CN106758503B - A kind of paper for cigarette filter tip and its preparation method and application with reduction ammonia of main stream smoke of cigarette content function - Google Patents

A kind of paper for cigarette filter tip and its preparation method and application with reduction ammonia of main stream smoke of cigarette content function Download PDF

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Publication number
CN106758503B
CN106758503B CN201611077416.9A CN201611077416A CN106758503B CN 106758503 B CN106758503 B CN 106758503B CN 201611077416 A CN201611077416 A CN 201611077416A CN 106758503 B CN106758503 B CN 106758503B
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China
Prior art keywords
cigarette
paper
cigarette filter
filter tip
ammonia
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CN201611077416.9A
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Chinese (zh)
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CN106758503A (en
Inventor
秦亮生
谢国勇
文建辉
刘金云
杜文
银董红
刘建福
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China Tobacco Hunan Industrial Co Ltd
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China Tobacco Hunan Industrial Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/12Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

The invention discloses a kind of with the paper for cigarette filter tip and its preparation method and application for reducing ammonia of main stream smoke of cigarette content function, sucrose octaacetate and/or triethyl citrate are coated on the paper for cigarette filter tip, preparation method is that sucrose octaacetate and/or triethyl citrate are dissolved in solvent to be configured to solution, the solution is coated on to the surface of paper for cigarette filter tip, it is dry, to obtain the final product, the paper for cigarette filter tip is rolled into cigarette, it can significantly reduce the harmful components burst size such as ammonia in main flume, cigarette taste is not influenced simultaneously reducing the harm caused by smoker, and the preparation method of the paper for cigarette filter tip is simple, it is at low cost, meet industrialization production requirements.

