CN106947337A - A kind of color steel heat reflection waterborne metallic paint - Google Patents

A kind of color steel heat reflection waterborne metallic paint Download PDF

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Publication number
CN106947337A
CN106947337A CN201710129797.9A CN201710129797A CN106947337A CN 106947337 A CN106947337 A CN 106947337A CN 201710129797 A CN201710129797 A CN 201710129797A CN 106947337 A CN106947337 A CN 106947337A
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China
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parts
color steel
metallic paint
coating
waterborne metallic
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Pending
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CN201710129797.9A
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Chinese (zh)
Inventor
金勇云
王隆经
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Shenyang Xuan Boxin Mstar Technology Ltd
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Shenyang Xuan Boxin Mstar Technology Ltd
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Priority to CN201710129797.9A priority Critical patent/CN106947337A/en
Publication of CN106947337A publication Critical patent/CN106947337A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/103Anti-corrosive paints containing metal dust containing Al
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams

Abstract

The color steel of the present invention addition nano titanium oxide, UV absorbers, antioxidant in waterborne metallic paint component, nano titanium oxide cause the present invention coating surface is weather-proof, UV resistant, UV absorbers can effectively absorb ultraviolet, antioxidant can effectively prevent the oxidation of coating, extend the service life of coating;Added with resorcinol in component, the adhesive force of coating is improved;Sericite in powder, nanometer basic zirconium phosphate etc. in component, can effectively improve the frothing percentage of coating, and with higher heat endurance, improve fire endurance;The coating of the present invention has good weatherability, physical and mechanical properties after tested, and resistance to UV aging is protruded, and heat reflection performance is excellent, while having excellent beautifying and decorating concurrently;The coating application of the present invention is convenient, durable in use, the coating protection for the color steel that is particularly suitable for use in, with multiple-protection performances such as the weather-proof heat reflections of anti-corrosion fire prevention.

