CN106871484A - A kind of gas refrigeration system based on thermal transpiration effect - Google Patents

A kind of gas refrigeration system based on thermal transpiration effect Download PDF

Info

Publication number
CN106871484A
CN106871484A CN201710053867.7A CN201710053867A CN106871484A CN 106871484 A CN106871484 A CN 106871484A CN 201710053867 A CN201710053867 A CN 201710053867A CN 106871484 A CN106871484 A CN 106871484A
Authority
CN
China
Prior art keywords
heat exchanger
outlet
import
gloomy compressor
refrigerant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710053867.7A
Other languages
Chinese (zh)
Other versions
CN106871484B (en
Inventor
卢苇
王博韬
王南
谢超许
徐昆
许浩
刘进阳
王祥
何鸣阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201710053867.7A priority Critical patent/CN106871484B/en
Publication of CN106871484A publication Critical patent/CN106871484A/en
Application granted granted Critical
Publication of CN106871484B publication Critical patent/CN106871484B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B27/00Machines, plants or systems, using particular sources of energy
    • F25B27/02Machines, plants or systems, using particular sources of energy using waste heat, e.g. from internal-combustion engines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • Y02A30/274Relating to heating, ventilation or air conditioning [HVAC] technologies using waste energy, e.g. from internal combustion engine

Landscapes

  • Engineering & Computer Science (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)

Abstract

The invention discloses a kind of gas refrigeration system based on thermal transpiration effect, it includes that refrigerant input pipe, master exert gloomy compressor set, refrigerant efferent duct, cooler, throttle mechanism, vacuum tank, refrigerating medium heat exchanger tube, auxiliary exert gloomy compressor set, hot chamber heat exchanger and cold chamber heat exchanger, every group of master exert gloomy compressor set including base station body and several exert gloomy compressor, exerting gloomy compressor includes cold chamber, hot chamber, porous interlayer and interface channel.The hot chamber for exerting gloomy compressor of the invention by hot chamber heat exchanger using industry more than (useless) heat maintain temperature higher, so that refrigerant flow to hot chamber by thermal transpiration effect from cold chamber, so that refrigerant is boosted and in system internal circulation flow, being conveyed to after refrigerating medium absorption cold needs awkward silence at a meeting to be used, it can save high-grade energy, and refrigerant using the gas to human body and environment non-hazardous.

