CN106772713B - A kind of anti-microbial coating resin lens and its manufacturing method - Google Patents
A kind of anti-microbial coating resin lens and its manufacturing method Download PDFInfo
- Publication number
- CN106772713B CN106772713B CN201611223227.8A CN201611223227A CN106772713B CN 106772713 B CN106772713 B CN 106772713B CN 201611223227 A CN201611223227 A CN 201611223227A CN 106772713 B CN106772713 B CN 106772713B
- Authority
- CN
- China
- Prior art keywords
- layer
- coated
- coating
- mbar
- resin lens
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 60
- 238000000576 coating method Methods 0.000 title claims abstract description 60
- 239000011347 resin Substances 0.000 title claims abstract description 50
- 229920005989 resin Polymers 0.000 title claims abstract description 50
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 26
- 239000004599 antimicrobial Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000010410 layer Substances 0.000 claims abstract description 176
- 238000000034 method Methods 0.000 claims abstract description 94
- 230000003115 biocidal effect Effects 0.000 claims abstract description 50
- 230000008569 process Effects 0.000 claims abstract description 48
- 238000005516 engineering process Methods 0.000 claims abstract description 44
- 239000007888 film coating Substances 0.000 claims abstract description 40
- 238000009501 film coating Methods 0.000 claims abstract description 40
- 239000006117 anti-reflective coating Substances 0.000 claims abstract description 36
- 238000004544 sputter deposition Methods 0.000 claims abstract description 36
- 239000012790 adhesive layer Substances 0.000 claims abstract description 29
- 238000007598 dipping method Methods 0.000 claims abstract description 4
- 150000002500 ions Chemical class 0.000 claims description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 238000007747 plating Methods 0.000 claims description 26
- 230000008020 evaporation Effects 0.000 claims description 22
- 238000001704 evaporation Methods 0.000 claims description 22
- 239000000853 adhesive Substances 0.000 claims description 17
- 230000001070 adhesive effect Effects 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 8
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 8
- 239000002356 single layer Substances 0.000 claims description 7
- 238000003618 dip coating Methods 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910003978 SiClx Inorganic materials 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 5
- 238000001771 vacuum deposition Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 5
- SHPBBNULESVQRH-UHFFFAOYSA-N [O-2].[O-2].[Ti+4].[Zr+4] Chemical compound [O-2].[O-2].[Ti+4].[Zr+4] SHPBBNULESVQRH-UHFFFAOYSA-N 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- -1 argon ion Chemical class 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 206010061245 Internal injury Diseases 0.000 description 2
- 241000235342 Saccharomycetes Species 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 208000030533 eye disease Diseases 0.000 description 2
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 2
- 210000002429 large intestine Anatomy 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000001976 improved effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/081—Oxides of aluminium, magnesium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/086—Oxides of zinc, germanium, cadmium, indium, tin, thallium or bismuth
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/10—Glass or silica
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
Abstract
The present invention is a kind of anti-microbial coating resin lens and its manufacturing method, it is characterised in that：1, wear-resisting stiffening layer is made using dipping process on resin lens surface；2, antireflective coating is coated in wear-resisting stiffened layer surface using vacuum sputtering coating technology and ion source Aided Film Coating Technique；3, antibiotic layer is coated with using vacuum sputtering coating technology and ion source Aided Film Coating Technique again on antireflective coating surface；4, adhesive layer is coated in antibacterial layer surface using vacuum sputtering coating technology and ion source Aided Film Coating Technique；5, continue to be coated with top layer waterproof layer in tie layer surface using vacuum sputtering coating technology.The present invention uses vacuum coating technology and ion source Aided Film Coating Technique, increases the cohesive force between each film layer, and realizes eyewear products obtained and not only kept while original antireflective coating performance but also had the effect of permanently effective outstanding anti-microbial property.
Description
Technical field
The present invention relates to a kind of film coating lense of spectacle manufacturing technology, a kind of anti-microbial coating resin lens and its system are especially disclosed
Method is made, the manufacturing field of resin lens is belonged to.
Background technology
As resin glasses market gradually expands, resin lens also increasingly obtain the concern of consumer.Therefore with
The diversification of customer demand, the various aspects of performance and technique of resin lens are all in continuous improve and perfect.Currently, in the market
Plated film resin lens, be all mainly, by the method for vacuum coating, to be coated with anti-reflection on the basis of adding resin lens really up to the mark
Penetrate film layer, top layer waterproof layer etc..To have the function that enhance transmitance, protection eyeglass.
