CN106947401A - High strength non-woven fabric adhesive tape and preparation method thereof - Google Patents
High strength non-woven fabric adhesive tape and preparation method thereof Download PDFInfo
- Publication number
- CN106947401A CN106947401A CN201710207762.2A CN201710207762A CN106947401A CN 106947401 A CN106947401 A CN 106947401A CN 201710207762 A CN201710207762 A CN 201710207762A CN 106947401 A CN106947401 A CN 106947401A
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- CN
- China
- Prior art keywords
- parts
- woven fabric
- adhesive tape
- high strength
- fabric adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of high strength non-woven fabric adhesive tape and preparation method thereof, it is made up of the raw material of following mass parts：40 ~ 60 parts of butadiene, 20 ~ 30 parts of styrene, 10 ~ 20 parts of polyester fiber, 10 ~ 30 parts of butyl acrylate, 10 ~ 20 parts of acrylic acid, 0.1 ~ 0.8 part of dibutyl phthalate, 2 ~ 8 parts of benzoyl peroxide, 5 ~ 10 parts of rosin, 1 ~ 10 part of carboxylic acid, 2 ~ 6 parts of emulsifying agent, 0.1 ~ 1 part of dispersant, 0.05 ~ 0.15 part of stabilizer, 1 ~ 5 part of reinforcing agent, 100 parts of water.Non-woven fabric glue milkiness of the present invention can be stablized, adhesion strength is strong, thermal stability of latex is good, 24 hours its colors that flowed back at 50 DEG C are constant, do not produce gel, and freeze-thaw stability is high, melt after being freezed 50 days at 20 DEG C, its color is constant, does not produce gel, can meet the requirement of Various Seasonal production, storage and transport.Preparation method is simple, high with Non-woven tape tensile strength made from the latex and extension at break degree, does not ftracture.
Description
Technical field
The invention belongs to Non-woven tape technical field, and in particular to a kind of high strength non-woven fabric adhesive tape and its preparation side
Method.
Background technology
Latex and other auxiliary materials are added in fiber, the solid and Non-woven tape of high resilience can be obtained.Mesh
The species of Non-woven tape is up to kind more than 500, generally daily living article and medical supplies on former world, and it is positive " with
Abandon " direction develop, therefore, measured the need for non-woven fabrics latex increasing.Non-woven tape has lot of advantages, for example：
Venting capability is strong;Possess strainability;There is heat insulating ability;Water imbibition is strong;Aqueous energy is strong;With retractility;It is not fluffy and disorderly when using;Nothing
Spin cloth rubber belt good hand touch, softness;Body weight is very slim and graceful;Non-woven tape is flexible, resilient;Non-woven tape does not have the side of cloth
Tropism;Non-woven tape price is low, can largely produce.Current Non-woven tape also has the following disadvantages：With weave cloth compared with it
Intensity and durability it is poor;Non-woven tape can not be cleaned as other clothes;Its fiber is entered according to certain orientation
Row arrangement, so easily split from right angle orientation etc..Therefore it is current to prepare high strength non-woven fabric adhesive tape not easy to crack
The focus of research.
The content of the invention
The present invention provides a kind of high strength non-woven fabric adhesive tape and preparation method thereof, and preparation method is simple, obtained non-woven fabrics
Belt strength is high, does not ftracture.
To achieve these goals, the technological means that uses of the present invention for：
A kind of high strength non-woven fabric adhesive tape, is made up of the raw material of following mass parts：40 ~ 60 parts of butadiene, styrene 20 ~ 30
Part, 10 ~ 20 parts of polyester fiber, 10 ~ 30 parts of butyl acrylate, 10 ~ 20 parts of acrylic acid, dibutyl phthalate 0.1 ~ 0.8
It is part, 2 ~ 8 parts of benzoyl peroxide, 5 ~ 10 parts of rosin, 1 ~ 10 part of carboxylic acid, 2 ~ 6 parts of emulsifying agent, 0.1 ~ 1 part of dispersant, steady
Determine 0.05 ~ 0.15 part of agent, 1 ~ 5 part of reinforcing agent, 100 parts of water.