Description

A kind of gas refrigeration system based on thermal transpiration effect
Technical field
The present invention relates to refrigeration technology field, more particularly to a kind of gas refrigeration system based on thermal transpiration effect.
Background technology
With society, economic fast development and the continuous improvement of living standards of the people, energy and environment problem is increasingly convex It is aobvious.China has been energy-consuming state and CO the biggest in the world2Discharge state, wherein industrial energy consumption energy proportion are maximum, mainly Concentrate on the industries such as electric power, petroleum gas, chemical industry, light industry, building materials and metallurgy.The production process of these industries is often with big (useless) hot driving more than amount, wherein at least has half rationally to be utilized, and causes energy waste and environmental pollution;If rationally sharp (useless) thermal resource, can effectively improve energy utilization rate more than these, be that the realization of China's target for energy-saving and emission-reduction provides strong support.
Industrial production link has many places to need cold, such as cooling down, the Yi Jishi of some technological processes or equipment Construction of suitable production environment etc..Main at present to solve the problems, such as refrigeration requirement using two class schemes, one is the steaming for using efficiency higher Air pressure compression type refrigerating system;Two is to make full use of remaining (useless) heat, uses absorption or adsorption refrigeration system.This two classes scheme is equal Some problems are individually present.Steam compression type refrigerating need to consume high-grade electric energy or mechanical energy, and its widely used HCFCs With HFCs classes refrigerant is because of ozone layer depletion or produces the environmental problems such as greenhouse effects to be among the process of eliminating.Absorption system Cold be working medium pair generally with ammonia-water or water-lithium-bromide solution, and ammonia has toxicity and inflammable and explosive, if leak that environment can be caused Pollution and initiation security incident;Lithium bromide also has certain toxicity and tool corrosivity, also pollutes the environment, and such as misoperation is also easy to Crystallization, influences refrigeration.Adsorption refrigeration system is usually intermittent duty, needs to increase if continuous operation is designed to and adsorbs Bed, makes system architecture and operation sequence become complicated.
It can be seen that, research and development effectively using remaining (useless) thermal drivers can avoid existing steam compression type, absorption, absorption again The New Refrigerating technology of formula refrigeration shortcoming is significant.
The information for being disclosed in the background section is merely intended to increase the understanding to general background of the invention, without answering In being considered as recognizing or imply in any form that the information structure has been the prior art well known to persons skilled in the art.
The content of the invention
It is an object of the invention to provide a kind of gas refrigeration system based on thermal transpiration effect, so as to overcome existing system Cooling system or complex structure or the shortcomings of need to consume high-grade energy and the working medium that uses not environmentally.
To achieve the above object, the invention provides a kind of gas refrigeration system based on thermal transpiration effect, wherein, bag Include:Refrigerant input pipe;At least one set master exerts gloomy compressor set, and master exerts gloomy compressor set described in every group includes:Base station body, it sets It is equipped with a main import and a primary outlet;The main import is connected with the refrigerant input pipe;And several exert gloomy compression Machine, each this exert gloomy compressor and include cold chamber, hot chamber, porous interlayer and interface channel, between the cold chamber and the hot chamber Separated by the porous interlayer, the molecule that the aperture in the hole on the porous interlayer is not more than gas refrigerant is averagely free Journey, the import of the interface channel is connected with the outlet in the hot chamber;Several this exert gloomy compressor be sequentially disposed in series in In the base station body, the import that the cold chamber of gloomy compressor is exerted described in first is connected with the main import, is exerted described in latter gloomy The import in the cold chamber of compressor is connected with the outlet of the previous interface channel for exerting gloomy compressor, described in last The outlet for exerting the interface channel of gloomy compressor is connected with the primary outlet;Refrigerant efferent duct, master exerts gloomy pressure described in every group The primary outlet of the base station body of contracting unit is connected with the refrigerant efferent duct;Cooler, the import of its heat passage and the refrigeration Agent efferent duct is connected;Throttle mechanism, its import is connected with the outlet of the heat passage of the cooler;Vacuum tank, it is provided with First tank import, the second tank import and tank outlet, first tank import are gone out by a vacuum valve and the throttle mechanism Mouth connection;Refrigerating medium heat exchanger tube, it is arranged in the vacuum tank, one end of the refrigerating medium heat exchanger tube and a refrigerating medium input pipe Connect, and the other end of the refrigerating medium heat exchanger tube is connected with a refrigerating medium efferent duct;It is auxiliary to exert gloomy compressor set, its structure with it is described The structure that master exerts gloomy compressor set is identical, and the primary outlet of the auxiliary base station body for exerting gloomy compressor set connects with the second tank import Connect;Hot chamber heat exchanger, master described in every group exerts in all of hot chamber for exerting gloomy compressor in gloomy compressor set and is each provided with one The hot chamber heat exchanger;The heat is also each provided with the auxiliary all of hot chamber for exerting gloomy compressor exerted in gloomy compressor set Chamber heat exchanger;The import of all of hot chamber heat exchanger is connected with a heat-carrying agent inlet tube;The all of hot chamber heat exchange The outlet of device is connected with a heat-carrying agent outlet;And cold chamber heat exchanger, master exerts the institute in gloomy compressor set described in every group Described the exerting having is each provided with the cold chamber heat exchanger in the described cold chamber of gloomy compressor;The all of cold chamber heat exchanger Import is connected with a cooling medium inlet pipe, and the cooling medium inlet pipe and the refrigerant input pipe pass through a threeway Valve is connected with the tank outlet of the vacuum tank jointly;The outlet of all of cold chamber heat exchanger goes out with a cooling medium Mouth pipe is connected, and the cooling medium outlet is connected with the main import of the auxiliary base station body for exerting gloomy compressor set.
Preferably, in above-mentioned technical proposal, the porous interlayer is porous membrane.
Preferably, in above-mentioned technical proposal, the throttle mechanism is choke valve or expanding machine.
Preferably, in above-mentioned technical proposal, the hot chamber heat exchanger and the cold chamber heat exchanger are fin tube type heat exchange Device.
Preferably, in above-mentioned technical proposal, the base station body that master described in every group exerts gloomy compressor set is provided with an epicoele and one Cavity of resorption, master exerts all of of gloomy compressor set and exerts gloomy compressor and be arranged in the epicoele described in every group;The cavity of resorption is provided with One cavity of resorption import and a cavity of resorption are exported, and the cavity of resorption is separated into a flow channel and a flow pass by a deflection plate, The cavity of resorption import is connected with the flow channel, and the cavity of resorption outlet is connected with the flow pass;The cavity of resorption import with The cooling medium inlet pipe connection, the cavity of resorption outlet is connected with the cooling medium outlet;Each described cold chamber heat exchange The import of device is connected by an air admission hole with the flow channel, and the outlet of each cold chamber heat exchanger passes through a venthole Connected with the flow pass.
Preferably, in above-mentioned technical proposal, a refrigerant is provided between the throttle mechanism and the cooler and is changed Hot device, the import of the heat passage of the refrigerant heat exchanger is connected with the outlet of the heat passage of the cooler, the section The import for flowing mechanism is connected with the outlet of the heat passage of the refrigerant heat exchanger;The cold flow passage of the refrigerant heat exchanger The tank outlet of import and the vacuum tank be connected, and the cooling medium inlet pipe and the refrigerant input pipe pass through Outlet of the triple valve jointly with the cold flow passage of the refrigerant heat exchanger is connected.
