CN106905780A - A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof - Google Patents
A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof Download PDFInfo
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- CN106905780A CN106905780A CN201710250456.7A CN201710250456A CN106905780A CN 106905780 A CN106905780 A CN 106905780A CN 201710250456 A CN201710250456 A CN 201710250456A CN 106905780 A CN106905780 A CN 106905780A
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- capsicim
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- pollution paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D115/00—Coating compositions based on rubber derivatives
- C09D115/02—Rubber derivatives containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of capsicim environmental protection type anti-pollution paint, including film forming matter, high concentration capsicum oleoresin, color stuffing, auxiliary agent, solvent.The invention also discloses a kind of capsicim environmental protection type anti-pollution paint and preparation method thereof；The present invention adds high concentration capsicum oleoresin, color stuffing, the auxiliary agent dissolved through solvent with film forming matter as base-material, is made by being well mixed after stirring, grinding.The capsicim environmental protection type anti-pollution paint that the present invention is provided, for the protection on ship and underwater facility surface, prevents attachment and the growth and breeding of marine organisms.Anti-fouling agent main component natural capsicum element used by the present invention, the main effect model to marine organisms is repellent, with degradability, will not destroy the marine eco-environment, broad-spectrum high efficacy, environmental protection.
Description
Technical field
The present invention relates to technical field of coatings, specifically a kind of capsicim environmental protection type anti-pollution paint and preparation method thereof.
Background technology
21 century be human development and using ocean century, naval vessels, shipbuilding, sea-freight, fishery, sea-bottom oil-gas exploitation and
The maritime project of the aspects such as sea-farming obtains unprecedented development.The comprehensive and forward position that above-mentioned maritime project is faced
Property problem be exactly either in fixed deep ocean installation, such as harbour, buoy, harbour, bridge pier, pipeline, fishing gear, or in dynamic navigation
Naval vessels, ship basal surface can all there are various different marine fouling organisms to adhere to and breed in surface, its substantial amounts, grow it is fast
Speed, seriously jeopardizes shipping cost and Marine case.Therefore, Jiao that marine biofouling is always domestic and international research is effectively prevented
Point and focus.
Marine anti-pollution means complexity is various, and technology species is various, but from the point of view of the developing history of marine anti-pollution, adds antifouling
It is one of economically with technically feasible and maximally efficient means that agent is made antifouling paint.Currently, generally use both at home and abroad
Anti-fouling agent is cuprous oxide, copper pyrithione (zinc), zineb, Sea-nine211, trichlorophenyl maleimide etc., its poison
Though property is smaller than TBT, DDT, but still is noxious material, marine organisms, destruction marine ecology balance, without solution ring can be killed
The problem of border friendly.As international community is to the growing interest of environmental problem, efficient, wide spectrum, environmentally friendly sea are developed
Foreign antifouling paint is imperative.
The content of the invention
It is an object of the invention to provide it is a kind of environmental protection, efficiently, wide spectrum, lasting capsicim environmental protection type anti-pollution paint and its
Preparation method, to solve the problems, such as to be proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of capsicim environmental protection type anti-pollution paint, comprises the following components in percentage by weight：Film forming matter 30~50%,
High concentration capsicum oleoresin 0.1~10%, color stuffing 10~40%, auxiliary agent 5~20%, solvent 10~30%.
As further scheme of the invention：The film forming matter is chlorinated rubber, vinyl chloride acetate ethylene copolymer, ring
One or more in oxygen tree fat, acrylic resin.
As further scheme of the invention：Total capsaicin content is 40~80% in the high concentration capsicum oleoresin,
Wherein capsicim monomer accounts for the 60~70% of total capsicim.
As further scheme of the invention：The color stuffing is iron oxide red, titanium dioxide, aluminum oxide, barium sulfate, oxidation
One or more in zinc, mica powder, calcium carbonate, talcum powder, kaolin, white carbon, rosin.
As further scheme of the invention：The auxiliary agent includes dispersant, defoamer, levelling agent, anti-settling agent, thickener
And wetting agent.
