CN106703311A - Heat-resisting waterproof wallpaper and production method thereof - Google Patents
Heat-resisting waterproof wallpaper and production method thereof Download PDFInfo
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- CN106703311A CN106703311A CN201611199953.0A CN201611199953A CN106703311A CN 106703311 A CN106703311 A CN 106703311A CN 201611199953 A CN201611199953 A CN 201611199953A CN 106703311 A CN106703311 A CN 106703311A
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/07—Cellulose esters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
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- Paper (AREA)
Abstract
The invention discloses a heat-resisting waterproof wallpaper. The heat-resisting waterproof wallpaper comprises a base material layer, a waterproof layer and a heat-resisting layer, wherein the heat-resisting layer is made of waterborne silicon-acrylate resin, hydroxyl-polyacrylate emulsion, cellulose acetate butyrate solution, amino resin, iron oxide red, iron oxide yellow, pearl powder, lauryl mercaptan, dimethylethanolamine, thiethylamine, triethanolamine, 2-amino-2-methylpropanol, ammonium hydroxide, acrylic glycidyl ether, ethylene glycol monobutyl ether, waterborne aluminum powder, charcoal powder, talcum powder, sodium bicarbonate, glass fiber, vermiculite powder, perlite powder, EVA (ethylene-vinyl acetate copolymer) wax, polyethylene wax, nano titanium dioxide, waterborne polyisocyanate curing agent, wetting agent, magnesium stearate, polyoxypropylene glycerol ether, carboxymethyl cellulose and anti-setting agent. The invention also discloses a preparation method of the heat-resisting waterproof wallpaper. The prepared heat-resisting waterproof wallpaper is excellent in heat-resisting and waterproof performance.
Description
Technical field
The present invention relates to wallpaper field, more particularly to a kind of heat-resisting waterproof wallpaper and preparation method thereof.
Background technology
Wallpaper is a kind of quite extensive house decorative material of application.Because wallpaper has, color is various, pattern is abundant, person of outstanding talent
The characteristics of various other house decorative materials institutes such as magnificent style, safety and environmental protection, easy construction, affordable are incomparable, therefore
The developed countries and regions such as America and Europe, Southeast Asia, Japan obtain considerable degree of popularization.Generally produce former with bleached wood pulp
Paper, then through the working process of different operations, such as modeling is covered on coating, printing, embossing or surface, is dispatched from the factory after last cut, packaging.Cause
It is, with certain intensity, appearance attractive in appearance and good water repelling property, to be widely used in the room in house, office, hotel, hotel
Interior decoration etc..
Heat-resisting poor waterproof properties of wallpaper in the prior art, it is impossible to demand when meeting actually used, therefore need design badly
A kind of heat-resisting waterproof wallpaper solves the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of heat-resisting waterproof wallpaper and its preparation side
Method, the wallpaper for preparing has excellent heat-resisting water resistance.
A kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer, waterproof layer and refractory layer, the periphery of substrate layer apply
Waterproof layer is covered with, the waterproof layer is coated with refractory layer away from the periphery of substrate layer, wherein：
Substrate layer is any one in wood pulp paper, non-woven paper, cloth；
The raw material of waterproof layer includes by weight：Aqueous saturated polyester resin 25-35 parts, HMMM
Resin 3-15 parts, aqueous 3-6 parts of pure third resin, Amino resin 1-5 parts, modifying epoxy resin by organosilicon 2-5 parts, it is organic
1-4 parts of Si modification alkyd resin, aluminium powder 2-5 parts, alumina silicate 1-3 parts, kaolin 2-5 parts, flake asbestos 4-6 parts, modified additive 3-6
Part, 1-3 parts of silane coupler KH-560, calcium stearate 2-5 parts, dimethyl silicone polymer 1-3 parts, PSI
4-6 parts, acetylbutyrylcellulose 1-3 parts, Tissuemat E 2-5 parts, dimethylethanolamine 2-5 parts, diethylene glycol monobutyl ether 1-3
Part, deionized water 4-8 parts；
The raw material of refractory layer includes by weight：Waterborne silicone-acrylate resin 45-55 parts, hydroxyl polyacrylate dispersion 10-
20 parts, 3-9 parts of acetylbutyrylcellulose solution, amino resins 1-4 parts, iron oxide red 2-5 parts, iron oxide yellow 3-6 parts, pearl essence
4-6 parts, lauryl mercaptan 2-5 parts, dimethylethanolamine 3-9 parts, triethylamine 1-4 parts, triethanolamine 2-6 parts, 2- amino -2-
Methylpropanol 3-8 parts, ammoniacal liquor 2-5 parts, 1-4 parts of glycidyl ether, ethylene glycol monobutyl ether 2-5 parts, aqueous aluminum powder 3-6
Part, 1-4 parts of charcoal powder, talcum powder 2-5 parts, sodium acid carbonate 3-9 parts, glass fibre 1-4 parts, vermiculite power 2-5 parts, crushed crude pearlite
4-8 parts, 2-6 parts of EVA waxes, Tissuemat E 4-8 parts, nano titanium oxide 2-5 parts, aqueous polyisocyanate curing agent 1-4 parts, profit
Humectant 2-5 parts, magnesium stearate 3-6 parts, polypropylene glycerol aether 1-4 parts, carboxymethylcellulose calcium 2-5 parts, anti-settling agent 3-6 parts.
