomer is made up of the mixture of styrene-acrylonitrile and polymethyl methacrylate, and wherein the percentage by weight of styrene-acrylonitrile and polymethyl methacrylate is 2：3.
Description
Technical field
The present invention relates to acrylic diamond of specifically related to a kind of strong hardness and preparation method thereof.
Background technology
Molding acrylic diamond is prepared by the way that inorganic filler such as aluminium hydroxide is mixed into acrylic resinoid, this sub- gram
Power diamond has various excellent a functions and performance, such as outward appearance, soft feel, but be due to acrylic resinoid in itself
Characteristic causes the intensity of product and heat resistance to there is certain defect.
The content of the invention
In order to solve the above problems, the invention provides a kind of acrylic diamond of strong hardness：
The acrylic diamond of a kind of strong hardness, by weight including following components：Acryl resin monomer 10-30%, thickener
0.25-1%, curing agent 0.001-0.1%, unsaturated-resin 0.1-2%, inorganic filler to 100%, the acryl resin monomer by
The mixture of styrene-acrylonitrile and polymethyl methacrylate is constituted, wherein styrene-acrylonitrile and polymethyl methacrylate
Percentage by weight be 2：3.
It is preferred that, the thickener is methyl methacrylate, butadiene, the terpolymer of styrene.
It is preferred that, the inorganic filler is one kind in aluminium hydroxide, silica, calcium carbonate, talcum powder or its mixing
Thing.
It is preferred that, described curing agent is one kind in organic peroxide, azo-compound.
It is preferred that, in addition to the one or more in reinforcing agent, colouring agent, shrinking agent.
A kind of preparation method of the acrylic diamond of strong hardness, step is as follows：Unsaturated-resin, Ya Ke are added in kneader
Power resin monomer, inorganic filler, curing agent, thickener, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, by sub- gram
Power moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 200-500MPa pressure, and acrylic diamond is made.
The present invention has the advantages that：Its transparency is had no while this product substantially increases its impact flexibility
Considerable influence, from regardless of whether sight outside is still all more nearly real diamond, and the process made in its performance
Simply, it is particularly suitable for industrialized production.
Embodiment
Embodiment 1：The acrylic diamond of a kind of strong hardness, by weight including following components：
Acryl resin monomer 10；
Thickener 0.25%（Methyl methacrylate, butadiene, the terpolymer of styrene）；
Curing agent 0.001%（Organic peroxide）；
Unsaturated-resin 0.1%；
Inorganic filler is to 100%（The mixture of aluminium hydroxide, silica）,
The acryl resin monomer is made up of the mixture of styrene-acrylonitrile and polymethyl methacrylate, wherein styrene
The percentage by weight of acrylonitrile and polymethyl methacrylate is 2：3.
Embodiment 2：The acrylic diamond of a kind of strong hardness, by weight including following components：
Acryl resin monomer 20%；
Thickener 0.5%（Methyl methacrylate, butadiene, the terpolymer of styrene）；
Curing agent 0.05%（Organic peroxide）；
Unsaturated-resin 1%；
Inorganic filler is to 100%（The mixture of aluminium hydroxide, talcum powder）,
The acryl resin monomer is made up of the mixture of styrene-acrylonitrile and polymethyl methacrylate, wherein styrene
The percentage by weight of acrylonitrile and polymethyl methacrylate is 2：3.
Embodiment 3：The acrylic diamond of a kind of strong hardness, by weight including following components：
Acryl resin monomer 30%；
Thickener 1%（Methyl methacrylate, butadiene, the terpolymer of styrene）；
Curing agent 0.1%（Organic peroxide）；
Unsaturated-resin 2%；
Inorganic filler is to 100%（The mixture of aluminium hydroxide, calcium carbonate）,
The acryl resin monomer is made up of the mixture of styrene-acrylonitrile and polymethyl methacrylate, wherein styrene
The percentage by weight of acrylonitrile and polymethyl methacrylate is 2：3.
