CN106893490A - 一种水乳型沥青涂料改性用乳液及其制备方法及涂料 - Google Patents
一种水乳型沥青涂料改性用乳液及其制备方法及涂料 Download PDFInfo
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- CN106893490A CN106893490A CN201710177332.0A CN201710177332A CN106893490A CN 106893490 A CN106893490 A CN 106893490A CN 201710177332 A CN201710177332 A CN 201710177332A CN 106893490 A CN106893490 A CN 106893490A
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- 239000000839 emulsion Substances 0.000 title claims abstract description 153
- 238000000576 coating method Methods 0.000 title claims abstract description 67
- 239000011248 coating agent Substances 0.000 title claims abstract description 66
- 239000010426 asphalt Substances 0.000 title claims abstract description 46
- 239000003973 paint Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000178 monomer Substances 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 28
- -1 acrylic ester Chemical class 0.000 claims abstract description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 8
- 239000000706 filtrate Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical group CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 claims description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 2
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims 1
- GHUXAYLZEGLXDA-UHFFFAOYSA-N 8-azido-5-ethyl-6-phenylphenanthridin-5-ium-3-amine;bromide Chemical compound [Br-].C12=CC(N=[N+]=[N-])=CC=C2C2=CC=C(N)C=C2[N+](CC)=C1C1=CC=CC=C1 GHUXAYLZEGLXDA-UHFFFAOYSA-N 0.000 claims 1
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims 1
- 229940038384 octadecane Drugs 0.000 claims 1
- 239000004566 building material Substances 0.000 abstract description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 20
- 239000003643 water by type Substances 0.000 description 15
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- 229910001870 ammonium persulfate Inorganic materials 0.000 description 10
- 239000000376 reactant Substances 0.000 description 10
- 238000007792 addition Methods 0.000 description 9
- 229920001084 poly(chloroprene) Polymers 0.000 description 8
- 238000004945 emulsification Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 230000003254 anti-foaming effect Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000004078 waterproofing Methods 0.000 description 5
- 150000003926 acrylamides Chemical class 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical class CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000009829 pitch coating Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007718 adhesive strength test Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical class CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical class CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
Description
样品 | 拉伸强度/MPa | 断裂延伸率/MPa | 粘结强度/MPa |
1号涂料样品 | 0.81 | 975 | 0.83 |
2号涂料样品 | 0.83 | 986 | 0.75 |
3号涂料样品 | 0.78 | 895 | 0.86 |
4号涂料样品 | 0.73 | 913 | 0.89 |
5号涂料样品 | 0.75 | 932 | 0.88 |
6号涂料样品 | 0.3 | 605 | 0.92 |
7号涂料样品 | 0.85 | 1056 | 0.46 |
样品 | 是否起泡 |
1号涂料样品 | 否 |
2号涂料样品 | 否 |
3号涂料样品 | 否 |
4号涂料样品 | 否 |
5号涂料样品 | 否 |
6号涂料样品 | 否 |
