CN106884118A - Forging Electroslag Cladding high-speed steel roll and its manufacture method - Google Patents

Forging Electroslag Cladding high-speed steel roll and its manufacture method Download PDF

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CN106884118A
CN106884118A CN201611244447.9A CN201611244447A CN106884118A CN 106884118 A CN106884118 A CN 106884118A CN 201611244447 A CN201611244447 A CN 201611244447A CN 106884118 A CN106884118 A CN 106884118A
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roll
electroslag
forging
steel
compound
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杨昱东
刘娣
朱学刚
袁乃博
孙满臣
杨保中
党坤会
葛晓红
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Sinosteel Xingtai Machinery and Mill Roll Co Ltd
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Sinosteel Xingtai Machinery and Mill Roll Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/02Die forging; Trimming by making use of special dies ; Punching during forging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D13/00Centrifugal casting; Casting by using centrifugal force
    • B22D13/02Centrifugal casting; Casting by using centrifugal force of elongated solid or hollow bodies, e.g. pipes, in moulds rotating around their longitudinal axis
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/38Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for roll bodies
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16Remelting metals
    • C22B9/18Electroslag remelting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)

Abstract

The invention discloses one kind forging Electroslag Cladding high-speed steel roll and its manufacture method, belong to roll manufacturing technology field, the chemical constituent and its weight/mass percentage composition of outer layer are in roll:Carbon 0.70~1.50%, silicon 0.20~1.20%, manganese 0.20~1.00%, chromium 4.00~12.00%, molybdenum 2.00~6.00%, vanadium 1.00~4.00%, tungsten 0.80~4.00%, nickel≤0.80%, phosphorus≤0.02%, sulphur≤0.02%, remaining is iron.Preparation method includes the shaping of tubular electrode, forging composite steel billet, conditioning treatment, machining and finished heat treatment step.Obtained finished product, body of roll surface hardness is 80~100HSD, and outer layer has excellent wearability, roughness retaining capability high and structure stability high etc., and core and roll neck hardness are 30~45HSD, with excellent toughness, tensile strength high.

Description

Forging Electroslag Cladding high-speed steel roll and its manufacture method
Technical field
The present invention relates to one kind forging Electroslag Cladding high-speed steel roll and its manufacture method, belong to roll manufacturing technology neck Domain.
Background technology
Roll, as the industrial important tool of steel rolling, is the main consumable part of steel rolling equipment.Roll is one kind not With the workpiece for being molded intermetallic composite coating by way of extruding under state, the requirement of its body of roll has anti-wear performance high, height Impact strength, structure stability high, and roll neck is needed with good toughness and tensile strength.Exist to meet roll The body of roll is different with roll neck in use needs, and reduces manufacturing cost generally using various complex methods:Such as centrifugal compound, Quan Chong Wash the technologies such as compound, molten multiple, the rotation Electroslag Claddings of electroslag of compound, CPC.Semi-high speed steel, high speed that wherein centrifugal compound is produced Steel hot roll core is alloy ductile iron, is limited by roll neck intensity and is only used for thin plate hot rolling.With scientific technological advance, ferrite , in the application of hot rolling, and high-performance cold rolled technology etc. is all for the performance steel rolling technology high such as the big Reduction Technology of rolling technique, low temperature Requirements at the higher level are proposed to roller neck intensity and body of roll performance.
In the operation of rolling, when body surface is contacted with red-hot stocking, temperature is raised rapidly Heat Working Rolls, then quilt Rapid water-cooled, the body of roll radially produces very steep thermograde, and then causes the nearly top layer of the body of roll to produce very big alternation heat to answer Power, under the ringing of this alternating thermal stress, body surface gradually produces micro-crack;When occur steel-fastening, skidding, curling round the roll, During the rolling accident such as roll banding, the deformation heat of frictional heat and stocking between stocking and roll increases suddenly in very short time, makes office Portion's roll surface temperature rises rapidly, and metal is expanded herein, forms very huge pressing stress, causes local elasticity's compression, with this Rolling mill power is also substantially increased simultaneously.When combined stress exceedes roll material elastic limit at this temperature, that is, produce Plastic compression deformation;Roll breakage will be caused when combined stress exceedes the ultimate strength of material, so as to cause larger rolling thing Therefore.As current rolled plate develops to high-strength steel, ultrathin strip, rolling rhythm to serialization, the outer layer to tropical roll resists Cool-hot fatigue ability, roll neck tensile strength propose requirement higher, working lining and core that traditional centrifugation is produced Nodular cast iron material progressively will be replaced by higher performance material.
