CN105331181B - A kind of high performance print detergent for ink and preparation method thereof - Google Patents

A kind of high performance print detergent for ink and preparation method thereof Download PDF

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Publication number
CN105331181B
CN105331181B CN201510891191.XA CN201510891191A CN105331181B CN 105331181 B CN105331181 B CN 105331181B CN 201510891191 A CN201510891191 A CN 201510891191A CN 105331181 B CN105331181 B CN 105331181B
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China
Prior art keywords
parts
ink
detergent
high performance
trisodium
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Expired - Fee Related
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CN201510891191.XA
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Chinese (zh)
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CN105331181A (en
Inventor
廉玉生
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Beijing Institute of Graphic Communication
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Beijing Institute of Graphic Communication
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Priority to CN201510891191.XA priority Critical patent/CN105331181B/en
Publication of CN105331181A publication Critical patent/CN105331181A/en
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Publication of CN105331181B publication Critical patent/CN105331181B/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/04Chemical paint or ink removers with surface-active agents

Abstract

The invention discloses a kind of high performance print detergent for ink and preparation method thereof, it is formulated by the raw material of following parts by weight:45 55 parts of kerosene, 48 parts of diethylene glycol ether, 35 parts of coconut oil monoglyceride ammonium sulfate, 56 parts of dibutyl phthalate, 10 14 parts of trisodium citrate, 14 18 parts of sodium lauroyl sarcosine, 24 parts of nitrilotriacetic acid trisodium, 12 parts of sodium tripolyphosphate, 35 parts of cetearyl glucoside, 23 parts of dodecyl Hydroxypropyl phosphate ester glycine betaine, 0.2 0.6 parts of triethanolamine, 0.5 0.9 parts of naphthenic acid imidazoline borate, 0.6 1 parts of n-butanol, 46 parts of nanometer 4A zeolite molecular sieves, 35 parts of sapindoside, 34 parts of urea, 23 parts of SAS, 85 95 parts of deionized water.Inventive formulation is simple, simple for production, and cleaning performance is good, safe and non-toxic, and stability is high.

