CN106810710B - 一种超疏水石墨烯/聚氨酯海绵的制备方法 - Google Patents
一种超疏水石墨烯/聚氨酯海绵的制备方法 Download PDFInfo
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- CN106810710B CN106810710B CN201510848103.8A CN201510848103A CN106810710B CN 106810710 B CN106810710 B CN 106810710B CN 201510848103 A CN201510848103 A CN 201510848103A CN 106810710 B CN106810710 B CN 106810710B
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- Prior art keywords
- super
- polyurethane sponge
- hydrophobic
- graphene
- sponge
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 46
- 239000004814 polyurethane Substances 0.000 title claims abstract description 44
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 43
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 19
- 239000010439 graphite Substances 0.000 claims abstract description 19
- 239000000243 solution Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 239000011259 mixed solution Substances 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 20
- 239000002131 composite material Substances 0.000 abstract description 5
- 239000003638 chemical reducing agent Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000001069 Raman spectroscopy Methods 0.000 description 4
- 238000007306 functionalization reaction Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 graphite alkene Chemical class 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
- Carbon And Carbon Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510848103.8A CN106810710B (zh) | 2015-11-27 | 2015-11-27 | 一种超疏水石墨烯/聚氨酯海绵的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510848103.8A CN106810710B (zh) | 2015-11-27 | 2015-11-27 | 一种超疏水石墨烯/聚氨酯海绵的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106810710A CN106810710A (zh) | 2017-06-09 |
| CN106810710B true CN106810710B (zh) | 2019-06-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510848103.8A Active CN106810710B (zh) | 2015-11-27 | 2015-11-27 | 一种超疏水石墨烯/聚氨酯海绵的制备方法 |
Country Status (1)
| Country | Link |
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| CN (1) | CN106810710B (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674236B (zh) * | 2017-11-07 | 2020-08-14 | 中国科学院金属研究所 | 一种超双亲聚氨酯泡沫材料及其制备方法 |
| CN108160036B (zh) * | 2018-01-29 | 2020-11-24 | 重庆工商大学 | 一种超疏水磁性泡沫材料的制备方法及应用 |
| CN109621906B (zh) * | 2018-12-15 | 2021-09-03 | 同济大学 | 一种制备可吸收粘稠态原油的复合海绵的方法 |
| CN114452960A (zh) * | 2022-03-08 | 2022-05-10 | 武汉工程大学 | 一种光驱动吸油的MXene改性三聚氰胺海绵及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102923700A (zh) * | 2012-11-30 | 2013-02-13 | 南京大学 | 一种巯基修饰石墨烯的制备方法 |
| CN103772975A (zh) * | 2012-10-25 | 2014-05-07 | 黑龙江鑫达企业集团有限公司 | 石墨烯/聚合物导电复合材料 |
| CN104338519A (zh) * | 2014-09-17 | 2015-02-11 | 上海大学 | 改性石墨烯负载聚氨酯海绵及其制备方法 |
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2015
- 2015-11-27 CN CN201510848103.8A patent/CN106810710B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103772975A (zh) * | 2012-10-25 | 2014-05-07 | 黑龙江鑫达企业集团有限公司 | 石墨烯/聚合物导电复合材料 |
| CN102923700A (zh) * | 2012-11-30 | 2013-02-13 | 南京大学 | 一种巯基修饰石墨烯的制备方法 |
| CN104338519A (zh) * | 2014-09-17 | 2015-02-11 | 上海大学 | 改性石墨烯负载聚氨酯海绵及其制备方法 |
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| Publication number | Publication date |
|---|---|
| CN106810710A (zh) | 2017-06-09 |
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Application publication date: 20170609 Assignee: Jiangsu LiHan Technology Co.,Ltd. Assignor: NANJING University OF SCIENCE AND TECHNOLOGY Contract record no.: X2023980052481 Denomination of invention: A preparation method of superhydrophobic graphene/polyurethane sponge Granted publication date: 20190607 License type: Common License Record date: 20231215 Application publication date: 20170609 Assignee: Jiangsu huizetong Environmental Technology Co.,Ltd. Assignor: NANJING University OF SCIENCE AND TECHNOLOGY Contract record no.: X2023980052479 Denomination of invention: A preparation method of superhydrophobic graphene/polyurethane sponge Granted publication date: 20190607 License type: Common License Record date: 20231215 Application publication date: 20170609 Assignee: Hemiao Environmental Technology (Jiangsu) Co.,Ltd. Assignor: NANJING University OF SCIENCE AND TECHNOLOGY Contract record no.: X2023980052478 Denomination of invention: A preparation method of superhydrophobic graphene/polyurethane sponge Granted publication date: 20190607 License type: Common License Record date: 20231215 Application publication date: 20170609 Assignee: NANJING LIHAN CHEMICAL Co.,Ltd. Assignor: NANJING University OF SCIENCE AND TECHNOLOGY Contract record no.: X2023980052231 Denomination of invention: A preparation method of superhydrophobic graphene/polyurethane sponge Granted publication date: 20190607 License type: Common License Record date: 20231214 |
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