Preferably, in the raw material of waterproof layer, modified additive is prepared by following technique：Vitrified powder is put into calcining furnace
2-5h is calcined at 820-920 DEG C, is cooled down, be put into mass percent to soak 1-3h in the hydrochloric acid solution of 4-6%, filtered to take
Go out, drying is cleaned with clear water, crushing obtains material a, then by material a, carbamate, isopropyl acrylate, white carbon, three
Antimony oxide, toughener, wood fibre and waterproofing agent are well mixed, and grinding distribution is uniform, obtains final product modified additive.
Preferably, it is carbamate, isopropyl acrylate, white in the preparation technology of modified additive in the raw material of waterproof layer
The weight ratio of carbon black, antimony trioxide, toughener, wood fibre, Vitrified powder and waterproofing agent can be 5-15：2-8：12-24：1-3：
2-5：3-9：1-6：1-5.
Preferably, the raw material of waterproof layer includes by weight：Aqueous saturated polyester resin 28-32 parts, hexamethoxy methyl
Melmac 4-14 parts, aqueous 4-5 parts of pure third resin, Amino resin 2-4 parts, modifying epoxy resin by organosilicon 3-
4 parts, silicone alkyd 2-3 parts, aluminium powder 3-4 parts, alumina silicate 1.5-2.5 parts, kaolin 3-4 parts, flake asbestos 4.5-
5.5 parts, modified additive 4-5 parts, 1.5-2.5 parts of silane coupler KH-560, calcium stearate 3-4 parts, dimethyl silicone polymer
1.5-2.5 parts, PSI 4.5-5.5 parts, acetylbutyrylcellulose 1.5-2.5 parts, Tissuemat E 3-4 parts, two
Methylethanolamine 3-4 parts, diethylene glycol monobutyl ether 1.5-2.5 parts, deionized water 5-7 parts.
Preferably, the raw material of waterproof layer includes by weight：30 parts of aqueous saturated polyester resin, hexamethoxy methyl trimerization
It is 9 parts of melamine resin, aqueous 4.5 parts of pure third resin, 3 parts of Amino resin, 3.5 parts of modifying epoxy resin by organosilicon, organic
2.5 parts of Si modification alkyd resin, 3.5 parts of aluminium powder, 2 parts of alumina silicate, 3.5 parts of kaolin, 5 parts of flake asbestos, 4.5 parts of modified additive,
2 parts of silane coupler KH-560,3.5 parts of calcium stearate, 2 parts of dimethyl silicone polymer, 5 parts of PSI, acetic acid
2 parts of cellulose butyrate, 3.5 parts of Tissuemat E, 3.5 parts of dimethylethanolamine, 2 parts of diethylene glycol monobutyl ether, 6 parts of deionized water.
Preferably, the raw material of refractory layer includes by weight：Waterborne silicone-acrylate resin 48-52 parts, hydroxyl polyacrylate
Emulsion 12-18 parts, 4-8 parts of acetylbutyrylcellulose solution, amino resins 2-3 parts, iron oxide red 3-4 parts, iron oxide yellow 4-5
Part, pearl essence 4.5-5.5 parts, lauryl mercaptan 3-4 parts, dimethylethanolamine 4-8 parts, triethylamine 2-3 parts, triethanolamine 3-
5 parts, 4-7 parts of 2- amino-2-methyl propyl alcohol, ammoniacal liquor 3-4 parts, 2-3 parts of glycidyl ether, ethylene glycol monobutyl ether 3-4 parts,
Aqueous aluminum powder 4-5 parts, 2-3 parts of charcoal powder, talcum powder 3-4 parts, sodium acid carbonate 4-8 parts, glass fibre 2-3 parts, vermiculite power 3-4
Part, crushed crude pearlite 5-7 part, 3-5 parts of EVA waxes, Tissuemat E 5-7 parts, nano titanium oxide 3-4 parts, aqueous PIC it is solid
Agent 2-3 parts, wetting agent 3-4 parts, magnesium stearate 4-5 parts, polypropylene glycerol aether 2-3 parts, carboxymethylcellulose calcium 3-4 parts, it is anti-
Heavy 4-5 parts of agent.