Description

It is a kind of with reduce ammonia of main stream smoke of cigarette content function paper for cigarette filter tip and Preparation method and application
Technical field
The present invention relates to a kind of paper for cigarette filter tip, in particular to a kind of to have reduction ammonia of main stream smoke of cigarette content function The cellulose paper or embossed paper of energy and their preparation method and application, belong to technical field of cigarette preparation.
Background technique
Ammonia, colourless have an intense irritation smell, can skin ambustion, eyes, respiratory apparatus mucous membrane, people's sucking is excessive, energy Cause lung swelling, so that it is dead.It is toxicant, blood ammonia increases most obvious to cranial nerve histologic lesion.It is main in flue gas One of harmful substance.Content of the ammonia in fresh tobacco leaves is seldom, the modulated fermentation of tobacco leaf, due to the metabolism of protein, amino acid (reaction such as oxidation, deoxidation), content increases.Amino acid, protein, nitrate and ammonium salt in tobacco leaf etc. are in cigarette smoke The precursor of ammonia.In cigarette, suitable ammonia cigarette more for carbohydrate and organic acid is necessary, and other Nitrogenous compound takes part in the formation of the jealous strength of flue gas.Ammonia content is too low, will cause the decline of flue gas strength, and richness is inadequate; But excess of ammonia can generate strong impulse, cause smoker throat to be shunk, make one to feel cough of choking, nasal cavity, tongue have pungent Feeling unbearably.Therefore, ammonia plays an important role to control cigarette odor-absorbing.Therefore, ammonia of main stream smoke of cigarette content is reduced, is improved Smoking safety has become great grinding of needing to solve in the target and tobacco industry development of current international consensus and pursuit Study carefully one of project.
Currently, reduction ammonia of main stream smoke of cigarette, alternatively property unique objects object is less come the document studied.China Patent (application number 201010288157.0) discloses a kind of cigarette processing method for reducing ammonia content, mainly using micro- Wave changes cigarette primary processing technique to realize.Chinese patent (application number 201210041550.9) uses electron beam/x-ray irradiation Means handle finished cigarette or tobacco leaf to realize.And what Chinese patent (application number 201210197501.4) used It is the addition active component protoporphyrin compound in filter stick.By the blocking and absorption of solid matter can reduce simultaneously tar and Other harmful substances matter, but applying its effect on middle low-coke tar cigarette is not that such as report is so obvious, and the reduction amplitude of tar is wanted Amplitude is reduced higher than harmful substance, and the highly selective requirement for reducing cigarette smoke harmful components cannot be reached.And these are specially Sharp technology is related to the problems such as technique is more complex or active component safety, at high cost, thus there are certain difficulty for application prospect.
Summary of the invention
In view of the defects existing in the prior art, the purpose of the present invention is intended to provide a kind of with selectivity reducing cigarette mainstream Ammonia in flue gas content function, and tar content etc. is not reduced, the paper for cigarette filter tip on cigarette taste without influence.
Another object of the present invention, which is to provide, a kind of easy to operate, inexpensive prepares the paper for cigarette filter tip Method.
Third object of the present invention is to be to provide the application of the paper for cigarette filter tip, is filtered with the standby cigarette made of paper Stick, the property of can choose reduces the ammonia content in cigarette mainstream flue gas, and oil of focusing does not influence substantially, realizes selective reduction Harmful substance in cigarette does not influence cigarette taste reducing the harm caused by smoker simultaneously.
In order to achieve the above technical purposes, have the function of to reduce ammonia of main stream smoke of cigarette content the present invention provides one kind Paper for cigarette filter tip, sucrose octaacetate and/or triethyl citrate are coated on the paper for cigarette filter tip.
Technical solution of the present invention key is to use sucrose octaacetate and triethyl citrate active material is modified Paper for cigarette filter tip is used by the conventional paper for cigarette filter tip of modified paper for cigarette filter tip replacement, has cigarette filter rod Ammonia content in selectivity reducing cigarette main flume, this is entirely unexpected effect.
Preferred scheme, the coated weight of the sucrose octaacetate and/or triethyl citrate on paper for cigarette filter tip To be measured by 2~10mg/ branch cigarette filter rod;More preferably for by the metering of 5~8mg/ branch cigarette filter rod.
Preferred scheme is coated with sucrose octaacetate and triethyl citrate on the paper for cigarette filter tip.It is a large amount of real It tests and shows that sucrose octaacetate and triethyl citrate are used alone all in certain selectivity reducing cigarette main flume The effect of ammonia content, and the two is applied in combination, there is preferably drop ammonia effect.
The mass percent of more preferably scheme, sucrose octaacetate and triethyl citrate be 55~65%:35%~ 45%;The mass percent of preferred scheme, sucrose octaacetate and triethyl citrate be 60~65%:35%~ 40%.The two is mixed in the ratio, can reach optimal drop ammonia effect.
Preferred scheme, paper for cigarette filter tip are cellulose paper and/or embossed paper.
The cigarette filter with reduction ammonia of main stream smoke of cigarette content function is prepared the present invention also provides a kind of The method of stick paper, this method are that sucrose octaacetate and/or triethyl citrate are dissolved in solvent to be configured to solution, will be described Solution is coated on the surface of paper for cigarette filter tip, it is dry to get.
Preferred scheme, the mass percent concentration of sucrose octaacetate and/or triethyl citrate is in the solution 5%~50%.
Preferred scheme, solvent are water and/or ethyl alcohol.
Preferred scheme, the drying are realized at a temperature of 60 DEG C~90 DEG C.
In technical solution of the present invention, sucrose octaacetate and triethyl citrate are coated on paper for cigarette filter tip, energy It is reacted with the active group on cellulose paper support surface rapidly, has the characteristics that load stabilization, reaction time are short.
The present invention also provides a kind of answering with the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function With, by the paper for cigarette filter tip be applied to selectivity reducing cigarette main flume in ammonia content cigarette filter rod.
