CN106747377B - A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite - Google Patents
A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite Download PDFInfo
- Publication number
- CN106747377B CN106747377B CN201710089846.0A CN201710089846A CN106747377B CN 106747377 B CN106747377 B CN 106747377B CN 201710089846 A CN201710089846 A CN 201710089846A CN 106747377 B CN106747377 B CN 106747377B
- Authority
- CN
- China
- Prior art keywords
- fabric
- silicon dioxide
- electrophoretic deposition
- dioxide gel
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/82—Asbestos; Glass; Fused silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Abstract
A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite, comprises the following steps：（1）By silica fibrage, the integral fabric of designated shape is formed, and the size on the fabric fibre surface is removed and dried；（2）In insulating vessel, quartz textile is placed between positive pole and negative pole, and is connected with dc source；（3）Silicon dioxide gel is injected in insulating vessel, colloidal sol is flooded electrode and fabric completely；（4）Dc source is opened, adjusts voltage, silica electrophoretic deposition is carried out to fabric, and clear liquid is extracted according to component size and supplements colloidal sol；（5）Fabric after electrophoretic deposition is taken out into drying, sintering, forms quartz fibre enhancing quartz-ceramics composite.The present invention has advantage simple to operate, reliable, the cycle is short, cost is low；The compactness and uniformity of material can be improved using the present invention.
Description
Technical field
The present invention relates to a kind of method for preparing quartzy composite, and in particular to a kind of electrophoretic deposition silicon dioxide gel
The method for preparing quartzy composite.
Background technology
Quartz fibre strengthens quartzy composite, and there is high temperature resistant, high intensity, high tenacity, low dielectric, low-loss, low-heat to lead
The features such as, available for the wave transparent window material such as spaceship, or the high temperature wave transparent window material used in industrial equipment, it can support
Drive more than 1000 DEG C of high temperature and there is the characteristic through electromagnetic wave.
The material preparation method is generally impregnating sol gel-sintering process, i.e., silicon dioxide gel is used into Vaccum Permeating
Stain impregnates gelation and sintering after gel drying, finally gives dense composite repeatedly into quartz textile.
Some existing patents of this traditional preparation method are reported with paper, such as a kind of " high wave transparent cell quartz/quartz at Chen Zhao peaks
Ceramic matric composite and preparation method thereof "（CN103724037A）, Cheng Zhiqiang " fibre-quartz ceramic-base composite material
Enhancement Method "（CN101591192）, Zhai Ping " quartz fibre strengthens the densifying method of quartz-ceramics composite "
（CN104909791A）, Jia Guangyao etc. " development of three-direction quartz fiber reinforced quartz composite "（《Silicate is circulated a notice of》2002,21 (1):3-6）
Deng.
Because the solids content of silicon dioxide gel is generally 25% or so, and pickling efficiency is than relatively low, therefore using tradition
The method for impregnating gel sintering repeatedly generally require the dipping of more than ten or even tens times, due to dipping, gelation, drying and burning
Knot often, makes the long preparation period of material and cost is high, greatly limit its extensive use.
Electrophoretic deposition, for example " pulsed hydrothermal electrophoresis sedimentation prepares carbon/carbon composite material mullite external coating to yellow sword cutting edge of a knife or a sword
Method "（CN101885623A）, Wang Hong " preparation method based on electrophoretic deposition nano-polymer composite material "
（CN102181912A）, Gao Junguo " method that a kind of electrophoresis-electrolysis composite electrodeposition prepares ceramic composite coating "
（CN102776549A）, Huang Jianfeng " a kind of method of preparing yttrium silicate coat by cathode rotation hydrothermal electrophoretic deposition "
（CN101514473）, Mei Hui " a kind of preparation method of electrophoretic deposition CNTs enhancings ceramic matric composite "
（CN104150939A）, Guo Lingjun " preparation method of electrophoretic deposition nano wire Strengthening and Toughening SiC antioxidant coatings "
（CN104591798A）, Li Hejun " a kind of method that dielectrophoresis technology prepares CNT/carbon/carbon compound material "
（CN103451708A）, " microwave hydrothermal electrophoresis arc discharge deposition prepares carbon/carbon compound material C-AlPO4 external coatings to Cao Liyun
Method "（CN102674885A）, Dai Changsong is " a kind of to put forward high calcium and phosphorus-chitosan electrophoretic deposition uniformity in foam metal
Method "（CN102560604A）, the Yao Xuming " sides of acidifying auxiliary electrophoretic deposition initiated oxidation graphene deposition modified carbon fiber
Method "（CN105696312A）Deng, but at present do not have also on electrophoretic deposition prepare quartz fibre enhancing quartz-ceramics answer
The report of condensation material.
