CN106757505A - A kind of ice sense mosquito proof fiber and preparation method thereof and ice sense anti-mosquito fabric - Google Patents
A kind of ice sense mosquito proof fiber and preparation method thereof and ice sense anti-mosquito fabric Download PDFInfo
- Publication number
- CN106757505A CN106757505A CN201611239544.9A CN201611239544A CN106757505A CN 106757505 A CN106757505 A CN 106757505A CN 201611239544 A CN201611239544 A CN 201611239544A CN 106757505 A CN106757505 A CN 106757505A
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- Prior art keywords
- mosquito
- fiber
- ice sense
- cool feeling
- cortex
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- 239000000835 fiber Substances 0.000 title claims abstract description 119
- 230000001442 anti-mosquito Effects 0.000 title claims abstract description 71
- 241000255925 Diptera Species 0.000 title claims abstract description 67
- 239000004744 fabric Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- -1 polypropylene Polymers 0.000 claims abstract description 30
- 239000004743 Polypropylene Substances 0.000 claims abstract description 29
- 229920001155 polypropylene Polymers 0.000 claims abstract description 29
- 239000004952 Polyamide Substances 0.000 claims abstract description 19
- 229920002647 polyamide Polymers 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims abstract description 15
- 239000004760 aramid Substances 0.000 claims abstract description 9
- 229920003235 aromatic polyamide Polymers 0.000 claims abstract description 9
- 238000010276 construction Methods 0.000 claims abstract description 8
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 39
- 239000002245 particle Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- 239000010977 jade Substances 0.000 claims description 13
- 238000002074 melt spinning Methods 0.000 claims description 12
- 241000723353 Chrysanthemum Species 0.000 claims description 6
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- 239000005946 Cypermethrin Substances 0.000 claims description 4
- GQNBIMLHUAWKHJ-UHFFFAOYSA-N [4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound C1=CC(COC)=CC=C1COC(=O)C1C(C)(C)C1C=C(C)C GQNBIMLHUAWKHJ-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical group CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 4
- 229960005424 cypermethrin Drugs 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 229940108410 resmethrin Drugs 0.000 claims description 4
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 claims description 4
- 229960005199 tetramethrin Drugs 0.000 claims description 4
- MIZYPRIEDMSCAC-UHFFFAOYSA-N (2-methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl) 2,2,3,3-tetramethylcyclopropane-1-carboxylate Chemical compound CC1=C(CC=C)C(=O)CC1OC(=O)C1C(C)(C)C1(C)C MIZYPRIEDMSCAC-UHFFFAOYSA-N 0.000 claims description 3
- 238000009941 weaving Methods 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 47
- 150000001875 compounds Chemical class 0.000 description 22
- 239000004677 Nylon Substances 0.000 description 14
- 239000011162 core material Substances 0.000 description 14
- 229920001778 nylon Polymers 0.000 description 14
- 229920000728 polyester Polymers 0.000 description 14
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000005469 granulation Methods 0.000 description 11
- 230000003179 granulation Effects 0.000 description 11
- 239000004753 textile Substances 0.000 description 11
- 238000009987 spinning Methods 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 9
- 238000005453 pelletization Methods 0.000 description 9
- 238000001291 vacuum drying Methods 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 6
- 230000001846 repelling effect Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000004804 winding Methods 0.000 description 5
- 230000001054 cortical effect Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 3
- 229960000490 permethrin Drugs 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- 208000035859 Drug effect increased Diseases 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
Abstract
This application provides a kind of ice sense mosquito proof fiber and preparation method thereof and fabric, fiber has includes the composite construction of cortex and sandwich layer, and the sandwich layer is the polypropylene layer containing anti-mosquito agent, and the cortex is the aramid layer containing cool feeling material；The percentage by weight that the anti-mosquito agent accounts for fiber is 1~30%, and the percentage by weight that the cool feeling material accounts for fiber is 1~20%.The fiber and fabric that the application is provided have mosquito proof and ice sense double effectses, meanwhile, the polyamide cortex containing cool feeling material can reach the effect of enhancing mosquito proof.Therefore, the application fabric is efficacy lasting, and washability is good, can dye, and it is wear-resisting, be unlikely to deform, be particularly suitable for summer dress use.