Preferably, in above-mentioned technical proposal, the refrigerating medium input pipe passes through a refrigerating medium heat exchanger and the refrigerating medium Heat exchanger tube is connected, and the import of the heat passage of the refrigerating medium heat exchanger is connected with the refrigerating medium input pipe, and the refrigerating The outlet of the heat passage of agent heat exchanger is connected with one end of the refrigerating medium heat exchanger tube;The cold flow of the refrigerating medium heat exchanger is led to The import in road is connected with the outlet of the throttle mechanism, and first tank import is exchanged heat by the vacuum valve with the refrigerating medium The outlet connection of the cold flow passage of device.
Compared with prior art, the present invention has the advantages that:
1st, to utilize (useless) heat more than industry to maintain by hot chamber heat exchanger higher in the hot chamber for exerting gloomy compressor of the invention Temperature so that gas refrigerant exert obtained in gloomy compressor set boosting so as to realized in system automatic cycle flow, its Directly can be combined with industrial processes, it is (useless) hot more than industrial generation to make full use of, it is not necessary to consume too many High-grade electric energy or mechanical energy.After the cold that refrigerating medium absorbs gas refrigerant release in refrigerating medium heat exchanger and vacuum tank Just can be conveyed to needs awkward silence at a meeting to be used such that it is able to which part substitutes conventional refrigerant unit and is technological process and builds suitable for producing ring Border etc. provides required cold.
2nd, it is of the invention to exert gloomy compressor for modularized design, and simple structure, can according to actual needs to exerting gloomy compression Machine carries out series and parallel combination.
3rd, simple structure of the invention, whole system movement-less part, it is not necessary to lubricating oil is reliable, and whole system The refrigerating efficiency of system is higher, and its refrigerating capacity can be adjusted according to actual needs.
4th, refrigerant of the invention can be using natural environmental-protective and the gas of stable chemical nature, to human body and environment without danger Evil.
Brief description of the drawings
Fig. 1 is the structural representation according to gas refrigeration system of the present invention based on thermal transpiration effect.
Fig. 2 is the structural representation that master of the invention exerts gloomy compressor set.
Fig. 3 is the structural representation of base station body of the invention.
Fig. 4 is the structural representation of the cavity of resorption of base station body of the invention.
Fig. 5 is of the invention multiple rows of to exert gloomy compressor and be arranged in series in the structural representation in base station body.
Fig. 6 is the structural representation of fin-tube heat exchanger of the invention.
Main Reference Numerals explanation:
1- refrigerant input pipes, 2- master exerts gloomy compressor set, 3- refrigerant efferent ducts, 4- coolers, 5- throttle mechanisms, 6- Refrigerating medium heat exchanger, 7- refrigerating medium input pipes, 8- vacuum tanks, 9- the first tank imports, 10- the second tank imports, the outlet of 11- tanks, 12- Vacuum valve, 13- refrigerating medium heat exchanger tubes, 14- refrigerating medium efferent ducts, 15- is auxiliary to exert gloomy compressor set, 16- cooling medium inlet pipes, 17- cooling medium outlets, 18- triple valves, 19- refrigerant heat exchangers, 20- heat-carrying agent inlet tubes, the outlet of 21- heat-carrying agents Pipe, 22- base station bodies, the main imports of 23-, 24- primary outlets, the cold chambers of 25-, the hot chambers of 26-, the porous interlayers of 27-, 28- interface channels, 29- Hot chamber heat exchanger, the cold chamber heat exchangers of 30-, 31- epicoeles, 32- cavity of resorption imports, 33- cavity of resorptions, the outlet of 34- cavity of resorptions, 35- deflection plates, 36- flow channels, 37- flow pass, 38- air admission holes, 39- ventholes, 40- adiabatic insulations, 41- fin-tube heat exchangers, 42- Bend pipe, 43- copper fins.
Specific embodiment
Below in conjunction with the accompanying drawings, specific embodiment of the invention is described in detail, it is to be understood that guarantor of the invention Shield scope is not limited by specific embodiment.
Explicitly indicated that unless otherwise other, otherwise in entire disclosure and claims, term " including " or its change Change such as "comprising" or " including " etc. and will be understood to comprise stated element or part, and do not exclude other units Part or other parts.
Fig. 1 to Fig. 6 shows a kind of gas refrigeration system based on thermal transpiration effect according to the preferred embodiment of the present invention The structural representation of system, it is gloomy that the gas refrigeration system based on thermal transpiration effect of being somebody's turn to do includes that refrigerant input pipe 1, at least one set of master are exerted Compressor set 2, refrigerant efferent duct 3, cooler 4, throttle mechanism 5, refrigerating medium heat exchanger 6, vacuum tank 8, refrigerating medium heat exchanger tube 13rd, auxiliary to exert gloomy compressor set 15, hot chamber heat exchanger 29 and cold chamber heat exchanger 30, with reference to Fig. 2, every group of master exerts gloomy compressor set 2 Including base station body 22 and several exert gloomy compressor, base station body 22 is provided with a main import 23 and a primary outlet 24, it is main enter Mouth 23 is connected with refrigerant input pipe 1, and when the quantity that master exerts gloomy compressor set 2 is two or more, these masters exert gloomy compression Unit 2 is just connected with refrigerant input pipe 1 in parallel, i.e., all of master is exerted gloomy compressor set 2 and respectively entered by the master of base station body 22 Mouthfuls 23 are connected with refrigerant input pipe 1 such that it is able to by refrigerant input pipe 1 gas refrigerant be conveyed to each group master exert it is gloomy Compressor set 2.The quantity that master exerts gloomy compressor set 2 can determine according to the refrigerating capacity size of system.Each exerts gloomy compressor Including cold chamber 25, hot chamber 26, porous interlayer 27 and interface channel 28,27 points of porous interlayer is passed through between cold chamber 25 and hot chamber 26 Every the aperture in the hole on porous interlayer 27 is not more than the molecule mean free path of gas refrigerant.Preferably, porous interlayer 27 is Porous membrane, it can be Bio-sil film, and the edge of porous membrane is sealingly disposed in base station body 22 by sealing ring.By It is not more than the molecule mean free path of gas refrigerant in the aperture in the hole on porous interlayer 27, when the temperature in hot chamber 26 is higher than cold When chamber 25 occurs the condition of thermal transpiration effect to meet gas, the molecule of the gas refrigerant entered into cold chamber 25 will pass through many Hole interlayer 27 is automatically flowed into hot chamber 26, and because gas refrigeration agent molecule is focused on and pressure rise in hot chamber 26.Connection is logical The import in road 28 is connected with the outlet in hot chamber 26, and several are exerted gloomy compressor and are sequentially disposed in series in base station body 22, with right Gas refrigerant is continued for boosting.First import in the cold chamber 25 for exerting gloomy compressor connects with the main import 23 of base station body 22 Connect, the import in the latter cold chamber 25 for exerting gloomy compressor is connected with the outlet of the previous interface channel 28 for exerting gloomy compressor, most The latter outlet of interface channel 28 for exerting gloomy compressor is connected with the primary outlet 24 of base station body 22.When gas refrigerant is sequentially passed through Cross it is all of exert gloomy compressor after, the pressure of gas refrigerant will obtain lasting rising.Every group of master is exerted in gloomy compressor set 2 The quantity for exerting gloomy compressor determined according to the operating pressure of cooler 4.Gloomy pressure is exerted when every group of master is exerted in gloomy compressor set 2 When the quantity of contracting machine is not a lot, the gloomy compressor of exerting in group can be made linearly to be together in series from A-P, and when every When the main quantity for exerting gloomy compressor exerted in gloomy compressor set 2 of group is more, with reference to Fig. 5, can make to exert gloomy compressor in base station body 1 It is interior in the parallel distribution of some rows, now being exerted for adjacent two row separated with adiabatic insulation 40 between gloomy compressor.
