CN106747313A - 一种低成本陶瓷渗水砖 - Google Patents

一种低成本陶瓷渗水砖 Download PDF

Info

Publication number
CN106747313A
CN106747313A CN201611269775.4A CN201611269775A CN106747313A CN 106747313 A CN106747313 A CN 106747313A CN 201611269775 A CN201611269775 A CN 201611269775A CN 106747313 A CN106747313 A CN 106747313A
Authority
CN
China
Prior art keywords
parts
permeable brick
weight
sand
ceramic water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611269775.4A
Other languages
English (en)
Inventor
薛念念
汤俊怀
李青松
王军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui city clean environment Technology Co., Ltd.
Original Assignee
Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Huapu Environmental Remediation Mstar Technology Ltd filed Critical Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority to CN201611269775.4A priority Critical patent/CN106747313A/zh
Publication of CN106747313A publication Critical patent/CN106747313A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352—Fuel ashes, e.g. fly ash
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/36—Reinforced clay-wares
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3215—Barium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52—Constituents or additives characterised by their shapes
    • C04B2235/5208—Fibers
    • C04B2235/5216—Inorganic
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52—Constituents or additives characterised by their shapes
    • C04B2235/5276—Whiskers, spindles, needles or pins
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52—Constituents or additives characterised by their shapes
    • C04B2235/5284—Hollow fibers, e.g. nanotubes
    • C04B2235/5288—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Ceramic Products (AREA)

Abstract

本发明公开了一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料50‑80份，黄土复合物20‑50份，混凝土5‑15份，粉煤灰5‑15份，铁尾矿2‑8份，玄武岩5‑13份，碳化硅晶须4‑16份，硼酸镁晶须5‑15份，玻璃纤维2‑8份，重晶砂4‑10份，碳纳米管2‑10份，钡渣4‑13份，珍珠岩2‑7份，莫来石1‑6份，油页岩2‑8份，云母粉4‑12份，石英砂2‑8份，减水剂1‑2份，胶黏剂1‑3份。本发明不仅成本低，且透水性好，经济环保。