The carboxylic acid is any one in malonic acid, succinic acid or phthalic acid.
The emulsifying agent is N- domiphens.Due to introducing carboxylic acid monomer, it is in acidity to make polymerization system, because
And the emulsifying agent being applied under acid condition is selected as the key polymerizeing.Use anionic (such as DBSA
Salt) emulsifying agent, reaction speed is too fast, and polymerization and p H values are also easy to produce gel when adjusting, anionic blended emulsifier
Reaction speed and conversion ratio are all relatively low, do not reach requirement；And nonionic emulsifier, large usage quantity；The present invention selects cation
Type emulsifying agent, conversion ratio and speed can meet requirement, and latex stability is good.
The dispersant is glyceryl monostearate or glyceryl tristearate.
The stabilizer is dimethylaniline or silicone oil.
The reinforcing agent is phenolic fibre.
A kind of described high strength non-woven fabric adhesive tape, is preferably made up of the raw material of following mass parts：50 parts of butadiene, benzene
25 parts of ethene, 15 parts of polyester fiber, 20 parts of butyl acrylate, 15 parts of acrylic acid, 0.6 part of dibutyl phthalate, peroxide
Change 5 parts of benzoyl, 8 parts of rosin, 6 parts of carboxylic acid, 4 parts of emulsifying agent, 0.5 part of dispersant, 0.1 part of stabilizer, 3 parts of reinforcing agent,
100 parts of water.
The preparation method of the high strength non-woven fabric adhesive tape, butyl acrylate, acrylic acid are mixed and are warming up to 80 ~ 90 DEG C,
Add benzoyl peroxide and carry out polymerisation, then add butadiene, styrene and carboxylic acid, be warming up to and 90 DEG C and be incubated 1 ~
3h, is cooled to room temperature, adds dibutyl phthalate, rosin, emulsifying agent, dispersant, stabilizer and water, stirs and evenly mixs and obtain
Non-woven fabrics latex, mixes calendering with polyester fiber, reinforcing agent by non-woven fabrics latex, dries to obtain Non-woven tape.
Beneficial effect：Non-woven fabric glue milkiness of the present invention can be stablized, and adhesion strength is strong, and thermal stability of latex is good, at 50 DEG C next time
Flow 24 hours its colors constant, do not produce gel, freeze-thaw stability is high, melt after being freezed 50 days at -20 DEG C, its color is not
Become, do not produce gel, the requirement of Various Seasonal production, storage and transport can be met.Preparation method is simple, with made from the latex
Non-woven tape tensile strength and extension at break degree are high, do not ftracture.
Embodiment
Embodiment 1
A kind of high strength non-woven fabric adhesive tape, is made up of the raw material of following mass parts：40 parts of butadiene, 20 parts of styrene, polyester
10 parts of fiber, 10 parts of butyl acrylate, 10 parts of acrylic acid, 0.1 part of dibutyl phthalate, 2 parts of benzoyl peroxide,
5 parts of rosin, 1 part of malonic acid, 2 parts of N- domiphens, 0.1 part of dispersant glyceryl tristearate, stabilizer
0.05 part of silicone oil, 1 part of phenolic fibre, 100 parts of water.
Butyl acrylate, acrylic acid are mixed and are warming up to 85 DEG C, benzoyl peroxide is added and carries out polymerisation, Ran Houjia
Enter butadiene, styrene and carboxylic acid, be warming up to 90 DEG C and be incubated 1h, be cooled to room temperature, add dibutyl phthalate, pine
Perfume, emulsifying agent, dispersant, stabilizer and water, stir and evenly mix and obtain non-woven fabrics latex, by obtained non-woven fabrics latex at 50 DEG C
Backflow 24 hours, melts, its color is constant, does not produce gel after then being freezed 50 days at -20 DEG C, with higher thermally-stabilised
Property and freeze-thaw stability.Non-woven fabrics latex is mixed into calendering with polyester fiber, reinforcing agent, Non-woven tape is dried to obtain.