Cold roll will bear very big rolling stress in the course of the work, add rolled piece weld seam, be mingled with, side is split etc. asks Topic, its condition of work is severe, is easily caused instantaneous high-temperature so that cold roll is subject to strong thermal shock, easily causes crackle, glues Roller, peeling are even scrapped.Due to cold roll in the course of the work suffered stress greatly, cold rolling roller surface is often peeling, chip off-falling, The failure modes such as abrasion, therefore it is required that its body surface possesses at a relatively high hardness, wearability and crack resistance, while its roll neck There are bending strength high, enough toughness, it is ensured that counter-bending fatigue strength etc..
It is used for manufacturing material mainly Cr3 and the Cr5 series of cold roll on current domestic and international market, Cr2 series is big multiplex In small-sized cold-rolling mill and the poor reversable cold-rolling machine of part equipment;Cr3 series cold rolls are mostly used for reversable cold-rolling machine And part Large Scale Cold milling train;Current Cr5 series is the main flow material of Chinese forging steel cold roll, most of cold-rolling mills and band The substantially all use Cr5 series of tasks roller of quality requirement Reversible Single Stand Cold Rolling Mill higher and intermediate calender rolls.
With the high speed development of the industries such as automobile, household electrical appliances, electronics, to the quality requirement of flat cold-rolled sheet and silicon steel sheet continuous Improve, to the quality requirement of cold roll also more and more higher.And the cold roll of above-mentioned chromium steel series is in rolled sheet metal or silicon steel sheet When, often occur the phenomenon skidded between working roll and material to be rolled in the operation of rolling;In working roll by using soon Afterwards, many work roll surface roughness are drastically reduced, and directly affect the surface quality and product percent of pass of rolled plate.These Situation be all due to the wearing no resistance of working roll, surface roughness holding capacity difference is caused.Conventional high-carbon chromium steel cold roll Due to being limited by material itself, while possessing higher abrasion resistance, it is difficult to possess good anti-accident ability, therefore cold Roll under the use environment higher to the requirement of cold roll combination property such as silicon steel, the limitation of conventional high-carbon chromium steel cold roll material Just highlight.Current these problems are general to be solved by frequently changing working roll or carrying out texturing and chromium plating to working roll, But these methods can not only reduce cold-rolling mill operating rate, manufacturing schedule is influenceed, and working roll texturing and chromium plating are expensive, Production cost is increased, while also result in environmental pollution, should not on a large scale, apply for a long time.
It is higher comprehensive to obtain with the continuous improvement required combination properties such as cold roll wearability, anti-accident performances Performance is closed, Cold Work Roll Material alloying levels are improved, making alloying level cold roll higher has turned into cold rolled sheet With the developing direction of roller, forging high-speed steel, semi-high speed steel cold roller turn into the latest development direction of cold roll material.
The content of the invention
The technical problem to be solved in the invention is to provide a kind of forging Electroslag Cladding high-speed steel roll and its manufacture method, The working lining of the roll barrel has high-wearing feature, roughness retaining capability high and a structure stability high, and roll neck has high strong Toughness, adapts to current hot roll higher and cold roll job requirement.
In order to solve the above technical problems, the technical solution adopted in the present invention is:
One kind forging Electroslag Cladding high-speed steel roll, chemical constituent and its weight/mass percentage composition in body of roll outer layer are:C 0.70~1.50%, Si 0.20~1.20%, Mn 0.20~1.00%, Cr 4.00~12.00%, Mo 2.00~ 6.00%, V 1.00~4.00%, W 0.80~4.00%, Ni≤0.80%, P≤0.02%, S≤0.02%, remaining is Fe With inevitable impurity;Core is that low-alloy steel or body of roll working lining use the forged steel working roll scrapped.
Technical solution of the present invention further improvement is that:Chemical constituent and its weight/mass percentage composition in body of roll outer layer For:C 0.90~1.30%, Si 0.40~1.00%, Mn 0.40~0.90%, Cr 8.00~12.00%, Mo 3.50~ 5.00%, V 1.50~3.00%, W 0.90~2.00%, Ni≤0.60%, P≤0.02%, S≤0.02%, remaining is Fe With inevitable impurity.