Description
Technical field
The present invention relates to function textile technical field, more particularly to a kind of ice sense mosquito proof fiber and preparation method thereof and
Ice sense anti-mosquito fabric.
Background technology
With the improvement of people ' s living standards, functional textile has become the focus of industry research and development, and in the market also goes out
Some such as moisture absorbing and sweat releasing, cool feeling, mosquito proof, uvioresistant function textile products are showed.In numerous function textile products,
It is the fabric for adding cool feeling material that cool feeling arranges fabric, applies and is generally received by everybody on summer dress ornament, and it can give people
Refrigerant impression.
For anti-mosquito functions textile product, exactly anti-mosquito functions are carried out with the textile of human contact to often whole
Reason.At present using it is more be the addition mosquito proof auxiliary agent in textile surface or Final finishing, dress or using so obtained
Insect prevention function textile, especially in the outdoor activities of hot summer, can prevent biting for mosquito, be conducive to healthy.
But, the washability of this anti-mosquito functions textile is poor.
The content of the invention
In view of this, the application provides a kind of ice sense mosquito proof fiber and preparation method thereof and ice sense anti-mosquito fabric, this
Applying for the fiber and fabric of offer has preferable anti-mosquito functions, and washability is good.
The application provides a kind of ice sense mosquito proof fiber, and it has the composite construction including cortex and sandwich layer, the sandwich layer
It is the polypropylene layer containing anti-mosquito agent, the cortex is the aramid layer containing cool feeling material；The anti-mosquito agent accounts for fiber
Percentage by weight be 1~30%, the cool feeling material account for fiber percentage by weight be 1~20%.
Preferably, the cortex has micropore, and the aperture of the cortex micropore is 0.1 micron~0.5 micron.
Preferably, the total cross sectional area of the micropore accounts for the 1~5% of fiber surface area.
Preferably, the percentage by weight that the anti-mosquito agent accounts for fiber is 5~20%.
Preferably, the percentage by weight that the cool feeling material accounts for fiber is 5~15%.
Preferably, the particle diameter of the cool feeling material is 0.1 micron~100 microns.
Preferably, the ratio between cross-sectional area of the cortex and sandwich layer is 1：9~5：5.
The application provides a kind of preparation method of ice sense mosquito proof fiber, comprises the following steps：
Polypropylene agglomerate containing anti-mosquito agent and the polyamide master batch containing cool feeling material are provided respectively；
The polypropylene agglomerate and polyamide master batch are carried out into melt spinning, ice sense mosquito proof fiber is obtained；
The ice sense mosquito proof fiber has includes the composite construction of cortex and sandwich layer, and the sandwich layer is to contain anti-mosquito agent
Polypropylene layer, the cortex is the aramid layer containing cool feeling material；The percentage by weight that the anti-mosquito agent accounts for fiber is 1
~30%, the percentage by weight that the cool feeling material accounts for fiber is 1~20%.
Preferably, the cool feeling material is selected from one or more in jade powder and mica sheet；
The anti-mosquito agent is selected from cypermethrin, bromine chrysanthemum ester, tetramethrin, resmethrin, terallethrin, methothrin
With one or more in Permethrin.
The application provides a kind of ice sense anti-mosquito fabric, is obtained by fiber weaving, and the fiber includes ice mentioned above
Sense mosquito proof fiber.
Compared with prior art, the application provide fiber be the core-sheath compound fibre for including cortex and sandwich layer, its with
Aramid layer containing cool feeling material is cortex, is sandwich layer with the polypropylene layer containing anti-mosquito agent, also, control anti-mosquito agent
It is 1~30% to account for the percentage by weight of fiber, and the percentage by weight that cool feeling material accounts for fiber is 1~20%.What the application was provided
Fiber and fabric have mosquito proof and ice sense double effectses, meanwhile, the polyamide cortex containing cool feeling material can reach enhancing
The effect of mosquito proof.Therefore, the application fabric is efficacy lasting, and washability is good, can dye, and it is wear-resisting, be unlikely to deform, be particularly suitable for
Summer dress is used.
Brief description of the drawings
Fig. 1 is the schematic cross-section of ice sense mosquito proof fiber provided in an embodiment of the present invention；
Fig. 2 is the structural representation of ice sense mosquito proof fiber provided in an embodiment of the present invention.
