CN106752121B - 二氧化硅包覆型铝颜料的制备方法 - Google Patents
二氧化硅包覆型铝颜料的制备方法 Download PDFInfo
- Publication number
- CN106752121B CN106752121B CN201611092277.7A CN201611092277A CN106752121B CN 106752121 B CN106752121 B CN 106752121B CN 201611092277 A CN201611092277 A CN 201611092277A CN 106752121 B CN106752121 B CN 106752121B
- Authority
- CN
- China
- Prior art keywords
- aluminium pigment
- silicon dioxide
- coating type
- dioxide coating
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 141
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 141
- 239000004411 aluminium Substances 0.000 title claims abstract description 139
- 239000000049 pigment Substances 0.000 title claims abstract description 124
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 111
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 56
- 235000012239 silicon dioxide Nutrition 0.000 title claims abstract description 47
- 239000011248 coating agent Substances 0.000 title claims abstract description 38
- 238000000576 coating method Methods 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 239000002904 solvent Substances 0.000 claims abstract description 46
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 39
- 150000001298 alcohols Chemical class 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003112 inhibitor Substances 0.000 claims abstract description 25
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 25
- 238000004140 cleaning Methods 0.000 claims abstract description 22
- 230000007062 hydrolysis Effects 0.000 claims abstract description 17
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims abstract description 15
- 239000012535 impurity Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000002378 acidificating effect Effects 0.000 claims abstract description 7
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 7
- 239000003607 modifier Substances 0.000 claims abstract description 6
- 235000019441 ethanol Nutrition 0.000 claims description 56
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 44
- 238000006243 chemical reaction Methods 0.000 claims description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 11
- 239000004210 ether based solvent Substances 0.000 claims description 10
- 230000001476 alcoholic effect Effects 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical group [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000010931 ester hydrolysis Methods 0.000 claims description 2
- 125000004494 ethyl ester group Chemical group 0.000 claims description 2
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 claims 1
- 125000005909 ethyl alcohol group Chemical group 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 238000003828 vacuum filtration Methods 0.000 claims 1
- 238000005253 cladding Methods 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000843 powder Substances 0.000 description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000006482 condensation reaction Methods 0.000 description 8
- 239000012528 membrane Substances 0.000 description 6
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 229910002808 Si–O–Si Inorganic materials 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229910002800 Si–O–Al Inorganic materials 0.000 description 4
- 150000001398 aluminium Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- 238000002479 acid--base titration Methods 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000011859 microparticle Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 229910008051 Si-OH Inorganic materials 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910006358 Si—OH Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 229910002656 O–Si–O Inorganic materials 0.000 description 1
- 229910007156 Si(OH)4 Inorganic materials 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000003371 toe Anatomy 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