Embodiment 2
A kind of high strength non-woven fabric adhesive tape, is made up of the raw material of following mass parts：60 parts of butadiene, 30 parts of styrene, polyester
20 parts of fiber, 30 parts of butyl acrylate, 20 parts of acrylic acid, 0.8 part of dibutyl phthalate, 8 parts of benzoyl peroxide,
10 parts of rosin, 10 parts of succinic acid, 6 parts of emulsifying agent N- domiphens, 1 part of dispersant glyceryl monostearate,
0.15 part of stabilizer dimethylaniline, 5 parts of phenolic fibre, 100 parts of water.
Butyl acrylate, acrylic acid are mixed and are warming up to 80 DEG C, benzoyl peroxide is added and carries out polymerisation, Ran Houjia
Enter butadiene, styrene and carboxylic acid, be warming up to 90 DEG C and be incubated 3h, be cooled to room temperature, add dibutyl phthalate, pine
Perfume, emulsifying agent, dispersant, stabilizer and water, stir and evenly mix and obtain non-woven fabrics latex, by obtained non-woven fabrics latex at 50 DEG C
Backflow 24 hours, melts, its color is constant, does not produce gel after then being freezed 50 days at -20 DEG C, with higher thermally-stabilised
Property and freeze-thaw stability.Non-woven fabrics latex is mixed into calendering with polyester fiber, reinforcing agent, Non-woven tape is dried to obtain.
Embodiment 3
A kind of high strength non-woven fabric adhesive tape, is made up of the raw material of following mass parts：50 parts of butadiene, 25 parts of styrene, polyester
15 parts of fiber, 20 parts of butyl acrylate, 15 parts of acrylic acid, 0.6 part of dibutyl phthalate, 5 parts of benzoyl peroxide,
8 parts of rosin, 6 parts of phthalic acid, 4 parts of emulsifying agent N- domiphens, dispersant glyceryl monostearate 0.5
Part, 0.1 part of stabilizer dimethylaniline, 3 parts of phenolic fibre, 100 parts of water.
Butyl acrylate, acrylic acid are mixed and are warming up to 85 DEG C, benzoyl peroxide is added and carries out polymerisation, Ran Houjia
Enter butadiene, styrene and carboxylic acid, be warming up to 90 DEG C and be incubated 2h, be cooled to room temperature, add dibutyl phthalate, pine
Perfume, emulsifying agent, dispersant, stabilizer and water, stir and evenly mix and obtain non-woven fabrics latex, by obtained non-woven fabrics latex at 50 DEG C
Backflow 24 hours, melts, its color is constant, does not produce gel after then being freezed 50 days at -20 DEG C, with higher thermally-stabilised
Property and freeze-thaw stability.Non-woven fabrics latex is mixed into calendering with polyester fiber, reinforcing agent, Non-woven tape is dried to obtain.
Comparative example 1
This comparative example be the same as Example 3 is differed only in latex formulations without styrene and carboxylic acid.
Comparative example 2
This comparative example be the same as Example 3 is differed only in without polyester fiber, phenolic fibre, and non-woven fabric glue is directly prepared with latex
Band.
The Non-woven tape that is prepared to embodiment 1 ~ 3 and reference examples 1,2 carries out performance test, testing standard referring to
Respective country standard.Test result is shown in Table 1.
Table 1：
Claims (8)
1. a kind of high strength non-woven fabric adhesive tape, it is characterised in that be made up of the raw material of following mass parts：40 ~ 60 parts of butadiene,
20 ~ 30 parts of styrene, 10 ~ 20 parts of polyester fiber, 10 ~ 30 parts of butyl acrylate, 10 ~ 20 parts of acrylic acid, phthalic acid
It is 0.1 ~ 0.8 part of dibutyl ester, 2 ~ 8 parts of benzoyl peroxide, 5 ~ 10 parts of rosin, 1 ~ 10 part of carboxylic acid, 2 ~ 6 parts of emulsifying agent, scattered
0.1 ~ 1 part of agent, 0.05 ~ 0.15 part of stabilizer, 1 ~ 5 part of reinforcing agent, 100 parts of water.
2. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that the carboxylic acid is malonic acid, fourth
Any one in diacid or phthalic acid.
3. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that the emulsifying agent is N- dodecanes
Base dimethylamine.
4. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that the dispersant is stearic acid list
Glyceride or glyceryl tristearate.
5. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that the stabilizer is dimethyl benzene
Amine or silicone oil.
6. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that the reinforcing agent is that phenolic aldehyde is fine
Dimension.
7. a kind of high strength non-woven fabric adhesive tape according to claim 1, it is characterised in that by the raw material group of following mass parts
Into：50 parts of butadiene, 25 parts of styrene, 15 parts of polyester fiber, 20 parts of butyl acrylate, 15 parts of acrylic acid, O-phthalic
0.6 part of dibutyl phthalate, 5 parts of benzoyl peroxide, 8 parts of rosin, 6 parts of carboxylic acid, 4 parts of emulsifying agent, 0.5 part of dispersant, stably
0.1 part of agent, 3 parts of reinforcing agent, 100 parts of water.
8. the preparation method of high strength non-woven fabric adhesive tape described in any one in claim 1 ~ 7, it is characterised in that by acrylic acid
Butyl ester, acrylic acid mixing are warming up to 80 ~ 90 DEG C, add benzoyl peroxide and carry out polymerisation, then add butadiene, benzene second
Alkene and carboxylic acid, are warming up to 90 DEG C and are incubated 1 ~ 3h, be cooled to room temperature, add dibutyl phthalate, rosin, emulsifying agent, point
Powder, stabilizer and water, stir and evenly mix and obtain non-woven fabrics latex, by non-woven fabrics latex mixed with polyester fiber, reinforcing agent calendering,
Dry to obtain Non-woven tape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710207762.2A CN106947401A (en) | 2017-03-31 | 2017-03-31 | High strength non-woven fabric adhesive tape and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710207762.2A CN106947401A (en) | 2017-03-31 | 2017-03-31 | High strength non-woven fabric adhesive tape and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106947401A true CN106947401A (en) | 2017-07-14 |
Family
ID=59473973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710207762.2A Pending CN106947401A (en) | 2017-03-31 | 2017-03-31 | High strength non-woven fabric adhesive tape and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106947401A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112281490A (en) * | 2020-09-27 | 2021-01-29 | 安徽圣佳服装辅料科技有限公司 | Non-woven fabric for garment base liner |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1427056A (en) * | 2001-12-10 | 2003-07-02 | 方大集团股份有限公司 | Composite hot melt rubber film |
| CN1782009A (en) * | 2004-11-30 | 2006-06-07 | 日东电工株式会社 | Pressure-sensitive adhesive sheet |
| CN101280163A (en) * | 2007-08-22 | 2008-10-08 | 浙江传化股份有限公司 | Nonwoven cloth adhesive and preparation thereof |
| CN101712853A (en) * | 2008-10-06 | 2010-05-26 | 日东电工株式会社 | Double-sided pressure-sensitive adhesive sheet and method for producing the same |
| CN103140557A (en) * | 2010-09-30 | 2013-06-05 | 3M创新有限公司 | Hot melt processable pressure sensitive adhesives containing fibrous materials |
-
2017
- 2017-03-31 CN CN201710207762.2A patent/CN106947401A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1427056A (en) * | 2001-12-10 | 2003-07-02 | 方大集团股份有限公司 | Composite hot melt rubber film |
| CN1782009A (en) * | 2004-11-30 | 2006-06-07 | 日东电工株式会社 | Pressure-sensitive adhesive sheet |
| CN101280163A (en) * | 2007-08-22 | 2008-10-08 | 浙江传化股份有限公司 | Nonwoven cloth adhesive and preparation thereof |
| CN101712853A (en) * | 2008-10-06 | 2010-05-26 | 日东电工株式会社 | Double-sided pressure-sensitive adhesive sheet and method for producing the same |
| CN103140557A (en) * | 2010-09-30 | 2013-06-05 | 3M创新有限公司 | Hot melt processable pressure sensitive adhesives containing fibrous materials |
Non-Patent Citations (1)
| Title |
|---|
| 黄涛: "无纺布胶乳的研制", 《合成橡胶工业》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112281490A (en) * | 2020-09-27 | 2021-01-29 | 安徽圣佳服装辅料科技有限公司 | Non-woven fabric for garment base liner |
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