CN106726753A

CN106726753A - One kind hair film and preparation method thereof

Info

Publication number: CN106726753A
Application number: CN201611179966.1A
Authority: CN
Inventors: 胡波; 钟勇财; 谢玉国
Original assignee: JIANGXI YIXINTANG MEDICAL TECHNOLOGY Co Ltd
Current assignee: JIANGXI YIXINTANG MEDICAL TECHNOLOGY Co Ltd
Priority date: 2016-12-19
Filing date: 2016-12-19
Publication date: 2017-05-31

Abstract

The invention belongs to daily chemical product field, and in particular to one kind hair film and preparation method thereof.The hair film that the present invention is provided includes following components and its percentage by weight：Glycine betaine 1 5%, behenyl base trimethyl ammonium chloride 10 20%, dimethyl silicone polymer 1 5%, menthol 1 3%, NMF 10 15%, care agent 15 25%, climbazole 1 5%, patchouli alcohol 1 3%, EDTA disodiums 0.1 0.5%, citric acid 0.1 0.5%, methyl hydroxybenzoate 0.1 0.5%, essence 0.1 0.5%, spermaceti ethylhydroxyethylcellulose 1 5% and water 12 58.6%.The hair film that the present invention is provided can not only repair damaged hair, enhancing hair toughness, additionally it is possible to moisten scalp and hair-care, relieving itching and removing dandruff.The hair film that the present invention is provided simultaneously is clearly comfortable, gentle to skin, non-stimulated.

Description

One kind hair film and preparation method thereof

Technical field

The invention belongs to daily chemical product field, and in particular to one kind hair film and preparation method thereof.

Background technology

Hair film can be entered as a kind of hair sealing compound, its nutriment for containing and moisture by the hair scale piece on hair In hair, repairing fiber tissue is helped, fundamentally change hair quality, be particularly suitable for withered and damaged hair.On existing market Hair film product it is numerous, but there is a problem of send out film in absorption of nutrient ingredients effect it is unsatisfactory, fail to be absorbed by hair Nutriment be deposited on hair for a long time, the burden of hair is increased on the contrary, cause hair quality to be damaged, and other can be produced to ask Topic.

Chinese patent application CN105232365A discloses a kind of hair treatment film and preparation method thereof, and its component is thickening Agent, emulsifying agent, hair conditioner, preservative, essence, citric acid and colouring agent CI42090, balance deionized water is solvent, together When additionally provide preparation method.The hair treatment film that the invention is provided has shield volume and moistening effect is good, hair is become submissive, rich Glossiness advantage, but the invention is not obvious to the repairing effect of damaged hair.

Chinese patent application CN104116665A discloses a kind of deep layer and moistens reparation hair film, the parts by weight of its each component For：Double -50 parts of aminopropyl dimethyl silicone polymer, 30-35 parts of behenyl base trimethyl ammonium chloride, glycerol stearate monoglyceride 10- 12 parts, cetanol 1-5 parts, glycerine 2-5 parts, propane diols 8-10 parts, dodecyldimethylammonium hydroxide inner salt 2-6 parts, fish pelargonium extraction Liquid 15-35 parts, 15-35 parts, preservative 0.2-0.5 parts, NMF 3-11 parts and deionized water 25-35 parts of cactus extract. The scalp for being removed grease is effectively repaired in the invention, and scalp deep layer is nourished, and protects scalp, recovers the internal system of scalp, The purpose of removal dandruff is fundamentally reached, but the invention is not obvious to the repairing effect of damaged hair.

The content of the invention

In order to solve problems of the prior art, it is an object of the invention to provide one kind hair film and its preparation side Method.The hair film that the present invention is provided can not only repair damaged hair, enhancing hair toughness, additionally it is possible to moisten scalp and hair-care, antipruritic It is anti-dandruff.The hair film that the present invention is provided simultaneously is clearly comfortable, gentle to skin, non-stimulated.

A kind of hair film of the present invention, including following components and its percentage by weight：

Glycine betaine 1-5%, behenyl base trimethyl ammonium chloride 10-20%, dimethyl silicone polymer 1-5%, menthol 1- 3%th, NMF 10-15%, care agent 15-25%, climbazole 1-5%, patchouli alcohol 1-3%, EDTA- disodium 0.1-0.5%, Citric acid 0.1-0.5%, methyl hydroxybenzoate 0.1-0.5%, essence 0.1-0.5%, spermaceti ethylhydroxyethylcellulose 1-5% and water 12-58.6%.APG is purchased from Guangzhou Jian Chuan bio tech ltd, dimethyl silicone polymer CAS NO：9006-65- 9, spermaceti ethylhydroxyethylcellulose is purchased from Guangzhou Shi Sheng Chemical Co., Ltd.s.