Preferably, the raw material of refractory layer includes by weight：50 parts of waterborne silicone-acrylate resin, hydroxyl polyacrylate dispersion
15 parts, 6 parts of acetylbutyrylcellulose solution, 2.5 parts of amino resins, 3.5 parts of iron oxide red, 4.5 parts of iron oxide yellow, pearl essence 5
Part, 3.5 parts of lauryl mercaptan, 6 parts of dimethylethanolamine, 2.5 parts of triethylamine, 4 parts of triethanolamine, 2- amino-2-methyls third
5.5 parts of alcohol, 3.5 parts of ammoniacal liquor, 2.5 parts of glycidyl ether, 3.5 parts of ethylene glycol monobutyl ether, 4.5 parts of aqueous aluminum powder, charcoal
2.5 parts of powder, 3.5 parts of talcum powder, 6 parts of sodium acid carbonate, 2.5 parts of glass fibre, 3.5 parts of vermiculite power, 6 parts of crushed crude pearlite, EVA waxes
4 parts, it is 6 parts of Tissuemat E, 3.5 parts of nano titanium oxide, 2.5 parts of aqueous polyisocyanate curing agent, 3.5 parts of wetting agent, stearic
4.5 parts of sour magnesium, 2.5 parts of polypropylene glycerol aether, 3.5 parts of carboxymethylcellulose calcium, 4.5 parts of anti-settling agent.
A kind of preparation method of heat-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer,
It is placed in after being completed for printing in baking oven and is dried, is cooled to room temperature and obtains heat-resisting waterproof wallpaper.
Preferably, in S3, cylinder overprinting process parameter is specially：Print speed printing speed is 5-15m/min；Oven temperature is first to use
100-120 DEG C of drying, then form adhesion effect with 160-180 DEG C of film forming；It is formed with hexagonal loop on cylinder, hexagonal loop is opened
Porosity is 30-45%；The thickness of net of finished product cylinder is 0.1-0.3mm.
Preferably, in S3, dry temperature is 70-90 DEG C, and the dry time is 4-6h.
A kind of heat-resisting waterproof wallpaper of the invention, including substrate layer, waterproof layer and refractory layer, the periphery of substrate layer is coated with
Waterproof layer, the waterproof layer is coated with refractory layer away from the periphery of substrate layer, wherein：The raw material of waterproof layer is poly- including aqueous saturation
Ester resin, HMMM resin, aqueous pure third resin, Amino resin, silicon-modified epoxy tree
It is fat, silicone alkyd, aluminium powder, alumina silicate, kaolin, flake asbestos, modified additive, silane coupler KH-560, hard
Resin acid calcium, dimethyl silicone polymer, PSI, acetylbutyrylcellulose, Tissuemat E, dimethylethanolamine,
Diethylene glycol monobutyl ether and deionized water；With aqueous saturated polyester resin, HMMM resin, aqueous pure third
Resin, Amino resin, modifying epoxy resin by organosilicon and silicone alkyd are base-material, with aluminium powder, silicic acid
Aluminium, kaolin, flake asbestos and modified additive be filler, with silane coupler KH-560, calcium stearate, dimethyl silicone polymer,
PSI, acetylbutyrylcellulose, Tissuemat E, dimethylethanolamine, diethylene glycol monobutyl ether and deionization
Water is auxiliary agent, and by the cooperation of base-material, filler and auxiliary agent, rationally control is matched, and the waterproof layer for obtaining has excellent water proofing property
Energy.Wherein modified additive is calcined by the way that Vitrified powder is put into calcining furnace, and cooling is put into immersion in hydrochloric acid solution, and filtering is taken out,
Drying is cleaned with clear water, crushing obtains material a, then by material a, carbamate, isopropyl acrylate, white carbon, three oxygen
Change antimony, toughener, wood fibre and waterproofing agent well mixed, grinding distribution is uniform, obtains final product modified additive, applies to waterproof layer
In, effectively increase the water resistance of waterproof layer.The raw material of refractory layer includes waterborne silicone-acrylate resin, hydroxyl polyacrylate breast
Liquid, acetylbutyrylcellulose solution, amino resins, iron oxide red, iron oxide yellow, pearl essence, lauryl mercaptan, dimethyl second
Hydramine, triethylamine, triethanolamine, 2- amino-2-methyls propyl alcohol, ammoniacal liquor, glycidyl ether, ethylene glycol monobutyl ether, water
Property aluminium powder, charcoal powder, talcum powder, sodium acid carbonate, glass fibre, vermiculite power, crushed crude pearlite, EVA waxes, Tissuemat E, nanometer
Titanium dioxide, aqueous polyisocyanate curing agent, wetting agent, magnesium stearate, polypropylene glycerol aether, carboxymethylcellulose calcium and anti-
Heavy agent；With waterborne silicone-acrylate resin, hydroxyl polyacrylate dispersion, acetylbutyrylcellulose solution and amino resins as base-material,
With iron oxide yellow, pearl essence, lauryl mercaptan, dimethylethanolamine, triethylamine, triethanolamine, 2- amino-2-methyls third
It is alcohol, ammoniacal liquor, glycidyl ether, ethylene glycol monobutyl ether, aqueous polyisocyanate curing agent, wetting agent, magnesium stearate, poly-
Oxypropylene glycerin ether, carboxymethylcellulose calcium and anti-settling agent be auxiliary agent, with aqueous aluminum powder, charcoal powder, talcum powder, sodium acid carbonate,
Glass fibre, vermiculite power, crushed crude pearlite, EVA waxes, Tissuemat E and nano titanium oxide are filler, by base-material, filler and are helped
The cooperation of agent, rationally control is matched, and the refractory layer for obtaining has excellent heat resistance.The present invention is by wood pulp paper, nonwoven
Used as substrate layer, then printed patterns first carry out waterproof layer and heat-resisting to any one in paper, cloth using cylinder overprinting process
The printing of layer, cooling is obtained after drying, and process is simple is easy to operate, and the wallpaper performance for obtaining is strong, with excellent heat-resisting waterproof
Performance.