With continued reference to Fig. 1, the primary outlet 24 of the base station body 22 that every group of master exerts gloomy compressor set 2 connects with refrigerant efferent duct 3 Connect, when master exert the quantity of gloomy compressor set 2 for it is two or more when, these masters exert gloomy compressor set 2 just in parallel with refrigerant Efferent duct 3 is connected, so that all of master exerts gloomy compressor set 2 intensively can be conveyed to refrigerant output gas refrigerant Pipe 3.The import of the heat passage of cooler 4 is connected with refrigerant efferent duct 3, and refrigerant efferent duct 3 conveys gas refrigerant Cooled down in cooler 4, cooler 4 can be micro-channel heat exchanger.The import of throttle mechanism 5 and the hot-fluid of cooler 4 The outlet connection of passage, its gas refrigerant being used for after being cooled down to the device 4 that is cooled carries out decrease temperature and pressure.Throttle mechanism 5 can be with It is choke valve or expanding machine, specifically depending on the gas refrigerant species for being used.For the highest that throttling refrigeration effect occurs Higher than most of gas of environment temperature, the temperature that can just make of throttling at ambient temperature is reduced conversion temperature, and now throttle machine Structure 5 just uses choke valve.And gas of the highest conversion temperature far below environment temperature for there is throttling refrigeration effect, such as helium Gas, argon gas and neon etc., at ambient temperature throttling can not reduce temperature, now throttle mechanism 5 must use expanding machine with Reach the purpose of cooling.
With continued reference to Fig. 1, vacuum tank 8 is both a pressure vessel, is again a heat exchanger, and insulation is coated with outside it Layer.Vacuum tank 8 is provided with the first tank import 9, the second tank import 10 and tank outlet 11, and the first tank import 9 is arranged at vacuum tank 8 Bottom, the second tank import 10 is arranged at the top of vacuum tank 8, and tank outlet 11 is arranged at the centres of vacuum tank 8.First tank import 9 are connected by a vacuum valve 12 with the outlet of throttle mechanism 5, and refrigerating medium heat exchanger tube 13 is arranged in vacuum tank 8, refrigerating medium heat exchange One end of pipe 13 is connected with a refrigerating medium input pipe 7, and the other end of refrigerating medium heat exchanger tube 13 connects with a refrigerating medium efferent duct 14 Connect.Refrigerating medium input pipe 7 is used for the defeated feeding system of refrigerating medium, and refrigerating medium can be the liquid such as water.Enter into vacuum tank 8 Low temperature low pressure gas refrigerant is expanded under low vacuum environment, and pressure and temperature is reduced again, so that increase the refrigerating capacity of system, After refrigerating medium enters into after refrigerating medium heat exchanger tube 13 cold for absorbing gas refrigerant release, just may be used by refrigerating medium efferent duct 14 Being conveyed to needs awkward silence at a meeting to be used.With continued reference to Fig. 1, it is preferable that refrigerating medium input pipe 7 passes through a refrigerating medium heat exchanger 6 and refrigerating Agent heat exchanger tube 13 is connected, and the import of the heat passage of refrigerating medium heat exchanger 6 is connected with refrigerating medium input pipe 7, and refrigerating medium exchanges heat The outlet of the heat passage of device 6 is connected with one end of refrigerating medium heat exchanger tube 13, the import of the cold flow passage of refrigerating medium heat exchanger 6 with The outlet connection of throttle mechanism 5, the first tank import 9 is connected by vacuum valve 12 with the outlet of the cold flow passage of refrigerating medium heat exchanger 6 Connect.Refrigerating medium heat exchanger 6 is a cryogenic heat exchanger, and it can use the gas of micro-channel heat exchanger, refrigerating medium and low-temp low-pressure Refrigerant is exchanged heat wherein, and temperature is tentatively raised after the heat absorption of low temperature low pressure gas refrigerant, and refrigerating medium is entering vacuum Initial absorption cold before tank 8, so as to improve refrigerating efficiency.
With continued reference to Fig. 1 and Fig. 2, the auxiliary structure for exerting gloomy compressor set 15 is identical with the structure that master exerts gloomy compressor set 2, auxiliary The primary outlet for exerting the base station body of gloomy compressor set 15 is connected with the second tank import 10.Every group of master exerts owning in gloomy compressor set 2 Exert a hot chamber heat exchanger 29 be each provided with the hot chamber of gloomy compressor, it is auxiliary exert in gloomy compressor set 15 all of exert gloomy pressure Also a hot chamber heat exchanger 29 is each provided with the hot chamber of contracting machine.The import of all of hot chamber heat exchanger 29 with a heat-carrying agent Inlet tube 20 is connected, and the outlet of all of hot chamber heat exchanger 29 is connected with a heat-carrying agent outlet 21.Heat-carrying agent enters Mouthful pipe 20 be used for carry industry produce more than (useless) hot medium be transported in hot chamber heat exchanger 29, exert gloomy pressure with to each The hot chamber 26 of contracting machine is heated, and each is exerted in the hot chamber 26 of gloomy compressor can maintain temperature higher, after absorbing heat Medium discharged from heat-carrying agent outlet 21 again.Heat-carrying agent can be the liquid such as water, or gas.Every group of master Exert in all of cold chamber 25 for exerting gloomy compressor in gloomy compressor set 2 and be each provided with a cold chamber heat exchanger 30, it is auxiliary to exert gloomy pressure Cold chamber heat exchanger 30 can be then not provided with the cold chamber 25 for exerting gloomy compressor in contracting unit 15, it is now, auxiliary to exert gloomy pressure to unit 15 Base station body the structure base station body 22 that can exert gloomy compressor set 2 with master structure it is incomplete same, and auxiliary exert gloomy compressor set The arrangement mode for exerting gloomy compressor that the arrangement mode for exerting gloomy compressor in 15 can also be exerted in gloomy compressor set 2 with master is incomplete It is identical.The import of all of cold chamber heat exchanger 30 is connected with a cooling medium inlet pipe 16, cooling medium inlet pipe 16 and system Cryogen input pipe 1 exports 11 and is connected with the tank of vacuum tank 8 jointly by a triple valve 18.All of cold chamber heat exchanger 30 goes out Mouthful be connected with a cooling medium outlet 17, and cooling medium outlet 17 and the auxiliary base station body for exerting gloomy compressor set 15 master Import is connected.Gas refrigerant is conveyed to refrigerant input pipe again from the tank outlet 11 of vacuum tank 8 through the major part of triple valve 18 1, fraction is conveyed to cooling medium inlet pipe 16 so that gas refrigerant to enter into cooling in each cold chamber heat exchanger 30 cold Chamber 25, so that each cold chamber 25 for exerting gloomy compressor that master is exerted in gloomy compressor set 2 maintains a relatively low temperature.From cold chamber The gas refrigerant out of heat exchanger 30 through cooling medium outlet 17 be conveyed to it is auxiliary exert gloomy compressor set 15, it is auxiliary to exert gloomy compressor Gloomy compressor is exerted sequentially gradually just being transmitted back to vacuum tank 8 after gas refrigerant adherence pressure in group 15.Preferably, hot chamber is changed Hot device 29 and cold chamber heat exchanger 30 are fin-tube heat exchanger 41, and it is miniature fin-tube heat exchanger, with reference to Fig. 6, wing If the bend pipe 42 and dried layer of Flat-tube type heat-exchanger 41 including several parallel distributions are around the copper fin between all bend pipes 42 43.One end of all bend pipes 42 is the import of fin-tube heat exchanger 41, and the other end of all bend pipes 42 is changed for fin tube type The outlet of hot device 41.