Various resin lens are as daily carrying articles for use in life, to provide vision correction, protection and fashion
Etc. functions, simultaneously because long periods of wear resin lens surface certainly exists various bacteriums, fungi, the microorganisms such as virus,
The use eye health and health that seriously threaten the mankind are propagated and spread to wherein various harmful microbes.Therefore people's confrontation
The product of bacterium function is also increasingly paid attention to.
The antibiotic layer proposition being made of metal oxide as disclosed in Chinese patent application CN201310653170 can answer
Antibacterial is realized for lens surface.But lens surface be coated with antibiotic layer there are two aspect defect：Structural instability first,
It easy tos produce film layer and combines bad problem, influence the persistence of antibacterial effect；In addition, since the antibiotic layer of its proposition is by oxygen
Change zinc or calcium oxide or it combines and is coated with, it is evident that it is limited in scope to the mushroom type that can play antibacterial action, no
Antimicrobial protection effect can be functioned well as.Therefore, it is necessary to a kind of completely new technical solutions to solve these problems.
Invention content
Present invention aim to address prior art plated film resin lens antibacterial effect is limited or antibiotic layer coating effects not
Permanent problem proposes a kind of anti-microbial coating resin lens and its manufacturing method, passes through vacuum sputtering coating technology and ion source
Aided Film Coating Technique is coated with antibiotic layer and adhesive layer between antireflective coating and top layer waterproof layer, both ensure that good optics
Performance also adds the adhesive force between top layer waterproof layer and antibiotic layer, and has excellent anti-microbial property, greatly reduces eye disease
Infect probability.
The invention is realized in this way：A kind of anti-microbial coating resin lens and its manufacturing method, including resin lens, dip-coating
In resin lens surface wear-resisting stiffening layer and be sputtered at the antireflective coating, antibiotic layer, bonding of the wear-resisting stiffening layer outer surface
Layer and top layer waterproof layer, it is characterised in that：The antibiotic layer and adhesive layer is sputtered at antireflective coating and top layer waterproof layer successively
Between, the antibiotic layer be coated on antireflective coating surface by one or more metal oxides in silver, copper, zinc, titanium and
At the adhesive layer is by one or more oxides in silica, silicon monoxide, aluminium oxide, zirconium oxide described
The surface of antibiotic layer is coated with, to increase the adhesive force between the antibiotic layer and top layer waterproof layer.
The antibiotic layer and the adhesive layer are plated using vacuum sputtering coating technology and ion source Aided Film Coating Technique
It makes, the waterproof layer is sputtered at the tie layer surface using vacuum sputtering coating technology.
The antireflective coating is a kind of 2~7 layers of multilayered structure, and each layer is by silica, zirconium oxide and oxidation
At least one of indium tin is coated with.
Thickness in monolayer in the antireflective coating is 10nm~150nm, and overall thickness control is described in 150nm~600nm
The thickness control of antibiotic layer is in 1nm~100nm, and the thickness control of the adhesive layer is in 1nm~20nm.
The manufacturing method of the bacterium plated film resin lens includes the following steps：
（1）The resin lens cleaned up are subjected to stiffened processing using dipping process, obtain the wear-resisting stiffened of high rigidity
Layer；
（2）Using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（1）The wear-resisting of processing acquisition adds
Hard formation surface is coated with antireflective coating, the antireflective coating be each single layer by silica, zirconium oxide and tin indium oxide extremely
Lack a kind of 2~7 layers made of be coated with of multilayered structure, each thickness in monolayer is 10nm~150nm, and overall thickness is controlled in 150nm
~600nm；The process conditions of ion source assisted deposition are 80~150V of anode voltage, the flow of anode current 0.8~1.5A, Ar
For 1~40sccm；
（3）Using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（2）It is coated with the anti-reflection film of acquisition
Layer surface is coated with antibiotic layer again, and thickness control is in 1nm~100nm, process for plating condition：Vacuum degree is 3.5 × 10-5 mbar
~1.5 × 10-5Mbar, evaporation rate are 0.1 ~ 0.5 nm/s, O2Flow be 1~40sccm；Ion source Aided Film Coating Technique
Process conditions be 80~150V of anode voltage, the flow of anode current 0.8~1.5A, Ar is 1~40sccm；
（4）Continue using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（3）It is coated with the anti-of acquisition
Bacterium layer surface is coated with adhesive layer, and thickness control is in 1nm~20nm, process for plating condition：Vacuum degree is 3.5 × 10-5 Mbar~
1.5×10-5Mbar, evaporation rate are 0.1 ~ 0.3 nm/s, O2Flow be 0~20sccm, ion source Aided Film Coating Technique
Process conditions are 80~150V of anode voltage, and the flow of anode current 0.8~1.5A, Ar are 1~40sccm；
（5）Continue using vacuum sputtering coating technology in step（4）The tie layer surface for being coated with acquisition is coated with top layer waterproof
Layer.
