CN106866184A - The three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles - Google Patents

The three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles Download PDF

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Publication number
CN106866184A
CN106866184A CN201710134442.9A CN201710134442A CN106866184A CN 106866184 A CN106866184 A CN 106866184A CN 201710134442 A CN201710134442 A CN 201710134442A CN 106866184 A CN106866184 A CN 106866184A
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China
Prior art keywords
glaze
lamination
production method
ceramic tiles
sludge ice
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Pending
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CN201710134442.9A
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Chinese (zh)
Inventor
林亮银
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FOSHAN SANSHUI HONGYUAN CERAMIC ENTERPRISE CO LTD
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FOSHAN SANSHUI HONGYUAN CERAMIC ENTERPRISE CO LTD
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Priority to CN201710134442.9A priority Critical patent/CN106866184A/en
Publication of CN106866184A publication Critical patent/CN106866184A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Finishing Walls (AREA)

Abstract

The invention discloses a kind of three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles, it is characterised in that it comprises the following steps：A, preparation bottom base；B, pattern layer is set with stamp or ink-jetting style；C, laying clear frit or translucent glaze layer above pattern layer；D, set again with stamp or ink-jetting style pattern layer, then re-lay clear frit or translucent glaze layer；E, burn till.Present invention process is simple, pattern is distributed among different planes, mutually sets off, and ceramic tile patterns is reached the color visual effect of solid, sludge ice, layer.