With reference to Fig. 3 and Fig. 4, it is preferable that the base station body 22 that every group of master exerts gloomy compressor set 2 is provided with an epicoele 31 and once Chamber 33, epicoele 31 is fixed capping by the cover plate of base station body 22 by bolt.Every group of master exerts all of of gloomy compressor set 2 and exerts Gloomy compressor is arranged in epicoele 31, and cavity of resorption 33 is provided with a cavity of resorption import 32 and cavity of resorption outlet 34, and cavity of resorption 33 passes through a folding Stream plate 35 is separated into a flow channel 36 and a flow pass 37, and cavity of resorption import 32 is connected with flow channel 36, and cavity of resorption goes out Mouth 34 is connected with flow pass 37.Cavity of resorption import 32 is connected with cooling medium inlet pipe 16, and cavity of resorption outlet 34 goes out with cooling medium Mouth pipe 17 is connected, and the import of each cold chamber heat exchanger 30 is connected by an air admission hole 38 with flow channel 36, and each cold chamber is changed The outlet of hot device 30 is connected by a venthole 39 with flow pass 37.It is in when master exerts the gloomy compressor of exerting in gloomy compressor set 2 During the parallel distribution of some rows, just S-shaped sigmoid is distributed in cavity of resorption 33 for flow channel 36 and flow pass 37.Cooling medium enters Mouth pipe 16 is conveyed into gas refrigerant to after flow channel 36 from cavity of resorption import 32 and is entered into by each air admission hole 38 correspondence In each cold chamber heat exchanger 30, the gas refrigerant after heat exchange in cold chamber heat exchanger 30 is discharged to flow pass from venthole 39 37, then concentrate and 34 transferred out to cooling medium outlet 17 from cavity of resorption outlet.Master exerts the base station body 22 of gloomy compressor set 2 by setting The cavity of resorption 33 put concentrates conveying gas refrigerant to each cold chamber heat exchanger 30, such that it is able to simplify structure.Gloomy pressure is exerted due to auxiliary The cold chamber 25 for exerting gloomy compressor in contracting unit 15 need not set cold chamber heat exchanger 30, therefore the auxiliary base station for exerting gloomy compressor set 15 Body 22 need not set cavity of resorption 33.
With continued reference to Fig. 1, it is preferable that be provided with a refrigerant heat exchanger 19 between throttle mechanism 5 and cooler 4, its It can be micro-channel heat exchanger.The import of the heat passage of refrigerant heat exchanger 19 connects with the outlet of the heat passage of cooler 4 Connect, the import of throttle mechanism 5 is connected with the outlet of the heat passage of refrigerant heat exchanger 19, the cold flow of refrigerant heat exchanger 19 is led to The import in road is connected with the tank outlet 11 of vacuum tank 8, and cooling medium inlet pipe 16 and refrigerant input pipe 1 pass through triple valve 18 Outlet with the cold flow passage of refrigerant heat exchanger 19 jointly is connected.Vacuum tank can be utilized by setting up refrigerant heat exchanger 19 The low temperature low pressure gas refrigerant of 8 outflows is exchanged heat with the middle temperature high-pressure gas refrigerant before throttle mechanism 5, makes middle temperature high pressure Gas refrigerant precooling before throttling, it is ensured that it is in throttle mechanism 5 by abundant reducing pressure by regulating flow and cooling;On the other hand, make low There is certain overheat before the main import 23 that gloomy compressor set 2 is exerted into master in warm low pressure refrigerant, to improve intake air temperature, enters And increase the pressure that master exerts the primary outlet 24 of gloomy compressor set 2, and reduce each wasted work for exerting gloomy compressor.In a word, the system of setting up Cryogen heat exchanger 19 can improve the economy of system circulation, improve refrigerating efficiency.
Operation principle of the invention is:
It is a kind of gas boost device based on thermal transpiration effect due to exerting gloomy compressor, when master is exerted in gloomy compressor set 2 The hot chamber 26 for exerting gloomy compressor by hot chamber heat exchanger 29 using carry (useless) hot medium more than industry maintain it is higher Temperature, and cold chamber 25 using the gas refrigerant of low-temp low-pressure by cold chamber heat exchanger 30 when maintaining relatively low temperature, if this When gas refrigerant molecule mean free path be not less than and exert the aperture in hole on the porous interlayer 27 of gloomy compressor and just can expire There is the condition of thermal transpiration effect in foot, gas refrigerant just moves to temperature hot chamber 26 higher from the relatively low cold chamber 25 of temperature, So that gas refrigeration agent molecule is assembled and pressure rising in hot chamber 26, exerting gloomy compressor plural serial stage can improve compression ratio, Gas refrigerant is set to obtain elevated pressures, but the temperature of gas compressed refrigerant is almost unchanged, and this makes master exert gloomy compressor Group 2 can substitute the increasing apparatus such as traditional compressor, working medium pump, and master exerts gloomy compressor set 2 and passes through preparation input pipe 1 constantly Gas refrigerant is extracted out and boosted from vacuum tank 8, being then conveyed to cooler 4 from refrigerant efferent duct 3 is cooled down, therefore Master exerts gloomy compressor set 2 and also acts as the effect vacuumized to vacuum tank 8, so that gas refrigerant is in system internal circulation flow.It is cold But 4 pairs of gas refrigerants for exerting the HTHP of discharge in gloomy compressor set 2 from master of device are cooled down, by gas refrigerant State is changed into middle temperature high pressure.The gas refrigerant of middle temperature high pressure is first carried out after being flowed into refrigerant heat exchanger 19 before throttling Precooling in advance, entering back into throttle mechanism 5 carries out decrease temperature and pressure.From the low temperature low pressure gas refrigerant out of throttle mechanism 5 Enter into after lowering the temperature to refrigerating medium in refrigerating medium heat exchanger 6, then flowed into vacuum tank 8 by vacuum valve 12, and to refrigerating Further cooling is made in agent, and refrigerating medium is just obtained enough colds, used with supply and demand awkward silence at a meeting.11 are exported from the tank of vacuum tank 8 After low temperature low pressure gas refrigerant out is preheated through refrigerant heat exchanger 19, system is conveyed to again by the major part of triple valve 18 Cryogen input pipe 1, fraction is conveyed to cooling medium inlet pipe 16.Cooling medium inlet pipe 16 is low temperature low pressure gas refrigerant After being transported to the flow channel 36 of the cavity of resorption 33 of the main base station body 22 for exerting gloomy compressor set 2, then entered by each air admission hole 38 Each the cold chamber 25 for exerting gloomy compressor in gloomy compressor set 2 is exerted in each cold chamber heat exchanger 30 to master to cool down, then This portion gas refrigerant flows to flow pass 37 from venthole 39 again, and is conveyed to through cooling medium outlet 17 and auxiliary exerts gloomy pressure The main-inlet of the base station body of contracting unit 15, it is auxiliary exert in gloomy compressor set 15 each exert gloomy compressor by thermal transpiration effect sequentially The relatively low gas refrigerant of the pressure discharged from cooling medium outlet 17 is risen into high pressure, so that gas refrigerant can flow back Into the of a relatively high vacuum tank 8 of pressure, so as to realize circulating.
Of the invention to exert gloomy compressor for modularized design, construction is fairly simple, exerts the hot chamber 26 of gloomy compressor by heat Chamber heat exchanger 29 utilizes (useless) heat more than industry to maintain temperature higher, and it directly can be combined with industrial processes, It is (useless) hot more than industrial generation to make full use of, it is not necessary to consume too many high-grade electric energy or mechanical energy.Refrigerating medium exists Just can be conveyed to after the cold that gas refrigerant release is absorbed in refrigerating medium heat exchanger 6 and vacuum tank 8 needs awkward silence at a meeting to be used, so that Conventional refrigerant unit can partly be substituted for technological process and the cold needed for suitable for producing environment etc. is provided is built.It is of the invention Simple structure, whole system movement-less part, it is not necessary to lubricating oil is reliable, and the refrigeration of whole system is higher, its refrigeration Amount can be adjusted according to actual needs.In addition, gas refrigerant of the invention can use natural environmental-protective and chemical property is steady Fixed gas.Gas (such as air, nitrogen) is used as refrigerant history very long, gas refrigerant and conventional refrigerants (such as ammonia, HFCs, HCFCs) is compared, cheap, is readily available, to human body and the complete non-hazardous of environment.
The foregoing description to specific illustrative embodiment of the invention be in order to illustrate and illustration purpose.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed And change.The purpose of selecting and describing the exemplary embodiment is that explaining that certain principles of the invention and its reality should With so that those skilled in the art can realize and using a variety of exemplaries of the invention and A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (7)