Specific embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
The invention provides a kind of ice sense mosquito proof fiber, it has the composite construction including cortex and sandwich layer, the core
Layer is the polypropylene layer containing anti-mosquito agent, and the cortex is the aramid layer containing cool feeling material；The anti-mosquito agent accounts for fibre
The percentage by weight of dimension is 1~30%, and the percentage by weight that the cool feeling material accounts for fiber is 1~20%.
The fiber that the present invention is provided has preferable anti-mosquito functions, and washability is good, beneficial to application.
Referring to the schematic cross-section that Fig. 1 and Fig. 2, Fig. 1 are ice sense mosquito proof fiber provided in an embodiment of the present invention；Fig. 2 is
The structural representation of ice sense mosquito proof fiber provided in an embodiment of the present invention.In Fig. 1,1 is polyamide cortex, and 2 is polypropylene cores
Layer, 3 is micropore.In Fig. 2,1 is polyamide cortex, and 2 is polypropylene core, and 3 is micropore.
The fiber that the present invention is provided has includes the composite construction of cortex and sandwich layer, as sheath core fiber.In the present invention
In, the sheath core fiber is that two kinds of component polymers are longitudinally continuous the composite fibre to form cortex and sandwich layer along fiber respectively,
Concentric ring type, eccentric round, profiled-cross-section etc. can be divided into several；The present invention is preferably concentric ring type section core-skin fibre.Wherein,
The ratio between cross-sectional area of the cortex and sandwich layer is preferably 1：9~5：5, more preferably 2：8~3：7.
In the structure of fiber of the present invention, sandwich layer is polypropylene (PP) layer containing anti-mosquito agent, be can be described as mosquito-proof
Worm agent improved polypropylene sandwich layer, makes fiber obtain anti-mosquito functions.The anti-mosquito agent can be pyrethroid compound, preferably be selected from
One or more in cypermethrin, bromine chrysanthemum ester, tetramethrin, resmethrin, terallethrin, methothrin and Permethrin,
Commercially available prod can be used.In an embodiment of the present invention, the percentage by weight that the anti-mosquito agent accounts for fiber is 1~30%, excellent
Elect 5~20% as.
In the structure of fiber of the present invention, cortex is polyamide (PA) layer containing cool feeling material, can be described as cool feeling
Substance modification nylon cortex, makes fiber obtain ice sense function, while strengthening anti-mosquito functions.The cool feeling material preferably is selected from jade
One or more in powder and mica sheet, more preferably jade powder.The cool feeling material is usually powdered, and particle diameter is preferably
0.1 micron~100 microns.In an embodiment of the present invention, the percentage by weight that the cool feeling material accounts for fiber is 1~20%,
Preferably 5~15%.
In a preferred embodiment of the invention, as depicted in figs. 1 and 2, there are micropore, i.e. cortex excellent in described fibrocortex
Elect porous modification of nylon as.The micropore can run through, penetrate cortex, perfectly even be distributed.The pore size of the cortex micropore
Preferably 0.1 micron~0.5 micron；Preferably, the total cross sectional area of the micropore accounts for the 1~5% of fiber surface area, more
Preferably 3%.
In the present invention, the fiber of the core-skin type is mainly short fibre；It can be preoriented yarn (POY), or complete
Drawn yarn (FDY)；Can be made of wet spinning, it would however also be possible to employ melt spinning is made.In an embodiment of the present invention, institute
The average length for stating the fiber of core-skin type is 40mm；The average linear density of the fiber of the core-skin type is 2.3dtex；Fiber it is flat
Equal fracture strength is 3.9CN/dtex.Also, the fiber mediopellis of the core-skin type can be 3 with the mass ratio of sandwich layer：7~6：4.
Different from conventional functional after-finishing technique, the anti-mosquito functions of functional fibre material of the present invention are held
Long, washability is strong, can dye, and it is wear-resisting, be unlikely to deform, be suitable as the materials such as summer function clothes.