Preferred scheme, the cellulose paper for being coated with sucrose octaacetate and/or triethyl citrate are filtered as cigarette Stick forming paper uses.
Preferred scheme is coated with the common embossing of embossed paper replacement of sucrose octaacetate and/or triethyl citrate Paper uses.
Compared with prior art, technical solution of the present invention has the advantage that
1) sucrose octaacetate and triethyl citrate are dexterously loaded to cigarette filter rod and used by technical solution of the present invention On paper, sucrose octaacetate and triethyl citrate can selectivity react with the ammonia in flue gas, and focusing is oily substantially without influence, Harmful substance in selectivity reducing cigarette is realized, does not influence cigarette taste simultaneously reducing the harm caused by smoker.
2) sucrose octaacetate and triethyl citrate stability that technical solution of the present invention uses are good, pacify to human body Entirely, compared with traditional solid adsorption material, the range of choice for dropping evil material has further been widened.
3) carrier that technical solution of the present invention uses is common cellulose paper or embossed paper, does not need other and adds Work can be directly used as cigarette filter rod forming paper or be used as cigarette filter rod embossed paper.
4) the paper for cigarette filter tip preparation method with reduction ammonia of main stream smoke of cigarette content function of the invention is simple, It is at low cost, meet the requirement of industrialized production.
Specific embodiment
Following embodiment is intended to be more specifically described the present invention rather than limitation of the invention further, and the present invention can be with Implement by formula either described in summary of the invention.
Embodiment 1
In ethanol by sucrose octaacetate dissolution, it is made into the solution that mass fraction is 12%, utilizes existing coating work Skill is respectively the additive amount of 2mg, 5mg and 10mg by every cigarette filter rod, is applied to cellulose paper surface, online dry in 85 DEG C It is dry.Standby at cigarette filter rod using this cellulose paper as forming paper and tow preparing, cigarette is at cigarette sample, three kinds of cigarette filter rod focusings Oil, ammonia removal rate are respectively 0%, 8.2%, 0%, 18.6%, 0,34.4%;Sample cigarette is smoked panel test, and smoking result shows sample Product cigarette not substantially changes suction mouthfeel.
Embodiment 2
In ethanol by triethyl citrate dissolution, it is made into the solution that mass fraction is 12%, utilizes existing coating work Skill, the additive amount for being 5mg by every cigarette filter rod, is applied on cellulose paper, in 85 DEG C of online dries, this cellulose paper is made Standby at cigarette filter rod for forming paper and tow preparing, cigarette is respectively to tar, ammonia removal rate at cigarette sample, the cigarette filter rod 0.5%, 15.3%.Sample cigarette is smoked panel test, and smoking result shows that sample cigarette not substantially changes cigarette taste.
Embodiment 3
Triethyl citrate is dissolved in water, the solution that mass fraction is 50% is made into, using existing coating process, By the additive amount of every cigarette filter rod 5mg, be applied on cellulose paper, in 85 DEG C of online dries, using this cellulose paper as at Shape paper and tow preparing are standby at cigarette filter rod, cigarette at cigarette sample, which is respectively 1.8% to tar, ammonia removal rate, 17.7%.Sample cigarette is smoked panel test, and smoking result shows that sample cigarette not substantially changes suction mouthfeel.
Embodiment 4
It is in mass ratio respectively 2:8,5.5:4.5,6:4,6.5:3.5,8:2 by sucrose octaacetate and triethyl citrate Mixing dissolves be made into the solution that mass fraction is 25% in ethanol respectively, using existing coating process, by every cigarette 5mg Additive amount, be applied on cellulose paper, in 85 DEG C of online dries, made these cellulose papers as forming paper and tow respectively It is standby that for cigarette at cigarette sample, five kinds of cigarette filter rods are respectively 0%, 24.5% to tar, ammonia removal rate at cigarette filter rod, 0%, 27.5%, 0%, 35.5%, 0%, 26.9%, 0%, 23.9%.Sample cigarette is smoked panel test, and smoking result shows that sample cigarette is basic On do not change suction mouthfeel.
Embodiment 5
It is in mass ratio that 5.5:4.5 is mixed by sucrose octaacetate and triethyl citrate, dissolution in ethanol, is made into matter The solution that score is 25% is measured, is applied to cellulose by the additive amount of every cigarette filter rod 8mg using existing coating process On paper, in 80 DEG C of online dries, standby at cigarette filter rod using this cellulose paper as forming paper and tow preparing, cigarette is at cigarette sample Product, the cigarette filter rod are respectively 0%, 32.6% to tar, ammonia removal rate.Sample cigarette is smoked panel test, and smoking result shows sample Cigarette not substantially changes suction mouthfeel.
Embodiment 6
It is in mass ratio that 5.5:4.5 is mixed by sucrose octaacetate and triethyl citrate, dissolution in ethanol, is made into matter The solution that score is 25% is measured, is applied to cellulose by the additive amount of every cigarette filter rod 8mg using existing coating process On paper, in 60 DEG C of online dries, standby at cigarette filter rod using this cellulose paper as forming paper and tow preparing, cigarette is at cigarette sample Product, the cigarette filter rod are respectively 0%, 30.5% to tar, ammonia removal rate.Sample cigarette is smoked panel test, and smoking result shows sample Cigarette not substantially changes suction mouthfeel.
Embodiment 7
It is in mass ratio that 5.5:4.5 is mixed by sucrose octaacetate and triethyl citrate, dissolution in ethanol, is made into matter The solution that score is 25% is measured, is applied to cellulose by the additive amount of every cigarette filter rod 6mg using existing coating process On paper, in 90 DEG C of online dries, standby at cigarette filter rod using this cellulose paper as forming paper and tow preparing, cigarette, should at cigarette Cigarette filter rod is respectively 0,29.4% to tar, ammonia removal rate.Sample cigarette is smoked panel test, and smoking result shows sample cigarette substantially Suction mouthfeel is not changed.
Embodiment 8
In ethanol by sucrose octaacetate dissolution, it is made into the solution that mass fraction is 12%, utilizes existing coating work Skill is applied on embossed paper by the additive amount of every cigarette 7.5mg, in 90 DEG C of online dries, this embossed paper paper and tow preparing is standby At paper mouth rod, cigarette is respectively 0,23.1% to tar, ammonia removal rate at cigarette sample, the paper mouth rod.Sample cigarette is smoked panel test, Smoking result shows that sample cigarette not substantially changes suction mouthfeel.