Brief description of the drawings
Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
Bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair
In bright protection domain.
Embodiment 1
As shown in figure 1, Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and refractory layer 3, base
The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with refractory layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：30 parts of aqueous saturated polyester resin, HMMM tree
It is 9 parts of fat, aqueous 4.5 parts of pure third resin, 3 parts of Amino resin, 3.5 parts of modifying epoxy resin by organosilicon, organic-silicon-modified
2.5 parts of alkyd resin, 3.5 parts of aluminium powder, 2 parts of alumina silicate, 3.5 parts of kaolin, 5 parts of flake asbestos, 4.5 parts of modified additive, silane idol
2 parts of connection agent KH-560,3.5 parts of calcium stearate, 2 parts of dimethyl silicone polymer, 5 parts of PSI, acetate butyrate are fine
2 parts of dimension element, 3.5 parts of Tissuemat E, 3.5 parts of dimethylethanolamine, 2 parts of diethylene glycol monobutyl ether, 6 parts of deionized water；
The raw material of refractory layer 3 includes by weight：50 parts of waterborne silicone-acrylate resin, 15 parts of hydroxyl polyacrylate dispersion,
6 parts of acetylbutyrylcellulose solution, 2.5 parts of amino resins, 3.5 parts of iron oxide red, 4.5 parts of iron oxide yellow, 5 parts of pearl essence, ten
3.5 parts of dialkyl group mercaptan, 6 parts of dimethylethanolamine, 2.5 parts of triethylamine, 4 parts of triethanolamine, 2- amino-2-methyls propyl alcohol 5.5
Part, 3.5 parts of ammoniacal liquor, 2.5 parts of glycidyl ether, 3.5 parts of ethylene glycol monobutyl ether, 4.5 parts of aqueous aluminum powder, charcoal powder
2.5 parts, 3.5 parts of talcum powder, 6 parts of sodium acid carbonate, 2.5 parts of glass fibre, 3.5 parts of vermiculite power, 6 parts of crushed crude pearlite, 4 parts of EVA waxes,
6 parts of Tissuemat E, 3.5 parts of nano titanium oxide, 2.5 parts of aqueous polyisocyanate curing agent, 3.5 parts of wetting agent, magnesium stearate
4.5 parts, 2.5 parts of polypropylene glycerol aether, 3.5 parts of carboxymethylcellulose calcium, 4.5 parts of anti-settling agent.
Embodiment 2
As shown in figure 1, Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and refractory layer 3, base
The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with refractory layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：25 parts of aqueous saturated polyester resin, HMMM tree
15 parts of fat, aqueous 3 parts of pure third resin, 5 parts of Amino resin, 2 parts of modifying epoxy resin by organosilicon, organic-silicon-modified alkyd
4 parts of resin, 2 parts of aluminium powder, 3 parts of alumina silicate, 2 parts of kaolin, 6 parts of flake asbestos, 3 parts of modified additive, silane coupler KH-560 3
Part, 2 parts of calcium stearate, 3 parts of dimethyl silicone polymer, 4 parts of PSI, 3 parts of acetylbutyrylcellulose, polyethylene
2 parts of wax, 5 parts of dimethylethanolamine, 1 part of diethylene glycol monobutyl ether, 8 parts of deionized water；
The raw material of refractory layer 3 includes by weight：45 parts of waterborne silicone-acrylate resin, 20 parts of hydroxyl polyacrylate dispersion,
3 parts of acetylbutyrylcellulose solution, 4 parts of amino resins, 2 parts of iron oxide red, 6 parts of iron oxide yellow, 4 parts of pearl essence, dodecyl
5 parts of mercaptan, 3 parts of dimethylethanolamine, 4 parts of triethylamine, 2 parts of triethanolamine, 8 parts of 2- amino-2-methyls propyl alcohol, 2 parts of ammoniacal liquor, third
4 parts of olefin(e) acid glycidol ether, 2 parts of ethylene glycol monobutyl ether, 6 parts of aqueous aluminum powder, 1 part of charcoal powder, 5 parts of talcum powder, sodium acid carbonate 3
Part, 4 parts of glass fibre, 2 parts of vermiculite power, 8 parts of crushed crude pearlite, 2 parts of EVA waxes, 8 parts of Tissuemat E, 2 parts of nano titanium oxide, water
4 parts of polyisocyanate curing agent of property, 2 parts of wetting agent, 6 parts of magnesium stearate, 1 part of polypropylene glycerol aether, carboxymethylcellulose calcium 5
Part, 3 parts of anti-settling agent.