Description

一种低成本陶瓷渗水砖
技术领域
本发明涉及渗水砖技术领域，尤其涉及一种低成本陶瓷渗水砖。
背景技术
目前，随着社会的进步和经济的发展，在消耗了大量资源的同时，也造成了严重的污染。内蒙古是煤炭基地，同时又是一个发电基地，虽然创造了很大的经济效益，但也造成了很多环境问题。煤矸石是煤炭开采和洗选加工过程中产生的固体废弃物，排放量约占煤矿原煤产量的8-10％，同时，燃煤电厂排山大量的粉煤灰，仅包头每年排放的粉煤灰就在几百万吨以上，刮大风时，灰尘满天，对环境和居民身体健康产生了严重的影响；近年来鄂尔多斯陶瓷行业的迅猛发展，随之也产生各种陶瓷废料。这些固体废弃物多数堆放在露天，长此以往，既占用了大量上地，又污染了环境，另外随着社会的不断进步，地表越来越多的被建筑物和混凝土等不透水的地面铺装覆盖，这些硬化路面使地表与空气的热量、水分交换很困难，自然调节城市地面温度和湿度的能力显著降低，如何采用陶瓷废料制备透水砖成为目前亟待解决的技术问题。
发明内容
本发明提出了一种低成本陶瓷渗水砖，不仅成本低，且透水性好，经济环保。
本发明提出的一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料50-80份，黄土复合物20-50份，混凝土5-15份，粉煤灰5-15份，铁尾矿2-8份，玄武岩5-13份，碳化硅晶须4-16份，硼酸镁晶须5-15份，玻璃纤维2-8份，重晶砂4-10份，碳纳米管2-10份，钡渣4-13份，珍珠岩2-7份，莫来石1-6份，油页岩2-8份，云母粉4-12份，石英砂2-8份，减水剂1-2份，胶黏剂1-3份。
优选地，黄土复合物采用如下工艺制备：将β-环糊精、氢氧化钠、吡啶混合搅拌，搅拌速度为600-800r/min，加入琥珀酸酐，在温度60-70℃搅拌，加入二甲基甲酰胺结晶，干燥，加入砂黄土、磷酸水溶液混合搅拌，搅拌速度为200-350r/min，加入四硼酸钠继续搅拌，干燥，粉碎，得到黄土复合物。
优选地，β-环糊精、氢氧化钠、吡啶的重量比为10-20：2-5：100-200。
优选地，β-环糊精、琥珀酸酐的重量比为10-20：2-6。
优选地，磷酸水溶液浓度为6-8％；砂黄土、磷酸水溶液的重量比为20-50：100-200。
优选地，四硼酸钠、砂黄土的重量比为1-5：20-50。
优选地，黄土复合物采用如下工艺制备：按重量份将10-20份β-环糊精、2-5份氢氧化钠、100-200份吡啶混合搅拌60-80min，搅拌速度为600-800r/min，加入2-6份琥珀酸酐，在温度60-70℃搅拌5-12min，加入二甲基甲酰胺结晶，干燥，加入20-50份砂黄土、100-200份浓度为6-8％磷酸水溶液混合搅拌1-2h，搅拌速度为200-350r/min，加入1-5份四硼酸钠继续搅拌60-80min，干燥，粉碎，得到黄土复合物。
优选地，所述的低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料65-72份，黄土复合物40-42份，混凝土10-13份，粉煤灰8-12份，铁尾矿4-6份，玄武岩8-10份，碳化硅晶须6-8份，硼酸镁晶须11-13份，玻璃纤维4-5份，重晶砂7-8份，碳纳米管5-7份，钡渣9-11份，珍珠岩3-4份，莫来石2-4份，油页岩5-6份，云母粉8-10份，石英砂5-7份，减水剂1.2-1.5份，胶黏剂2-2.6份。
本发明的黄土复合物中，β-环糊精分子形状为内疏水，外亲水略呈锥筒状的空腔结构，其含有大量的伯羟基和仲羟基，在一定条件下与琥珀酸酐作用，水溶性极好，可有效促使砂黄土在磷酸水溶液中酸化并破坏砂黄土的粒状架空微结构，与四硼酸钠结合，并通过合理控制各组分间配比，制品在保证抗冲击强度高的前提下，渗水性极好，与陶瓷废料配合不仅成本低，且可实现无害化和资源化的利用；其余砂料在烧结过程中，会在砖块结构中形成具有一定孔隙率的结构，既保证了砖块有一定的机械强度，也使砖块之间形成可以透水的空隙，提高了其渗水性能，与黄土复合物配合其抗压强度可达到26MPa以上，同时渗水系数可达1.61×10-2cm/s以上。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料50份，黄土复合物50份，混凝土5份，粉煤灰15份，铁尾矿2份，玄武岩13份，碳化硅晶须4份，硼酸镁晶须15份，玻璃纤维2份，重晶砂10份，碳纳米管2份，钡渣13份，珍珠岩2份，莫来石6份，油页岩2份，云母粉12份，石英砂2份，减水剂2份，胶黏剂1份。
实施例2
一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料80份，黄土复合物20份，混凝土15份，粉煤灰5份，铁尾矿8份，玄武岩5份，碳化硅晶须16份，硼酸镁晶须5份，玻璃纤维8份，重晶砂4份，碳纳米管10份，钡渣4份，珍珠岩7份，莫来石1份，油页岩8份，云母粉4份，石英砂8份，减水剂1份，胶黏剂3份。
实施例3
一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料72份，黄土复合物40份，混凝土13份，粉煤灰8份，铁尾矿6份，玄武岩8份，碳化硅晶须8份，硼酸镁晶须11份，玻璃纤维5份，重晶砂7份，碳纳米管7份，钡渣9份，珍珠岩4份，莫来石2份，油页岩6份，云母粉8份，石英砂7份，减水剂1.2份，胶黏剂2.6份。
黄土复合物采用如下工艺制备：按重量份将10份β-环糊精、5份氢氧化钠、100份吡啶混合搅拌80min，搅拌速度为600r/min，加入6份琥珀酸酐，在温度60℃搅拌12min，加入二甲基甲酰胺结晶，干燥，加入20份砂黄土、200份浓度为6％磷酸水溶液混合搅拌2h，搅拌速度为200r/min，加入5份四硼酸钠继续搅拌60min，干燥，粉碎，得到黄土复合物。
实施例4
一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料65份，黄土复合物42份，混凝土10份，粉煤灰12份，铁尾矿4份，玄武岩10份，碳化硅晶须6份，硼酸镁晶须13份，玻璃纤维4份，重晶砂8份，碳纳米管5份，钡渣11份，珍珠岩3份，莫来石4份，油页岩5份，云母粉10份，石英砂5份，减水剂1.5份，胶黏剂2份。
黄土复合物采用如下工艺制备：按重量份将20份β-环糊精、2份氢氧化钠、200份吡啶混合搅拌60min，搅拌速度为800r/min，加入2份琥珀酸酐，在温度70℃搅拌5min，加入二甲基甲酰胺结晶，干燥，加入50份砂黄土、100份浓度为8％磷酸水溶液混合搅拌1h，搅拌速度为350r/min，加入1份四硼酸钠继续搅拌80min，干燥，粉碎，得到黄土复合物。
实施例5
一种低成本陶瓷渗水砖，其原料按重量份包括：陶瓷废料69份，黄土复合物41份，混凝土12份，粉煤灰10份，铁尾矿5份，玄武岩9份，碳化硅晶须7份，硼酸镁晶须12份，玻璃纤维4.5份，重晶砂7.2份，碳纳米管8份，钡渣10份，珍珠岩3.5份，莫来石3份，油页岩5.2份，云母粉9份，石英砂6份，减水剂1.35份，胶黏剂2.3份。
黄土复合物采用如下工艺制备：按重量份将16份β-环糊精、3份氢氧化钠、140份吡啶混合搅拌72min，搅拌速度为720r/min，加入4份琥珀酸酐，在温度66℃搅拌10min，加入二甲基甲酰胺结晶，干燥，加入35份砂黄土、140份浓度为7％磷酸水溶液混合搅拌1.5h，搅拌速度为320r/min，加入3份四硼酸钠继续搅拌72min，干燥，粉碎，得到黄土复合物。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (8)

