CN106833121A - A kind of tipping paper of application novel resin material and preparation method thereof - Google Patents

A kind of tipping paper of application novel resin material and preparation method thereof Download PDF

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Publication number
CN106833121A
CN106833121A CN201710166378.2A CN201710166378A CN106833121A CN 106833121 A CN106833121 A CN 106833121A CN 201710166378 A CN201710166378 A CN 201710166378A CN 106833121 A CN106833121 A CN 106833121A
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CN
China
Prior art keywords
water
resin
parts
paper
tipping
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710166378.2A
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Chinese (zh)
Inventor
杜盛钢
焦剑
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Printing Co Ltd Jiangsu Sheng State Printing
Original Assignee
Printing Co Ltd Jiangsu Sheng State Printing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Printing Co Ltd Jiangsu Sheng State Printing filed Critical Printing Co Ltd Jiangsu Sheng State Printing
Priority to CN201710166378.2A priority Critical patent/CN106833121A/en
Publication of CN106833121A publication Critical patent/CN106833121A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paper (AREA)

Abstract

The invention provides a kind of tipping paper of application novel resin material, it is characterised in that including tipping base paper and the water-based ink being printed on the tipping base paper, the water-based ink is prepared from by the raw material of following weight portion:45~50 parts of resin;1~2 part of antiseptic;10~20 parts of dispersant;3~5 parts of iron oxide color paste;20~25 parts of titanium dioxide;10~15 parts of water;And 5~8 parts of auxiliary agent;Wherein, the resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin.The tipping paper of above-mentioned application novel resin material, as the water-based ink of main component, the adhesive force of water-based ink can be significantly improved due to using water-based acrylic resin and Acrylate Modified Aqueous Polyurethane mixed with resin resin, reduce production cost, energy-conserving and environment-protective;Simultaneously as addition has antiseptic, the antibacterial effect of water-based ink can be strengthened, making the tipping paper of printing has bacteriostasis property.

