CN106927769A - A kind of alkaline residue pervious concrete and preparation method thereof - Google Patents

A kind of alkaline residue pervious concrete and preparation method thereof Download PDF

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Publication number
CN106927769A
CN106927769A CN201710230169.XA CN201710230169A CN106927769A CN 106927769 A CN106927769 A CN 106927769A CN 201710230169 A CN201710230169 A CN 201710230169A CN 106927769 A CN106927769 A CN 106927769A
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CN
China
Prior art keywords
alkaline residue
pervious concrete
cement
slag
alkaline
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710230169.XA
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Chinese (zh)
Inventor
赵庆新
王冬丽
刘继中
兰永秋
尹必晶
于树杰
袁浩
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Yanshan University
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Yanshan University
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Publication date
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Priority to CN201710230169.XA priority Critical patent/CN106927769A/en
Publication of CN106927769A publication Critical patent/CN106927769A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of alkaline residue pervious concrete, its every cubic metre component is:80~145kg of alkaline residue, 80~120kg of cement, 200~250kg of slag, the 1500kg of rubble 1400,110~130kg of water.The preparation method of the alkaline residue pervious concrete is that alkaline residue is pre-processed, and is crushed and crossed 4.76mm square hole screens;During the alkaline residue of aforementioned proportion, cement, slag, water put into forced mixer successively, 1min is stirred;Rubble is put into again, stirs 2min;Divide three layers respectively to vibrate 25 times to be molded, you can prepare alkaline residue pervious concrete.The coefficient of permeability and 28d intensity of alkaline residue pervious concrete of the invention reach C15 pervious concrete requirements, cost than same intensity cement pervious concrete low cost more than 30%, while using a large amount of alkaline residues, environmental protection and energy saving, environment, remarkable in economical benefits.