Description

The three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles
Technical field
The present invention relates to technical field of ceramic production, more particularly to the three-dimensional sludge ice lamination in-glaze decoration life of Ceramic Tiles Product method.
Background technology
Ceramic Tiles are by clay and other inorganic non-metallic raw materials, through the tabular or bulk of the technique productions such as shaping, sintering Ceramic, for decorating and protecting building, the metope of structures and ground.Generally at room temperature by dry-pressing, extruding or Other forming methods are molded, and then dry, and burn till at a certain temperature.At present, the surface decorating method of Ceramic Tiles is a lot, example Such as：Micro mist cloth, silk-screen printing, ink-jet, spray mill base, marble paper trans-printing etc..These technologies are all individual layer floral designs dresses Decorations, that is, colour image is to be showed in approximately the same plane, lacks cubic appearance.
The content of the invention
What the purpose of the present invention was provided to solve the deficiency of prior art a kind of can keep each glaze layer Transparency and crystalistic sense, make pattern be distributed among different planes so that it is color that ceramic tile patterns reach solid, sludge ice, layer Visual effect Ceramic Tiles three-dimensional sludge ice lamination in-glaze decoration production method.
The present invention is to realize above-mentioned purpose using following technical solution：A kind of three-dimensional sludge ice lamination glaze of Ceramic Tiles Prize production method, it is characterised in that it comprises the following steps：
A, preparation bottom base；
B, pattern layer is set with stamp or ink-jetting style；
C, laying clear frit or translucent glaze layer above pattern layer；
D, set again with stamp or ink-jetting style pattern layer, then re-lay clear frit or translucent glaze layer；
E, burn till.
As further illustrating for such scheme, before the step b, ground glaze layer is also applied with.
Further, the applying mode of ground glaze layer is, using pouring glaze mode, to drench the number of plies of ground-coat enamel at least one of which, ground floor The formula composition of ground-coat enamel includes potassium feldspar 30-50%, albite 17-20%, quartz 18-25%, kaolinite according to percentage by weight Native 5-8%, zinc oxide 1-3%, burning talcum 2-5%, aluminum oxide 6-18%.
Further, after the preparation bottom base of the step a, micro mist cloth operation can be as needed carried out, after cloth It is dried again or biscuiting, carries out the stamp or jet ink process as described in step b again afterwards.
Further, the operation of the step d can repeat to set, and form multilayer colored glaze pattern.
Further, during the preparation bottom base of step a, its formula composition includes potassium feldspar according to percentage by weight 55-60%, albite 22-25%, black mud 13-20%, kaolin 3-8%, burning talcum 1-3%.
Further, during the preparation bottom base of step a, after dispensing by ball milling, sieving, except iron, stock tank homogenizing, spray Mist is made powder after drying.
Further, the formula composition of clear frit includes according to percentage by weight：Wollastonite 6-15%, potassium feldspar 25- 40%th, albite 10-25%, quartz 5-15%, kaolin 5-10%, barium carbonate 8-17%, zinc oxide 5-13%, burning talcum 2- 8%th, aluminum oxide 0-8%.
It is of the invention to be using the above-mentioned technical solution beneficial effect to be reached：
The present invention uses two-layer or multilayer in-glaze decoration mode, and by kiln once-firing, keeps the saturating of each layer glaze layer Lightness and crystalistic sense, make pattern be distributed among different planes, mutually set off, make ceramic tile patterns reach solid, sludge ice, The color visual effect of layer.
Specific embodiment
The technical program is explained in detail below in conjunction with specific embodiment.
The present invention is the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles, and it comprises the following steps：
A, blank are prepared (formula as below is according to percentage by weight)；
Potassium feldspar 55-60%, albite 22-25%, black mud 13-20%, kaolin 3-8%, burning talcum 1-3%.Formula Composition：SiO2 68-70%, Al2O3 19-21%, K2O 3-4%, Na2O 2-3%, CaO 0-1%, MgO 0-1%, Fe2O3 0-1%, TiO2 0-1%, loss on ignition 5-6%.Further, the present embodiment uses potassium feldspar 57%, albite 23%th, black mud 15%, kaolin 3%, burning talcum 2%.
By ball milling, the speed of 4-8 hours is ground with 15 tons -60 tons of pellet, sieved 5-10 minutes, except iron 3-8 minutes, slurry Pond is homogenized 1-2 days, and spray drying is made powder；
B, compressing, press-molding pressure 300bar, product specification 800*800mm；
C, dry kiln are dried, and kiln is long 220 meters, and 60 minutes arid cycles, moisture requirement is less than 1.5% after drying；
D, water spray, typically carry out water spray treatment, injection flow rate 40g/ pieces to every ceramic tile using two pressure type spray guns；
E, pouring ground-coat enamel：Proportion 1.9, flow velocity duration 30 seconds, weight 320g/ pieces；
The formula of ground-coat enamel is constituted according to percentage by weight：
Title Potassium feldspar Albite Quartz Kaolin Zinc oxide Burn talcum Aluminum oxide
The first floor 30-50 17-20 18-25 5-8 1-3 2-5 6-18
Two layers 25-30 14-17 15-20 6-10 1-3 1-4 18-23
Three layers 20-25 10-14 10-15 7-10 1-3 1-3 23-35
In the present embodiment, the optimization formula of ground-coat enamel is constituted according to percentage by weight
Title Potassium feldspar Albite Quartz Kaolin Zinc oxide Burn talcum Aluminum oxide
The first floor 35 18 20 6 2 3 16
Two layers 30 16 18 8 2 3 23
Three layers 24 13 14 8 3 3 35
F, ink-jet：With Tao Lixi inks and Mei Jia ink jet numbering machines；
G, pouring clear frit：Proportion 1.81, flow velocity duration 35 seconds, weight 320g/ pieces；
Repeat step f and g tri- times；
Wherein, the formula of clear frit is constituted according to percentage by weight：
Title Wollastonite Potassium feldspar Albite Quartz Kaolin Barium carbonate Zinc oxide Burn talcum Aluminum oxide
The first floor 10-15 35-40 10-15 5-10 5-10 8-13 5-9 2-5 0-8
Two layers 8-13 30-35 15-20 8-13 6-8 10-15 7-11 3-6 0-5
Three layers 6-10 25-30 20-25 10-15 7-10 11-17 8-13 3-8 0-3
In the present embodiment, the optimization formula of clear frit is constituted according to percentage by weight：
Title Wollastonite Potassium feldspar Albite Quartz Kaolin Barium carbonate Zinc oxide Burn talcum Aluminum oxide
The first floor 13 36 14 6 6 9 6 4 6
Two layers 10 32 18 10 7 13 8 1 1
Three layers 7 27 23 10 8 12 9 1 3
It is worth noting that, the number of times of the step f and g can also be once, twice, or it is more more than three times.
H, once-firing, kiln are long 210 meters, and according to two-layer clear frit and ink-jet layer process, firing period is 58 minutes, 1210 degrees Celsius of temperature, three layers are then firing period 70 minutes, 1205 degrees Celsius of temperature；Four layers of then firing period 80 minute, temperature 1200 degrees Celsius of degree；
I, polishing, edging, waxing；
J, classification, packaging.
The place of production of the potassium feldspar used is Hunan, and the albite place of production is Hunan, and the kaolinic place of production is Maoming, burns and slides The place of production of stone is Jiangxi, and the place of production of black mud is Huizhou, the present invention compared with prior art, using two-layer or multilayer in-glaze decoration side Formula, and by kiln once-firing, the transparency and crystalistic sense of each layer glaze layer are kept, pattern is distributed in different putting down Among face, mutually set off, ceramic tile patterns is reached the color visual effect of solid, sludge ice, layer.
Above-described is only the preferred embodiment of the present invention, it is noted that for one of ordinary skill in the art For, without departing from the concept of the premise of the invention, various modifications and improvements can be made, these belong to the present invention Protection domain.