The reasonable science of compatibility of the present invention, each component interphase interaction, cooperateed with reparation damaged hair, enhancing hair toughness, Moisten effect of scalp and hair-care and relieving itching and removing dandruff.

Further, described hair film is made up of following components and its percentage by weight：

Glycine betaine 3%, behenyl base trimethyl ammonium chloride 15%, dimethyl silicone polymer 3%, menthol 2%, NMF 12%th, care agent 20%, climbazole 3%, patchouli alcohol 2%, EDTA- disodiums 0.3%, citric acid 0.3%, methyl hydroxybenzoate 0.3%th, essence 0.3%, spermaceti ethylhydroxyethylcellulose 3% and water 35.8%.Further, the NMF is by hyaluronic acid Sodium, cetostearyl alcohol and glycerine are by weight 3:1:1 composition.

Further, the care agent is by hydrolyzed wheat protein, lecithin and lanolin by weight 2:2:1 composition.

Meanwhile, present invention also offers a kind of preparation method for sending out film, comprise the following steps：

S1 is added water in container, is heated to 70~80 DEG C, and glycine betaine, behenyl base trimethyl ammonia chloride are added while stirring Ammonium and dimethyl silicone polymer, stir to being completely dissolved, and obtain solution A；

Step S1 resulting solutions A is cooled to 65~75 DEG C by S2, and EDTA- disodiums and methyl hydroxybenzoate are added while stirring, is stirred Mix uniform, obtain solution B；

Step S2 resulting solutions B is cooled to 50~60 DEG C by S3, and menthol, NMF, care agent, sweet is added while stirring Precious element and patchouli alcohol, stir to being completely dissolved, and obtain solution C；

Step S3 resulting solutions C is cooled to 30~40 DEG C by S4, adds essence, while with lemon acid for adjusting pH value to 5.5- 6.5, it is eventually adding coconut oleoyl amine MEA and adjusts viscosity to 4000-5000, stir, obtain final product.

Further, pH is 6.0 in the step S4, and viscosity is 4500.

The hair film that the present invention is provided, by the order and its temperature that control raw material to add, makes its each component preferably mutual Effect, maximum its synergy of performance so that damaged hair is being repaired in the invention for preparing, and strengthens hair toughness, is moistened Scalp and hair-care and relieving itching and removing dandruff aspect effect are obvious, while beneficial to the absorption of hair.

Compared with prior art, the hair film that the present invention is provided has the advantage that：

1) the hair film that the present invention is provided, can repair damaged hair, strengthen hair toughness, moisten scalp and hair-care；

2) the hair film that the present invention is provided, can be salubrious comfortable with relieving itching and removing dandruff；

3) the hair film that the present invention is provided, non-stimulated to skin safe, it is easy to absorb.

Specific embodiment

Below by specific embodiment, the present invention is described in further detail, and following examples are only limitted to the mesh of illustration , it is not intended to limit protection scope of the present invention.

A kind of hair film of embodiment 1

Described hair film is made up of following components and its percentage by weight：

Glycine betaine 1%, behenyl base trimethyl ammonium chloride 10%, dimethyl silicone polymer 1%, menthol 1%, hyaluronic acid Sodium 6%, cetostearyl alcohol 2%, glycerine 2%, hydrolyzed wheat protein 6%, lecithin 6%, lanolin 3%, climbazole 1%, hundred Autumn Lee's alcohol 1%, EDTA- disodiums 0.1%, citric acid 0.1%, methyl hydroxybenzoate 0.1%, essence 0.1%, cetyl hydroxy ethyl fiber Element 1% and water 58.6%.

Preparation method：

S1 is added water in container, is heated to 75 DEG C, while stirring add glycine betaine, behenyl base trimethyl ammonium chloride and Dimethyl silicone polymer, stirs to being completely dissolved, and obtains solution A；

Step S1 resulting solutions A is cooled to 70 DEG C by S2, and EDTA- disodiums and methyl hydroxybenzoate are added while stirring, and stirring is equal It is even, obtain solution B；

Step S2 resulting solutions B is cooled to 55 DEG C by S3, and menthol, Sodium Hyaluronate, cetearyl alcohol are added while stirring Alcohol, glycerine, hydrolyzed wheat protein, lecithin, lanolin, climbazole and patchouli alcohol, stir to being completely dissolved, and obtain solution C；

Step S3 resulting solutions C is cooled to 35 DEG C by S4, adds essence, while be 6.0 with lemon acid for adjusting pH value, finally It is 4500 to add coconut oleoyl amine MEA regulation viscosity, is stirred, and is obtained final product.