The step（2）In be coated with the process for plating condition of antireflective coating and be：Vacuum degree is 3.5 × 10-5 Mbar~1.0
×10-5Mbar, evaporation rate are 0.1 ~ 0.6 nm/s, O2Flow be 0 ~ 50sccm.
Further, the step（3）In be coated with the process for plating condition of antibiotic layer and be：Vacuum degree is 3.5 × 10-5
Mbar~1.5 × 10-5Mbar, evaporation rate are 0.25 nm/s, O2Flow be 1~20sccm, the step（4）Middle plating
The process for plating condition of adhesive layer processed is：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate 0.25
Nm/s, O2Flow be 0~10sccm, the process conditions of ion source Aided Film Coating Technique are when being coated with antibiotic layer and adhesive layer：
The flow of 100~120V of anode voltage, anode current 1.0~1.5A, Ar are 10~30sccm.
The step（5）In be coated with the process for plating condition of top layer waterproof layer and be：Vacuum degree is 3.5 × 10-5 Mbar~
1.5×10-5Mbar, evaporation rate are 0.3 nm/s, O2Flow be 0sccm.
The beneficial effects of the invention are as follows：It is wear-resisting being coated with using vacuum coating technology and ion source Aided Film Coating Technique
Outside is coated with antireflective coating, antibiotic layer, adhesive layer, top layer waterproof layer successively again in the resin lens of stiffening layer, resists in crucial
It is provided with transition zone between bacterium layer and outermost layer protective layer to be assisted, increases the adhesive fastness of each film layer, and realize system
The eyewear products obtained had not only kept while original antireflective coating performance but also had had the effect of permanently effective outstanding anti-microbial property, right
Common microbiological, Escherichia coli, the antibiotic rate 99% of staphylococcus aureus, Candida albicans and saccharomycete, mould etc.（Antibacterial
Activity value 2）More than.And since antibiotic layer is set among multilayer film, the validity of antibacterial ability and the multiple film of its outer layer
Service life is the same, can be permanently effective, and safe health protection is provided for user, especially greatly reduces the sense of eye disease
Contaminate probability.
The present invention uses ion source Aided Film Coating Technique during to resin lens vacuum coating, is brilliant based on metal
Body film forming mechanism is more specifically applied on resin material surface.Its maximum difficult point is the control of the settling velocity of metal material
System, which is to integrate and to be formed according to the surface nature of base material and the characteristic of metal material, and pass through the anode to ion source
Voltage and current controls to realize.
Ion source Aided Film Coating Technique is generally used on Glass optical camera lens plated film, and resin lens plated film is seldom applied to
On, the argon ion bombardment of high-energy can increase the adhesive force between film layer and base material, between film layer in ion source supporting process
With the compactness of film layer, while because resin lens are relatively soft, excessive energy cannot discharge to form a large amount of stress in time, film layer mistake
It is mismatched in fine and close and resin lens base material coefficient of thermal expansion, the rear surface that the eyeglass for causing plated film good places certain time occurs
There is the problem of micro-crack in internal injury and film layer.
And the present invention is by a large amount of earnest experiments and data analysis, to vacuum coating technology and ion source ancillary technique
Technological parameter optimizes, and will not be caused not to resin lens surface and film layer while solving the adhesion problem between film layer
Good damage, and while increasing film layer compactness and improving the adhesive force with base material, it is also apparent for resin lens
The problem of easy ting produce internal injury when alleviating traditional plated film.Densification of the technical solution of the present invention to the film layer obtained after plated film
Degree, purity and it is obviously improved effect with the adhesive force of base material etc..
Description of the drawings
Fig. 1 is anti-microbial coating resin lens structure of the present invention and manufacturing sequence block diagram.
Specific implementation mode
With reference to the accompanying drawings 1, a kind of anti-microbial coating resin lens of the present invention, including resin lens, dip-coating are in resin lens surface
Wear-resisting stiffening layer and be sputtered at the antireflective coating of the wear-resisting stiffened layer surface, antibiotic layer, adhesive layer, top layer waterproof successively
Layer.The antibiotic layer is coated with by one or more metal oxides in silver, copper, zinc, titanium on antireflective coating surface, institute
The adhesive layer stated is by one or more oxides in silica, silicon monoxide, aluminium oxide, zirconium oxide in the antibiotic layer table
Face is coated with, to increase the adhesive force between top layer waterproof layer and the antibiotic layer.