A kind of manufacture method for forging Electroslag Cladding high-speed steel roll, comprises the following steps that:
A, refining tubular electrode:Raw material is smelted in smelting furnace, then molten steel is placed in refining furnace, to molten steel Refined, molten steel is placed in ladle after the completion of refining, incited somebody to action under the effect of centrifuge power and under the conditions of gas shield Molten steel casts tubular electrode ingot, is made the compound electroslag ingots of ESR using electroslag remelting complex method afterwards;
B, forging composite steel billet:By the compound electroslag ingots of ESR obtained in step A by heating, insulation, die forging into roller stock;
C, conditioning treatment:Conditioning treatment is carried out to roller stock, 1000~1050 DEG C of insulation 18~25h after-blow are first heated to Air cooling;Air cooling after 800~850 DEG C of 15~20h of insulation is again heated to, temper is finally carried out, temperature is 630~ 680 DEG C, tempering time is 70~100h;
D, machining and finished heat treatment:Roller stock is carried out into roughing, through ultrasonic examination inspection it is qualified after, to roller stock Body of roll top layer carry out continuous induction hardening, hardening heat is 1100~1210 DEG C, and roller stock is carried out into temper afterwards, is tempered Temperature is 460~580 DEG C, and room temperature is air cooled to after 20~30h of insulation;
After the completion of tempering, roller stock is finished by required size, be made roll, carried out ultrasound examination, hardness and survey Examination and microstructure examination.
Technical solution of the present invention further improvement is that:Smelting temperature is 1580~1680 DEG C, refining temperature in step A It it is 1600~1800 DEG C, the protective gas for being used is nitrogen or inert gas.
Technical solution of the present invention further improvement is that:After tubular electrode ingot is made in step A, tubular electrode ingot is added Hot to 700~750 DEG C carry out isothermal annealing, and compound electroslag remelting system is then carried out to tubular electrode ingot and solid-state low-alloy rod iron Electroslag ingot is combined into ESR.
Technical solution of the present invention further improvement is that:The heating-up temperature of the compound electroslag ingots of ESR is 1080 in step B ~1250 DEG C, soaking time is 30~40h.
Technical solution of the present invention further improvement is that:Temper needs to repeat three times, three times times in step D The fiery common 80h of soaking time.
By adopting the above-described technical solution, the technological progress that the present invention is obtained is:
In the present invention in the chemical constituent of steel, Cr increased the quenching degree of steel, improve steel hardness and wearability and Steel will not be made to become fragile;Mo improves the quenching degree and heat resistance of steel, prevents temper brittleness, keeps the hardness stabilization of steel, increased Drag of the steel to deformation, cracking and abrasion etc..The content of the carbide formers such as Cr, Mo, V, W of the present invention is higher, formation Larger Aliquation carbide Cr7C3Impart the excellent wearability of cold roll and roughness retaining capability high, the height of small and dispersed distribution Hardness carbide Mo2C, VC, WC, impart cold roll matrix and obtain high rigidity at high temperature tempering and have high tissue steady It is qualitative, it is ensured that high-speed steel roll has excellent wearability, a roughness retaining capability high, thus the cold roll need not be entered Row chromium plating is just used directly for the rolling of high-grade sheet material, and in the course of work of roll, thermal shock resistance is substantially better than Conventional roll, can make Heat Working Rolls more suitable for rolling high-strength degree wide plate band, and its surface quality is substantially better than common high-speed steel Heat Working Rolls.
Using cold roll obtained in material of the present invention, the body of roll surface hardness of its roll is 86~96HSD, with excellent Wearability, roughness retaining capability high and structure stability high.Applied on accident rate milling train higher, cold roll is comprehensively used Performance can be significantly improved;Cold roll has excellent abrasion resistance properties, is applied on tandem mill after-frame and planisher, reduces plating The processing step of chromium, greatly reduces production cost, also eliminates the environmental pollution that chromium plating is caused.
Using hot roll obtained in material of the present invention, the body of roll surface hardness of its roll is 80~86HSD, with excellent Wearability, excellent oxide-film ability and structure stability high.Applied on rolling high-strength degree sheet mill, hot roll comprehensively makes Can be significantly improved with performance;Hot rolled plate surface quality can also be significantly improved simultaneously.Realization is hot under certain conditions Roll plate and replace cold-reduced sheet, reduce steel rolling process step, greatly reduce production cost, energy saving consumption.
Electroslag remelting complex method of the invention, is the rapid sequential solidification complex method of uniform orientation, is thoroughly avoided Large-scale steel ingot center solidifying segregation, improves compound ingot quality, realizes that different use functions use different materials best fit. Heat treatment method ensure that the performance of roll, its quenching, the temperature and time of tempering, roll is had optimal mechanical properties and is made Use performance.
The shaping of tubular electrode, two kinds of different chemical constituent materials electroslag metallurgy complex methods produce compound steel ingot, most The compound electroslag ingots of ESR being made eventually, body of roll outer layer is high alloy high speed steel material, and core and roll neck are low-alloy steel material.