Description

A kind of color steel heat reflection waterborne metallic paint
Technical field
The present invention relates to technical field of aqueous paint, and in particular to a kind of color steel heat reflection waterborne metallic paint.
Background technology
Color steel is widely used in building field, because it is placed under illumination for a long time, thus be accordingly used in the coating requirement of color steel There is excellent anti-oxidant, weather resistance and to visible ray and the heat reflection performance of infra-red radiation;In addition, color steel is anti- Fiery performance is also increasingly paid close attention to by people, and although steel belong to incombustible material, but its fire resistance is more than masonry structure Poor with reinforced concrete structure, with the rise of temperature, the mechanical strength of steel can decline.When temperature is increased to the stagnation temperature of steel Degree(Generally 540 DEG C)When, its yield stress is only the 40% of normal temperature.Steel are under the direct calcination of thermal-flame, only 15min fire endurance.The use of fireproof coating is a kind of more satisfactory method of steel building fireproof.Steel structure fireproofing Coating is coated in steel member surface, plays fire-proof and thermal-insulation protective effect, prevents steel to be brought rapidly up in a fire and reduces intensity, keeps away Exempt from steel construction to lose support force and cause building to collapse.
The content of the invention
The problem of existing for prior art, the present invention is directed to propose a kind of high weathering, anti-oxidant, fire protecting performance it is excellent and Anticorrosion water-soluble metallic paint with heat reflection performance.
The technical solution adopted by the present invention is:A kind of color steel waterborne metallic paint, its component is included by mass fraction:
45 parts of acrylic resin
12 parts of amino resins
28 parts of deionized water
10 parts of magnesium powder or aluminium powder
2 parts of anti-corrosion paint
2 parts of curing agent
2 parts of coalescents
1 part of dispersant
1 part of wetting agent
1 part of defoamer
2 parts of resorcinol
3 parts of nano titanium oxide
1 part of UV absorbers
1 part of antioxidant
1 part of modified nano montmorillonite
0.8 part of basic zirconium phosphate of nanometer
2 parts of cenosphere.
Further, described coalescents are the one or two in dipropylene glycol n-butyl ether, ethylene glycol monobutyl ether.
Further, described dispersant is the one or more in SN5040, CY540, DP518.
Further, described wetting agent is the one or more in PE100, DOW405, H436.
Further, described defoamer is the one or more in A10, SPA202, D160.
Further, described anti-corrosion paint includes sericite in powder, titanium dioxide, superfine talcum powder and Firebrake ZB, wherein thin,tough silk 0.5 part of mica powder, 0.5 part of titanium dioxide, 0.5 part of superfine talcum powder, 0.5 part of Firebrake ZB.
Further, described curing agent is diethylenetriamine or dimethylamine propylamine.
Further, described UV absorbers be aminodithioformic acid nickel salt or one kind in phosphate monoester nickel or Two kinds.
Further, described antioxidant can be one kind or two in tributyl phosphite or phosphorous acid benzene di-isooctyl Kind.
Further, described cenosphere is the ceramic fine bead or glass microballoon that average grain diameter is 10-30 microns.
Compared with prior art, the invention has the advantages that:
1. adding nano titanium oxide, UV absorbers, antioxidant in the coating composition of the present invention, nano titanium oxide causes Coating surface of the invention is weather-proof, UV resistant, and UV absorbers can effectively absorb ultraviolet, and antioxidant can be effective The service life for preventing the oxidation of coating, extending coating;
2. added with resorcinol in component, improve the adhesive force of coating;
3. sericite in powder, nanometer basic zirconium phosphate etc. in component, the frothing percentage of coating can be effectively improved, and with higher thermally-stabilised Property, improve fire endurance;
4. the coating of the present invention has good weatherability, physical and mechanical properties after tested, resistance to UV aging is protruded, and heat is anti- Excellent performance is penetrated, while having excellent beautifying and decorating concurrently;
5. the coating application of the present invention is convenient, durable in use, the coating protection for the color steel that is particularly suitable for use in, prevent fires resistance to anti-corrosion Wait the multiple-protection performances such as heat reflection.
Embodiment
Embodiment one
A kind of color steel waterborne metallic paint, its component by mass parts state including:
45 parts of acrylic resin
12 parts of amino resins
28 parts of deionized water
10 parts of magnesium powder
2 parts of anti-corrosion paint
2 parts of diethylenetriamine
2 parts of dipropylene glycol n-butyl ether
1 part of SN5040
1 part of PE100
1 part of A10
2 parts of resorcinol
3 parts of nano titanium oxide
1 part of aminodithioformic acid nickel salt
1 part of tributyl phosphite
1 part of modified nano montmorillonite
0.8 part of basic zirconium phosphate of nanometer
Average grain diameter is 10-30 microns of 2 parts of ceramic fine bead.
Described anti-corrosion paint includes sericite in powder, titanium dioxide, superfine talcum powder and Firebrake ZB, wherein sericite in powder 0.5 Part, 0.5 part of titanium dioxide, 0.5 part of superfine talcum powder, 0.5 part of Firebrake ZB.
Embodiment two
A kind of color steel waterborne metallic paint, its component by mass parts state including:
45 parts of acrylic resin
12 parts of amino resins
28 parts of deionized water
10 parts of aluminium powder
2 parts of anti-corrosion paint
2 parts of dimethylamine propylamine
2 parts of ethylene glycol monobutyl ether
1 part of CY540
1 part of DOW405
1 part of SPA202
2 parts of resorcinol
3 parts of nano titanium oxide
1 part of phosphate monoester nickel
1 part of phosphorous acid benzene di-isooctyl
1 part of modified nano montmorillonite
0.8 part of basic zirconium phosphate of nanometer
Average grain diameter is 10-30 microns of 2 parts of glass microballoon.
Described anti-corrosion paint includes sericite in powder, titanium dioxide, superfine talcum powder and Firebrake ZB, wherein sericite in powder 0.5 Part, 0.5 part of titanium dioxide, 0.5 part of superfine talcum powder, 0.5 part of Firebrake ZB.
Embodiment three
A kind of color steel waterborne metallic paint, its component by mass parts state including:
45 parts of acrylic resin
12 parts of amino resins
28 parts of deionized water
10 parts of aluminium powder
2 parts of anti-corrosion paint
2 parts of dimethylamine propylamine
2 parts of ethylene glycol monobutyl ether
1 part of DP518
1 part of H436
1 part of D160
2 parts of resorcinol
3 parts of nano titanium oxide
1 part of phosphate monoester nickel
1 part of phosphorous acid benzene di-isooctyl
1 part of modified nano montmorillonite
0.8 part of basic zirconium phosphate of nanometer
Average grain diameter is 10-30 microns of 2 parts of glass microballoon.
Described anti-corrosion paint includes sericite in powder, titanium dioxide, superfine talcum powder and Firebrake ZB, wherein sericite in powder 0.5 Part, 0.5 part of titanium dioxide, 0.5 part of superfine talcum powder, 0.5 part of Firebrake ZB.