Description

A kind of tipping paper of application novel resin material and preparation method thereof
Technical field
The present invention relates to tipping paper field, the tipping paper of more particularly to a kind of application novel resin material and its preparation side Method.
Background technology
Tipping paper, belongs to auxiliary material for cigarette, is the extraordinary paper products for connecting cigarette filter and Cigarette, That is that layer of paper of cigarette filter outermost, it is typically to be printed with white tipping base paper, belongs to special industrial paper.It is existing A large amount of chemicals are used in printing process in tipping paper, with alcohol ink or alcohol-soluble printing ink print, tipping paper Surface can remain a certain amount of VOC, and filter tip and cigarette are connected with this paper, packaged to be sealed In cigarette case, the VOC remained in tipping paper can be diffused into pipe tobacco go unavoidably, during smoking property of cigarette, The oxious component in flue gas is increased, the suction taste of flue gas is have impact on;Further, tipping paper is printed using alcohols, esters solvent ink During, the organic exhaust gas containing these solvents can be largely discharged, burden not only is caused to environment, and also result in The waste of machine solvent resource;In addition, compared with water-based ink, tipping paper is printed using alcohols, esters solvent ink, can also increase Production cost, also have impact on Business Economic Benefit.
The content of the invention
Based on this, it is necessary to provide tipping paper and its preparation side of a kind of relatively low application novel resin material of production cost Method.
A kind of tipping paper of application novel resin material, including tipping base paper and be printed on aqueous on the tipping base paper Ink, the water-based ink is prepared from by the raw material of following weight portion:
Wherein, the resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin.
Wherein in one embodiment, the weight of the water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin Than being 5:2.
Wherein in one embodiment, the auxiliary agent is 2,4,7,9- tetramethyl -5- decine -4,7- glycol.
Wherein in one embodiment, the antiseptic drenches ketone or quaternary ammonium salt using isothiazole.
A kind of preparation method of the tipping paper of application novel resin material, comprises the following steps:
1) it is 1 with ratio:1 ethanol and aqueous mixtures dilution water-based ink, the water-based ink is by following weight portion Each group is grouped into:45~50 parts of resin;1~2 part of antiseptic;10~20 parts of dispersant;3~5 parts of iron oxide color paste;Titanium dioxide 20~25 parts;10~15 parts of water;And 5~8 parts of auxiliary agent;Wherein, the resin is water-based acrylic resin and acrylic acid modified water The hybrid resin of property polyurethane resin;The ethanol and aqueous mixtures and the weight ratio of water-based ink are 1:2~3;
2) tipping base paper is positioned over the Printing Zone of printing machine, it is former using being hinged with described in the water-based ink printing paper after dilution On paper, squeegee pressure is 0.3~0.5MPa, and 10~15s is toasted under the conditions of being then 100~120 DEG C in temperature, is applied new The tipping paper of type resin material.
Wherein in one embodiment, the weight of the water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin Than being 5:2.
The tipping paper of above-mentioned application novel resin material, due to poly- using water-based acrylic resin and acrylic modified waterborne Urethane mixed with resin resin can significantly improve the adhesive force of water-based ink as the water-based ink of main component, reduce production Cost, energy-conserving and environment-protective;Simultaneously as addition has antiseptic, the antibacterial effect of water-based ink can be strengthened, make the tipping paper of printing With bacteriostasis property.
Specific embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that apparent clearly being defined so as to be made to protection scope of the present invention.
Embodiment 1
A kind of preparation method of the tipping paper of application novel resin material, comprises the following steps:
1) it is 1 with ratio:1 ethanol and aqueous mixtures dilution water-based ink, water-based ink by following weight portion each group It is grouped into:45 parts of resin;1 part of antiseptic;10 parts of dispersant;3 parts of iron oxide color paste;20 parts of titanium dioxide;10 parts of water;And auxiliary agent 5 parts;Wherein, resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin;Second alcohol and water is mixed Compound is 1 with the weight ratio of water-based ink:2;
2) tipping base paper is positioned over the Printing Zone of printing machine, it is former using being hinged with described in the water-based ink printing paper after dilution On paper, squeegee pressure is 0.3MPa, and 10s is toasted under the conditions of being then 100 DEG C in temperature, and the novel resin material that is applied connects Dress paper.
Wherein, the weight ratio of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin is 5:2, auxiliary agent is 2,4, 7,9- tetramethyl -5- decine -4,7- glycol, antiseptic drenches ketone using isothiazole.
Embodiment 2
A kind of preparation method of the tipping paper of application novel resin material, comprises the following steps:
1) it is 1 with ratio:1 ethanol and aqueous mixtures dilution water-based ink, the water-based ink is by following weight portion Each group is grouped into:45 parts of resin;2 parts of antiseptic;20 parts of dispersant;5 parts of iron oxide color paste;25 parts of titanium dioxide;15 parts of water;And 8 parts of auxiliary agent;Wherein, resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin;Ethanol and Aqueous mixtures are 1 with the weight ratio of water-based ink:3;
2) tipping base paper is positioned over the Printing Zone of printing machine, it is former using being hinged with described in the water-based ink printing paper after dilution On paper, squeegee pressure is 0.5MPa, and 15s is toasted under the conditions of being then 120 DEG C in temperature, and the novel resin material that is applied connects Dress paper.
Wherein, the weight ratio of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin is 5:2, auxiliary agent is 2,4, 7,9- tetramethyl -5- decine -4,7- glycol, antiseptic uses quaternary ammonium salt.
Embodiment 3
A kind of preparation method of the tipping paper of application novel resin material, comprises the following steps:
1) it is 1 with ratio:1 ethanol and aqueous mixtures dilution water-based ink, the water-based ink is by following weight portion Each group is grouped into:48 parts of resin;1.5 parts of antiseptic;18 parts of dispersant;4 parts of iron oxide color paste;23 parts of titanium dioxide;13 parts of water; And 7 parts of auxiliary agent;Wherein, resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin;Ethanol It is 1 with the weight ratio of aqueous mixtures and water-based ink:2;
2) tipping base paper is positioned over the Printing Zone of printing machine, it is former using being hinged with described in the water-based ink printing paper after dilution On paper, squeegee pressure is 0.4MPa, and 13s is toasted under the conditions of being then 110 DEG C in temperature, and the novel resin material that is applied connects Dress paper.
Wherein, the weight ratio of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin is 5:2, auxiliary agent is 2,4, 7,9- tetramethyl -5- decine -4,7- glycol, antiseptic drenches ketone using isothiazole.
The tipping paper of above-mentioned application novel resin material, due to poly- using water-based acrylic resin and acrylic modified waterborne Urethane mixed with resin resin can significantly improve the adhesive force of water-based ink as the water-based ink of main component, reduce production Cost, energy-conserving and environment-protective;Simultaneously as addition has antiseptic, the antibacterial effect of water-based ink can be strengthened, make the tipping paper of printing With bacteriostasis property.
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Shield scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (6)