Description

A kind of high performance print detergent for ink and preparation method thereof
Invention field
The present invention relates to a kind of cleaning agent, concretely relates to a kind of high performance print detergent for ink and its preparation side Method.
Background technology
Ink is the important materials for printing, and it is shown pattern, word on stock by printing.Ink is general It is made up of pigment, link stuff, solvent and auxiliary agent etc., these compositions equably mix and form a kind of stickiness glue through repeat-rolling Fluid, ink are widely used in the various printings such as books and periodicals, packing and decorating, building decoration.Because ink has stronger adhesive force and glues Knot property, the hand of printing worker are printed after ink makes dirty, and superfine pigment can enter palmmprint with ink base, and cleaning is stranded very much Difficulty, it is difficult to clean with soap and general detergent, severe jamming and the normal work for affecting workpeople.At present, in the market There are products of some special cleaning ink, but the cleaning performance of these products be not it is obvious that and price compare Expensive, application method is inconvenient, therefore develops a kind of cleaning ink significant effect and product low-cost, that application method is easy shows Obtain very necessary.
The content of the invention
It is an object of the invention to provide a kind of high performance print detergent for ink and preparation method thereof.
To reach above-mentioned purpose, the technical solution used in the present invention is:
A kind of high performance print detergent for ink, it is characterised in that in parts by weight, by the preparation of following weight raw material Into:Kerosene 45-55 parts, diethylene glycol ether 4-8 parts, coconut oil monoglyceride ammonium sulfate 3-5 parts, dibutyl phthalate 5- 6 parts, trisodium citrate 10-14 parts, sodium lauroyl sarcosine 14-18 parts, nitrilotriacetic acid trisodium 2-4 parts, sodium tripolyphosphate 1-2 Part, cetearyl glucoside 3-5 parts, dodecyl Hydroxypropyl phosphate ester glycine betaine 2-3 parts, triethanolamine 0.2-0.6 parts, ring Alkanoic acid Imidazoline Borate 0.5-0.9 parts, n-butanol 0.6-1 parts, nanometer 4A zeolite molecular sieve 4-6 parts, sapindoside 3-5 Part, urea 3-4 parts, SAS 2-3 parts, deionized water 85-95 parts.
A kind of preparation method of high performance print detergent for ink, it is characterised in that comprise the following steps:
(1) will kerosene add stirred tank in, stir while add diethylene glycol ether, cetearyl glucoside, Dibutyl phthalate, trisodium citrate, sodium lauroyl sarcosine, nitrilotriacetic acid trisodium, sodium tripolyphosphate, are stirred to complete Fully dissolved, obtain component A;
(2) deionized water is heated to 65-75 DEG C in water-bath, then adds coconut oil monoglyceride ammonium sulfate, ten Dialkyl group Hydroxypropyl phosphate ester glycine betaine, nanometer 4A zeolite molecular sieves, sapindoside, urea, SAS, stirring 15-20min, obtain B component;
(3) component A and B component obtained above-mentioned steps be mixed evenly after transparent shape add triethanolamine, The raw materials such as naphthenic acid imidazoline borate, n-butanol, stir 20-30min, and filtering and impurity removing matter obtains the cleaning of high performance print ink Agent.
Beneficial effects of the present invention:
Cetearyl glucoside, dodecyl Hydroxypropyl phosphate ester glycine betaine and the coconut oil list glycerine that the present invention adds Ester ammonium sulfate can reduce the surface tension in solution, improve cleaning efficiency, the nitrilotriacetic acid trisodium of addition, sodium tripolyphosphate Sapindoside can be cooperateed with to improve the activity of solution, nanometer 4A zeolite molecular sieves, urea and the SAS of addition can To strengthen dirt-removing power, and there is the effect such as certain emulsion dispersion to greasy dirt, the triethanolamine of addition can adjust pH value, and Sodium lauroyl sarcosine, naphthenic acid imidazoline borate and use can improve antirust ability, and the n-butanol of addition can strengthen cleaning agent Stability and penetration.Inventive formulation is simple, simple for production, and cleaning performance is good, safe and non-toxic, and stability is high.
Embodiment
Technical scheme of the present invention is further described with reference to specific embodiment.
Embodiment 1:
A kind of high performance print detergent for ink, in parts by weight, it is formulated by following weight raw material:45 parts of kerosene, 4 parts of diethylene glycol ether, 3 parts of coconut oil monoglyceride ammonium sulfate, 5 parts of dibutyl phthalate, trisodium citrate 10 part, month 14 parts of osmanthus acylsarcosine sodium, 2 parts of nitrilotriacetic acid trisodium, 1 part of sodium tripolyphosphate, 3 parts of cetearyl glucoside, dodecyl 2 parts of Hydroxypropyl phosphate ester glycine betaine, 0.2 part of triethanolamine, 0.5 part of naphthenic acid imidazoline borate, n-butanol 0.6 part, nanometer 4 parts of 4A zeolite molecular sieves, 3 parts of sapindoside, 3 parts of urea, 2 parts of SAS, 85 parts of deionized water.
A kind of preparation method of high performance print detergent for ink, comprises the following steps:
(1) will kerosene add stirred tank in, stir while add diethylene glycol ether, cetearyl glucoside, Dibutyl phthalate, trisodium citrate, sodium lauroyl sarcosine, nitrilotriacetic acid trisodium, sodium tripolyphosphate, are stirred to complete Fully dissolved, obtain component A;
(2) deionized water is heated to 65-75 DEG C in water-bath, then adds coconut oil monoglyceride ammonium sulfate, ten Dialkyl group Hydroxypropyl phosphate ester glycine betaine, nanometer 4A zeolite molecular sieves, sapindoside, urea, SAS, stirring 15-20min, obtain B component;
(3) component A and B component obtained above-mentioned steps be mixed evenly after transparent shape add triethanolamine, The raw materials such as naphthenic acid imidazoline borate, n-butanol, stir 20-30min, and filtering and impurity removing matter obtains the cleaning of high performance print ink Agent.
Embodiment 2:
A kind of high performance print detergent for ink, in parts by weight, it is formulated by following weight raw material:50 parts of kerosene, 6 parts of diethylene glycol ether, 4 parts of coconut oil monoglyceride ammonium sulfate, 5.5 parts of dibutyl phthalate, 12 parts of trisodium citrate, 16 parts of sodium lauroyl sarcosine, 3 parts of nitrilotriacetic acid trisodium, 1.5 parts of sodium tripolyphosphate, 4 parts of cetearyl glucoside, 12 2.5 parts of alkyl hydroxypropyl base phosphate glycine betaine, 0.4 part of triethanolamine, 0.7 part of naphthenic acid imidazoline borate, n-butanol 0.8 Part, 5 parts of nanometer 4A zeolite molecular sieves, 4 parts of sapindoside, 3.5 parts of urea, 2.5 parts of SAS, deionized water 90 Part.
Preparation method is the same as embodiment 1.
Embodiment 3:
A kind of high performance print detergent for ink, in parts by weight, it is formulated by following weight raw material:55 parts of kerosene, 8 parts of diethylene glycol ether, 5 parts of coconut oil monoglyceride ammonium sulfate, 6 parts of dibutyl phthalate, trisodium citrate 14 part, month 18 parts of osmanthus acylsarcosine sodium, 4 parts of nitrilotriacetic acid trisodium, 2 parts of sodium tripolyphosphate, 5 parts of cetearyl glucoside, dodecyl 3 parts of Hydroxypropyl phosphate ester glycine betaine, 0.6 part of triethanolamine, 0.9 part of naphthenic acid imidazoline borate, n-butanol 0.7 part, nanometer 5 parts of 4A zeolite molecular sieves, 4 parts of sapindoside, 3.5 parts of urea, 2.5 parts of SAS, 90 parts of deionized water.
Preparation method is the same as embodiment 1.
The performance test results of high performance print detergent for ink are as shown in the table made from above-described embodiment 1-3:
Embodiment 1 Embodiment 2 Embodiment 3
Detersive efficiency, % 98.5 98.4 98.7
Surface tension, N/m 8.5×10-2 8.8×10-2 9.3×10-2