Description

A kind of alkaline residue pervious concrete and preparation method thereof
Technical field
The invention belongs to building material field, more particularly to a kind of alkaline residue pervious concrete and preparation method thereof.
Background technology
In October, 2014, house and town and country construction portion put into effect《Sponge urban construction technical manual》, instructed from technological layer Carry out sponge urban construction in various regions.16 cities are determined within 2015 as pilot, and following 3 years, average each experimental city is annual About hundred million yuan of sponge urban construction special funds will be obtained, a large amount of is the important measure of sponge urban construction using pervious concrete.
Alkaline residue refers to the alkaline scrap material discharged during alkaline and alkali process in industrial production.Comprising ammonium alkaline process alkali producing process The waste residue of middle discharge and the alkaline scrap material of other industrial processes discharge.This bulk deposition is adversely affected to environment Waste material, dispersion is applied in sponge urban construction in laying the pervious concrete of humanoid road, has not only embodied commercial value but also reality Environment protection significance is showed.
The present invention forms a kind of hydraulicity gelling material material by alkaline residue activated slag, largely replaces portland cement. Theoretical foundation of the invention is alkali-activated slag, and stronger chemical bond is formed using soda ash NaOH activated slags.Alkaline residue is applied Wherein contain a certain amount of salkali waste, the Binder Materials of some strength is formed using its activated slag, realize alkaline residue reproducible utilization, make It is standby go out a kind of alkaline residue activated slag as Binder Materials pervious concrete.
The content of the invention
It is an object of the invention to provide a kind of alkaline residue pervious concrete, the same of existing pervious concrete intensity is being reached When, industrial waste alkaline residue is rationally utilized, reduce cement consumption and cost.
The present invention also aims to provide a kind of preparation method of above-mentioned alkaline residue pervious concrete.
To achieve these goals, the solution of the present invention is:
A kind of alkaline residue pervious concrete, its every cubic metre component is:80~145kg of alkaline residue, 80~120kg of cement, ore deposit 200~250kg of slag, rubble 1400-1500kg, 110~130kg of water.
Preferably, the alkaline residue is the solid-state alkaline residue of moisture content 31.1%, wherein Mg (OH)2、Ca(OH)2Mass fraction point Wei 6.01%, 0.01%.
Preferably, the cement is the usual PII cement for using in concrete technology.
Preferably, the slag is S95 grades of ground slag.
Preferably, the particle size range of the rubble is 5~10mm.
Preferably, the best composition of every cubic metre of alkaline residue pervious concrete is:Alkaline residue 80kg, cement 120kg, slag 200kg, rubble 1445kg, water 126kg.
Present invention also offers the preparation method of above-mentioned alkaline residue pervious concrete, comprise the following steps:
A. alkaline residue is pre-processed, is crushed and crossed 4.76mm square hole screens;
B. in the alkaline residue of aforementioned proportion, cement, slag, water being put into forced mixer successively, 1min is stirred;
C. rubble is put into again, stirs 2min;
D. divide three layers respectively to vibrate 25 times to be molded, you can prepare alkaline residue pervious concrete.
It is of the invention to be had the advantages that compared with present technology:
(1) portland cement needs to consume substantial amounts of mineral resources and the energy in process of production, discharges a large amount of titanium dioxides Carbon, also brings dust and noise pollution, has not met the requirement of energy-saving and emission-reduction, Green Sustainable.
(2) by alkaline enterprise a large amount of alkaline residue discarded objects that pile up like a mountain, the technology of preparing of pervious concrete is applied to. Reduce conventional processing mode such as to pile up, fill out the secondary pollution that sea is brought, not only processed industrial refuse but also brought practicality And commercial value.
Specific embodiment
With reference to embodiment, specific embodiment of the invention is described in further detail.Following examples are used for The present invention is illustrated, but is not limited to the scope of the present invention.
Embodiment 1:
Alkaline residue is pre-processed before preparing, is crushed and crossed 4.76mm square hole screens.Take sieving alkaline residue 80kg, PII Cement 120kg, S95 grade ground slag 200kg, water 126kg are put into forced mixer, stir 1min.Particle diameter is put into again Scope is 5~10mm, rubble 1445kg of the clay content less than 0.5%, stirs 2min, divides three layers respectively to vibrate 25 times and is molded, and is obtained Concrete sample 1.
Embodiment 2:
Alkaline residue is pre-processed before preparing, is crushed and crossed 4.76mm square hole screens.Take sieving alkaline residue 100kg, PII Cement 80kg, S95 grade ground slag 220kg, water 126kg are put into forced mixer, stir 1min.Particle diameter model is put into again It is 5~10mm to enclose, discontinuous gradation, rubble 1445kg of the clay content less than 0.5%, stirs 2min, divides three layers and respectively vibrates 25 times Shaping, obtains concrete sample 2.
Embodiment 3:
Alkaline residue is pre-processed before preparing, is crushed and crossed 4.76mm square hole screens.Take sieving alkaline residue 116kg, PII Cement 120kg, S95 grade ground slag 200kg, water 124kg are put into forced mixer, stir 1min.Particle diameter is put into again Scope is 5~10mm, discontinuous gradation, rubble 1445kg of the clay content less than 0.5%, stirs 2min, and points three layers respectively vibrate 25 Secondary shaping, obtains concrete sample 3.
Sample as obtained by above-described embodiment, carries out effective drainage porosity, 7d intensity, 28d intensity and coefficient of permeability respectively Test, result of the test is as shown in table 1.The performance of alkaline residue pervious concrete prepared by the present invention reaches C15 pervious concrete skills Art requirement (C15 alkaline residue pervious concrete 28d intensity is not less than 15MPa, and coefficient of permeability is not less than 2.00mm/s).Sample 1~3 is equal More than intensity 15MPa is can reach, almost, the combination property of the compression strength of sample 1 and water penetration is relatively more preferable for combination property.
The concrete sample characteristic of table 1
Sample number into spectrum Effective drainage porosity (%) 7d intensity (MPa) 28d intensity (MPa) Coefficient of permeability (mm/s)
Sample 1 23.1 9.83 16.78 2.22
Sample 2 24.1 8.82 15.10 2.27
Sample 3 22.8 9.94 16.88 2.08
Each technical characteristic of above-mentioned disclosure is not limited to disclosed and further feature combination, and those skilled in the art are also Other combinations between each technical characteristic can be carried out according to the purpose of invention, is defined by the purpose for realizing the present invention.