1.一种低成本陶瓷渗水砖，其特征在于，其原料按重量份包括：陶瓷废料50-80份，黄土复合物20-50份，混凝土5-15份，粉煤灰5-15份，铁尾矿2-8份，玄武岩5-13份，碳化硅晶须4-16份，硼酸镁晶须5-15份，玻璃纤维2-8份，重晶砂4-10份，碳纳米管2-10份，钡渣4-13份，珍珠岩2-7份，莫来石1-6份，油页岩2-8份，云母粉4-12份，石英砂2-8份，减水剂1-2份，胶黏剂1-3份。
2.根据权利要求1所述的低成本陶瓷渗水砖，其特征在于，黄土复合物采用如下工艺制备：将β-环糊精、氢氧化钠、吡啶混合搅拌，搅拌速度为600-800r/min，加入琥珀酸酐，在温度60-70℃搅拌，加入二甲基甲酰胺结晶，干燥，加入砂黄土、磷酸水溶液混合搅拌，搅拌速度为200-350r/min，加入四硼酸钠继续搅拌，干燥，粉碎，得到黄土复合物。
3.根据权利要求2所述的低成本陶瓷渗水砖，其特征在于，β-环糊精、氢氧化钠、吡啶的重量比为10-20：2-5：100-200。
4.根据权利要求2所述的低成本陶瓷渗水砖，其特征在于，β-环糊精、琥珀酸酐的重量比为10-20：2-6。
5.根据权利要求2所述的低成本陶瓷渗水砖，其特征在于，磷酸水溶液浓度为6-8％；砂黄土、磷酸水溶液的重量比为20-50：100-200。
6.根据权利要求2所述的低成本陶瓷渗水砖，其特征在于，四硼酸钠、砂黄土的重量比为1-5：20-50。
7.根据权利要求1-6任一项所述的低成本陶瓷渗水砖，其特征在于，黄土复合物采用如下工艺制备：按重量份将10-20份β-环糊精、2-5份氢氧化钠、100-200份吡啶混合搅拌60-80min，搅拌速度为600-800r/min，加入2-6份琥珀酸酐，在温度60-70℃搅拌5-12min，加入二甲基甲酰胺结晶，干燥，加入20-50份砂黄土、100-200份浓度为6-8％磷酸水溶液混合搅拌1-2h，搅拌速度为200-350r/min，加入1-5份四硼酸钠继续搅拌60-80min，干燥，粉碎，得到黄土复合物。
8.根据权利要求1-7任一项所述的低成本陶瓷渗水砖，其特征在于，其原料按重量份包括：陶瓷废料65-72份，黄土复合物40-42份，混凝土10-13份，粉煤灰8-12份，铁尾矿4-6份，玄武岩8-10份，碳化硅晶须6-8份，硼酸镁晶须11-13份，玻璃纤维4-5份，重晶砂7-8份，碳纳米管5-7份，钡渣9-11份，珍珠岩3-4份，莫来石2-4份，油页岩5-6份，云母粉8-10份，石英砂5-7份，减水剂1.2-1.5份，胶黏剂2-2.6份。
CN201611269775.4A 2016-12-30 2016-12-30 一种低成本陶瓷渗水砖 Pending CN106747313A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611269775.4A CN106747313A (zh) 2016-12-30 2016-12-30 一种低成本陶瓷渗水砖