Claims (8)

1. the three-dimensional sludge ice lamination in-glaze decoration production method of a kind of Ceramic Tiles, it is characterised in that it comprises the following steps：
A, preparation bottom base；
B, pattern layer is set with stamp or ink-jetting style；
C, laying clear frit or translucent glaze layer above pattern layer；
D, set again with stamp or ink-jetting style pattern layer, then re-lay clear frit or translucent glaze layer；
E, burn till.
2. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that described Before step b, ground glaze layer is also applied with.
3. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 2, it is characterised in that ground glaze layer Applying mode be that using drenching glaze mode, the number of plies for drenching ground-coat enamel is at least one of which, and the formula of ground floor ground-coat enamel is constituted according to weight Percentage includes potassium feldspar 30-50%, albite 17-20%, quartz 18-25%, kaolin 5-8%, zinc oxide 1-3%, burning Talcum 2-5%, aluminum oxide 6-18%.
4. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that described After the preparation bottom base of step a, micro mist cloth operation is carried out, be dried again or biscuiting after cloth, carried out again afterwards such as step b institutes The stamp or jet ink process stated.
5. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that the step The operation of rapid d repeats to set, and forms multilayer colored glaze pattern.
6. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that in step During the preparation bottom base of a, its formula composition includes potassium feldspar 55-60%, albite 22-25%, black according to percentage by weight Mud 13-20%, kaolin 3-8%, burning talcum 1-3%.
7. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that in step During the preparation bottom base of a, after dispensing by ball milling, sieving, except iron, stock tank homogenizing, spray drying after be made powder.
8. the three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles according to claim 1, it is characterised in that clear frit Formula composition include according to percentage by weight：Wollastonite 6-15%, potassium feldspar 25-40%, albite 10-25%, quartz 5- 15%th, kaolin 5-10%, barium carbonate 8-17%, zinc oxide 5-13%, burning talcum 2-8%, aluminum oxide 0-8%.
CN201710134442.9A 2017-03-08 2017-03-08 The three-dimensional sludge ice lamination in-glaze decoration production method of Ceramic Tiles Pending CN106866184A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793953A (en) * 2018-06-29 2018-11-13 河源市东源鹰牌陶瓷有限公司 Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof
CN109627052A (en) * 2019-01-16 2019-04-16 佛山欧神诺陶瓷有限公司 A kind of Ceramic Tiles and preparation method thereof with three-dimensional decorative effect
CN109795017A (en) * 2019-03-29 2019-05-24 东莞市唯美陶瓷工业园有限公司 Stablize the preparation method of brindled brick
CN110117197A (en) * 2019-05-30 2019-08-13 湖南醴陵红官窑瓷业有限公司 A kind of formula and preparation method preventing multi-layer intelligent colored drawing glaze ceramics contracting glaze
CN112094137A (en) * 2020-11-20 2020-12-18 广东欧文莱陶瓷有限公司 Ceramic tile with metal texture and preparation method thereof
CN113248144A (en) * 2021-05-06 2021-08-13 佛山市三水宏源陶瓷企业有限公司 Preparation method of matte and fine surface of dry grain glazed rock plate
CN115724648A (en) * 2022-11-02 2023-03-03 广东简一(集团)陶瓷有限公司 In-glaze color ceramic tile and preparation method thereof
CN116003168A (en) * 2023-01-12 2023-04-25 佛山市东鹏陶瓷有限公司 Glazed tile containing ink-jet printed three-dimensional pattern and preparation method thereof