As further scheme of the invention：The solvent is toluene, dimethylbenzene, butyl acetate, ethyl acetate, acetic acid
One or more mixture in isobutyl ester, butanol, cyclohexanone.
Its preparation method of the capsicim environmental protection type anti-pollution paint, comprises the following steps that：
(1) supplementary material prepares, and prepares each component by weight percentage respectively；
(2) step (1) middle and high concentration chilli oil oleoresin solvent is fully first dissolved into rear and other each liquid groups completely
Divide and be sufficiently mixed uniformly, then in the liquid component that solid constituent addition is well mixed, it is well mixed after stirring, grinding to be
.
Compared with prior art, the beneficial effects of the invention are as follows：
1. using the capsicum oleoresin of high concentration as anti-fouling agent, the main component in anti-fouling agent is capsicim to the present invention,
Capsicim is the active material extracted from natural capsicum, and environmental protection is not polluted to ocean, to the main work of marine organisms
It is repellent with mode, marine organisms, destruction marine ecology balance will not be killed.
2. the antifouling agent concentration of capsicim that the present invention is used is high, its total capsaicin content up to 40~80%, in total capsicim
Capsicim content of monomer is up to 60~70%.Addition is less during use, does not interfere with the performance of paint itself, and cost
It is relatively low.
3. the present invention is first all molten by the capsicum oleoresin of high concentration with organic solvent in the preparation process of antifouling paint
Solution, then be well mixed with other liquid components, solid constituent is finally added, mixed by stirring, ball mill grinding, it is ensured that anti-
Dirty agent and other components are sufficiently mixed uniformly, it is ensured that the characteristic of antifouling paint is given full play to.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of preparation method of capsicim environmental protection type anti-pollution paint, comprises the following steps：
(1) component according to the following percentages by weight is got the raw materials ready：Film forming matter 35%, high concentration capsicum oleoresin 5%, color stuffing
25%th, auxiliary agent 10%, solvent 25%.
Wherein, the film forming matter is chlorinated rubber；The total capsaicin content of high concentration capsicum oleoresin is 20%, single
Body capsaicin content is 60%；The color stuffing is iron oxide red, titanium dioxide, talcum powder；The auxiliary agent is dispersant, anti-settling agent
And wetting agent；The solvent is toluene.
(2) prepare：Step (1) middle and high concentration chilli oil oleoresin solvent is fully first dissolved into rear and other each liquid completely
Body component is sufficiently mixed uniformly, then solid constituent is added in well mixed liquid component, is mixed by after stirring, grinding
It is uniform.
The present invention has carried out antifouling property according to above-mentioned technical proposal to the present embodiment capsicim environmental protection type anti-pollution paint
Test, good in 12 months, coating does not have cracking and comes off, any surface finish, without marine organisms attachment.
Embodiment 2
A kind of preparation method of capsicim environmental protection type anti-pollution paint, comprises the following steps：
(1) component according to the following percentages by weight is got the raw materials ready：Film forming matter 45%, high concentration capsicum oleoresin 1%, color stuffing
20%th, auxiliary agent：14%th, solvent 20%.
Wherein, the film forming matter is epoxy resin；The total capsaicin content of high concentration capsicum oleoresin is 50%, single
Body capsaicin content is 65%；The color stuffing is aluminum oxide, titanium dioxide, calcium carbonate；The auxiliary agent be levelling agent, anti-settling agent and
Wetting agent；The solvent is dimethylbenzene.
(2) prepare：Step (1) middle and high concentration chilli oil oleoresin solvent is fully first dissolved into rear and other each liquid completely
Body component is sufficiently mixed uniformly, then solid constituent is added in well mixed liquid component, is mixed by after stirring, grinding
It is uniform.
The present invention has carried out antifouling property according to above-mentioned technical proposal to the present embodiment capsicim environmental protection type anti-pollution paint
Test, good in 12 months, coating does not have cracking and comes off, any surface finish, without marine organisms attachment.
Embodiment 3
A kind of preparation method of capsicim environmental protection type anti-pollution paint, comprises the following steps：
(1) component according to the following percentages by weight is got the raw materials ready：Film forming matter 50%, high concentration capsicum oleoresin 5%, color stuffing
20%th, auxiliary agent：10%th, solvent 15%.