1. a kind of tipping paper of application novel resin material, it is characterised in that including tipping base paper and to be printed on the tipping former Water-based ink on paper, the water-based ink is prepared from by the raw material of following weight portion:
Wherein, the resin is the hybrid resin of water-based acrylic resin and Acrylate Modified Aqueous Polyurethane resin.
2. the tipping paper of application novel resin material according to claim 1, it is characterised in that the water soluble acrylic acid tree The weight ratio of fat and Acrylate Modified Aqueous Polyurethane resin is 5:2.
3. the tipping paper of application novel resin material according to claim 1, it is characterised in that the auxiliary agent is 2,4,7, 9- tetramethyl -5- decine -4,7- glycol.
4. the tipping paper of application novel resin material according to claim 1, it is characterised in that the antiseptic is using different Thiazole drenches ketone or quaternary ammonium salt.
5. a kind of preparation method of the tipping paper of application novel resin material, it is characterised in that comprise the following steps:
1) it is 1 with ratio:1 ethanol and aqueous mixtures dilution water-based ink, the water-based ink by following weight portion each group It is grouped into:45~50 parts of resin;1~2 part of antiseptic;10~20 parts of dispersant;3~5 parts of iron oxide color paste;Titanium dioxide 20~ 25 parts;10~15 parts of water;And 5~8 parts of auxiliary agent;Wherein, the resin is that water-based acrylic resin and acrylic modified waterborne are poly- The hybrid resin of urethane resin;The ethanol and aqueous mixtures and the weight ratio of water-based ink are 1:2~3;
2) tipping base paper is positioned over the Printing Zone of printing machine, tipping base paper described in the water-based ink printing paper after dilution is used On, squeegee pressure is 0.3~0.5MPa, and 10~15s is toasted under the conditions of being then 100~120 DEG C in temperature, is applied new The tipping paper of resin material.
6. the preparation method of the tipping paper of application novel resin material according to claim 5, it is characterised in that the water Property acrylic resin and Acrylate Modified Aqueous Polyurethane resin weight ratio be 5:2.
CN201710166378.2A 2017-03-20 2017-03-20 A kind of tipping paper of application novel resin material and preparation method thereof Pending CN106833121A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710166378.2A CN106833121A (en) 2017-03-20 2017-03-20 A kind of tipping paper of application novel resin material and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710166378.2A CN106833121A (en) 2017-03-20 2017-03-20 A kind of tipping paper of application novel resin material and preparation method thereof

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CN106833121A true CN106833121A (en) 2017-06-13

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777197A (en) * 2019-01-28 2019-05-21 宜昌金兴新材料有限公司 A kind of laser paper ink and preparation method thereof
CN109972434A (en) * 2017-12-28 2019-07-05 阜阳卷烟材料厂 A kind of waterproof safety body paper for tobacco-use tipping paper and preparation method thereof
CN111454611A (en) * 2020-06-06 2020-07-28 浙江荣丰纸业有限公司 Printing ink for colorful tipping paper and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101718056A (en) * 2009-11-17 2010-06-02 何金星 Method for preparing water-based ink tipping paper with anti-bacterial and anti-virus function

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101718056A (en) * 2009-11-17 2010-06-02 何金星 Method for preparing water-based ink tipping paper with anti-bacterial and anti-virus function

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109972434A (en) * 2017-12-28 2019-07-05 阜阳卷烟材料厂 A kind of waterproof safety body paper for tobacco-use tipping paper and preparation method thereof
CN109777197A (en) * 2019-01-28 2019-05-21 宜昌金兴新材料有限公司 A kind of laser paper ink and preparation method thereof
CN111454611A (en) * 2020-06-06 2020-07-28 浙江荣丰纸业有限公司 Printing ink for colorful tipping paper and preparation method thereof

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Application publication date: 20170613