The content of the invention
The technical problem to be solved by the invention is to provide one kind can shorten manufacturing cycle, reduce the electrophoresis of manufacturing cost
The method that deposition silicon dioxide gel prepares quartzy composite.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite, comprises the following steps：
（1）By silica fibrage, the integral fabric of designated shape is formed, and the size on the fabric fibre surface is gone
Remove and dry；
（2）In insulating vessel, quartz textile is placed between positive pole and negative pole, and is connected with dc source；
（3）Silicon dioxide gel is injected in insulating vessel, colloidal sol is flooded electrode and fabric completely；
（4）Dc source is opened, adjusts voltage, silica electrophoretic deposition is carried out to fabric, and take out according to component size
Take clear liquid and supplement colloidal sol；
（5）Fabric after electrophoretic deposition is taken out into drying, sintering, forms quartz fibre enhancing quartz-ceramics composite.
Further, step（1）In, the quartz fibre is that diameter is less than 10 microns, purity >=99.95wt% high-purity stone
English fiber.Filament strength is generally higher than 1.5GPa, and fiber surface is typically with the presence of size.
Further, step（1）In, the thickness of the fabric is between 5.0-20mm.
Further, step（2）In, described positive pole, the material of negative pole are graphite material, and thickness is between 3-30mm.Just
Pole, the size of negative pole and fabric are in the same size, the same fabric of shape.
Further, step（2）In, the relative position between described fabric, positive pole, negative pole three is in positive pole for fabric
Between negative pole, and three is in upper-lower position.Graphite electrode is with fabric distance between 0-800mm, preferred distance 100mm.
Further, step（3）In, inject silicon dioxide gel by the way of vacuum injection silicon dioxide gel.
Further, step（4）In, described direct current power source voltage is between 0.01-20 volts, preferably 4-5 volts.
Further, step（5）In, described drying temperature is between 30-300 DEG C, preferably 100 DEG C, is dried to and not weightless is
Only.
Further, step（5）In, described sintering temperature is between 500-1200 DEG C, preferably 1000 DEG C, sinters 2-9 hours.
There is composite obtained by the present invention high temperature resistant, high intensity, high tenacity, low dielectric, low-loss, low-heat to lead
Characteristic, composite density are generally higher than 1.6g/cm3, bending strength is not less than 30MPa, has machinability.
The present invention makes sol particle orientated deposition gradually form densification into fabric in the presence of positive and negative electrode
Gelation complex, then through high temperature sintering obtain quartz fibre enhancing quartz-ceramics composite.This method is in dipping, gel
Change, sinter these three key links and only need once.
Compared with conventional method, the present invention has advantage simple to operate, reliable, the cycle is short, cost is low.In addition, utilize
The present invention can improve the compactness and uniformity of material.
Embodiment
The invention will be further described with reference to embodiments.
Embodiment 1
A kind of electrophoretic deposition silicon dioxide gel prepares the method for quartz fibre enhancing quartz-ceramics composite material flat plate, bag
Include following steps：
（1）Quartz glass fibre using purity as 99.95wt%, use three-dimensional orthogonal weaving manner be prepared into size for
200*200*10mm fabric；Fiber surface size is removed using the method for calcination；
（2）In the square insulating container that size is 300*300*80mm, it is sequentially placed into and the same chi of fabric in vertical direction
Very little graphite positive pole, quartz textile, graphite cathode, and be connected with dc source；
（3）Vacuum injection mass concentration is 25% silicon dioxide gel in a reservoir；
（4）Dc source is opened, adjustment voltage is 5 volts, and silica electrophoretic deposition is carried out to fabric, when discovery container
After upper strata colloidal sol becomes clarification, clarification part is extracted out, then supplement the silicon dioxide gel of equivalent；
（5）After 10 hours, the fabric after electrophoretic deposition is taken out, dried 5 hours at 150 DEG C, then at 1000 DEG C
Sintering 6 hours, form quartz fibre enhancing quartz-ceramics composite.