A kind of hair film of embodiment 2

Glycine betaine 3%, behenyl base trimethyl ammonium chloride 15%, dimethyl silicone polymer 3%, menthol 2%, hyaluronic acid Sodium 7.2%, cetostearyl alcohol 2.4%, glycerine 2.4%, hydrolyzed wheat protein 8%, lecithin 8%, lanolin 4%, climbazole 3%th, patchouli alcohol 2%, EDTA- disodiums 0.3%, citric acid 0.3%, methyl hydroxybenzoate 0.3%, essence 0.3%, cetyl hydroxyl second Base cellulose 3% and water 35.3%.

Preparation method is similar to Example 1.

A kind of hair film of embodiment 3

Glycine betaine 5%, behenyl base trimethyl ammonium chloride 20%, dimethyl silicone polymer 5%, menthol 3%, hyaluronic acid Sodium 9%, cetostearyl alcohol 3%, glycerine 3%, hydrolyzed wheat protein 10%, lecithin 10%, lanolin 5%, climbazole 5%, Patchouli alcohol 3%, EDTA- disodiums 0.5%, citric acid 0.5%, methyl hydroxybenzoate 0.5%, essence 0.5%, cetyl ethoxy are fine Dimension element 5% and water 12%.

Preparation method is similar to Example 1.

A kind of hair film of comparative example 1

Glycine betaine 3%, behenyl base trimethyl ammonium chloride 15%, dimethyl silicone polymer 3%, menthol 2%, hyaluronic acid Sodium 4%, cetostearyl alcohol 4%, glycerine 4%, hydrolyzed wheat protein 8%, lecithin 8%, lanolin 4%, climbazole 3%, hundred Autumn Lee's alcohol 2%, EDTA- disodiums 0.3%, citric acid 0.3%, methyl hydroxybenzoate 0.3%, essence 0.3%, cetyl hydroxy ethyl fiber Element 3% and water 35.3%.

Preparation method is similar to Example 1.

Difference with embodiment 2 is that the weight of Sodium Hyaluronate, cetostearyl alcohol and glycerine is compared into 3:1:1 replaces with 1:1:1。

A kind of hair film of comparative example 2

Glycine betaine 3%, behenyl base trimethyl ammonium chloride 15%, dimethyl silicone polymer 3%, menthol 2%, hyaluronic acid Sodium 7.2%, cetostearyl alcohol 2.4%, glycerine 2.4%, hydrolyzed wheat protein 6.66%, lecithin 6.66%, lanolin 6.68%th, climbazole 3%, patchouli alcohol 2%, EDTA- disodiums 0.3%, citric acid 0.3%, methyl hydroxybenzoate 0.3%, essence 0.3%th, spermaceti ethylhydroxyethylcellulose 3% and water 35.3%.

Preparation method is similar to Example 1.

Difference with embodiment 2 is that the weight of hydrolyzed wheat protein, lecithin and lanolin is compared into 2:2:1 replaces with 1:1:1。

Test example one, irritation test/toxicology test

1. test material：Hair film prepared by embodiment 1-3.

2. subjects：Choose healthy rabbit 60, body weight 180-220g, male and female half and half.

3. content of the test：

Rabbit is randomly divided into 3 groups, every group 20, embodiment 1-3 groups is denoted as.24h before experiment, cuts off experiment white rabbit back The hair of backbone both sides, it is respectively 3cm × 3cm not damage epidermis, unhairing scope or so.Each 0.5g of hair film prepared by Example 1-3 It is added on 4 layers of gauze of 2.5cm × 2.5cm, is affixed on side skin, after being covered with one layer of oilpaper, with immobilization with adhesive tape, opposite side is Blank.Remove gauze after closing 4h, and cleaned with clear water, this is after 1,24,48h observation recipient site local skins it is anti- Should, press《Cosmetics health specification》(version in 2007) skin irritation/corrosion test carries out dermoreaction scoring, with tested dynamic The average value of thing integration carries out overall merit, and observes other side effects effect in addition to excitant.