A kind of preparation method of heat-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer,
It is placed in after being completed for printing in baking oven and is dried, dry temperature is 70 DEG C, and the dry time is 6h, is cooled to room temperature and obtains heat-resisting anti-
Waterwall paper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 5m/min；Oven temperature is first to be dried with 120 DEG C,
Again adhesion effect is formed with 160 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 45%；Finished product is justified
The thickness of net of net is 0.1mm.
Embodiment 3
As shown in figure 1, Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and refractory layer 3, base
The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with refractory layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is cloth；
The raw material of waterproof layer 2 includes by weight：35 parts of aqueous saturated polyester resin, HMMM tree
3 parts of fat, aqueous 6 parts of pure third resin, 1 part of Amino resin, 5 parts of modifying epoxy resin by organosilicon, organic-silicon-modified alkyd
1 part of resin, 5 parts of aluminium powder, 1 part of alumina silicate, 5 parts of kaolin, 4 parts of flake asbestos, 6 parts of modified additive, silane coupler KH-560 1
Part, 5 parts of calcium stearate, 1 part of dimethyl silicone polymer, 6 parts of PSI, 1 part of acetylbutyrylcellulose, polyethylene
5 parts of wax, 2 parts of dimethylethanolamine, 3 parts of diethylene glycol monobutyl ether, 4 parts of deionized water；
The raw material of refractory layer 3 includes by weight：55 parts of waterborne silicone-acrylate resin, 10 parts of hydroxyl polyacrylate dispersion,
9 parts of acetylbutyrylcellulose solution, 1 part of amino resins, 5 parts of iron oxide red, 3 parts of iron oxide yellow, 6 parts of pearl essence, dodecyl
2 parts of mercaptan, 9 parts of dimethylethanolamine, 1 part of triethylamine, 6 parts of triethanolamine, 3 parts of 2- amino-2-methyls propyl alcohol, 5 parts of ammoniacal liquor, third
1 part of olefin(e) acid glycidol ether, 5 parts of ethylene glycol monobutyl ether, 3 parts of aqueous aluminum powder, 4 parts of charcoal powder, 2 parts of talcum powder, sodium acid carbonate 9
Part, 1 part of glass fibre, 5 parts of vermiculite power, 4 parts of crushed crude pearlite, 6 parts of EVA waxes, 4 parts of Tissuemat E, 5 parts of nano titanium oxide, water
1 part of polyisocyanate curing agent of property, 5 parts of wetting agent, 3 parts of magnesium stearate, 4 parts of polypropylene glycerol aether, carboxymethylcellulose calcium 2
Part, 6 parts of anti-settling agent.
In the raw material of waterproof layer 2, modified additive is prepared by following technique：6 parts of Vitrified powders are put into by weight are forged
Burn and 5h is calcined at 820 DEG C in stove, cool down, be put into the hydrochloric acid solution that mass percent is 4% and soak 3h, filtering is taken out, and is used
Clear water cleans drying, and crushing obtains material a, then by material a, 5 parts of carbamates, 8 parts of isopropyl acrylates, 12 parts of hard charcoals
Black, 3 parts of antimony trioxides, 2 parts of toughener, 9 parts of wood fibres and 1 part of waterproofing agent are well mixed, and grinding distribution is uniform, obtains final product modified
Auxiliary agent.
A kind of preparation method of heat-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer,
It is placed in after being completed for printing in baking oven and is dried, dry temperature is 90 DEG C, and the dry time is 4h, is cooled to room temperature and obtains heat-resisting anti-
Waterwall paper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 15m/min；Oven temperature is first to be dried with 100 DEG C,
Again adhesion effect is formed with 180 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30%；Finished product is justified
The thickness of net of net is 0.3mm.
Embodiment 4
As shown in figure 1, Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and refractory layer 3, base
The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with refractory layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：28 parts of aqueous saturated polyester resin, HMMM tree
14 parts of fat, aqueous 4 parts of pure third resin, 4 parts of Amino resin, 3 parts of modifying epoxy resin by organosilicon, organic-silicon-modified alkyd
3 parts of resin, 3 parts of aluminium powder, 2.5 parts of alumina silicate, 3 parts of kaolin, 5.5 parts of flake asbestos, 4 parts of modified additive, silane coupler KH-
560 2.5 parts, 3 parts of calcium stearate, 2.5 parts of dimethyl silicone polymer, 4.5 parts of PSI, acetate butyrate fiber
2.5 parts of element, 3 parts of Tissuemat E, 4 parts of dimethylethanolamine, 1.5 parts of diethylene glycol monobutyl ether, 7 parts of deionized water；
The raw material of refractory layer 3 includes by weight：48 parts of waterborne silicone-acrylate resin, 18 parts of hydroxyl polyacrylate dispersion,
4 parts of acetylbutyrylcellulose solution, 3 parts of amino resins, 3 parts of iron oxide red, 5 parts of iron oxide yellow, 4.5 parts of pearl essence, dodecane
4 parts of base mercaptan, 4 parts of dimethylethanolamine, 3 parts of triethylamine, 3 parts of triethanolamine, 7 parts of 2- amino-2-methyls propyl alcohol, 3 parts of ammoniacal liquor,
3 parts of glycidyl ether, 3 parts of ethylene glycol monobutyl ether, 5 parts of aqueous aluminum powder, 2 parts of charcoal powder, 4 parts of talcum powder, bicarbonate
4 parts of sodium, 3 parts of glass fibre, 3 parts of vermiculite power, 7 parts of crushed crude pearlite, 3 parts of EVA waxes, 7 parts of Tissuemat E, 3 parts of nano titanium oxide,
3 parts of aqueous polyisocyanate curing agent, 3 parts of wetting agent, 5 parts of magnesium stearate, 2 parts of polypropylene glycerol aether, carboxymethylcellulose calcium 4
Part, 4 parts of anti-settling agent.