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Publication number Priority date Publication date Assignee Title
WO2000056558A1 (en) * 1999-03-24 2000-09-28 3 Dts, A.S. A ceramic tile provided with a decor
CN102329135A (en) * 2011-09-30 2012-01-25 广东东鹏陶瓷股份有限公司 Production method capable of firing polished crystal tile in one step
CN103992141A (en) * 2014-05-09 2014-08-20 佛山市东鹏陶瓷有限公司 Manufacturing method of glazed brick and product thereof
CN105330342A (en) * 2015-10-15 2016-02-17 蒙娜丽莎集团股份有限公司 One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000056558A1 (en) * 1999-03-24 2000-09-28 3 Dts, A.S. A ceramic tile provided with a decor
CN102329135A (en) * 2011-09-30 2012-01-25 广东东鹏陶瓷股份有限公司 Production method capable of firing polished crystal tile in one step
CN103992141A (en) * 2014-05-09 2014-08-20 佛山市东鹏陶瓷有限公司 Manufacturing method of glazed brick and product thereof
CN105330342A (en) * 2015-10-15 2016-02-17 蒙娜丽莎集团股份有限公司 One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793953A (en) * 2018-06-29 2018-11-13 河源市东源鹰牌陶瓷有限公司 Low clay glazed tile green body of a kind of low temperature fast firing and preparation method thereof
CN108793953B (en) * 2018-06-29 2021-09-17 河源市东源鹰牌陶瓷有限公司 Low-clay glazed brick blank capable of being quickly fired at low temperature and preparation method thereof
CN109627052A (en) * 2019-01-16 2019-04-16 佛山欧神诺陶瓷有限公司 A kind of Ceramic Tiles and preparation method thereof with three-dimensional decorative effect
CN109627052B (en) * 2019-01-16 2021-07-13 佛山欧神诺陶瓷有限公司 Ceramic tile with three-dimensional decoration effect and preparation method thereof
CN109795017A (en) * 2019-03-29 2019-05-24 东莞市唯美陶瓷工业园有限公司 Stablize the preparation method of brindled brick
CN110117197A (en) * 2019-05-30 2019-08-13 湖南醴陵红官窑瓷业有限公司 A kind of formula and preparation method preventing multi-layer intelligent colored drawing glaze ceramics contracting glaze
CN112094137A (en) * 2020-11-20 2020-12-18 广东欧文莱陶瓷有限公司 Ceramic tile with metal texture and preparation method thereof
CN113248144A (en) * 2021-05-06 2021-08-13 佛山市三水宏源陶瓷企业有限公司 Preparation method of matte and fine surface of dry grain glazed rock plate
CN115724648A (en) * 2022-11-02 2023-03-03 广东简一(集团)陶瓷有限公司 In-glaze color ceramic tile and preparation method thereof
CN116003168A (en) * 2023-01-12 2023-04-25 佛山市东鹏陶瓷有限公司 Glazed tile containing ink-jet printed three-dimensional pattern and preparation method thereof

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