A kind of preparation method of the acrylic diamond of strong hardness, step is as follows：Unsaturated-resin, Ya Ke are added in kneader
Power resin monomer, inorganic filler, curing agent, thickener, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, by sub- gram
Power moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 200-500MPa pressure, and acrylic diamond is made.
Considerable influence is had no to its transparency while this product substantially increases its impact flexibility, from regardless of whether seeing outside
Or real diamond is all more nearly in its performance, and the process made is simple, is particularly suitable for industrialized production.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, it can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The obvious changes or variations that the connotation of invention is amplified out still falls within protection scope of the present invention.
Claims (6)
1. the acrylic diamond of a kind of strong hardness, by weight including following components：
Acryl resin monomer 10-30%；
Thickener 0.25-1%；
Curing agent 0.001-0.1%；
Unsaturated-resin 0.1-2%；
Inorganic filler is to 100%；
The acryl resin monomer is made up of the mixture of styrene-acrylonitrile and polymethyl methacrylate, wherein styrene
The percentage by weight of acrylonitrile and polymethyl methacrylate is 2：3.
2. a kind of acrylic diamond of strong hardness according to claim 1, it is characterised in that：The thickener is methyl-prop
E pioic acid methyl ester, butadiene, the terpolymer of styrene.
3. a kind of acrylic diamond of strong hardness according to claim 1, it is characterised in that：The inorganic filler is hydrogen-oxygen
Change aluminium, silica, calcium carbonate, one kind in talcum powder or its mixture.
4. a kind of acrylic diamond of strong hardness according to claim 1, it is characterised in that：Described curing agent is organic
One kind in peroxide, azo-compound.
5. a kind of acrylic diamond of strong hardness according to claim 1, it is characterised in that：Also include reinforcing agent, coloring
One or more in agent, shrinking agent.
6. a kind of preparation method of the acrylic diamond of strong hardness according to claim 1-5, it is characterised in that：Step is such as
Under：Unsaturated-resin, acryl resin monomer, inorganic filler, curing agent, thickener are added in kneader, above-mentioned raw materials are pinched
Close and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould, in 100-145 degrees Celsius, 200-
Solidify under 500MPa pressure, acrylic diamond is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710293226.9A CN106966635A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of strong hardness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710293226.9A CN106966635A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of strong hardness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106966635A true CN106966635A (en) | 2017-07-21 |
Family
ID=59330217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710293226.9A Pending CN106966635A (en) | 2017-04-28 | 2017-04-28 | A kind of acrylic diamond of strong hardness |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106966635A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06155679A (en) * | 1992-11-24 | 1994-06-03 | Matsushita Electric Works Ltd | Artificial marble molding |
| JPH09295845A (en) * | 1996-05-02 | 1997-11-18 | Toagosei Co Ltd | Artificial marble |
| CN101514280A (en) * | 2008-12-31 | 2009-08-26 | 上海新天和树脂有限公司 | Method for preparing an acrylic material adhesive resin |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
-
2017
- 2017-04-28 CN CN201710293226.9A patent/CN106966635A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06155679A (en) * | 1992-11-24 | 1994-06-03 | Matsushita Electric Works Ltd | Artificial marble molding |
| JPH09295845A (en) * | 1996-05-02 | 1997-11-18 | Toagosei Co Ltd | Artificial marble |
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN101514280A (en) * | 2008-12-31 | 2009-08-26 | 上海新天和树脂有限公司 | Method for preparing an acrylic material adhesive resin |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
| CN103553430A (en) * | 2013-11-06 | 2014-02-05 | 江门市德山复合材料科技有限公司 | Artificial acrylic quartz stone slab and preparation method thereof |
| CN103553430B (en) * | 2013-11-06 | 2016-06-15 | 江门市德山复合材料科技有限公司 | A kind of Artificial acrylic quartz stone slab and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 周殿明: "《塑料制品成型材料》", 31 October 2011, 机械工业出版社 * |
| 罗河胜: "《塑料加工手册（第三版）》", 31 March 2010, 广东科技出版社 * |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170721 |