In the raw material of waterproof layer 2, modified additive is prepared by following technique：2 parts of Vitrified powders are put into by weight are forged
Burn and 3h is calcined at 900 DEG C in stove, cool down, be put into the hydrochloric acid solution that mass percent is 5.5% and soak 1.5h, filter to take
Go out, drying is cleaned with clear water, crushing obtains material a, then by material a, 12 parts of carbamates, 3 parts of isopropyl acrylates, 22
Part white carbon, 1.5 parts of antimony trioxides, 4 parts of toughener, 4 parts of wood fibres and 4 parts of waterproofing agents are well mixed, and grinding distribution is uniform,
Obtain final product modified additive.
A kind of preparation method of heat-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer,
It is placed in after being completed for printing in baking oven and is dried, dry temperature is 75 DEG C, and the dry time is 5.5h, is cooled to room temperature and obtains heat-resisting
Waterproof wallpaper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 8m/min；Oven temperature is for first with 115 DEG C of bakings
It is dry, then form adhesion effect with 165 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 40%；Finished product
The thickness of net of cylinder is 0.15mm.
Embodiment 5
As shown in figure 1, Fig. 1 is a kind of structural representation of heat-resisting waterproof wallpaper proposed by the present invention.
Reference picture 1, a kind of heat-resisting waterproof wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and refractory layer 3, base
The periphery of material layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with refractory layer 3 away from the periphery of substrate layer 1, wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：32 parts of aqueous saturated polyester resin, HMMM tree
4 parts of fat, aqueous 5 parts of pure third resin, 2 parts of Amino resin, 4 parts of modifying epoxy resin by organosilicon, organic-silicon-modified alkyd
2 parts of resin, 4 parts of aluminium powder, 1.5 parts of alumina silicate, 4 parts of kaolin, 4.5 parts of flake asbestos, 5 parts of modified additive, silane coupler KH-
560 1.5 parts, 4 parts of calcium stearate, 1.5 parts of dimethyl silicone polymer, 5.5 parts of PSI, acetate butyrate fiber
1.5 parts of element, 4 parts of Tissuemat E, 3 parts of dimethylethanolamine, 2.5 parts of diethylene glycol monobutyl ether, 5 parts of deionized water；
The raw material of refractory layer 3 includes by weight：52 parts of waterborne silicone-acrylate resin, 12 parts of hydroxyl polyacrylate dispersion,
8 parts of acetylbutyrylcellulose solution, 2 parts of amino resins, 4 parts of iron oxide red, 4 parts of iron oxide yellow, 5.5 parts of pearl essence, dodecane
3 parts of base mercaptan, 8 parts of dimethylethanolamine, 2 parts of triethylamine, 5 parts of triethanolamine, 4 parts of 2- amino-2-methyls propyl alcohol, 4 parts of ammoniacal liquor,
2 parts of glycidyl ether, 4 parts of ethylene glycol monobutyl ether, 4 parts of aqueous aluminum powder, 3 parts of charcoal powder, 3 parts of talcum powder, bicarbonate
8 parts of sodium, 2 parts of glass fibre, 4 parts of vermiculite power, 5 parts of crushed crude pearlite, 5 parts of EVA waxes, 5 parts of Tissuemat E, 4 parts of nano titanium oxide,
2 parts of aqueous polyisocyanate curing agent, 4 parts of wetting agent, 4 parts of magnesium stearate, 3 parts of polypropylene glycerol aether, carboxymethylcellulose calcium 3
Part, 5 parts of anti-settling agent.
In the raw material of waterproof layer 2, modified additive is prepared by following technique：5 parts of Vitrified powders are put into by weight are forged
Burn and 4h is calcined at 840 DEG C in stove, cool down, be put into the hydrochloric acid solution that mass percent is 4.5% and soak 2.5h, filter to take
Go out, drying is cleaned with clear water, crushing obtains material a, then by material a, 8 parts of carbamates, 7 parts of isopropyl acrylates, 14
Part white carbon, 2.5 parts of antimony trioxides, 3 parts of toughener, 8 parts of wood fibres and 2 parts of waterproofing agents are well mixed, and grinding distribution is uniform,
Obtain final product modified additive.