Correspondingly, this application provides a kind of preparation method of ice sense mosquito proof fiber, comprise the following steps：
Polypropylene agglomerate containing anti-mosquito agent and the polyamide master batch containing cool feeling material are provided respectively；
The polypropylene agglomerate and polyamide master batch are carried out into melt spinning, ice sense mosquito proof fiber is obtained；
The ice sense mosquito proof fiber has includes the composite construction of cortex and sandwich layer, and the sandwich layer is to contain anti-mosquito agent
Polypropylene layer, the cortex is the aramid layer containing cool feeling material；The percentage by weight that the anti-mosquito agent accounts for fiber is 1
~30%, the percentage by weight that the cool feeling material accounts for fiber is 1~20%.
The preparation method that the present invention is provided prepares the excellent work(of anti-mosquito functions with textile polymer raw material as base material
Energy fiber is ice sense anti-mosquito functions fiber, can improve the comfortableness and security of wearer, is adapted to summer outdoor activities person and wears
And use.
The embodiment of the present invention can prepare mosquito proof master batch, specially：Using including anti-mosquito agent and polyacrylic material, warp
Melt pelletization is crossed, the polypropylene agglomerate containing anti-mosquito agent is obtained, dried, it is standby.
In an embodiment of the present invention, the mosquito proof master batch is made up of the material including polypropylene, anti-mosquito agent.Wherein
Polypropylene cut into slices using fibrous polypropylene commonly used in the art, mix with anti-mosquito agent after being vacuum dried, fill
Divide stirring 20 minutes~30 minutes, by twin-screw melting granulator, you can obtain mosquito proof master batch.
In the present invention, the anti-mosquito agent preferably is selected from cypermethrin, bromine chrysanthemum ester, tetramethrin, resmethrin, cyclopentene third
One or more in chrysanthemum ester, methothrin and Permethrin.The percentage by weight that the anti-mosquito agent accounts for fiber is 1~30%,
Preferably 5~20%.The temperature of the melt pelletization is preferably 200~220 DEG C；Granulation particle diameter can be 0.5 centimetre~1 centimetre.
Similarly, the embodiment of the present invention can prepare cool feeling nylon master batch, specially：Will be including polyamide, cool feeling material etc.
Material, by melt pelletization, obtain the polyamide master batch containing cool feeling material, dry, it is standby.
In a preferred embodiment of the invention, the cool feeling nylon master batch is by including polyamide, cool feeling material and water solubility
The material of polyester and dispersant is made.Polyamide therein can use nylon chips commonly used in the art, such as nylon 6 slice；
After being vacuum dried, with cool feeling material and water-soluble polyester section mix, while addition dispersant, be sufficiently stirred for 20 minutes~
40 minutes, master batch preparation is carried out by twin-screw melting granulator, obtain cool feeling nylon master batch.
In the present invention, the cool feeling material preferably is selected from one or more in jade powder and mica sheet, more preferably beautiful
Stone flour.The cool feeling material is usually powdered, and particle diameter is preferably 0.1 micron~100 microns.The cool feeling material accounts for fiber
Percentage by weight is 1~20%, preferably 5~15%.In an embodiment of the present invention, the water-soluble polyester and dispersant are adopted
With commercially available prod；The addition quality of water-soluble polyester can be the 1~5% of fiber quality；Dispersant is preferably silane series
In one or more.The temperature of the melt pelletization is preferably arranged to 240~260 DEG C；Granulation particle diameter can be 0.8 centimetre~1
Centimetre.
After respectively obtaining the polypropylene agglomerate containing anti-mosquito agent and the polyamide master batch containing cool feeling material, the present invention is real
Apply example carries out melt spinning by two kinds of master batches, will both master batches respectively by single screw extrusion machine melt, then lead to respectively
Sandwich layer and the cortex extrusion of composite spinneret are crossed, is condensed in atmosphere, obtain core-sheath compound fibre, abbreviation sheath core fiber.
In the present invention, described core-sheath compound fibre has ice sense, anti-mosquito functions, the skin of the sheath core fiber
Layer is the aramid layer containing cool feeling material, and sandwich layer is the polypropylene layer containing anti-mosquito agent.The temperature of the melt spinning is excellent
Elect 265~275 DEG C as；The winding speed of the melt spinning is preferably 500~800m/min.The present invention is preferably concentric ring type
Section core-skin fibre, and cortex can have micropore.Wherein, the ratio between cross-sectional area of the cortex and sandwich layer can be 1：9~5：
5, preferably 2：8~3：7.