The manufacturing method of anti-microbial coating resin lens of the present invention includes the following steps：
（1）The resin lens cleaned up are subjected to stiffened processing using dipping process, then in 105~130 DEG C of high temperature
Solidification 2~3 hours, makes hardening liquid be sufficiently hardened, obtains the wear-resisting stiffening layer of high rigidity.
（2）Using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（1）The wear-resisting of processing acquisition adds
Hard formation surface is coated with antireflective coating, the antireflective coating be each single layer by silica, zirconium oxide and tin indium oxide extremely
Lack a kind of 2~7 layers made of be coated with of multilayered structure, each thickness in monolayer is 10nm~150nm, and overall thickness is controlled in 150nm
~600nm：First in vacuum condition 3.5 × 10-5~1.0 × 10-5Under mbar, pass through ion with ion source Aided Film Coating Technique
Source generates argon ion and carries out 30~180S of bombardment to stiffened layer surface, to enhance the adhesive force of film layer and stiffening layer, it is described from
The process conditions of component Aided Film Coating Technique are 80~150V of anode voltage, the flow of anode current 0.8~1.5A, Ar is 1~
40sccm。
The process for plating condition of vacuum sputtering coating technology is such as following table.
（3）Using vacuum sputtering coating technology in step（2）The antireflective coating surface for being coated with acquisition is coated with antibiotic layer again, plating
It is combined during antibiotic layer processed and uses ion source Aided Film Coating Technique, increase the adhesive force of antibiotic layer and anti-reflection film, what is be coated with is anti-
Bacterium layer thickness is controlled in 1nm~100nm, and process for plating condition is：Vacuum degree is mbar~1.5 3.5 × 10-5 × 10-5
Mbar, evaporation rate are 0.1~0.5 nm/s, O2Flow be 1~40sccm；The process conditions of ion source Aided Film Coating Technique
Flow for 80~150V of anode voltage, anode current 0.8~1.5A, Ar is（1~40）sccm.
（4）Continue using vacuum sputtering coating technology in step（3）The antibacterial layer surface for being coated with acquisition is coated with adhesive layer, plating
It is combined during adhesive layer processed and uses ion source Aided Film Coating Technique, increase the adhesive force of adhesive layer and antibiotic layer, what is be coated with is viscous
Layer thickness control is tied in 1nm~20nm, the condition of being coated with is：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar steams
Hair rate is 0.1~0.3nm/s, O2Flow be 0~20sccm, the process conditions of ion source Aided Film Coating Technique are anode electricity
80~150V is pressed, the flow of anode current 0.8~1.5A, Ar are 1~40sccm.
（5）Continue using vacuum sputtering coating technology in step（4）The tie layer surface for being coated with acquisition is coated with top layer waterproof
Layer.Process for plating condition is：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate are 0.3 nm/s, O2
Flow be 0sccm.
Step in the present invention（3）The best process for plating condition for being coated with antibiotic layer be：Vacuum degree is 3.5 × 10-5 mbar
~1.5 × 10-5Mbar, evaporation rate are 0.25 nm/s, O2Flow be 1~20sccm；Step（4）In be coated with adhesive layer
Best process for plating condition be：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate are 0.25 nm/
S, O2Flow be 0~10sccm；The optimum process condition of ion source Aided Film Coating Technique when being coated with antibiotic layer and adhesive layer
For：The flow of 100~120V of anode voltage, anode current 1.0~1.5A, Ar are 10~30sccm.
The present invention is effective by vacuum sputtering coating technology and ion source Aided Film Coating Technique with antibiotic layer by antireflective coating
Superpower antibacterial ability is had both while in conjunction with, all optical properties for maintaining original film layer, through German HOHENSTEIN
It is tested with Japanese SIAA certification authorities, eyes product is to Escherichia coli, staphylococcus aureus, white made from the method for the present invention
The antibiotic rate 99% of candida albicans and saccharomycete, mould etc.（Antibacterial activity value 2）More than, and antibacterial ability is permanently effective.And this hair
Anti-microbial coating resin lens product made from bright method the consistency of film layer, purity and with the adhesive force of base material etc. with
The prior art, which is compared, significant raising.