Obtained forging Electroslag Cladding high-speed steel roll of the invention, body of roll surface hardness is 80~100HSD, and outer layer has Excellent wearability, roughness retaining capability high and structure stability high etc., core and roll neck hardness are 30~45HSD, are had Excellent toughness, tensile strength high.Production technology of the invention can save substantial amounts of alloy resource, meet cold rolling, hot rolling Working roll rolling high-performance sheet material needs, and production cost is reduced, with application value higher.
Specific embodiment
The present invention is described in further details with reference to embodiment:
Embodiment 1
One kind forging Electroslag Cladding high-speed steel roll, the chemical constituent and its weight/mass percentage composition of outer layer in the cold roll Design object is:C 0.9~1.0%, Si 0.4~0.6%, Mn 0.4~0.9%, Cr 5.0~8.0%, Mo 3.8~ 4.0%, V 1.5~2.0%, W 0.90~2.00%, Ni 0.5~0.6%, P≤0.02%, S≤0.02%, remaining is Fe With inevitable impurity.Core material is:C 0.8~1.00%, Si 0.40~0.80%, Mn 0.40~1.00%, Cr 2.00~6.00%, Mo 0.15~0.70%, V 0.05~0.20%, Ni≤0.80%, P≤0.02%, S≤0.02%.
The preparation method of the cold roll is comprised the following steps that:
A, refining tubular steel ingot:Required raw material is smelted in smelting furnace, smelting temperature is 1580~1680 DEG C, this Embodiment is 1630 DEG C, and then molten steel is placed in refining furnace, starts to refine molten steel, and refining temperature is 1600~1800 DEG C, the present embodiment is 1650 DEG C, and molten steel is placed in ladle after the completion of refining, (such as nitrogen or inertia under the conditions of gas shield Gases argon), carry out centrifugal casting into tubular electrode ingot.
By tubular electrode ingot be heated to 720 DEG C carry out isothermal annealing after, to tubular electrode ingot and solid-state low-alloy rod iron (or Body of roll working lining using the forged steel working roll scrapped, as core constituents) carry out compound electroslag remelting and be made ESR compound electrics Slag steel ingot, concretely comprises the following steps:By tubular electrode ingot and solid-state low-alloy rod, (or body of roll working lining has used the forged steel scrapped to work Roller) it is immersed in the slag bath of junker mold, electric current is passed through, electric current is by electrode and tubular electrode ingot is fused into metal by heating Liquid, molten metal after fusing reaches the bottom of junker mold, and gradually (or body of roll working lining is using scrapping with solid-state low-alloy rod Forged steel working roll) be frozen into new compound steel ingot, again composite solidification into middle part top layer steel ingot be the ESR that finally gives Compound electroslag ingot.
Chemical constituent analysis is carried out to the compound electroslag ingot outer layers of ESR, obtain the compound electroslag ingots of ESR chemical constituent and Its weight/mass percentage composition is:C 0.95.%, Si 0.5%, Mn 0.4%, Cr 8.0%, Mo 4.0%, V 2.0%, W 1.5%, Ni 0.6%, P 0.02%, S 0.02%, remaining is Fe and inevitable impurity.Core chemical constituent and its matter Measuring percentage composition is:C 0.82.%, Si 0.5%, Mn 0.4%, Cr 3.0%, Mo 0.5%, V 0.12%, Ni 0.4%, P 0.02%, S 0.02%, remaining is Fe and inevitable impurity;
B, forging composite steel billet:After the compound electroslag ingots of ESR that step A is obtained carry out 1200 DEG C of heating, insulation 35h, Come out of the stove, by being made roller stock after a series of deformation operations of die forging;
C, conditioning treatment:Conditioning treatment is carried out to roller stock, quenching after 1030 DEG C of insulation 20h is first heated to;Again Air cooling after 820 DEG C of insulation 15h is heated to, temper is finally carried out, temperature is 650 DEG C, and tempering time is 80h;
D, machining and finished heat treatment:Roller stock size as requested is first carried out into mechanical roughing, by ultrasonic wave After flaw detection is qualified, sensing air blast quenching is carried out to the body of roll top layer of roller stock using Induction Hardening Machine, hardening heat is 1100~1180 DEG C.
Temper is carried out to roller stock after the completion of quenching:Roller stock is heated to 460~560 DEG C, room is air cooled to after insulation 30h Temperature.Temper after the completion of quenching needs to repeat three times, second, the temperature of third time be 460~560 DEG C, second, the tempering insulation time of third time be respectively 20h, 30h, three common 80h of tempering insulation time.
After the completion of tempering, roller stock is finished according to delivery gauge requirement, final desired cold roll is obtained.Afterwards Ultrasound examination, hardness test, microstructure examination are carried out to cold roll.