Claims (2)

1. a kind of high performance print detergent for ink, in parts by weight, it is formulated by following weight raw material:45 parts of kerosene, two 4 parts of ethylene glycol ethyl ether, 3 parts of coconut oil monoglyceride ammonium sulfate, 5 parts of dibutyl phthalate, 10 parts of trisodium citrate, bay 14 parts of acylsarcosine sodium, 2 parts of nitrilotriacetic acid trisodium, 1 part of sodium tripolyphosphate, 3 parts of cetearyl glucoside, dodecyl hydroxyl 2 parts of propyl phosphate glycine betaine, 0.2 part of triethanolamine, 0.5 part of naphthenic acid imidazoline borate, n-butanol 0.6 part, nanometer 4A 4 parts of zeolite molecular sieve, 3 parts of sapindoside, 3 parts of urea, 2 parts of SAS, 85 parts of deionized water.
2. a kind of preparation method of high performance print detergent for ink as claimed in claim 1, comprises the following steps:
(1) kerosene is added in stirred tank, stirred while adding diethylene glycol ether, cetearyl glucoside, adjacent benzene Dibutyl carboxylic acid, trisodium citrate, sodium lauroyl sarcosine, nitrilotriacetic acid trisodium, sodium tripolyphosphate, stir to completely molten Solution, obtains component A;
(2) deionized water is heated to 65-75 DEG C in water-bath, then adds coconut oil monoglyceride ammonium sulfate, dodecane Base Hydroxypropyl phosphate ester glycine betaine, nanometer 4A zeolite molecular sieves, sapindoside, urea, SAS, stir 15- 20min, obtain B component;
(3) component A and B component obtained above-mentioned steps adds triethanolamine, cycloalkanes after transparent shape is mixed evenly The raw materials such as imidazole acid quinoline borate, n-butanol, stir 20-30min, and filtering and impurity removing matter obtains high performance print detergent for ink.
CN201510891191.XA 2015-12-07 2015-12-07 A kind of high performance print detergent for ink and preparation method thereof Expired - Fee Related CN105331181B (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN105331181B true CN105331181B (en) 2018-02-13

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Publication number Priority date Publication date Assignee Title
CN107304316A (en) * 2016-04-20 2017-10-31 天津市有为印刷包装有限公司 A kind of environmentally friendly low foam detergent for ink and preparation method thereof
CN108530975A (en) * 2018-04-17 2018-09-14 句容市合力印刷有限公司 A kind of high-property water-based detergent for ink and preparation method thereof

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US8222194B2 (en) * 2008-05-09 2012-07-17 Rhodia Operations Cleaning compositions incorporating green solvents and methods for use
CN104098951B (en) * 2013-04-03 2016-01-20 东莞市剑鑫电子材料有限公司 A kind of five metals detergent for ink and preparation method thereof
CN103214898A (en) * 2013-04-26 2013-07-24 南京信息工程大学 Water-based printing ink cleaning agent and preparation method thereof
CN103613977A (en) * 2013-10-20 2014-03-05 安徽美翔塑业有限公司 Printing ink detergent
CN103865317B (en) * 2014-02-27 2016-04-27 安徽颍美彩印包装有限公司 A kind of printing ink washing agent and preparation method thereof

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