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611269775.4A CN106747313A (zh) 2016-12-30 2016-12-30 一种低成本陶瓷渗水砖

Publications (1)

Publication Number Publication Date
CN106747313A true CN106747313A (zh) 2017-05-31

Family

ID=58951902

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611269775.4A Pending CN106747313A (zh) 2016-12-30 2016-12-30 一种低成本陶瓷渗水砖

Country Status (1)

Country Link
CN (1) CN106747313A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108409291A (zh) * 2018-04-26 2018-08-17 合肥天沃能源科技有限公司 一种相变蓄热环保节能砖及其制备方法
CN108467254A (zh) * 2018-02-22 2018-08-31 李刚 一种玄武岩尾矿透水砖及其制备方法
CN109111173A (zh) * 2018-10-22 2019-01-01 东莞理工学院 一种透水混凝土及其制备方法
LU101393A1 (en) * 2018-10-09 2020-04-09 Henan Best Builder Network Tech Co Ltd Method for preparing an earth yellow brick from loess.
CN114230243A (zh) * 2021-12-10 2022-03-25 柳州市大星混凝土有限公司 高耐久性混凝土及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850038A (zh) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 一种陶瓷渗水砖
CN103420666A (zh) * 2013-07-26 2013-12-04 和县明生环保材料有限责任公司 一种矿石尾砂陶粒空心砖及其制备方法
CN104072060A (zh) * 2014-07-01 2014-10-01 谢伟杰 一种陶瓷渗水砖
CN104177061A (zh) * 2014-08-09 2014-12-03 浙江特拉建材有限公司 一种空心砖的制造方法
CN105174995A (zh) * 2015-09-14 2015-12-23 马鞍山科诺墙体材料制造有限公司 一种静压高强耐磨混凝土防堵透水砖及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850038A (zh) * 2012-08-30 2013-01-02 苏州市德莱尔建材科技有限公司 一种陶瓷渗水砖
CN103420666A (zh) * 2013-07-26 2013-12-04 和县明生环保材料有限责任公司 一种矿石尾砂陶粒空心砖及其制备方法
CN104072060A (zh) * 2014-07-01 2014-10-01 谢伟杰 一种陶瓷渗水砖
CN104177061A (zh) * 2014-08-09 2014-12-03 浙江特拉建材有限公司 一种空心砖的制造方法
CN105174995A (zh) * 2015-09-14 2015-12-23 马鞍山科诺墙体材料制造有限公司 一种静压高强耐磨混凝土防堵透水砖及其制备方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108467254A (zh) * 2018-02-22 2018-08-31 李刚 一种玄武岩尾矿透水砖及其制备方法
CN108409291A (zh) * 2018-04-26 2018-08-17 合肥天沃能源科技有限公司 一种相变蓄热环保节能砖及其制备方法
LU101393A1 (en) * 2018-10-09 2020-04-09 Henan Best Builder Network Tech Co Ltd Method for preparing an earth yellow brick from loess.
CN109111173A (zh) * 2018-10-22 2019-01-01 东莞理工学院 一种透水混凝土及其制备方法
CN114230243A (zh) * 2021-12-10 2022-03-25 柳州市大星混凝土有限公司 高耐久性混凝土及其制备方法
CN114230243B (zh) * 2021-12-10 2022-07-26 柳州市大星混凝土有限公司 高耐久性混凝土及其制备方法