In an embodiment of the present invention, the sheath core fiber can be POY, i.e., by melt spinning process, extrusion, it is cold
After solidifying, obtain compound POY.The embodiment of the present invention can also prepare FDY, specially：Compound POY for obtaining is in drawing-off
Drawing-off is carried out on machine, the core-skin type FDY fiber with ice sense anti-mosquito functions is obtained.Wherein, the drawing-off is art technology
Technological means known to personnel, its temperature of heat plate can be 50~110 DEG C, and the temperature of heating plate can be 80~180 DEG C.The drawing-off
Multiple is preferably 3~5, and speed can be 800~1000m/min.
In addition, the embodiment of the present invention, using microcapsules technology etc., can also be prepared with ice sense by wet spinning
The sheath core fiber of anti-mosquito functions.The embodiment of the present invention can be by polymer solution spun, adding the micro- glue of anti-mosquito agent
Capsule and cool feeling material, with reference to skin-core structure so that fiber reaches stabilization, lasting ice sense anti-mosquito functions effect.Specific steps
For：
Dry different polymeric substrates are dissolved, polymer solution spun is obtained respectively；
Anti-mosquito agent microcapsules are dispersed in polypropylene spinning solution, sandwich layer spinning solution is obtained；Cool feeling material is disperseed into Buddhist nun
In imperial spinning solution, cortex spinning solution is obtained；
Extruded by spinning equipment spinneret orifice, obtain the sheath core fiber i.e. ice sense mosquito proof fiber.
Present invention also provides a kind of ice sense anti-mosquito fabric, obtained by fiber weaving, the fiber includes mentioned above
Ice sense mosquito proof fiber.
In the present invention, the ice sense mosquito proof fiber can be used as weft yarn, also can be used as warp thread.The fabric can be mixed
Textile fabric, can be woven fabric；Normal tissue structure is conventionally weaved into, the application is not particularly limited.
In embodiments herein, it is weft yarn that can use 75D/72F ice sense mosquito proof fibers, with conventional func 75D/72F nylon warp thread
Conventionally weave, obtain common plain fabric；Consumption of the ice sense mosquito proof fiber in fabric can for 40~
50%, preferably 45wt%.
The present invention strongly, speed is absorbed using maximum heat using fiber strength tester test ice sense mosquito proof fiber yarn
Rate (Q-max values) and Cool-Ex-2008Method measurement of test method cool feeling degree, and use standard GB/T/T
28408-2012《Protective clothes insect prevention protective garment》Method tests mosquito proof, obtains fiber, the performance of fabric.
Result shows that fabric lining of the present invention washes preceding to mosquito repelling rate >=90%, to mosquito repelling rate after 15 washings
>=45%, therefore fabric has good repellent effect to mosquito, washability is good.Therefore, the functional fibre fabric is in the hot summer
Season has a good application prospect.
For a further understanding of the application, the ice sense mosquito proof fiber provided the application with reference to embodiment and its system
Preparation Method and ice sense anti-mosquito fabric are specifically described.
In following examples, polypropylene chip used is that the BH type polypropylene of Gansu Lan Gang petrochemical industry Co., Ltd production is cut
Piece, polyamide section is the PA-6 fibre-grades polyamide section of Ba Ling branch companies of Co., Ltd of Sinopec production, water-soluble
Property the FC511 water-soluble polyesters section that provides for responsible company of Sinopec Yizheng Fiber Optical plant Co., Ltd of polyester slice, mosquito proof
The SPA01 anti-mosquito agents that agent is provided for Tuo Na trades (Shanghai) Co., Ltd., jade powder is that Shanghai Kombi reaches Science and Technology Ltd.
The CBD-YS type jade powders of offer, the CH-1A type dispersants that dispersant is provided for ShangHai SanZheng polymer Materials Co., Ltd.
The percentage of each material is on the basis of fiber quality in following examples.
Embodiment 1
(1) core material prepares：Anti-mosquito agent is mixed with vacuum drying polypropylene chip, is sufficiently stirred for 20 minutes,
Master batch preparation is carried out by twin-screw melting granulator, mosquito proof master batch is obtained, it is standby by rotary-drum vacuum dried process；It is anti-
Mosquito agent addition is 5%, and the temperature setting of melt pelletization is 200 DEG C, and granulation particle diameter is 0.5 centimetre.
