CN106893874B - 一种从氨性含镍废水中回收镍的方法 - Google Patents
一种从氨性含镍废水中回收镍的方法 Download PDFInfo
- Publication number
- CN106893874B CN106893874B CN201710093587.9A CN201710093587A CN106893874B CN 106893874 B CN106893874 B CN 106893874B CN 201710093587 A CN201710093587 A CN 201710093587A CN 106893874 B CN106893874 B CN 106893874B
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- Prior art keywords
- nickel
- ammonia
- waste water
- organic phase
- containing waste
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 204
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 101
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000002351 wastewater Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 41
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 38
- 239000012074 organic phase Substances 0.000 claims abstract description 43
- 238000000605 extraction Methods 0.000 claims abstract description 39
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 36
- NBFQLHGCEMEQFN-UHFFFAOYSA-N N.[Ni] Chemical compound N.[Ni] NBFQLHGCEMEQFN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000008346 aqueous phase Substances 0.000 claims abstract description 17
- 238000000638 solvent extraction Methods 0.000 claims abstract description 14
- 238000000622 liquid--liquid extraction Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000003085 diluting agent Substances 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- 238000011084 recovery Methods 0.000 claims abstract description 5
- 230000008929 regeneration Effects 0.000 claims abstract description 4
- 238000011069 regeneration method Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 3
- 239000011593 sulfur Substances 0.000 claims abstract description 3
- 230000008569 process Effects 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000003350 kerosene Substances 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 2
- JHNRZXQVBKRYKN-VQHVLOKHSA-N (ne)-n-(1-phenylethylidene)hydroxylamine Chemical compound O\N=C(/C)C1=CC=CC=C1 JHNRZXQVBKRYKN-VQHVLOKHSA-N 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 238000011017 operating method Methods 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- ANCRJJPPHRNUON-UHFFFAOYSA-N n-(1-phenylundecylidene)hydroxylamine Chemical compound CCCCCCCCCCC(=NO)C1=CC=CC=C1 ANCRJJPPHRNUON-UHFFFAOYSA-N 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 13
- 230000009514 concussion Effects 0.000 description 10
- 238000013517 stratification Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 4
- UHSURKDCQCGNGM-UHFFFAOYSA-N 5-(2-hydroxyimino-2-phenylethyl)nonan-2-ol Chemical class CCCCC(CCC(C)O)CC(=NO)C1=CC=CC=C1 UHSURKDCQCGNGM-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 229910018095 Ni-MH Inorganic materials 0.000 description 2
- 229910018477 Ni—MH Inorganic materials 0.000 description 2
- 241000255964 Pieridae Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009854 hydrometallurgy Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000009615 deamination Effects 0.000 description 1
- 238000006481 deamination reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- -1 it is green Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- SPIFDSWFDKNERT-UHFFFAOYSA-N nickel;hydrate Chemical compound O.[Ni] SPIFDSWFDKNERT-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710093587.9A CN106893874B (zh) | 2017-02-21 | 2017-02-21 | 一种从氨性含镍废水中回收镍的方法 |
Applications Claiming Priority (1)
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CN201710093587.9A CN106893874B (zh) | 2017-02-21 | 2017-02-21 | 一种从氨性含镍废水中回收镍的方法 |
Publications (2)
Publication Number | Publication Date |
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CN106893874A CN106893874A (zh) | 2017-06-27 |
CN106893874B true CN106893874B (zh) | 2018-01-05 |
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CN201710093587.9A Active CN106893874B (zh) | 2017-02-21 | 2017-02-21 | 一种从氨性含镍废水中回收镍的方法 |
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Families Citing this family (1)
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CN107746951A (zh) * | 2017-09-26 | 2018-03-02 | 北京矿冶研究总院 | 一种硫酸盐溶液中镍的分离方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004108973A1 (en) * | 2003-06-06 | 2004-12-16 | Cytec Technology Corp. | Solvent extraction composition comprising sulphonic acid with a 4-(alpha branched) acyl-(3h)-pyrazol-3-ones and processes of metal extraction |
CN101428933A (zh) * | 2008-12-09 | 2009-05-13 | 中南大学 | 镍氨废水生物制剂配合水解-吹脱处理方法 |
CN105152388A (zh) * | 2015-07-13 | 2015-12-16 | 江苏凯力克钴业股份有限公司 | 镍、钴生产企业萃余废水的深度处理回收方法 |
CN105219965A (zh) * | 2015-10-07 | 2016-01-06 | 天祝宏达经贸有限责任公司 | 利用含镍电镀污泥、镍废催化剂、废镍渣提取镍、铜的方法 |
CN105861827A (zh) * | 2016-04-08 | 2016-08-17 | 中南大学 | 一种用于多金属溶液萃取分离的酸碱耦合萃取体系及其应用 |
-
2017
- 2017-02-21 CN CN201710093587.9A patent/CN106893874B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004108973A1 (en) * | 2003-06-06 | 2004-12-16 | Cytec Technology Corp. | Solvent extraction composition comprising sulphonic acid with a 4-(alpha branched) acyl-(3h)-pyrazol-3-ones and processes of metal extraction |
CN101428933A (zh) * | 2008-12-09 | 2009-05-13 | 中南大学 | 镍氨废水生物制剂配合水解-吹脱处理方法 |
CN105152388A (zh) * | 2015-07-13 | 2015-12-16 | 江苏凯力克钴业股份有限公司 | 镍、钴生产企业萃余废水的深度处理回收方法 |
CN105219965A (zh) * | 2015-10-07 | 2016-01-06 | 天祝宏达经贸有限责任公司 | 利用含镍电镀污泥、镍废催化剂、废镍渣提取镍、铜的方法 |
CN105861827A (zh) * | 2016-04-08 | 2016-08-17 | 中南大学 | 一种用于多金属溶液萃取分离的酸碱耦合萃取体系及其应用 |
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Effective date of registration: 20230323 Address after: 410116 room 402, 4 / F, building A1, lingzhi Industrial Park, No. 128 Jinhai Road, Yuhua District, Changsha City, Hunan Province Patentee after: HUNAN BOE ENVIRONMENT PROTECTION TECHNOLOGY CO.,LTD. Address before: 410083 Hunan province Changsha Lushan Road No. 932 Patentee before: CENTRAL SOUTH University |
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CP03 | Change of name, title or address |
Address after: 410000 room 402, 4th floor, building A1, lingzhi Industrial Park, No. 128 Jinhai Road, Yuhua District, Changsha City, Hunan Province Patentee after: Zhongke Boyi Environmental Protection Technology Co.,Ltd. Address before: 410116 room 402, 4 / F, building A1, lingzhi Industrial Park, No. 128 Jinhai Road, Yuhua District, Changsha City, Hunan Province Patentee before: HUNAN BOE ENVIRONMENT PROTECTION TECHNOLOGY CO.,LTD. |
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