With reference to specific embodiment, invention is further described in detail, but these embodiments are not intended to this
The restriction of invention.
Embodiment 1：
The present invention prepares a kind of anti-microbial coating resin lens, is as follows：
（1）Resin lens select refractive index 1.60（MR-8）, using dip-coating hardening process, it is 2.5 μm resistance to obtain thickness
The good wear-resisting stiffening layer of mill property.
（2）Then in vacuum condition 3.5 × 10-5Under mbar, generates argon ion with ion source and stiffening layer is bombarded
120S, to enhance the adhesive force of film layer and stiffening layer, the process conditions of the ion source Aided Film Coating Technique used is anode voltages
The flow of 80V, anode current 0.8A, Ar are 18sccm, are then coated with successively in stiffening layer using vacuum sputtering coating technology
Silicon dioxide layer 49.22nm, titanium dioxide zirconium layer 21.70nm, silicon dioxide layer 44.89nm, titanium dioxide zirconium layer 67.10nm, oxidation
Indium tin layer 5.00nm, silicon dioxide layer 73.58nm constitute the antireflective coating of multilayered structure.
The process for plating condition of the vacuum sputtering coating technology used is such as following table.
（3）Secondly using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（2）In six layers obtained
The antibiotic layer of 10nm thickness is coated on antireflective coating again.The process for plating condition that vacuum sputtering coating technology is coated with antibiotic layer is：
Vacuum degree is 3.5 × 10-5 Mbar, evaporation rate 0.15nm/s, O2Flow be 18sccm, ion source Aided Film Coating Technique
Process conditions be anode voltage 80V, the flow of anode current 0.8A, Ar is 18sccm.
（4）Continue to be coated with adhesive layer SiO using vacuum sputtering coating technology in antibacterial layer surface2Layer, thickness are 10 nm,
In combination with ion source Aided Film Coating Technique to increase the adhesive force of adhesive layer and antibiotic layer.Vacuum sputtering coating technology is coated with
Process conditions are：Vacuum degree is 3.5 × 10-5 Mbar, evaporation rate are 0.25 nm/s, O2Flow be 1sccm.Ion source
The process conditions of Aided Film Coating Technique are：The flow of anode voltage 80V, anode current 0.8A, Ar are 18sccm.
（5）Continue using vacuum sputtering coating technology in step（4）The tie layer surface for being coated with acquisition is coated with top layer waterproof
Layer, vacuum degree is 3.5 × 10 when being coated with-5 Mbar, evaporation rate are 0.3 nm/s, O2Flow be 0sccm.
By above-mentioned anti-microbial coating eyeglass, sends to German HOHENSTEIN and SIAA certification authorities of Japan are tested to large intestine
Bacillus, the antibiotic rate 99% of staphylococcus aureus etc.（Antibacterial activity value 2）More than, antibacterial ability validity is with multiple membrane lifetime
Equally, permanently effective, while antireflective coating send national Glasses detection Spot detection, film quality to meet national standard, 380~
Visible light mean transmissivity is more than 99% within the scope of 780nm light waves.
Embodiment 2：
The present invention prepares a kind of anti-microbial coating resin lens, is as follows：
（1）Resin lens select refractive index 1.74, and using dip-coating hardening process, it is that 2.5 μm of wearabilities are good to obtain thickness
Wear-resisting stiffening layer.
（2）Then in vacuum degree 2.0 × 10-5Under mbar, generates argon ion with ion source and stiffening layer is bombarded
180S, to enhance the adhesive force of film layer and stiffening layer, the process conditions of ion source Aided Film Coating Technique are anode voltage 120V,
The flow of anode current 1.0A, Ar are 25sccm.Then dioxy is coated with successively in stiffening layer using vacuum sputtering coating technology
SiClx layer, titanium dioxide zirconium layer, silicon dioxide layer, titanium dioxide zirconium layer, silicon dioxide layer, titanium dioxide zirconium layer, indium tin oxide layer, dioxy
SiClx layer constitutes antireflective coating, each thicknesses of layers is respectively 35.19,15.72,53.24,52.86,76.40,50.94,5.00,
32.52nm。
The process for plating condition such as following table of the vacuum sputtering coating technology of use.
（3）Use vacuum sputtering coating technology in step again（2）In to be coated with 30nm on eight layers obtained of antireflective coating anti-
Bacterium layer is coated with while using ion source Aided Film Coating Technique, to increase the adhesive force of antibiotic layer and antireflective coating.Vacuum sputtering plates
The process conditions of membrane technology are：Vacuum degree is 2 × 10-5 Mbar, evaporation rate are 0.1 nm/s, O2Flow be 20sccm；From
The process conditions of component Aided Film Coating Technique are anode voltage 80V, and the flow of anode current 0.8A, Ar are 18sccm.