- C09C1/642—Aluminium treated with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611092277.7A CN106752121B (zh) | 2016-12-01 | 2016-12-01 | 二氧化硅包覆型铝颜料的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611092277.7A CN106752121B (zh) | 2016-12-01 | 2016-12-01 | 二氧化硅包覆型铝颜料的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106752121A CN106752121A (zh) | 2017-05-31 |
CN106752121B true CN106752121B (zh) | 2019-01-04 |
Family
ID=58915756
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611092277.7A Active CN106752121B (zh) | 2016-12-01 | 2016-12-01 | 二氧化硅包覆型铝颜料的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106752121B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107502002A (zh) * | 2017-09-05 | 2017-12-22 | 长沙族兴新材料股份有限公司 | 硅薄膜包覆型铝颜料及其制备方法和应用 |
CN109694591A (zh) * | 2019-01-03 | 2019-04-30 | 长沙族兴新材料股份有限公司 | 改性铝颜料及其制备方法和包含其的涂料 |
CN111100484A (zh) * | 2019-12-27 | 2020-05-05 | 河南兴安新型建筑材料有限公司 | 一种纳米SiO2包覆片状颜料Al粉的制备方法 |
CN112679999B (zh) * | 2020-12-29 | 2022-07-19 | 长沙族兴新材料股份有限公司 | 一种用于氟碳粉末涂料的铝颜料及其制备方法 |
CN113999548B (zh) * | 2021-11-15 | 2022-09-02 | 深圳市绚图新材科技有限公司 | 一种水性铝颜料的制备方法及制备用的反应釜 |
CN118185389A (zh) * | 2024-05-16 | 2024-06-14 | 长沙族兴新材料股份有限公司 | 一种低voc水性铝浆涂料的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101235226A (zh) * | 2008-02-25 | 2008-08-06 | 中南大学 | 一种二氧化硅包覆型水性铝银浆的制备方法 |
CN102732068A (zh) * | 2012-04-11 | 2012-10-17 | 江苏大学 | 在铝粉表面进行SiO2/Fe2O3复合包膜的方法 |
CN103333531A (zh) * | 2013-07-23 | 2013-10-02 | 长沙族兴新材料股份有限公司 | 一种水性铝银浆及其制备方法 |
-
2016
- 2016-12-01 CN CN201611092277.7A patent/CN106752121B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101235226A (zh) * | 2008-02-25 | 2008-08-06 | 中南大学 | 一种二氧化硅包覆型水性铝银浆的制备方法 |
CN102732068A (zh) * | 2012-04-11 | 2012-10-17 | 江苏大学 | 在铝粉表面进行SiO2/Fe2O3复合包膜的方法 |
CN103333531A (zh) * | 2013-07-23 | 2013-10-02 | 长沙族兴新材料股份有限公司 | 一种水性铝银浆及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN106752121A (zh) | 2017-05-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106752121B (zh) | 二氧化硅包覆型铝颜料的制备方法 | |
CN101815676B (zh) | 改性金属氧化物复合溶胶、涂布组合物和光学部件 | |
CN101815675B (zh) | 金属氧化物复合溶胶、涂布组合物和光学部件 | |
CN101184695B (zh) | 中空状SiO2微粒分散液的制造方法、涂料组合物及带防反射涂膜的基材 | |
JP6241700B1 (ja) | ケイ素化合物被覆酸化物粒子の製造方法 | |
CN101861365B (zh) | 经表面处理的氧化锌微粒的制造方法、经表面处理的氧化锌微粒、其分散液体及分散固体、以及氧化锌微粒包覆的基体材料 | |
JP6218945B2 (ja) | 中空シリカ粒子の製造方法、中空シリカ粒子及びそれらを含む組成物、並びに断熱シート | |
KR101724603B1 (ko) | 중공실리카 입자의 제조방법, 중공실리카 입자 및 그를 포함하는 조성물 및 내부공동들이 형성된 시트 | |
CN106634314B (zh) | 一种高亮标线涂料及其制备方法 | |
CN110494505B (zh) | 包核颜料 | |
CN108587447A (zh) | 一种适应多种基底的耐久性透明超疏水涂层的制备方法 | |
CN101525504A (zh) | 具有自分层隔离作用的光催化自清洁涂膜剂及其制备方法 | |
CN103205142A (zh) | 一种有机改性陶瓷不粘涂层及其涂覆方法 | |
JP2003147226A (ja) | アルミニウム顔料、その製造方法および樹脂組成物 | |
CN102993793B (zh) | 一种抗裂汽车底漆及其制备方法 | |
JP2001011342A (ja) | 変性シリカ被覆顔料、その製法およびそれを含有する組成物 | |
CN106752555A (zh) | 一种净味无甲醛的内墙环保涂料及其制备方法 | |
CN107308928A (zh) | 乳胶漆专用二氧化钛制备方法 | |
CN114539862B (zh) | 一种无人驾驶标定板及其制备方法 | |
CN104011148B (zh) | 低聚物修饰微粒与其制造方法以及涂料 | |
CN101134598A (zh) | 与有机络合物螯合的二氧化钛溶胶,其制备方法,以及包含二氧化钛溶胶的组合物 | |
CN101659822A (zh) | 水性水转印清漆涂料及其制备方法 | |
CN113500838A (zh) | 一种高强度自清洁反光膜及其制备方法 | |
CN112063296A (zh) | 一种高硬度防火疏水型仿石材陶瓷涂料、制备工艺及应用 | |
JP4562492B2 (ja) | 棒状二酸化チタン及びそれを含む近赤外線遮蔽剤並びに該近赤外線遮蔽剤を含む樹脂組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of silica coated aluminum pigment Effective date of registration: 20210918 Granted publication date: 20190104 Pledgee: Ningxiang sub branch of Bank of Changsha Co.,Ltd. Pledgor: ZUXING NEW MATERIAL Co.,Ltd. Registration number: Y2021980009561 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20190104 Pledgee: Ningxiang sub branch of Bank of Changsha Co.,Ltd. Pledgor: ZUXING NEW MATERIAL CO.,LTD. Registration number: Y2021980009561 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of silica coated aluminum pigment Granted publication date: 20190104 Pledgee: Ningxiang sub branch of Bank of Changsha Co.,Ltd. Pledgor: ZUXING NEW MATERIAL CO.,LTD. Registration number: Y2024980013898 |