Similar Documents

Publication Publication Date Title
CN106747313A (zh) 一种低成本陶瓷渗水砖
CN102464497B (zh) 一种废砖瓦/秸秆泡沫混凝土及其制备方法
CN101428994B (zh) 一种用植物纤维和水泥增强的轻质保温隔热生土材料
CN107602072B (zh) 一种基于石墨烯与固态废弃物的透水砖及其制备方法
CN106365578A (zh) 利用磷石膏制备建筑材料的方法
CN102875066B (zh) 一种铬渣加气砖及其制备方法
CN103755322B (zh) 低硅铁尾矿膨胀陶粒及其制备方法
CN103420666A (zh) 一种矿石尾砂陶粒空心砖及其制备方法
CN101628797A (zh) 无机保温隔热承重混凝土
CN102531668B (zh) 一种磷石膏电石渣体系加气混凝土及其制备方法
CN104944862B (zh) 一种利用建筑固废物生产的节能墙材及其制作方法
CN107200544A (zh) 一种节能环保建筑材料及其制备方法
CN106316326A (zh) 利用脱硫石膏制备建筑材料的方法
CN102795831A (zh) 深基坑土烧结多孔砖及其生产方法
CN103922791B (zh) 一种超轻质玻化泡沫陶瓷及其制备方法
CN104817303A (zh) 一种新型水泥基植物秸秆纤维微粒墙体材料的制备方法
CN106278038A (zh) 一种全轻自保温混凝土及制备方法
CN107188589A (zh) 一种高强轻质隔热耐火砖及其制备方法
CN107162533A (zh) 一种建筑用防渗抗压轻质生态砖及其制备方法
CN107140915A (zh) 一种轻质耐热尾砂空心砖及其制备
CN107151133A (zh) 一种仿古建筑中的青砖及其制备方法
CN109180107B (zh) 纤维水泥制品及其制备方法和应用
CN109020378A (zh) 一种以铁尾矿为原料制备的膨胀珍珠岩气凝胶复合保温板及其制备方法
CN107188483A (zh) 一种玄武岩矿石尾料蒸压加气混凝土砌块及其制备方法
CN101172799A (zh) 一种天然活性的火山灰质混凝土掺合料及应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20181113

Address after: 242300 No. 102 outer ring road, Ningguo, Xuancheng, Anhui.

Applicant after: Anhui city clean environment Technology Co., Ltd.

Address before: 242300 Anhui Ningguo Xuancheng port eco industrial park passes two way.

Applicant before: Anhui Huapu environmental remediation Mstar Technology Ltd

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531