（4）Continue to be coated with adhesive layer one silica layer using vacuum sputtering coating technology in antibacterial layer surface, is coated with thickness
For 5nm, in combination with ion source Aided Film Coating Technique to increase the adhesive force of adhesive layer and antibiotic layer.Vacuum sputtering coating technology
Process for plating condition be：Vacuum degree is 2 × 10-5 Mbar, evaporation rate are 0.25 nm/s, O2Flow be 5sccm.From
The process conditions of component Aided Film Coating Technique are：The flow of anode voltage 80V, anode current 0.8A, Ar are 18sccm.
（5）Continue using vacuum sputtering coating technology in step（4）The tie layer surface for being coated with acquisition is coated with top layer waterproof
Layer, vacuum degree is 2 × 10 when being coated with-5 Mbar, evaporation rate are 0.3 nm/s, O2Flow be 0sccm.
By above-mentioned anti-microbial coating eyeglass, sends to German HOHENSTEIN and SIAA certification authorities of Japan are tested to large intestine
Bacillus, the antibiotic rate 99% of staphylococcus aureus etc.（Antibacterial activity value 2）More than, antibacterial ability validity is with multiple membrane lifetime
Equally, permanently effective, while antireflective coating send national Glasses detection Spot detection, film quality to meet national standard, 380~
Visible light mean transmissivity is more than 99% within the scope of 780nm light waves.
Embodiment described above is only used for explaining technical scheme of the present invention, the protection model being not intended to limit the invention
It encloses, protection scope of the present invention is subject to described in claims of the present invention, all according to technology contents disclosed by the invention, is led to
It crosses any modification of the design number of plies and other material classifications of modification anti-reflection film or reflective coating, equivalent replacement and there is no meaning
The improvement etc. of unimaginable advantageous effect, should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of anti-microbial coating resin lens, including resin lens, dip-coating in resin lens surface wear-resisting stiffening layer and be coated with
Antireflective coating, antibiotic layer, adhesive layer and top layer waterproof layer in the wear-resisting stiffening layer outer surface, it is characterised in that：Described
Antibiotic layer and adhesive layer are sputtered at successively between antireflective coating and top layer waterproof layer, and the antibiotic layer is by silver, copper, zinc, titanium
In one or more metal oxides be coated on antireflective coating surface, the adhesive layer is by silica, an oxygen
One or more oxides in SiClx, aluminium oxide, zirconium oxide are coated on the surface of the antibiotic layer, described to increase
Adhesive force between antibiotic layer and top layer waterproof layer.
2. a kind of anti-microbial coating resin lens according to claim 1, it is characterised in that：The antibiotic layer and described
Adhesive layer is coated with using vacuum sputtering coating technology and ion source Aided Film Coating Technique, and the waterproof layer is splashed using vacuum
It penetrates coating technique and is sputtered at the tie layer surface.
3. a kind of anti-microbial coating resin lens according to claim 1, it is characterised in that：The antireflective coating is a kind of
2~7 layers of multilayered structure, each layer are coated with by least one of silica, zirconium oxide and tin indium oxide.
4. a kind of anti-microbial coating resin lens according to claim 1, it is characterised in that：List in the antireflective coating
Layer thickness is 10nm~150nm, overall thickness control in 150nm~600nm, the thickness control of the antibiotic layer 1nm~
100nm, the thickness control of the adhesive layer is in 1nm~20nm.