4. result of the test：

Each observing time point top average ＜ 0.5 in experiment, belongs to nonirritant.That is, skin irritation test result For：It is nonirritant.Acute ocular irritation test result is：It is nonirritant.Therefore the hair film of present invention offer is gentleer to skin, nothing Poison is non-stimulated.

Test example two, sensory evaluation is tested

1. test material：Hair film prepared by embodiment 1-3 and comparative example 1-2.

2. subjects：The people of crowd 100 on probation, at 20-40 Sui, women, hair generally occurs in that hair is done for age distribution Phenomenon that is withered, following the string with flexibility, may not influence the other diseases of this result of the test.

3. content of the test：

Crowd on probation is divided into 5 groups, every group of 20 people, i.e. embodiment 1-3 groups and comparative example 1-2 groups, respectively to embodiment 1-3 And comparative example 1-2 prepare the sensory evaluation of hair film test, each sampling January, tester according to oneself feel commented Point.Standards of grading：Ten point system is taken, 1 point worst, 10 points best, and fraction more high effect is better.

4. result of the test：Various hair film using effect evaluation results are as shown in table 1.

Table 1 sends out film sensory evaluation effect

As shown in Table 1, preferably, i.e., the hair film that prepared by the present invention can not only be repaiied for the sensory evaluation of the hair film that prepared by the present invention Multiple damaged hair, enhancing hair toughness, additionally it is possible to moisten scalp and hair-care, relieving itching and removing dandruff.And the sense of hair film prepared by comparative example 1-2 Official evaluate it is relatively of the invention poor, illustrate compatibility of the present invention rationally, science, each component mutually cooperateed with repairs damaged hair, increasing Strong hair toughness, moistens scalp and hair-care, the effect of relieving itching and removing dandruff.Meanwhile, the hair film that the present invention is provided substantially feels clear using rear It is refreshing, comfortable, without greasy feeling.

Claims

1. it is a kind of to send out film, it is characterised in that including following components and its percentage by weight：

Glycine betaine 1-5%, behenyl base trimethyl ammonium chloride 10-20%, dimethyl silicone polymer 1-5%, menthol 1-3%, guarantor Humectant 10-15%, care agent 15-25%, climbazole 1-5%, patchouli alcohol 1-3%, EDTA- disodium 0.1-0.5%, citric acid 0.1-0.5%, methyl hydroxybenzoate 0.1-0.5%, essence 0.1-0.5%, spermaceti ethylhydroxyethylcellulose 1-5% and water 12- 58.6%.

2. it is as claimed in claim 1 to send out film, it is characterised in that to be made up of following components and its percentage by weight：Glycine betaine 3%th, behenyl base trimethyl ammonium chloride 15%, dimethyl silicone polymer 3%, menthol 2%, NMF 12%, care agent 20%, Climbazole 3%, patchouli alcohol 2%, EDTA- disodiums 0.3%, citric acid 0.3%, methyl hydroxybenzoate 0.3%, essence 0.3%, spermaceti Ethylhydroxyethylcellulose 3% and water 35.8%.

3. hair film as claimed in claim 1 or 2, it is characterised in that the NMF by Sodium Hyaluronate, cetostearyl alcohol and Glycerine is by weight 3:1:1 composition.

4. it is as claimed in claim 1 or 2 to send out film, it is characterised in that the care agent is by hydrolyzed wheat protein, lecithin and sheep Hair fat is by weight 2:2:1 composition.

5. as described in claim 1-4 is any hair film preparation method, it is characterised in that comprise the following steps：

S1 is added water in container, is heated to 70~80 DEG C, while stirring add glycine betaine, behenyl base trimethyl ammonium chloride and Dimethyl silicone polymer, stirs to being completely dissolved, and obtains solution A；

Step S1 resulting solutions A is cooled to 65~75 DEG C by S2, and EDTA- disodiums and methyl hydroxybenzoate are added while stirring, and stirring is equal It is even, obtain solution B；

Step S2 resulting solutions B is cooled to 50~60 DEG C by S3, and menthol, NMF, care agent, climbazole are added while stirring And patchouli alcohol, stir to being completely dissolved, obtain solution C；

Step S3 resulting solutions C is cooled to 30~40 DEG C by S4, adds essence, while with lemon acid for adjusting pH value to 5.5-6.5, It is eventually adding coconut oleoyl amine MEA and adjusts viscosity to 4000-5000, stir, obtains final product.

6. the preparation method of film is sent out as claimed in claim 5, it is characterised in that pH is 6.0 in the step S4, viscosity is 4500。