Wherein, the film forming matter is acrylic resin；The total capsaicin content of high concentration capsicum oleoresin is
60%, monomer capsaicin content is 62%；The color stuffing is aluminum oxide, titanium dioxide, talcum powder, calcium carbonate；The auxiliary agent is
Levelling agent, defoamer and wetting agent；The solvent is butyl acetate.
(2) prepare：Step (1) middle and high concentration chilli oil oleoresin solvent is fully first dissolved into rear and other each liquid completely
Body component is sufficiently mixed uniformly, then solid constituent is added in well mixed liquid component, is mixed by after stirring, grinding
It is uniform.
The present invention has carried out antifouling property according to above-mentioned technical proposal to the present embodiment capsicim environmental protection type anti-pollution paint
Test, good in 12 months, coating does not have cracking and comes off, any surface finish, without marine organisms attachment.
High concentration capsicum oleoresin with high-quality capsicum as raw material, through scientific method extracting and developing, purifying, it is refined form, have
There are a kind of pure natural oily pasty masses of strong acid, main component is capsicim.Capsicim is a kind of pungent perfume (or spice) of extreme
Oxamides alkaloid, with broad-spectrum antibacterial effect, has repellent action to marine fouling organism, and to marine fouling organism
Breeding rise inhibitory action, do not produce injury to marine attaching organism, ecological benefits are fairly obvious.
The present invention is using the capsicum oleoresin of high concentration as anti-fouling agent, and the main component in anti-fouling agent is capsicim, peppery
Green pepper element is the active material extracted from natural capsicum, and environmental protection is not polluted to ocean, to the Main Function of marine organisms
Mode is repellent, will not kill marine organisms, destruction marine ecology balance.The antifouling agent concentration of capsicim that the present invention is used is high,
, up to 40~80%, capsicim content of monomer is up to 60~70% in total capsicim for its total capsaicin content.Addition during use
It is less, the performance of paint itself is not interfered with, and also cost is relatively low.The present invention in the preparation process of antifouling paint, first with having
Machine solvent all dissolves the capsicum oleoresin of high concentration, then is well mixed with other liquid components, finally adds solid group
Point, mixed by stirring, ball mill grinding, it is ensured that anti-fouling agent and other components are sufficiently mixed uniformly, it is ensured that antifouling paint
Characteristic is given full play to.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from
Various changes can be made.
Claims (7)
1. a kind of capsicim environmental protection type anti-pollution paint, it is characterised in that comprise the following components in percentage by weight：Film forming matter
30~50%, high concentration capsicum oleoresin 0.1~10%, color stuffing 10~40%, auxiliary agent 5~20%, solvent 10~30%.
2. capsicim environmental protection type anti-pollution paint according to claim 1, it is characterised in that the film forming matter is chlorination rubber
One or more in glue, vinyl chloride acetate ethylene copolymer, epoxy resin, acrylic resin.
3. capsicim environmental protection type anti-pollution paint according to claim 1, it is characterised in that the high concentration capsicum oleoresin
In total capsaicin content be 40~80%, wherein capsicim monomer accounts for the 60~70% of total capsicim.
4. capsicim environmental protection type anti-pollution paint according to claim 1, it is characterised in that the color stuffing is iron oxide
In red, titanium dioxide, aluminum oxide, barium sulfate, zinc oxide, mica powder, calcium carbonate, talcum powder, kaolin, white carbon, rosin one
Plant or several.
5. capsicim environmental protection type anti-pollution paint according to claim 1, it is characterised in that the auxiliary agent include dispersant,
Defoamer, levelling agent, anti-settling agent, thickener and wetting agent.
6. capsicim environmental protection type anti-pollution paint according to claim 1, it is characterised in that the solvent is toluene, diformazan
One or more mixture in benzene, butyl acetate, ethyl acetate, isobutyl acetate, butanol, cyclohexanone.