Claims (6)

1. a kind of application with the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function, it is characterised in that: volume Cigarette filter is applied to the cigarette filter rod of ammonia content in selectivity reducing cigarette main flume with paper;
Sucrose octaacetate and triethyl citrate are coated on the paper for cigarette filter tip;
The mass percent of sucrose octaacetate and triethyl citrate is 55~65%:35%~45%;
The coated weight of the sucrose octaacetate and triethyl citrate on paper for cigarette filter tip is by 2~10mg/ branch cigarette Filter stick metering.
2. according to claim 1 have answering for the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function With, it is characterised in that: the coated weight of the sucrose octaacetate and triethyl citrate on paper for cigarette filter tip be by 5~ The metering of 8mg/ branch cigarette filter rod.
3. according to claim 1 have answering for the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function With, it is characterised in that: the mass percent of sucrose octaacetate and triethyl citrate is 60~65%:35%~40%.
4. the paper for cigarette filter tip with reduction ammonia of main stream smoke of cigarette content function according to claim 1 or 2 Using, it is characterised in that: the paper for cigarette filter tip is cellulose paper and/or embossed paper.
5. according to claim 1 have answering for the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function With, it is characterised in that: the cellulose paper of sucrose octaacetate and triethyl citrate is coated with as cigarette filter rod forming paper It uses.
6. according to claim 1 have answering for the paper for cigarette filter tip for reducing ammonia of main stream smoke of cigarette content function With, it is characterised in that: the embossed paper for being coated with sucrose octaacetate and triethyl citrate replaces common embossed paper use.
CN201611077416.9A 2016-11-30 2016-11-30 A kind of paper for cigarette filter tip and its preparation method and application with reduction ammonia of main stream smoke of cigarette content function Active CN106758503B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111317171B (en) * 2018-12-14 2022-01-11 湖南中烟工业有限责任公司 Alkalized glucose, preparation method thereof and application of alkalized glucose as functional additive for reducing ammonia content in main stream smoke of cigarettes
CN112841718A (en) * 2019-11-28 2021-05-28 湖南中烟工业有限责任公司 Cigarette filter stick additive with function of reducing ammonia release amount in main stream smoke of cigarette, and preparation method and application thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN101858042A (en) * 2010-06-13 2010-10-13 湖南中烟工业有限责任公司 Cigarette forming paper functional paint for selectively reducing harmful substances such as phenol and the like in smoke gas
CN102720001A (en) * 2012-06-06 2012-10-10 云南瑞升烟草技术(集团)有限公司 Paper filter material capable of effectively reducing phenol content in cigarette smoke and processing method thereof
CN103126074A (en) * 2013-03-05 2013-06-05 湖南中烟工业有限责任公司 Paper filter stick core base material additive capable of reducing phenolic compound in main cigarette stream smoke and application
CN103141941A (en) * 2013-03-05 2013-06-12 湖南中烟工业有限责任公司 Groove filter stick cellulose paper additive capable of selectively reducing phenolic compounds in cigarette mainstream smoke and application
US20140261502A1 (en) * 2013-03-13 2014-09-18 Celanese Acetate Llc Smoke filters for reducing components in a smoke stream

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101858042A (en) * 2010-06-13 2010-10-13 湖南中烟工业有限责任公司 Cigarette forming paper functional paint for selectively reducing harmful substances such as phenol and the like in smoke gas
CN102720001A (en) * 2012-06-06 2012-10-10 云南瑞升烟草技术(集团)有限公司 Paper filter material capable of effectively reducing phenol content in cigarette smoke and processing method thereof
CN103126074A (en) * 2013-03-05 2013-06-05 湖南中烟工业有限责任公司 Paper filter stick core base material additive capable of reducing phenolic compound in main cigarette stream smoke and application
CN103141941A (en) * 2013-03-05 2013-06-12 湖南中烟工业有限责任公司 Groove filter stick cellulose paper additive capable of selectively reducing phenolic compounds in cigarette mainstream smoke and application
US20140261502A1 (en) * 2013-03-13 2014-09-18 Celanese Acetate Llc Smoke filters for reducing components in a smoke stream

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