The density of the material is 1.68g/cm3, bending strength 89MPa.
Embodiment 2
A kind of electrophoretic deposition silicon dioxide gel prepares hemispheric quartz fibre enhancing quartz-ceramics composite element
Method, comprise the following steps：
（1）Quartz glass fibre using purity as 99.95wt%, diameter is prepared into using the weaving manner of three-dimensional four-way
200mm thickness is 15mm hemispherical fabric；Fiber surface size is removed using the method for calcination；
（2）In a diameter of 300mm, depth is in 400mm drum insulating vessel, is sequentially placed into and fabric in vertical direction
Profiling and graphite positive pole, quartz textile, the plate shaped graphite cathode of no-float, and be connected with dc source；
（3）Vacuum injection mass concentration is 27% silicon dioxide gel in a reservoir；
（4）Dc source is opened, adjustment voltage is 4 volts, and silica electrophoretic deposition is carried out to fabric, when discovery container
After upper strata colloidal sol becomes clarification, clarification part is extracted out, then supplement the silicon dioxide gel of equivalent；
（5）After 20 hours, the fabric after electrophoretic deposition is taken out, dried 5 hours at 150 DEG C, after deviating from graphite electrode,
Sintered 5 hours at 1000 DEG C, form hemispheric quartz fibre enhancing quartz-ceramics composite element.
The density of the material is 1.67g/cm3, bending strength 76MPa.
Claims (9)
1. a kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite, it is characterised in that comprise the following steps：
（1）By silica fibrage, the integral fabric of designated shape is formed, and the size on the fabric fibre surface is removed simultaneously
Drying；
（2）In insulating vessel, quartz textile is placed between positive pole and negative pole, and is connected with dc source；
（3）Silicon dioxide gel is injected in insulating vessel, colloidal sol is flooded electrode and fabric completely；
（4）Dc source is opened, adjusts voltage, silica electrophoretic deposition is carried out to fabric, and extract clearly according to component size
Liquid simultaneously supplements colloidal sol；
（5）Fabric after electrophoretic deposition is taken out into drying, sintering, forms quartz fibre enhancing quartz-ceramics composite.
2. the method that electrophoretic deposition silicon dioxide gel according to claim 1 prepares quartzy composite, its feature exist
In step（1）In, the quartz fibre is that diameter is less than 10 microns, purity >=99.95wt% high purity quartz fiber.
3. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（1）In, the thickness of the fabric is between 5.0-20mm.
4. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（2）In, described positive pole, the material of negative pole are graphite material, and thickness is between 3-30mm；Positive pole, negative pole it is big
It is small in the same size with fabric, the same fabric of shape.
5. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（2）In, relative position between described fabric, positive pole, negative pole three for fabric be in positive pole and negative pole it
Between, and three is in upper-lower position.
6. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（3）In, inject silicon dioxide gel by the way of vacuum injection silicon dioxide gel.
7. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（4）In, described direct current power source voltage is between 0.01-20 volts.
8. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（5）In, described drying temperature between 30-300 DEG C, be dried to it is not weightless untill.