7. its preparation method of a kind of capsicim environmental protection type anti-pollution paint as described in claim 1-6 is any, it is characterised in that
Comprise the following steps that：
(1) supplementary material prepares, and prepares each component by weight percentage respectively；
(2) filled with other each liquid components after first step (1) middle and high concentration chilli oil oleoresin solvent is fully dissolved completely
Divide well mixed, then by the well mixed liquid component of solid constituent addition, be well mixed after stirring, grinding and obtained final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250456.7A CN106905780A (en) | 2017-04-17 | 2017-04-17 | A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710250456.7A CN106905780A (en) | 2017-04-17 | 2017-04-17 | A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106905780A true CN106905780A (en) | 2017-06-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710250456.7A Pending CN106905780A (en) | 2017-04-17 | 2017-04-17 | A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110358396A (en) * | 2019-08-09 | 2019-10-22 | 江苏海晟涂料有限公司 | A kind of long-acting controlled release marine antifouling coating |
| CN110437689A (en) * | 2019-08-09 | 2019-11-12 | 江苏海晟涂料有限公司 | A kind of low-surface-energy environment-friendly type marine antifouling coating |
| CN114032683A (en) * | 2021-11-15 | 2022-02-11 | 东华大学 | Polyformaldehyde fiber for breeding net and preparation method thereof |
| CN114702879A (en) * | 2022-04-02 | 2022-07-05 | 瑞格特新材料科技(佛山市)有限公司 | Anti-corrosion antifouling coating and preparation method thereof |
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|---|---|---|---|---|
| US5397385A (en) * | 1994-03-28 | 1995-03-14 | Watts; James L. | Anti-fouling coating composition containing capsaicin |
| CN1557896A (en) * | 2004-02-11 | 2004-12-29 | 国家***天津海水淡化与综合利用研 | Environmental protection composite antifouling paint |
| CN102732122A (en) * | 2012-07-24 | 2012-10-17 | 中国科学院理化技术研究所 | Long-acting self-polishing antifouling paint and preparation method thereof |
| CN105400270A (en) * | 2015-12-03 | 2016-03-16 | 昆明七零五所科技发展总公司 | Grease for driving marine biological pollution |
| CN106280820A (en) * | 2016-07-27 | 2017-01-04 | 上海巨峰化工有限公司 | A kind of fluorine silicon acrylate paint |
-
2017
- 2017-04-17 CN CN201710250456.7A patent/CN106905780A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5397385A (en) * | 1994-03-28 | 1995-03-14 | Watts; James L. | Anti-fouling coating composition containing capsaicin |
| CN1557896A (en) * | 2004-02-11 | 2004-12-29 | 国家***天津海水淡化与综合利用研 | Environmental protection composite antifouling paint |
| CN102732122A (en) * | 2012-07-24 | 2012-10-17 | 中国科学院理化技术研究所 | Long-acting self-polishing antifouling paint and preparation method thereof |
| CN105400270A (en) * | 2015-12-03 | 2016-03-16 | 昆明七零五所科技发展总公司 | Grease for driving marine biological pollution |
| CN106280820A (en) * | 2016-07-27 | 2017-01-04 | 上海巨峰化工有限公司 | A kind of fluorine silicon acrylate paint |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110358396A (en) * | 2019-08-09 | 2019-10-22 | 江苏海晟涂料有限公司 | A kind of long-acting controlled release marine antifouling coating |
| CN110437689A (en) * | 2019-08-09 | 2019-11-12 | 江苏海晟涂料有限公司 | A kind of low-surface-energy environment-friendly type marine antifouling coating |
| CN114032683A (en) * | 2021-11-15 | 2022-02-11 | 东华大学 | Polyformaldehyde fiber for breeding net and preparation method thereof |
| CN114702879A (en) * | 2022-04-02 | 2022-07-05 | 瑞格特新材料科技(佛山市)有限公司 | Anti-corrosion antifouling coating and preparation method thereof |
| CN114702879B (en) * | 2022-04-02 | 2023-03-14 | 瑞格特新材料科技(佛山市)有限公司 | Anti-corrosion antifouling coating and preparation method thereof |
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