A kind of preparation method of heat-resisting waterproof wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer,
It is placed in after being completed for printing in baking oven and is dried, dry temperature is 85 DEG C, and the dry time is 4.5h, is cooled to room temperature and obtains heat-resisting
Waterproof wallpaper, wherein, cylinder overprinting process parameter is specially：Print speed printing speed is 12m/min；Oven temperature is for first with 105 DEG C of bakings
It is dry, then form adhesion effect with 175 DEG C of film forming；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 35%；Finished product
The thickness of net of cylinder is 0.25mm.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (10)
1. a kind of heat-resisting waterproof wallpaper, including substrate layer (1), waterproof layer (2) and refractory layer (3), the periphery coating of substrate layer (1)
There is waterproof layer (2), the waterproof layer (2) is coated with refractory layer (3) away from the periphery of substrate layer (1), it is characterised in that wherein：
Substrate layer (1) is wood pulp paper, any one in non-woven paper, cloth；
The raw material of waterproof layer (2) includes by weight：Aqueous saturated polyester resin 25-35 parts, HMMM
Resin 3-15 parts, aqueous 3-6 parts of pure third resin, Amino resin 1-5 parts, modifying epoxy resin by organosilicon 2-5 parts, it is organic
1-4 parts of Si modification alkyd resin, aluminium powder 2-5 parts, alumina silicate 1-3 parts, kaolin 2-5 parts, flake asbestos 4-6 parts, modified additive 3-6
Part, 1-3 parts of silane coupler KH-560, calcium stearate 2-5 parts, dimethyl silicone polymer 1-3 parts, PSI
4-6 parts, acetylbutyrylcellulose 1-3 parts, Tissuemat E 2-5 parts, dimethylethanolamine 2-5 parts, diethylene glycol monobutyl ether 1-3
Part, deionized water 4-8 parts；
The raw material of refractory layer (3) includes by weight：Waterborne silicone-acrylate resin 45-55 parts, hydroxyl polyacrylate dispersion 10-20
Part, 3-9 parts of acetylbutyrylcellulose solution, amino resins 1-4 parts, iron oxide red 2-5 parts, iron oxide yellow 3-6 parts, pearl essence 4-
6 parts, lauryl mercaptan 2-5 parts, dimethylethanolamine 3-9 parts, triethylamine 1-4 parts, triethanolamine 2-6 parts, 2- amino -2- first
3-8 parts of base propyl alcohol, ammoniacal liquor 2-5 parts, 1-4 parts of glycidyl ether, ethylene glycol monobutyl ether 2-5 parts, aqueous aluminum powder 3-6 parts,
1-4 parts of charcoal powder, talcum powder 2-5 parts, sodium acid carbonate 3-9 parts, glass fibre 1-4 parts, vermiculite power 2-5 parts, crushed crude pearlite 4-8
Part, 2-6 parts of EVA waxes, Tissuemat E 4-8 parts, nano titanium oxide 2-5 parts, aqueous polyisocyanate curing agent 1-4 parts, wetting
Agent 2-5 parts, magnesium stearate 3-6 parts, polypropylene glycerol aether 1-4 parts, carboxymethylcellulose calcium 2-5 parts, anti-settling agent 3-6 parts.
2. heat-resisting waterproof wallpaper according to claim 1, it is characterised in that in the raw material of waterproof layer (2), modified additive is pressed
Following technique is prepared：Vitrified powder is put into calcining furnace 2-5h is calcined at 820-920 DEG C, cooled down, be put into quality percentage
Number to soak 1-3h in the hydrochloric acid solution of 4-6%, taken out by filtering, and drying is cleaned with clear water, and crushing obtains material a, then by thing
Material a, carbamate, isopropyl acrylate, white carbon, antimony trioxide, toughener, wood fibre and waterproofing agent are well mixed,
Grinding distribution is uniform, obtains final product modified additive.
3. heat-resisting waterproof wallpaper according to claim 1 and 2, it is characterised in that in the raw material of waterproof layer (2), it is modified to help
In the preparation technology of agent, carbamate, isopropyl acrylate, white carbon, antimony trioxide, toughener, wood fibre, Vitrified powder
Can be 5-15 with the weight ratio of waterproofing agent：2-8：12-24：1-3：2-5：3-9：1-6：1-5.
4. the heat-resisting waterproof wallpaper according to claim any one of 1-3, it is characterised in that the raw material of waterproof layer (2) is by weight
Amount part includes：Aqueous saturated polyester resin 28-32 parts, HMMM resin 4-14 parts, aqueous pure third resin
4-5 parts, Amino resin 2-4 parts, modifying epoxy resin by organosilicon 3-4 parts, silicone alkyd 2-3 parts, aluminium
Powder 3-4 parts, alumina silicate 1.5-2.5 parts, kaolin 3-4 parts, flake asbestos 4.5-5.5 parts, modified additive 4-5 parts, silane coupler
KH-560 1.5-2.5 parts, calcium stearate 3-4 parts, dimethyl silicone polymer 1.5-2.5 parts, PSI 4.5-
5.5 parts, acetylbutyrylcellulose 1.5-2.5 parts, Tissuemat E 3-4 parts, dimethylethanolamine 3-4 parts, diethylene glycol monobutyl ether
1.5-2.5 parts, deionized water 5-7 parts.