(2) cortical material prepares：Jade powder is mixed with vacuum drying nylon 6 slice and water-soluble polyester section, together
When add 1% dispersant, be sufficiently stirred for 20 minutes, carry out master batch preparation by twin-screw melting granulator, obtain cool feeling nylon
Master batch, it is standby by rotary-drum vacuum dried process；Jade powder addition is 5%, and water-soluble polyester addition is 2%, and melting is made
The temperature setting of grain is 250 DEG C, and granulation particle diameter is 0.8 centimetre.
(3) melt spinning process prepares compound POY：Prepared by mosquito proof master batch and step (2) prepared by step (1) cool
Sense nylon master batch is melted by single screw extrusion machine respectively, is then extruded by the sandwich layer and cortex of composite spinneret respectively,
Condensed in air, obtain compound POY；Described spinning temperature is 265 DEG C, and winding speed is 800m/min.
(4) FDY is prepared：Compound POY that step (3) is obtained carries out drawing-off, the hot plate of the drawing-off on drafting machine
Temperature be 70 DEG C, temperature of heating plate be 120 DEG C, drafting multiple is 5, and speed is 1000m/min, thus be obtained cortex cool feeling,
The ratio between cross-sectional area of the core-sheath compound fibre of sandwich layer anti-mosquito functions, fibrocortex and sandwich layer is 2:8.
Embodiment 2
(1) core material prepares：Anti-mosquito agent is mixed with vacuum drying polypropylene chip, is sufficiently stirred for 20 minutes,
Master batch preparation is carried out by twin-screw melting granulator, mosquito proof master batch is obtained, it is standby by rotary-drum vacuum dried process；It is anti-
Mosquito agent addition is 20%, and the temperature setting of melt pelletization is 220 DEG C, and granulation particle diameter is 0.6 centimetre.
(2) cortical material prepares：Jade powder is mixed with vacuum drying nylon 6 slice and water-soluble polyester section, together
When add 1% dispersant, be sufficiently stirred for 20 minutes, carry out master batch preparation by twin-screw melting granulator, obtain cool feeling nylon
Master batch, it is standby by rotary-drum vacuum dried process；Jade powder addition is 15%, and water-soluble polyester addition is 3%, melting
The temperature setting of granulation is 260 DEG C, and granulation particle diameter is 1 centimetre.
(3) melt spinning process prepares compound POY：Prepared by mosquito proof master batch and step (2) prepared by step (1) cool
Sense nylon master batch is melted by single screw extrusion machine respectively, is then extruded by the sandwich layer and cortex of composite spinneret respectively,
Condensed in air, obtain compound POY；Described spinning temperature is 275 DEG C, and winding speed is 500m/min.
(4) FDY is prepared：Compound POY that step (3) is obtained carries out drawing-off, the hot plate of the drawing-off on drafting machine
Temperature is 70 DEG C, and temperature of heating plate is 120 DEG C, and drafting multiple is 4, and speed is 800m/min, so as to cortex cool feeling, core has been obtained
The ratio between cross-sectional area of the core-sheath compound fibre of layer anti-mosquito functions, fibrocortex and sandwich layer is 3:7.
Embodiment 3
(1) core material prepares：Anti-mosquito agent is mixed with vacuum drying polypropylene chip, is sufficiently stirred for 20 minutes,
Master batch preparation is carried out by twin-screw melting granulator, mosquito proof master batch is obtained, it is standby by rotary-drum vacuum dried process；It is anti-
Mosquito agent addition is 10%, and the temperature setting of melt pelletization is 210 DEG C, and granulation particle diameter is 0.6 centimetre.
(2) cortical material prepares：Jade powder is mixed with vacuum drying nylon 6 slice and water-soluble polyester section, together
When add 1wt% dispersants, be sufficiently stirred for 20 minutes, carry out master batch preparation by twin-screw melting granulator, obtain cool feeling Buddhist nun
Imperial master batch, it is standby by rotary-drum vacuum dried process；Jade powder addition is 10%, and water-soluble polyester addition is 5%, is melted
Melt the temperature setting of granulation for 260 DEG C, granulation particle diameter is 0.8 centimetre.