1. a kind of gas refrigeration system based on thermal transpiration effect, it is characterised in that including:
Refrigerant input pipe;
At least one set master exerts gloomy compressor set, and master exerts gloomy compressor set described in every group includes:
Base station body, it is provided with a main import and a primary outlet;The main import is connected with the refrigerant input pipe;And
Several exert gloomy compressor, each this exert gloomy compressor and include cold chamber, hot chamber, porous interlayer and interface channel, it is described Separated by the porous interlayer between cold chamber and the hot chamber, the aperture in the hole on the porous interlayer is not more than gas refrigeration The molecule mean free path of agent, the import of the interface channel is connected with the outlet in the hot chamber;Several this exert gloomy compressor The import in the cold chamber in the base station body, exerting gloomy compressor described in first is sequentially disposed in series to connect with the main import Connect, the import in the latter cold chamber for exerting gloomy compressor and the outlet of the previous interface channel for exerting gloomy compressor Connection, the outlet that the interface channel of gloomy compressor is exerted described in last is connected with the primary outlet;
Refrigerant efferent duct, the primary outlet of the base station body that master described in every group exerts gloomy compressor set is connected with the refrigerant efferent duct;
Cooler, the import of its heat passage is connected with the refrigerant efferent duct;
Throttle mechanism, its import is connected with the outlet of the heat passage of the cooler;
Vacuum tank, it is provided with the outlet of the first tank import, the second tank import and tank, and first tank import passes through a vacuum valve Outlet with the throttle mechanism is connected;
Refrigerating medium heat exchanger tube, it is arranged in the vacuum tank, and one end of the refrigerating medium heat exchanger tube connects with a refrigerating medium input pipe Connect, and the other end of the refrigerating medium heat exchanger tube is connected with a refrigerating medium efferent duct;
Auxiliary to exert gloomy compressor set, its structure is identical with the structure that the master exerts gloomy compressor set, the auxiliary base for exerting gloomy compressor set The primary outlet of stage body is connected with the second tank import;
Hot chamber heat exchanger, master described in every group exerts in all of hot chamber for exerting gloomy compressor in gloomy compressor set and is each provided with one The hot chamber heat exchanger;The heat is also each provided with the auxiliary all of hot chamber for exerting gloomy compressor exerted in gloomy compressor set Chamber heat exchanger;The import of all of hot chamber heat exchanger is connected with a heat-carrying agent inlet tube;The all of hot chamber heat exchange The outlet of device is connected with a heat-carrying agent outlet;And
Cold chamber heat exchanger, all of described the exerting that master described in every group is exerted in gloomy compressor set sets in the described cold chamber of gloomy compressor It is equipped with the cold chamber heat exchanger;The import of all of cold chamber heat exchanger is connected with a cooling medium inlet pipe, described Cooling medium inlet pipe and the refrigerant input pipe are exported with the tank of the vacuum tank and connected jointly by a triple valve Connect;The outlet of all of cold chamber heat exchanger is connected with a cooling medium outlet, and the cooling medium outlet with The main import connection of the auxiliary base station body for exerting gloomy compressor set.
2. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that the porous interlayer It is porous membrane.
3. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that the throttle mechanism It is choke valve or expanding machine.
4. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that the hot chamber heat exchange Device and the cold chamber heat exchanger are fin-tube heat exchanger.
5. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that master exerts described in every group The base station body of gloomy compressor set is provided with an epicoele and a cavity of resorption, and master exerts all of of gloomy compressor set and exerts gloomy compression described in every group Machine is arranged in the epicoele;The cavity of resorption is provided with a cavity of resorption import and cavity of resorption outlet, and the cavity of resorption passes through a deflection plate A flow channel and a flow pass are separated into, the cavity of resorption import is connected with the flow channel, the cavity of resorption outlet Connected with the flow pass;The cavity of resorption import is connected with the cooling medium inlet pipe, and the cavity of resorption outlet is cold with described But media outlet pipe connection;The import of each cold chamber heat exchanger is connected by an air admission hole with the flow channel, and often The outlet of the individual cold chamber heat exchanger is connected by a venthole with the flow pass.
6. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that the throttle mechanism Be provided with a refrigerant heat exchanger between the cooler, the import of the heat passage of the refrigerant heat exchanger with it is described The outlet connection of the heat passage of cooler, the import of the throttle mechanism goes out with the heat passage of the refrigerant heat exchanger Mouth connection;The import of the cold flow passage of the refrigerant heat exchanger is connected with the tank outlet of the vacuum tank, and described cold But medium inlet and the refrigerant input pipe by the triple valve jointly with the cold flow passage of the refrigerant heat exchanger Outlet connection.
7. the gas refrigeration system based on thermal transpiration effect according to claim 1, it is characterised in that the refrigerating medium is defeated Enter pipe to be connected with the refrigerating medium heat exchanger tube by a refrigerating medium heat exchanger, the import of the heat passage of the refrigerating medium heat exchanger It is connected with the refrigerating medium input pipe, and the outlet of the heat passage of the refrigerating medium heat exchanger and the refrigerating medium heat exchanger tube One end connects;The import of the cold flow passage of the refrigerating medium heat exchanger is connected with the outlet of the throttle mechanism, first tank Import is connected by the vacuum valve with the outlet of the cold flow passage of the refrigerating medium heat exchanger.
CN201710053867.7A 2017-01-22 2017-01-22 A kind of gas refrigeration system based on thermal transpiration effect Active CN106871484B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710053867.7A CN106871484B (en) 2017-01-22 2017-01-22 A kind of gas refrigeration system based on thermal transpiration effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710053867.7A CN106871484B (en) 2017-01-22 2017-01-22 A kind of gas refrigeration system based on thermal transpiration effect