5. the heat-resisting waterproof wallpaper according to claim any one of 1-4, it is characterised in that the raw material of waterproof layer (2) is by weight
Amount part includes：30 parts of aqueous saturated polyester resin, 9 parts of HMMM resin, aqueous 4.5 parts of pure third resin,
3 parts of Amino resin, 3.5 parts of modifying epoxy resin by organosilicon, 2.5 parts of silicone alkyd, 3.5 parts of aluminium powder,
2 parts of alumina silicate, 3.5 parts of kaolin, 5 parts of flake asbestos, 4.5 parts of modified additive, 2 parts of silane coupler KH-560, calcium stearate
3.5 parts, 2 parts of dimethyl silicone polymer, 5 parts of PSI, 2 parts of acetylbutyrylcellulose, 3.5 parts of Tissuemat E,
3.5 parts of dimethylethanolamine, 2 parts of diethylene glycol monobutyl ether, 6 parts of deionized water.
6. the heat-resisting waterproof wallpaper according to claim any one of 1-5, it is characterised in that the raw material of refractory layer (3) is by weight
Amount part includes：Waterborne silicone-acrylate resin 48-52 parts, 12-18 parts of hydroxyl polyacrylate dispersion, acetylbutyrylcellulose solution 4-
8 parts, amino resins 2-3 parts, iron oxide red 3-4 parts, iron oxide yellow 4-5 parts, pearl essence 4.5-5.5 parts, lauryl mercaptan 3-4
Part, dimethylethanolamine 4-8 parts, triethylamine 2-3 parts, triethanolamine 3-5 parts, 4-7 parts of 2- amino-2-methyl propyl alcohol, ammoniacal liquor 3-4
Part, 2-3 parts of glycidyl ether, ethylene glycol monobutyl ether 3-4 parts, aqueous aluminum powder 4-5 parts, 2-3 parts of charcoal powder, talcum powder
3-4 parts, sodium acid carbonate 4-8 parts, glass fibre 2-3 parts, vermiculite power 3-4 parts, crushed crude pearlite 5-7 parts, 3-5 parts of EVA waxes, polyethylene
Wax 5-7 parts, nano titanium oxide 3-4 parts, aqueous polyisocyanate curing agent 2-3 parts, wetting agent 3-4 parts, magnesium stearate 4-5
Part, polypropylene glycerol aether 2-3 parts, carboxymethylcellulose calcium 3-4 parts, anti-settling agent 4-5 parts.
7. the heat-resisting waterproof wallpaper according to claim any one of 1-6, it is characterised in that the raw material of refractory layer (3) is by weight
Amount part includes：50 parts of waterborne silicone-acrylate resin, 15 parts of hydroxyl polyacrylate dispersion, 6 parts of acetylbutyrylcellulose solution, amino
2.5 parts of resin, 3.5 parts of iron oxide red, 4.5 parts of iron oxide yellow, 5 parts of pearl essence, 3.5 parts of lauryl mercaptan, dimethyl ethanol
6 parts of amine, 2.5 parts of triethylamine, 4 parts of triethanolamine, 5.5 parts of 2- amino-2-methyls propyl alcohol, 3.5 parts of ammoniacal liquor, glycidyl
2.5 parts of ether, 3.5 parts of ethylene glycol monobutyl ether, 4.5 parts of aqueous aluminum powder, 2.5 parts of charcoal powder, 3.5 parts of talcum powder, sodium acid carbonate 6
Part, 2.5 parts of glass fibre, 3.5 parts of vermiculite power, 6 parts of crushed crude pearlite, 4 parts of EVA waxes, 6 parts of Tissuemat E, nano titanium oxide 3.5
Part, 2.5 parts of aqueous polyisocyanate curing agent, 3.5 parts of wetting agent, 4.5 parts of magnesium stearate, 2.5 parts of polypropylene glycerol aether, carboxylic
3.5 parts of methylcellulose, 4.5 parts of anti-settling agent.
8. the preparation method of a kind of heat-resisting waterproof wallpaper according to claim any one of 1-7, it is characterised in that including such as
Lower step：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper semi-finished product are obtained；
S2, the front of wallpaper semi-finished product by cylinder overprinting process print waterproof layer；
S3, the feedstock composition of refractory layer is printed on the layer of waterproof layer using cylinder overprinting process, forms refractory layer, printing
After the completion of be placed in baking oven dry, be cooled to room temperature and obtain heat-resisting waterproof wallpaper.
9. the preparation method of heat-resisting waterproof wallpaper according to claim 8, it is characterised in that in S3, cylinder overprinting process
Parameter is specially：Print speed printing speed is 5-15m/min；Oven temperature for first with 100-120 DEG C of drying, then with 160-180 DEG C of film forming
Form adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30-45%；The thickness of net of finished product cylinder
It is 0.1-0.3mm.
10. the preparation method of heat-resisting waterproof wallpaper according to claim 8 or claim 9, it is characterised in that in S3, dry temperature
It is 70-90 DEG C to spend, and the dry time is 4-6h.
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