The body of roll top layer Shore hardness for obtaining cold roll through last test is 90~96HSD, ultrasound examination and metallographic group Knit and reach requirement.
Embodiment 2
Processing step is identical with the processing step in embodiment 1 in embodiment 2, and the difference with embodiment 1 is:
The chemical constituent of hot roll outer layer and its weight/mass percentage composition design object are in the present embodiment:
C 1.2~1.3%, Si 0.60~0.9%, Mn 0.40~0.9%, Cr 10.8~12.0%, Mo 3.8~ 4.0%, V 2.8~3.0%, W 1.4~1.5%, Ni 0.4~0.6%, P≤0.015%, S≤0.015%, remaining is Fe With inevitable impurity.The design object of core chemical constituent and its weight/mass percentage composition is:C 0.40~0.80%, Si 0.20~0.80%, Mn 0.20~1.00%, Cr 0.80~1.20%, Mo 0.15~0.60%, Ni≤0.80%, P≤ 0.02%, S≤0.02%.
By carrying out chemical constituent analysis to Electroslag Cladding steel ingot, chemical constituent and its quality percentage in electroslag ingot outer layer Content is:C 1.26%, Si 0.8%, Mn 0.61%, Cr 11.0%, Mo 3.9%, V 3.0%, W 1.2%, Ni 0.4%, P 0.014%, S 0.003%, remaining is Fe and inevitable impurity.Core chemical constituent and its quality percentage contain Amount be:C 0.43.%, Si 0.46%, Mn 0.42%, Cr 0.8%, Mo 0.4%, Ni 0.6%, P 0.02%, S 0.02%, remaining is Fe and inevitable impurity.
After tubular electrode ingot is made in step A, by tubular electrode ingot be heated to 715 DEG C carry out isothermal annealing after, to tubular Electrode ingot carries out compound electroslag remelting and is made the compound electroslag ingots of ESR with solid-state low-alloy rod iron.
After the compound electroslag ingots of ESR that will be obtained in step B carry out 1120 DEG C of heating, insulation 30h, come out of the stove, by die forging Roller stock is made after a series of deformation operations;
Step C conditioning treatments:Conditioning treatment is carried out to roller stock, quenching after 1015 DEG C of insulation 18h is first heated to; Air cooling after 810 DEG C of insulation 17h is again heated to, temper is finally carried out, temperature is 640 DEG C, and tempering time is 70h;
Hardening heat in step D is 1100 DEG C;Three temperatures are respectively 540 DEG C, 550 DEG C, 560 DEG C, three times and return The fiery time is respectively 23h, 28h, 29h.
The body of roll top layer Shore hardness that hot roll is obtained after the completion of final production is 82~84HSD, ultrasound examination and gold Phase constitution reaches requirement.
Embodiment 3
Processing step is identical with the processing step in embodiment 1 in embodiment 3, and the difference with embodiment 1 is:This implementation The outer layer chemical constituent and its weight/mass percentage composition design object of cold roll are in example:
C 0.9~1.0%, Si 0.9~1.0%, Mn 0.40~0.50%, Cr 11.5~12.0%, Mo 3.8~ 4.0%, V 3.8~4.0%, W 0.9~1.0%, Ni 0.35~0.45%, P≤0.01%, S≤0.01%, remaining is Fe With inevitable impurity.The design object of core chemical constituent and its weight/mass percentage composition is:C 0.40~0.60%, Si 0.20~0.80%, Mn 0.20~0.80%, Cr 0.80~1.20%, Mo 0.15~0.60%, Ni≤0.80%, P≤ 0.02%, S≤0.02%.
Chemical constituent analysis is carried out by compound electroslag ingot, chemical constituent and its quality percentage in electroslag ingot outer layer Content is:C 0.96%, Si 1.0%, Mn 0.56%, Cr 12.0%, Mo 3.8%, V 4.0%, W 1.0%, Ni 0.4%, P 0.01%, S 0.009%, remaining is Fe and inevitable impurity.Core chemical constituent and its quality percentage contain Measure and be::C 0.45%, Si 0.570%, Mn 0.66%, Cr 0.90%, Mo 0.60%, Ni 0.70%, P 0.020%, S 0.012%.
After tubular electrode ingot is made in step A, by tubular electrode ingot be heated to 700 DEG C carry out isothermal annealing after, to tubular Electrode ingot carries out compound electroslag remelting and is made the compound electroslag ingots of ESR with solid-state low-alloy rod iron.