(3) melt spinning process prepares compound POY：Prepared by mosquito proof master batch and step (2) prepared by step (1) cool
Sense nylon master batch is melted by single screw extrusion machine respectively, is then extruded by the sandwich layer and cortex of composite spinneret respectively,
Condensed in air, obtain compound POY；Described spinning temperature is 265 DEG C, and winding speed is 600m/min.
(4) FDY is prepared：Compound POY that step (3) is obtained carries out drawing-off, the hot plate of the drawing-off on drafting machine
Temperature is 70 DEG C, and temperature of heating plate is 120 DEG C, and drafting multiple is 3, and speed is 900m/min, so as to cortex cool feeling, core has been obtained
The ratio between cross-sectional area of the core-sheath compound fibre of layer anti-mosquito functions, fibrocortex and sandwich layer is 4:6.
Comparative example 1
(1) core material prepares：Anti-mosquito agent is mixed with vacuum drying polypropylene chip, is sufficiently stirred for 20 minutes,
Master batch preparation is carried out by twin-screw melting granulator, mosquito proof master batch is obtained, it is standby by rotary-drum vacuum dried process；It is anti-
Mosquito agent addition is 20%, and the temperature setting of melt pelletization is
220 DEG C, granulation particle diameter is 0.6 centimetre.
(2) cortical material prepares：By vacuum drying nylon 6 slice and water-soluble polyester section mixing, while add dividing
Powder, is sufficiently stirred for 20 minutes, and master batch preparation is carried out by twin-screw melting granulator, obtains nylon master batch, true by rotary drum
Empty dried process, it is standby；Wherein water-soluble polyester addition is 3%, and the temperature setting of melt pelletization is 260 DEG C, granulates particle diameter
It is 1 centimetre.
(3) melt spinning process prepares compound POY：Buddhist nun prepared by mosquito proof master batch and step (2) prepared by step (1)
Imperial master batch is melted by single screw extrusion machine respectively, is then extruded by the sandwich layer and cortex of composite spinneret respectively, in air
Middle condensation, obtains compound POY；Described spinning temperature is 275 DEG C, and winding speed is 500m/min.
(4) FDY is prepared：Compound POY that step (3) is obtained carries out drawing-off, the hot plate of the drawing-off on drafting machine
Temperature is 70 DEG C, and temperature of heating plate is 120 DEG C, and drafting multiple is 4, and speed is 800m/min, so as to only mosquito proof has been obtained
The ratio between cross-sectional area of the core-sheath compound fibre of function, fibrocortex and sandwich layer is 3:7.
Embodiment 4
It is weft yarn that embodiment 1~3 and the 75D/72F composite fibres obtained by comparative example is respectively adopted, with conventional func 75D/
72F nylon warp thread is conventionally weaved, and common plain fabric is obtained respectively.
Using fiber strength tester test weft fibres strongly, using maximum heat absorption rate (Q-max values) and
Cool-Ex-2008Method measurement of test method cool feeling degree, and use standard GB/T/T28408-2012《Protective garment
Dress insect prevention protective garment》Method tests mosquito proof, obtains fiber, the performance of fabric.Result such as table 1 below, table 1 is embodiment 1~3
With comparative example gained fiber, the performance of fabric.
The embodiment 1~3 of table 1 and comparative example gained fiber, the performance of fabric
Remarks：" Q-max values " serves extra large SGS with " continuing cool feeling " project；" to mosquito repelling rate " item follows Jiangsu Province's spinning with one's eyes
Knit the test of product quality supervision and inspection research institute.
As can be seen from the above data, it is right after 15 washings to mosquito repelling rate >=90% before fabric lining of the present invention is washed
Mosquito repelling rate >=45%, therefore fabric has good repellent effect to mosquito.Meanwhile, embodiment 2 shows with the data of comparative example 1
Show, the fabric with ice sense effect increased 4.75% to mosquito repelling rate, strengthen mosquito proof effect, thus the work(of the invention
Energy fabric lining has a good application prospect during the broiling summer.
The above is only the preferred embodiment of the present invention, it is noted that for making the professional technique of the art
Personnel, on the premise of the technology of the present invention principle is not departed from, are that by various modifications of these embodiments, and these
Modification also should be regarded as the scope that the present invention should be protected.