5. a kind of manufacturing method of any one of Claims 1 to 4 anti-microbial coating resin lens, it is characterised in that including
Following steps：
（1）The resin lens cleaned up are subjected to stiffened processing using dipping process, obtain the wear-resisting stiffening layer of high rigidity；
（2）Using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（1）Handle the wear-resisting stiffening layer obtained
Surface is coated with antireflective coating, and the antireflective coating is each single layer by least one in silica, zirconium oxide and tin indium oxide
2~7 layers of multilayered structure made of kind being coated with, each thickness in monolayer are 10nm~150nm, overall thickness control 150nm~
600nm；The process conditions of ion source assisted deposition are anode voltage 80V~150V, the flow of anode current 0.8A~1.5A, Ar
For 1sccm~40sccm；
（3）Using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（2）It is coated with the antireflective coating table of acquisition
Face is coated with antibiotic layer again, and thickness control is in 1nm~100nm, process for plating condition：Vacuum degree is 3.5 × 10-5 Mbar~1.5
×10-5Mbar, evaporation rate are 0.1nm/s ~ 0.5 nm/s, O2Flow be 1sccm~40sccm；Ion source assisted deposition
The process conditions of technology are anode voltage 80V~150V, and the flow of anode current 0.8A~1.5A, Ar are 1sccm~40sccm；
（4）Continue using vacuum sputtering coating technology and ion source Aided Film Coating Technique in step（3）It is coated with the antibiotic layer of acquisition
Surface is coated with adhesive layer, and thickness control is in 1nm~20nm, process for plating condition：Vacuum degree is 3.5 × 10-5 Mbar~1.5
×10-5Mbar, evaporation rate are 0.1nm/s ~ 0.3 nm/s, O2Flow be 0sccm~20sccm, ion source assisted deposition
The process conditions of technology are anode voltage 80V~150V, and the flow of anode current 0.8A~1.5A, Ar are 1sccm~40sccm；
（5）Continue using vacuum sputtering coating technology in step（4）The tie layer surface for being coated with acquisition is coated with top layer waterproof layer.
6. the manufacturing method of anti-microbial coating resin lens according to claim 5, it is characterised in that the step（2）Middle plating
The process for plating condition of antireflective coating processed is：Vacuum degree is 3.5 × 10-5 Mbar~1.0 × 10-5Mbar, evaporation rate are
0.1nm/s ~ 0.6 nm/s, O2Flow be 0sccm ~ 50sccm.
7. the manufacturing method of anti-microbial coating resin lens according to claim 5, it is characterised in that the step（3）Middle plating
The process for plating condition of antibiotic layer processed is：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate 0.25
Nm/s, O2Flow be 1sccm~20sccm, the step（4）In be coated with the process for plating condition of adhesive layer and be：Vacuum degree
It is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate are 0.25 nm/s, O2Flow be 0sccm~10sccm,
The process conditions of ion source Aided Film Coating Technique are when being coated with antibiotic layer and adhesive layer：Anode voltage 100V~120V, anode electricity
1.0A~1.5A is flowed, the flow of Ar is 10sccm~30sccm.
8. the manufacturing method of anti-microbial coating resin lens according to claim 5, it is characterised in that：The step（5）In
The process for plating condition for being coated with top layer waterproof layer is：Vacuum degree is 3.5 × 10-5 Mbar~1.5 × 10-5Mbar, evaporation rate
For 0.3 nm/s, O2Flow be 0sccm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611223227.8A CN106772713B (en) | 2016-12-27 | 2016-12-27 | A kind of anti-microbial coating resin lens and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611223227.8A CN106772713B (en) | 2016-12-27 | 2016-12-27 | A kind of anti-microbial coating resin lens and its manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106772713A CN106772713A (en) | 2017-05-31 |
| CN106772713B true CN106772713B (en) | 2018-08-21 |
Family
ID=58927146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611223227.8A Active CN106772713B (en) | 2016-12-27 | 2016-12-27 | A kind of anti-microbial coating resin lens and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106772713B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107957600B (en) * | 2018-01-17 | 2020-08-21 | 江苏康耐特光学有限公司 | Anti-reflection anti-infrared coated resin lens and preparation method thereof |
| CN110646871A (en) * | 2019-10-08 | 2020-01-03 | 苏州鑫河镜业有限公司 | High-strength waterproof antibacterial automobile sun visor lens and production process thereof |
| WO2021232216A1 (en) | 2020-05-19 | 2021-11-25 | Carl Zeiss Vision International Gmbh | Transparent article, in particular a spectacle lens, with antibacterial and/or antiviral properties and method for manufacturing thereof |
| WO2022016482A1 (en) | 2020-07-24 | 2022-01-27 | Carl Zeiss Vision International Gmbh | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same |