Claims (10)

1. a kind of color steel heat reflection waterborne metallic paint, it is characterised in that the color steel is applied with heat reflection water-based metal The component of material is included by mass fraction:
45 parts of acrylic resin
12 parts of amino resins
28 parts of deionized water
10 parts of magnesium powder or aluminium powder
2 parts of anti-corrosion paint
2 parts of curing agent
2 parts of coalescents
1 part of dispersant
1 part of wetting agent
1 part of defoamer
2 parts of resorcinol
3 parts of nano titanium oxide
1 part of UV absorbers
1 part of antioxidant
1 part of modified nano montmorillonite
0.8 part of basic zirconium phosphate of nanometer
2 parts of cenosphere.
2. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described coalescents are One or two in dipropylene glycol n-butyl ether, ethylene glycol monobutyl ether.
3. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described dispersant is One or more in SN5040, CY540, DP518.
4. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described wetting agent is One or more in PE100, DOW405, H436.
5. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described defoamer is One or more in A10, SPA202, D160.
6. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described anti-corrosion paint bag Include sericite in powder, titanium dioxide, superfine talcum powder and Firebrake ZB, wherein 0.5 part of sericite in powder, 0.5 part of titanium dioxide, superfine talcum powder 0.5 part, 0.5 part of Firebrake ZB.
7. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described curing agent is two Ethene triamine or dimethylamine propylamine.
8. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described UV Absorption Agent is the one or two in aminodithioformic acid nickel salt or phosphate monoester nickel.
9. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described antioxidant can be One or two in tributyl phosphite or phosphorous acid benzene di-isooctyl.
10. a kind of color steel waterborne metallic paint according to claim 1, it is characterised in that:Described cenosphere For the ceramic fine bead or glass microballoon that average grain diameter is 10-30 microns.
CN201710129797.9A 2017-03-07 2017-03-07 A kind of color steel heat reflection waterborne metallic paint Pending CN106947337A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710129797.9A CN106947337A (en) 2017-03-07 2017-03-07 A kind of color steel heat reflection waterborne metallic paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710129797.9A CN106947337A (en) 2017-03-07 2017-03-07 A kind of color steel heat reflection waterborne metallic paint

Publications (1)

Publication Number Publication Date
CN106947337A true CN106947337A (en) 2017-07-14

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CN201710129797.9A Pending CN106947337A (en) 2017-03-07 2017-03-07 A kind of color steel heat reflection waterborne metallic paint

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948915A (en) * 2018-06-25 2018-12-07 合肥易美特建材有限公司 A kind of low reflecting rate color steel plate surface coating material
CN108948917A (en) * 2018-06-25 2018-12-07 合肥易美特建材有限公司 A kind of preparation method of color steel plate weather-resistant coating
CN109021742A (en) * 2018-06-25 2018-12-18 合肥易美特建材有限公司 A kind of color steel plate shock resistance resist bending coating
CN109251613A (en) * 2018-08-09 2019-01-22 深圳华美板材有限公司 A kind of aqueous PCM steel plate and its manufacturing process
CN109517459A (en) * 2018-11-20 2019-03-26 四川华邦保和涂料有限公司 A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486864A (en) * 2009-02-18 2009-07-22 中山创美涂料有限公司 Waterborne metallic paint and preparation thereof
CN104419315A (en) * 2013-08-26 2015-03-18 上海优漫新材料科技有限公司 Waterborne metal anticorrosive coating
CN105111886A (en) * 2015-08-28 2015-12-02 中国科学院合肥物质科学研究院 Water-based epoxy multifunctional steel structure paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486864A (en) * 2009-02-18 2009-07-22 中山创美涂料有限公司 Waterborne metallic paint and preparation thereof
CN104419315A (en) * 2013-08-26 2015-03-18 上海优漫新材料科技有限公司 Waterborne metal anticorrosive coating
CN105111886A (en) * 2015-08-28 2015-12-02 中国科学院合肥物质科学研究院 Water-based epoxy multifunctional steel structure paint and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108948915A (en) * 2018-06-25 2018-12-07 合肥易美特建材有限公司 A kind of low reflecting rate color steel plate surface coating material
CN108948917A (en) * 2018-06-25 2018-12-07 合肥易美特建材有限公司 A kind of preparation method of color steel plate weather-resistant coating
CN109021742A (en) * 2018-06-25 2018-12-18 合肥易美特建材有限公司 A kind of color steel plate shock resistance resist bending coating
CN109251613A (en) * 2018-08-09 2019-01-22 深圳华美板材有限公司 A kind of aqueous PCM steel plate and its manufacturing process
CN109517459A (en) * 2018-11-20 2019-03-26 四川华邦保和涂料有限公司 A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint

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Application publication date: 20170714

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