7号涂料样品 | 是 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710177332.0A CN106893490B (zh) | 2017-03-23 | 2017-03-23 | 一种水乳型沥青涂料改性用乳液及其制备方法及涂料 |
Applications Claiming Priority (1)
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CN201710177332.0A CN106893490B (zh) | 2017-03-23 | 2017-03-23 | 一种水乳型沥青涂料改性用乳液及其制备方法及涂料 |
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Publication Number | Publication Date |
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CN106893490A true CN106893490A (zh) | 2017-06-27 |
CN106893490B CN106893490B (zh) | 2019-08-27 |
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CN201710177332.0A Active CN106893490B (zh) | 2017-03-23 | 2017-03-23 | 一种水乳型沥青涂料改性用乳液及其制备方法及涂料 |
Country Status (1)
Country | Link |
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CN (1) | CN106893490B (zh) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325224A (zh) * | 2017-08-08 | 2017-11-07 | 芜湖通全科技有限公司 | 一种沥青涂料改性用乳液的制备方法 |
CN107964069A (zh) * | 2017-12-24 | 2018-04-27 | 王琪宇 | 一种高弹性丙烯酸酯防水涂料的制备方法 |
CN108178933A (zh) * | 2017-12-29 | 2018-06-19 | 重庆市盛百利防水建材有限公司 | 一种改性沥青及其制备方法 |
CN109233379A (zh) * | 2018-10-12 | 2019-01-18 | 扬州中涂科技集团有限公司 | 一种高弹性防水沥青乳液 |
CN109355041A (zh) * | 2018-10-25 | 2019-02-19 | 陈云 | 一种沥青改性防水乳液及其制备方法 |
CN109553717A (zh) * | 2018-11-15 | 2019-04-02 | 东方雨虹民用建材有限责任公司 | 一种疏水型丙烯酸酯类聚合物乳液和混凝土界面剂及其制备方法 |
CN111234640A (zh) * | 2020-01-17 | 2020-06-05 | 日照广大建筑材料有限公司 | 一种喷涂速凝用苯丙乳液、制备方法以及在防水涂料中的应用 |
CN112194760A (zh) * | 2020-09-24 | 2021-01-08 | 珠海展辰新材料股份有限公司 | 聚丙烯酸酯乳液及其制备方法 |
CN116589925A (zh) * | 2022-11-10 | 2023-08-15 | 贵州梵亚高新科技有限公司 | 一种高密封防水涂料及其制备方法 |
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US20070148357A1 (en) * | 2005-10-03 | 2007-06-28 | The Sherwin-Williams Company | Fast Hardening Aqueous Coating Composition |
CN101633573A (zh) * | 2009-08-14 | 2010-01-27 | 武汉广益工程咨询有限公司 | 水乳型有机硅复合丙烯酸改性沥青水泥基防水涂料及其制备方法 |
CN103992430A (zh) * | 2013-02-18 | 2014-08-20 | 罗门哈斯公司 | 用于提高弹性墙体和屋顶涂料的防污性和防水性的衣康酸聚合物 |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107325224A (zh) * | 2017-08-08 | 2017-11-07 | 芜湖通全科技有限公司 | 一种沥青涂料改性用乳液的制备方法 |
CN107964069A (zh) * | 2017-12-24 | 2018-04-27 | 王琪宇 | 一种高弹性丙烯酸酯防水涂料的制备方法 |
CN108178933B (zh) * | 2017-12-29 | 2020-06-02 | 重庆市盛百利防水建材有限公司 | 一种改性沥青及其制备方法 |
CN108178933A (zh) * | 2017-12-29 | 2018-06-19 | 重庆市盛百利防水建材有限公司 | 一种改性沥青及其制备方法 |
CN109233379A (zh) * | 2018-10-12 | 2019-01-18 | 扬州中涂科技集团有限公司 | 一种高弹性防水沥青乳液 |
CN109355041A (zh) * | 2018-10-25 | 2019-02-19 | 陈云 | 一种沥青改性防水乳液及其制备方法 |
CN109355041B (zh) * | 2018-10-25 | 2020-07-24 | 广东雄辉市政公用工程有限公司 | 一种沥青改性防水乳液及其制备方法 |
CN109553717A (zh) * | 2018-11-15 | 2019-04-02 | 东方雨虹民用建材有限责任公司 | 一种疏水型丙烯酸酯类聚合物乳液和混凝土界面剂及其制备方法 |
CN109553717B (zh) * | 2018-11-15 | 2021-07-02 | 东方雨虹民用建材有限责任公司 | 一种疏水型丙烯酸酯类聚合物乳液和混凝土界面剂及其制备方法 |
CN111234640A (zh) * | 2020-01-17 | 2020-06-05 | 日照广大建筑材料有限公司 | 一种喷涂速凝用苯丙乳液、制备方法以及在防水涂料中的应用 |
CN111234640B (zh) * | 2020-01-17 | 2022-03-29 | 日照广大建筑材料有限公司 | 一种喷涂速凝用苯丙乳液、制备方法以及在防水涂料中的应用 |
CN112194760A (zh) * | 2020-09-24 | 2021-01-08 | 珠海展辰新材料股份有限公司 | 聚丙烯酸酯乳液及其制备方法 |
CN116589925A (zh) * | 2022-11-10 | 2023-08-15 | 贵州梵亚高新科技有限公司 | 一种高密封防水涂料及其制备方法 |
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