Claims (10)
1. a kind of ice sense mosquito proof fiber, it is characterised in that with the composite construction including cortex and sandwich layer, the sandwich layer be containing
There is the polypropylene layer of anti-mosquito agent, the cortex is the aramid layer containing cool feeling material；The anti-mosquito agent accounts for the weight of fiber
Amount percentage is 1~30%, and the percentage by weight that the cool feeling material accounts for fiber is 1~20%.
2. ice sense mosquito proof fiber according to claim 1, it is characterised in that the cortex has micropore, the cortex
The aperture of micropore is 0.1 micron~0.5 micron.
3. ice sense mosquito proof fiber according to claim 2, it is characterised in that the total cross sectional area of the micropore accounts for fibre
The 1~5% of dimension table area.
4. ice sense mosquito proof fiber according to claim 1, it is characterised in that the anti-mosquito agent accounts for the weight hundred of fiber
Divide than being 5~20%.
5. ice sense mosquito proof fiber according to claim 1, it is characterised in that the cool feeling material accounts for the weight hundred of fiber
Divide than being 5~15%.
6. ice sense mosquito proof fiber according to claim 1, it is characterised in that the particle diameter of the cool feeling material is 0.1 micro-
Rice~100 microns.
7. ice sense mosquito proof fiber according to claim 1, it is characterised in that the cross-sectional area of the cortex and sandwich layer
The ratio between be 1：9~5：5.
8. a kind of preparation method of ice sense mosquito proof fiber, comprises the following steps：
Polypropylene agglomerate containing anti-mosquito agent and the polyamide master batch containing cool feeling material are provided respectively；
The polypropylene agglomerate and polyamide master batch are carried out into melt spinning, ice sense mosquito proof fiber is obtained；
The ice sense mosquito proof fiber has includes the composite construction of cortex and sandwich layer, and the sandwich layer is poly- containing anti-mosquito agent
Propylene layer, the cortex is the aramid layer containing cool feeling material；The anti-mosquito agent account for the percentage by weight of fiber for 1~
30%, the percentage by weight that the cool feeling material accounts for fiber is 1~20%.
9. preparation method according to claim 8, it is characterised in that the cool feeling material is selected from jade powder and mica sheet
One or more；
The anti-mosquito agent is selected from cypermethrin, bromine chrysanthemum ester, tetramethrin, resmethrin, terallethrin, methothrin and chlorine
One or more in chrysanthemum ester.
10. a kind of ice sense anti-mosquito fabric, is obtained by fiber weaving, it is characterised in that the fiber includes claim 1~7
Any one of ice sense mosquito proof fiber or ice sense obtained in the preparation method any one of claim 8~9 it is anti-
Mosquito fiber.
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| CN107668808A (en) * | 2017-11-27 | 2018-02-09 | 苏州市叶绣工艺厂 | A kind of cool feeling embroidery ceremonial dress face fabric |
| CN109837603A (en) * | 2019-03-01 | 2019-06-04 | 疏博（上海）纳米科技有限公司 | A kind of preparation method of sun-proof mosquito proof cool feeling fabric |
| CN110117838A (en) * | 2019-05-27 | 2019-08-13 | 宁波石墨烯创新中心有限公司 | A kind of functional fibre, preparation method and fibre |
| CN111074409A (en) * | 2019-12-09 | 2020-04-28 | 浙江正辉纺织有限公司 | Mosquito-proof spandex blended knitted fabric and production method thereof |
| CN111411419A (en) * | 2020-04-14 | 2020-07-14 | 浙江恒澜科技有限公司 | Mosquito-repellent antibacterial fiber with skin-core structure and preparation method thereof |
| CN112695396A (en) * | 2020-12-17 | 2021-04-23 | 厦门安踏体育用品有限公司 | Preparation process of cool quick-drying composite fiber and fabric |
| CN112779644A (en) * | 2020-12-24 | 2021-05-11 | 陕西元丰纺织技术研究有限公司 | Temperature-adjusting antibacterial mosquito-proof yarn and fabric and preparation method thereof |
| CN112755651A (en) * | 2020-12-31 | 2021-05-07 | 东华大学 | Multi-combination functional electrostatic spinning submicron fiber air filter material and preparation thereof |
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Application publication date: 20170531 |