After the compound electroslag ingots of ESR that will be obtained in step B carry out 1080 DEG C of heating, insulation 38h, come out of the stove, by die forging Roller stock is made after a series of deformation operations;
Step C conditioning treatments:Conditioning treatment is carried out to roller stock, quenching after 1025 DEG C of insulation 22h is first heated to; Air cooling after 830 DEG C of insulation 18h is again heated to, temper is finally carried out, temperature is 660 DEG C, and tempering time is 76h;
Hardening heat in step D is 1120 DEG C;Three times temperature is respectively 510 DEG C, 540 DEG C, 570 DEG C of three tempering Time is respectively 25h, 30h, 25h.
The body of roll top layer Shore hardness that cold roll is obtained after the completion of final production is 90~93HSD, ultrasound examination and gold Phase constitution reaches requirement.
Embodiment 4
Processing step is identical with the processing step in embodiment 1 in embodiment 4, and the difference with embodiment 1 is:This implementation The outer layer chemical constituent and its weight/mass percentage composition design object of hot roll are in example:
C 1.1~1.2%, Si 0.8~1.2%, Mn 0.40~0.60%, Cr 8.5~9.5%, Mo 4.8~ 5.0%, V 2.5~3.0%, W 1.3~1.4%, Ni 0.05~0.15%, P≤0.02%, S≤0.018%, remaining is Fe With inevitable impurity.The design object of core and roll neck regiochemistry component and its weight/mass percentage composition is:C 0.40~ 0.80%, Si 0.20~0.60%, Mn 0.20~0.60%, Cr 0.80~1.20%, Mo 0.15~0.60%, Ni≤ 0.80%, P≤0.02%, S≤0.02%.
Chemical constituent analysis is carried out by compound electroslag ingot, chemical constituent and its quality percentage in electroslag ingot outer layer Content is:C 1.2%, Si 1.0%, Mn 0.57%, Cr 9.1%, Mo 4.8%, V 2.8%, W 1.35%, Ni 0.1%, P 0.018%, S 0.015%, remaining is Fe and inevitable impurity.Core and roll neck regiochemistry component and its Weight/mass percentage composition is:C 0.60%, Si 0.50%, Mn 0.60%, Cr 1.20%, Mo 0.35%, Ni 0.40%, P 0.018%, S 0.012%.
After tubular electrode ingot is made in step A, by tubular electrode ingot be heated to 740 DEG C carry out isothermal annealing after, to tubular Electrode ingot carries out compound electroslag remelting and is made the compound electroslag ingots of ESR with solid-state low-alloy rod iron.
After the compound electroslag ingots of ESR that will be obtained in step B carry out 1200 DEG C of heating, insulation 38h, come out of the stove, by die forging Roller stock is made after a series of deformation operations;
Step C conditioning treatments:Conditioning treatment is carried out to roller stock, quenching after 1040 DEG C of insulation 23h is first heated to; Air cooling after 840 DEG C of insulation 19h is again heated to, temper is finally carried out, temperature is 670 DEG C, and tempering time is 90h;
Hardening heat in step D is 1100 DEG C;Temperature is respectively 560 DEG C, 570 DEG C, 580 DEG C, during three tempering Between be respectively 23h, 28h, 29h.
The body of roll top layer Shore hardness that hot roll is obtained after the completion of final production is 82~85HSD, ultrasound examination and gold Phase constitution reaches requirement.
Embodiment 5
Processing step is identical with the processing step in embodiment 1 in embodiment 5, and the difference with embodiment 1 is:This implementation The outer layer chemical constituent and its weight/mass percentage composition of cold roll are in example:
C 1.0~1.1%, Si 0.2~0.3%, Mn 0.9~1.0%, Cr 8.5~9.0%, Mo 3.5~4.0%, V 2.0~2.2%, W 1.2~1.5%, Ni 0.7~0.8%, P≤0.015%, S≤0.01%, remaining is Fe and can not keep away The impurity exempted from.Core and roll neck regiochemistry component and its weight/mass percentage composition are:C 0.43%, Si 0.42%, Mn 0.6%, Cr 5.0%, Mo 0.5%, Ni 0.8%, P 0.013%, S 0.008%, remaining is Fe miscellaneous with inevitable Matter.
After tubular electrode ingot is made in step A, by tubular electrode ingot be heated to 750 DEG C carry out isothermal annealing after, to tubular Electrode ingot carries out compound electroslag remelting and is made the compound electroslag ingots of ESR with solid-state low-alloy rod iron.