9. the method that electrophoretic deposition silicon dioxide gel according to claim 1 or 2 prepares quartzy composite, its feature
It is, step（5）In, described sintering temperature sinters 2-9 hours between 500-1200 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710089846.0A CN106747377B (en) | 2017-02-20 | 2017-02-20 | A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710089846.0A CN106747377B (en) | 2017-02-20 | 2017-02-20 | A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106747377A CN106747377A (en) | 2017-05-31 |
| CN106747377B true CN106747377B (en) | 2017-11-21 |
Family
ID=58957654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710089846.0A Expired - Fee Related CN106747377B (en) | 2017-02-20 | 2017-02-20 | A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106747377B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111484262B (en) * | 2020-05-26 | 2022-01-11 | 深圳大学 | Carbon fiber composite material and preparation method and application thereof |
| CN113956058A (en) * | 2021-11-29 | 2022-01-21 | 航天特种材料及工艺技术研究所 | Preparation method of high-performance alumina fiber ceramic matrix composite |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1501897A (en) * | 2000-09-07 | 2004-06-02 | �Ϻ���ͨ��ѧ | Electrophoretically redensified sio2 moulded body, method for the production and use thereof |
| CN104446580A (en) * | 2014-12-16 | 2015-03-25 | 中国人民解放军国防科学技术大学 | Method for preparing continuous fiber cloth reinforced silica ceramic-based composite material |
-
2017
- 2017-02-20 CN CN201710089846.0A patent/CN106747377B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1501897A (en) * | 2000-09-07 | 2004-06-02 | �Ϻ���ͨ��ѧ | Electrophoretically redensified sio2 moulded body, method for the production and use thereof |
| CN104446580A (en) * | 2014-12-16 | 2015-03-25 | 中国人民解放军国防科学技术大学 | Method for preparing continuous fiber cloth reinforced silica ceramic-based composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106747377A (en) | 2017-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106747377B (en) | A kind of method that electrophoretic deposition silicon dioxide gel prepares quartzy composite | |
| CN104532549B (en) | A kind of method based on Microwave Induced Plasma quick obtaining carbon/coaxial fiber of carborundum and application | |
| CN106866148A (en) | The SiC of SiC nanowire In-sltu reinforcementf/ SiC ceramic matrix composite material and preparation method thereof | |
| CN103044086B (en) | Method for preparing carbon/carbon composite yttrium silicate whisker reinforced C-AlPO4-SiCn complex external coating | |
| CN109722674B (en) | Two-dimensional layered WS prepared by molten salt electrochemical stripping method2Method of producing a material | |
| CN106757239A (en) | A kind of method of silicon carbide fibre electroplating nickel on surface | |
| CN106702732A (en) | Graphene-copper composite fiber and preparation method thereof | |
| CN105297395B (en) | A kind of method and processing unit of liquid phase plasma continuous processing carbon fiber surface | |
| CN104926343B (en) | Aluminum silicate fiber reinforced oxide ceramic containing interface phase and preparation method thereof | |
| WO2016026340A1 (en) | Tio2 nanocrystal and synthesis method therefor | |
| CN109081684A (en) | A kind of preparation method of carbon nanotube enhancing alumina matrix composite | |
| CN108147403A (en) | A kind of preparation method of graphene oxide quantum dot and products thereof | |
| CN107354500A (en) | A kind of glass fiber compound material of the grapheme modified claddings of nanoscale Fe3O4 and preparation method thereof | |
| CN105690807A (en) | Preparation method and application of carbon fiber reinforced polymer-based composite | |
| Ren et al. | The selective fabrication of large-area highly ordered TiO2 nanorod and nanotube arrays on conductive transparent substrates via sol–gel electrophoresis | |
| CN109485032B (en) | Method for preparing high-quality graphene quantum dots or large-sheet-layer graphene oxide | |
| CN103044076B (en) | Method for preparing carbon/carbon composite yttrium silicate whisker reinforced mullite-C-AlPO4 complex external coating | |
| CN107244877B (en) | A kind of bimetallic oxide-silicon carbide fibre multi-scale reinforcing body enhancing aluminum phosphate ceramic base structural wave-absorbing material and preparation method thereof | |
| CN109455758A (en) | A kind of titanium dioxide nanorod array film and preparation method thereof | |
| Manocha et al. | Silica/silica composites through electrophoretic infiltration-Effect of processing conditions on densification of composites | |
| CN109666946B (en) | Two-dimensional layered MoS prepared by molten salt electrochemical intercalation method2Method of producing a material | |
| Li et al. | Synthesis of TiO2 nanorings and nanorods on TCO substrate by potentiostatic anodization of titanium powder | |
| EP0613454B1 (en) | Method of manufacturing a composite material | |
| CN109721367A (en) | A kind of preparation method of the highly conductive CNT interface modification ceramic matric composite of high thermal conductivity | |
| CN113428892B (en) | Preparation method of simple controllable preparation of ultra-long hydrohalolead nanowire |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171121 Termination date: 20190220 |