Publications (2)

Publication Number Publication Date
CN106871484A true CN106871484A (en) 2017-06-20
CN106871484B CN106871484B (en) 2019-05-17

Family

ID=59158717

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710053867.7A Active CN106871484B (en) 2017-01-22 2017-01-22 A kind of gas refrigeration system based on thermal transpiration effect

Country Status (1)

Country Link
CN (1) CN106871484B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109140866A (en) * 2018-07-18 2019-01-04 广西大学 It is a kind of to use the vacuum precooling device for exerting gloomy pump
CN109237856A (en) * 2018-07-18 2019-01-18 广西大学 It is a kind of to use the hypobaric and refrigerated preservation system for exerting gloomy pump
CN109269146A (en) * 2018-07-18 2019-01-25 广西大学 It is a kind of to use the vacuum refrigeration system for exerting gloomy pump
CN109630378A (en) * 2018-11-26 2019-04-16 广西大学 A kind of Zhu Tang workshop section pumped vacuum systems based on thermal transpiration effect
CN110897227A (en) * 2019-12-17 2020-03-24 广西大学 Clothing capable of instantly and continuously preparing oxygen-enriched air for health care and outdoor activities
CN113418298A (en) * 2021-07-02 2021-09-21 河北工业大学 Heat energy driven steam compression type heat pump hot water system