Claims (7)

1. a kind of alkaline residue pervious concrete, it is characterised in that its every cubic metre component is:80~145kg of alkaline residue, cement 80~ 120kg, 200~250kg of slag, rubble 1400-1500kg, 110~130kg of water.
2. alkaline residue pervious concrete according to claim 1, it is characterised in that the alkaline residue is consolidated for moisture content 31.1% State alkaline residue, wherein Mg (OH)2、Ca(OH)2Mass fraction is respectively 6.01%, 0.01%.
3. alkaline residue pervious concrete according to claim 1, it is characterised in that the cement be in concrete technology generally The PII cement of use.
4. alkaline residue pervious concrete according to claim 1, it is characterised in that the slag is S95 grades of ground slag.
5. alkaline residue pervious concrete according to claim 1, it is characterised in that the particle size range of the rubble is 5~ 10mm。
6. alkaline residue pervious concrete according to claim 1, it is characterised in that every cubic metre of alkaline residue pervious concrete is most Good component is:Alkaline residue 80kg, cement 120kg, slag 200kg, rubble 1445kg, water 126kg.
7. the preparation method of the high-hydroscopicity Behavior of Hardened Cement Paste according to claim any one of 1-6, it is characterised in that methods described Comprise the following steps:
A. alkaline residue is pre-processed, is crushed and crossed 4.76mm square hole screens;
B. in the alkaline residue of aforementioned proportion, cement, slag, water being put into forced mixer successively, 1min is stirred;
C. rubble is put into again, stirs 2min;
D. divide three layers respectively to vibrate 25 times to be molded, you can prepare alkaline residue pervious concrete.
CN201710230169.XA 2017-04-10 2017-04-10 A kind of alkaline residue pervious concrete and preparation method thereof Pending CN106927769A (en)

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Application Number Priority Date Filing Date Title
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CN106927769A true CN106927769A (en) 2017-07-07

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108821713A (en) * 2018-07-17 2018-11-16 燕山大学 Based on alkaline residue-slag-cement ternary cementitious material mortar specimen and preparation method thereof
CN108863254A (en) * 2018-07-17 2018-11-23 燕山大学 Based on alkaline residue-slag binary cementitious material mortar specimen and preparation method thereof
EP4043416A1 (en) * 2021-02-12 2022-08-17 Povazská cementáren, a.s. Thermal energy storage media based on concrete and use of hybrid cement as a binder for production of such concrete media

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104072048A (en) * 2014-07-11 2014-10-01 赵玲强 Formula for preparing building material and product thereof by utilizing caustic sludge
CN104402390A (en) * 2014-10-16 2015-03-11 河海大学 Water permeability concrete barrier board and preparation method thereof
CN104926244A (en) * 2015-06-04 2015-09-23 河海大学 Method for in-situ curing of alkaline residue field by use of ground granulated blast-furnace slag as curing agent
CN106277998A (en) * 2015-05-19 2017-01-04 湖南三恒建设园林工程有限公司 A kind of permeable concrete and the construction method of concrete road surface thereof
CN106278350A (en) * 2016-08-10 2017-01-04 卓达新材料科技集团威海股份有限公司 A kind of alkaline residue building waste water-permeable brick and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104072048A (en) * 2014-07-11 2014-10-01 赵玲强 Formula for preparing building material and product thereof by utilizing caustic sludge
CN104402390A (en) * 2014-10-16 2015-03-11 河海大学 Water permeability concrete barrier board and preparation method thereof
CN106277998A (en) * 2015-05-19 2017-01-04 湖南三恒建设园林工程有限公司 A kind of permeable concrete and the construction method of concrete road surface thereof
CN104926244A (en) * 2015-06-04 2015-09-23 河海大学 Method for in-situ curing of alkaline residue field by use of ground granulated blast-furnace slag as curing agent
CN106278350A (en) * 2016-08-10 2017-01-04 卓达新材料科技集团威海股份有限公司 A kind of alkaline residue building waste water-permeable brick and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108821713A (en) * 2018-07-17 2018-11-16 燕山大学 Based on alkaline residue-slag-cement ternary cementitious material mortar specimen and preparation method thereof
CN108863254A (en) * 2018-07-17 2018-11-23 燕山大学 Based on alkaline residue-slag binary cementitious material mortar specimen and preparation method thereof
EP4043416A1 (en) * 2021-02-12 2022-08-17 Povazská cementáren, a.s. Thermal energy storage media based on concrete and use of hybrid cement as a binder for production of such concrete media

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Application publication date: 20170707