After the compound electroslag ingots of ESR that will be obtained in step B carry out 1250 DEG C of heating, insulation 40h, come out of the stove, by die forging Roller stock is made after a series of deformation operations;
Step C conditioning treatments:Conditioning treatment is carried out to roller stock, quenching after 1050 DEG C of insulation 25h is first heated to; Air cooling after 850 DEG C of insulation 20h is again heated to, temper is finally carried out, temperature is 680 DEG C, and tempering time is 100h;
Hardening heat in step D is 1140 DEG C;Three temperatures are respectively 500 DEG C, 520 DEG C, 540 DEG C, three times and return The fiery time is respectively 25h, 28h, 27h.
The body of roll top layer Shore hardness that cold roll is obtained after the completion of final production is 92~96HSD, ultrasound examination and gold Phase constitution reaches requirement.
Compared with conventional cold roll, thermal shock resistance is good using the cold roll for being produced of the invention in the course of the work, The service life extension of cold roll, without frequently changing cold roll again, accelerates manufacturing schedule.
Compared with conventional hot roll, thermal shock resistance is good using the hot roll for being produced of the invention in the course of the work, The service life extension of hot roll, roll neck tensile strength can be realized more than more than 800MPa.

Claims (7)

  1. It is 1. a kind of to forge Electroslag Cladding high-speed steel roll, it is characterised in that:Chemical constituent and its quality percentage in body of roll outer layer Content is:C 0.70~1.50%, Si 0.20~1.20%, Mn 0.20~1.00%, Cr 4.00~12.00%, Mo 2.00~6.00%, V 1.00~4.00%, W 0.80~4.00%, Ni≤0.80%, P≤0.02%, S≤0.02%, its It is remaining for Fe and inevitable impurity;Core is that low-alloy steel or body of roll working lining use the forged steel working roll scrapped.
  2. It is 2. according to claim 1 to forge Electroslag Cladding high-speed steel roll, it is characterised in that:Chemical group in body of roll outer layer Divide and its weight/mass percentage composition is:C 0.90~1.30%, Si 0.40~1.00%, Mn 0.40~0.90%, Cr 8.00~ 12.00%, Mo 3.50~5.00%, V 1.50~3.00%, W 0.90~2.00%, Ni≤0.60%, P≤0.02%, S ≤ 0.02%, remaining is Fe and inevitable impurity.
  3. 3. it is a kind of forge Electroslag Cladding high-speed steel roll manufacture method, it is characterised in that comprise the following steps that:
    A, refining tubular electrode:Raw material is smelted in smelting furnace, then molten steel is placed in refining furnace, molten steel is carried out , be placed in molten steel in ladle after the completion of refining by refining, by molten steel under the effect of centrifuge power and under the conditions of gas shield Tubular electrode ingot is cast, the compound electroslag ingots of ESR is made using electroslag remelting complex method afterwards;
    B, forging composite steel billet:By the compound electroslag ingots of ESR obtained in step A by heating, insulation, die forging into roller stock;
    C, conditioning treatment:Conditioning treatment is carried out to roller stock, 1000~1050 DEG C of insulation 18~25h after-blow is first heated to air-cooled But;Air cooling after 800~850 DEG C of 15~20h of insulation is again heated to, temper is finally carried out, temperature is 630~680 DEG C, Tempering time is 70~100h;
    D, machining and finished heat treatment:Roller stock is carried out into roughing, through ultrasonic examination inspection it is qualified after, to the roller of roller stock Body top layer carries out continuous induction hardening, and hardening heat is 1100~1210 DEG C, and roller stock is carried out into temper, temperature afterwards It is 460~580 DEG C, room temperature is air cooled to after 20~30h of insulation;
    After the completion of tempering, roller stock is finished by required size, is made roll, carry out ultrasound examination, hardness test and Microstructure examination.
  4. 4. it is according to claim 3 forging Electroslag Cladding high-speed steel roll manufacture method, it is characterised in that:In step A Smelting temperature is 1580~1680 DEG C, and refining temperature is 1600~1800 DEG C, and the protective gas for being used is nitrogen or indifferent gas Body.
  5. 5. it is according to claim 3 forging Electroslag Cladding high-speed steel roll manufacture method, it is characterised in that:In step A After being made tubular electrode ingot, tubular electrode ingot is heated into 700~750 DEG C carries out isothermal annealing, then to tubular electrode ingot with Solid-state low-alloy rod iron carries out compound electroslag remelting and is made the compound electroslag ingots of ESR.
  6. 6. it is according to claim 3 forging Electroslag Cladding high-speed steel roll manufacture method, it is characterised in that:In step B The heating-up temperature of the compound electroslag ingots of ESR is 1080~1250 DEG C, and soaking time is 30~40h.
  7. 7. it is according to claim 3 forging Electroslag Cladding high-speed steel roll manufacture method, it is characterised in that:In step D Temper needs to repeat three times, three common 80h of tempering insulation time.
CN201611244447.9A 2016-12-29 2016-12-29 Forging Electroslag Cladding high-speed steel roll and its manufacture method Pending CN106884118A (en)

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CN109594018A (en) * 2018-12-26 2019-04-09 中钢集团邢台机械轧辊有限公司 A kind of centrifugal casting quick-cutting steel pinch roller and its manufacturing method
CN110373605A (en) * 2019-06-20 2019-10-25 浙江精瑞工模具有限公司 A kind of novel high-toughness alloy steel and its method of smelting
CN110373599A (en) * 2019-06-28 2019-10-25 浙江精瑞工模具有限公司 A kind of method of refining of high-toughness alloy steel
CN112264465A (en) * 2020-09-29 2021-01-26 武汉钢铁有限公司 Centrifugal composite roller
CN112410673A (en) * 2020-11-18 2021-02-26 宝钢轧辊科技有限责任公司 High-speed steel roll for rolling ultrahigh-strength steel plate and manufacturing method thereof
CN114959506A (en) * 2022-07-13 2022-08-30 河冶科技股份有限公司 High-speed steel for ultrathin stainless steel rolling roller and preparation method thereof
CN115074625A (en) * 2022-06-23 2022-09-20 宝钢轧辊科技有限责任公司 Intermediate roll of sendzimir mill and its manufacturing method
CN115194422A (en) * 2022-06-01 2022-10-18 中钢集团邢台机械轧辊有限公司 Method for forging composite roller
CN115976427A (en) * 2022-12-09 2023-04-18 铜陵有色金神耐磨材料有限责任公司 Corrosion-resistant high-wear-resistance large-size forged steel ball for semi-autogenous mill and manufacturing method
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Publication number Priority date Publication date Assignee Title
CN108060353A (en) * 2017-12-19 2018-05-22 安徽天重工股份有限公司 A kind of shield engine disk type hobbing cutter ring alloy
CN109594018A (en) * 2018-12-26 2019-04-09 中钢集团邢台机械轧辊有限公司 A kind of centrifugal casting quick-cutting steel pinch roller and its manufacturing method
CN109594018B (en) * 2018-12-26 2021-09-10 中钢集团邢台机械轧辊有限公司 Centrifugal casting high-speed steel pinch roll and manufacturing method thereof
CN110373605A (en) * 2019-06-20 2019-10-25 浙江精瑞工模具有限公司 A kind of novel high-toughness alloy steel and its method of smelting
CN110373599B (en) * 2019-06-28 2021-05-14 浙江精瑞工模具有限公司 Refining method of high-toughness alloy steel
CN110373599A (en) * 2019-06-28 2019-10-25 浙江精瑞工模具有限公司 A kind of method of refining of high-toughness alloy steel
CN112264465B (en) * 2020-09-29 2022-06-17 武汉钢铁有限公司 Centrifugal composite roller
CN112264465A (en) * 2020-09-29 2021-01-26 武汉钢铁有限公司 Centrifugal composite roller
CN112410673A (en) * 2020-11-18 2021-02-26 宝钢轧辊科技有限责任公司 High-speed steel roll for rolling ultrahigh-strength steel plate and manufacturing method thereof
CN115194422A (en) * 2022-06-01 2022-10-18 中钢集团邢台机械轧辊有限公司 Method for forging composite roller
CN115074625A (en) * 2022-06-23 2022-09-20 宝钢轧辊科技有限责任公司 Intermediate roll of sendzimir mill and its manufacturing method
CN114959506A (en) * 2022-07-13 2022-08-30 河冶科技股份有限公司 High-speed steel for ultrathin stainless steel rolling roller and preparation method thereof
CN114959506B (en) * 2022-07-13 2023-04-25 河冶科技股份有限公司 High-speed steel for ultrathin stainless steel rolling roller and preparation method thereof
CN115976427A (en) * 2022-12-09 2023-04-18 铜陵有色金神耐磨材料有限责任公司 Corrosion-resistant high-wear-resistance large-size forged steel ball for semi-autogenous mill and manufacturing method
CN115976427B (en) * 2022-12-09 2024-04-12 铜陵有色金神耐磨材料有限责任公司 Corrosion-resistant high-wear-resistant large-size forged steel ball for semi-autogenous mill and manufacturing method
CN116516259A (en) * 2023-06-02 2023-08-01 丹阳市曙光新材料科技有限公司 Cobalt-containing low-alloy high-speed steel twist drill and preparation method thereof

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Application publication date: 20170623