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11132593A (en) * 1997-10-29 1999-05-21 Daikin Ind Ltd Air conditioner
JP2000179914A (en) * 1998-12-09 2000-06-30 Sanyo Electric Co Ltd Air conditioning device
CN1689928A (en) * 2004-04-21 2005-11-02 阿尔卡特公司 Transport box comprising a thermophoresis protection effect
JP2012202369A (en) * 2011-03-28 2012-10-22 Aisin Seiki Co Ltd Heat pump integrated with evaporator and rankine cycle system
WO2013135135A1 (en) * 2012-03-12 2013-09-19 Rong Guohua Air conditioning system for use in restaurant
CN104048447A (en) * 2014-06-18 2014-09-17 广西大学 Refrigerating system with Knudsen compressor as core
CN104567089A (en) * 2014-12-23 2015-04-29 广西大学 Compression-ejection compound refrigerating system using Knudsen compressor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11132593A (en) * 1997-10-29 1999-05-21 Daikin Ind Ltd Air conditioner
JP2000179914A (en) * 1998-12-09 2000-06-30 Sanyo Electric Co Ltd Air conditioning device
CN1689928A (en) * 2004-04-21 2005-11-02 阿尔卡特公司 Transport box comprising a thermophoresis protection effect
JP2012202369A (en) * 2011-03-28 2012-10-22 Aisin Seiki Co Ltd Heat pump integrated with evaporator and rankine cycle system
WO2013135135A1 (en) * 2012-03-12 2013-09-19 Rong Guohua Air conditioning system for use in restaurant
CN104048447A (en) * 2014-06-18 2014-09-17 广西大学 Refrigerating system with Knudsen compressor as core
CN104567089A (en) * 2014-12-23 2015-04-29 广西大学 Compression-ejection compound refrigerating system using Knudsen compressor

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109140866A (en) * 2018-07-18 2019-01-04 广西大学 It is a kind of to use the vacuum precooling device for exerting gloomy pump
CN109237856A (en) * 2018-07-18 2019-01-18 广西大学 It is a kind of to use the hypobaric and refrigerated preservation system for exerting gloomy pump
CN109269146A (en) * 2018-07-18 2019-01-25 广西大学 It is a kind of to use the vacuum refrigeration system for exerting gloomy pump
CN109140866B (en) * 2018-07-18 2020-11-03 广西大学 Vacuum precooling device using Knudsen pump
CN109237856B (en) * 2018-07-18 2021-02-05 广西大学 Pressure reduction refrigeration system using Knudsen pump
CN109630378A (en) * 2018-11-26 2019-04-16 广西大学 A kind of Zhu Tang workshop section pumped vacuum systems based on thermal transpiration effect
CN110897227A (en) * 2019-12-17 2020-03-24 广西大学 Clothing capable of instantly and continuously preparing oxygen-enriched air for health care and outdoor activities
CN113418298A (en) * 2021-07-02 2021-09-21 河北工业大学 Heat energy driven steam compression type heat pump hot water system

Also Published As

Publication number Publication date
CN106871484B (en) 2019-05-17

Similar Documents

Publication Publication Date Title
CN106871484B (en) A kind of gas refrigeration system based on thermal transpiration effect
CN102914080A (en) Two-stage single-effect and double-effect lithium bromide absorption refrigerating unit with smoke and hot water afterburning
CN106839204B (en) A kind of air-conditioning refrigeration system based on thermal transpiration effect
CN201779768U (en) CO2 heat pump lower temperature heating system
CN102914081A (en) Two-section flue gas hot-water single/double-effect composite lithium bromide absorption type refrigerating unit
CN203516008U (en) Dual-recovery system for oil and gas heat
CN104165477A (en) Combined heating and power system, combined cooling and power system and dual-purpose combined heat and power and cooling and power system
CN201206917Y (en) Multi-stage cycle type cold and hot water equipment
CN101093118B (en) Single stage composite absorption type compressor
CN202915597U (en) Two-section flue gas hot-water single-effect and double-effect composite lithium bromide absorption type refrigerating unit
CN103123181A (en) Single-effect and double-effect compound-type lithium bromide absorption refrigerating device with smoke and hot water afterburning
CN202973647U (en) Flue gas hot water single/double-effect composite lithium bromide absorption refrigerating unit
CN215295426U (en) Smoke hot water type lithium bromide absorption cold-water heat pump unit
CN202915598U (en) Two-stage smoke and hot water afterburning single-effect and double-effect composite lithium bromide absorption refrigerating unit
CN202973646U (en) Flue gas hot water afterburning single/double-effect composite lithium bromide absorption refrigerating unit
CN106839511B (en) A kind of thermal transpiration formula gas separation system
CN211695946U (en) Waste heat recycling device
CN108088111A (en) Two-stage isothermal ammonia-water reabsorbs formula heat pump cycle and heat supply method
CN211233431U (en) Direct-current variable-frequency air-supplementing enthalpy-increasing carbon dioxide heat pump unit
CN203719224U (en) Direct-combustion lithium bromide absorption cold and hot water unit used for producing high-temperature hot water
CN209267917U (en) A kind of heat recovery module data center
CN102997481A (en) Hot water direct-fired single-double effect composite type lithium bromide absorption refrigerating unit
CN106705484A (en) Jetting type heat exchange system
CN100567853C (en) A kind of backheating type sodium rhodanate-ammonia absorption heat pump system
CN110307663B (en) Two-stage type steam heat pump and hot water type refrigerating lithium bromide absorption unit

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Lu Wei

Inventor after: He Mingyang

Inventor after: Mo Qianci

Inventor after: Wang Botao

Inventor after: Wang Nan

Inventor after: Xie Chaoxu

Inventor after: Xu Kun

Inventor after: Xu Hao

Inventor after: Liu Jinyang

Inventor after: Wang Xiang

Inventor before: Lu Wei

Inventor before: Wang Botao

Inventor before: Wang Nan

Inventor before: Xie Chaoxu

Inventor before: Xu Kun

Inventor before: Xu Hao

Inventor before: Liu Jinyang

Inventor before: Wang Xiang

Inventor before: He Mingyang

CB03 Change of inventor or designer information
GR01 Patent grant
GR01 Patent grant