| WO2022099592A1 (en) | 2020-11-13 | 2022-05-19 | Carl Zeiss Vision International Gmbh | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing thereof |
| CN112649904B (en) * | 2020-12-29 | 2022-05-10 | 江苏淘镜有限公司 | Vacuum coating antifogging lens and preparation method thereof |
| EP4053186B1 (en) | 2021-03-01 | 2023-10-25 | Essilor International | Article having a surface displaying antimicrobial and antifog properties |
| WO2022193292A1 (en) | 2021-03-19 | 2022-09-22 | Carl Zeiss Vision International Gmbh | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same |
| CN113512703A (en) * | 2021-06-29 | 2021-10-19 | 明月镜片股份有限公司 | Manufacturing process of efficient antibacterial tablets |
| CN115094387A (en) * | 2022-07-01 | 2022-09-23 | 深圳市佳尚光学有限公司 | Antibacterial film coating agent and film coating process thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3859144B2 (en) * | 2002-08-07 | 2006-12-20 | 株式会社竹中工務店 | Waterproof sheet, waterproof sheet joining structure, and waterproof sheet joining method |
| CN104020513B (en) * | 2014-05-24 | 2015-10-28 | 江苏康耐特光学有限公司 | A kind of anti-skidding plated film resin eyeglass and preparation method thereof |
| CN104898189B (en) * | 2015-06-11 | 2016-05-25 | 丹阳市精通眼镜技术创新服务中心有限公司 | Adopt fog-proof lens and the process thereof of dopamine as surface binded layer |
| CN205539779U (en) * | 2016-01-13 | 2016-08-31 | 江苏康美达光学有限公司 | Antibiotic grease proofing dirty chameleon glass block |
| CN205539780U (en) * | 2016-01-13 | 2016-08-31 | 江苏康美达光学有限公司 | Antifog anti bacterial type chameleon glass block |
-
2016
- 2016-12-27 CN CN201611223227.8A patent/CN106772713B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106772713A (en) | 2017-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106772713B (en) | A kind of anti-microbial coating resin lens and its manufacturing method | |
| CN206671589U (en) | A kind of anti-microbial coating resin lens | |
| JP6117109B2 (en) | Optical component with antireflective coating with low reflectivity in both ultraviolet and visible regions | |
| TW459058B (en) | Dual titanium nitride layers for solar control | |
| JP2017533842A (en) | Temperature and corrosion resistant surface reflectors | |
| WO2011145613A1 (en) | Plastic optical product and plastic lens for eyeglasses | |
| CN113227848B (en) | High abrasion resistant optical articles with reflective coatings | |
| CN105425418A (en) | Blue light filtering, radiation protection and wear resisting lens and preparation method thereof | |
| CN105425417A (en) | Blue light filtering, water and oil dirt preventing and wear resisting lens and preparation method thereof | |
| CN105404022A (en) | Blue light-filtering sterilizing wear-resistant lens and manufacturing method thereof | |
| CN205880256U (en) | Camera lens demister | |
| CN209201115U (en) | Substrate package | |
| KR20160108321A (en) | Spectacle lens | |
| CN116802523A (en) | Ophthalmic lens with antibacterial and/or antiviral properties and method for manufacturing same | |
| CN105425419A (en) | Blue light filtering and wear resisting lens and preparation method thereof | |
| CN112513722B (en) | Ophthalmic lens with anti-reflective and electrochromic functionality | |
| CN107111001B (en) | Ophthalmic lens comprising an anti-reflective coating designed for scotopic conditions | |
| BR112021009280A2 (en) | optical lens having an interferential coating and a multilayer system for improving abrasion resistance | |
| CN105467619A (en) | Sterilizing, anti-hard-light and wear-resisting lens and preparing method thereof | |
| BR112021009279A2 (en) | optical lens having an improved interferential coating and a multilayer system for improved abrasion resistance | |
| CN105445957A (en) | Antiseptic, radiation-proof and abrasion-resistant lens and preparation method thereof | |
| CN109164515A (en) | A kind of wear-resisting plated film lens of antibacterial | |
| US10955589B2 (en) | Optical coating having nano-laminate for improved durability | |
| CN105487255A (en) | Sterilization wear-resisting lens and manufacturing method thereof | |
| BR112021009285A2 (en) | optical lens having a mirror coating and a multilayer system for improving abrasion resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: No. 555 Chuan Da Lu, Pudong New Area, Shanghai Applicant after: Shanghai Conant's Smart Meter Technology Group Co. Address before: No. 555 Chuan Da Lu, Pudong New Area, Shanghai Applicant before: SHANGHAI CONANT OPTICS Co.,Ltd. |
|
| CB02 | Change of applicant information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180709 Address after: 201299 1-15, 555, 585, Chuan Da Road, Pudong New Area, Shanghai. Applicant after: SHANGHAI CONANT OPTICAL Co.,Ltd. Address before: No. 555 Chuan Da Lu, Pudong New Area, Shanghai Applicant before: Shanghai Conant's Smart Meter Technology Group Co. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |