CN107325654B - A kind of air brushing coating and preparation method thereof adapting to Latex ink - Google Patents
A kind of air brushing coating and preparation method thereof adapting to Latex ink Download PDFInfo
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- CN107325654B CN107325654B CN201710538345.6A CN201710538345A CN107325654B CN 107325654 B CN107325654 B CN 107325654B CN 201710538345 A CN201710538345 A CN 201710538345A CN 107325654 B CN107325654 B CN 107325654B
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- 238000000576 coating method Methods 0.000 title claims abstract description 59
- 239000011248 coating agent Substances 0.000 title claims abstract description 58
- 239000004816 latex Substances 0.000 title claims abstract description 37
- 229920000126 latex Polymers 0.000 title claims abstract description 36
- 230000001680 brushing effect Effects 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 33
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 33
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 22
- 239000004005 microsphere Substances 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 21
- 239000000080 wetting agent Substances 0.000 claims abstract description 21
- 241001417490 Sillaginidae Species 0.000 claims abstract description 8
- 238000005703 Whiting synthesis reaction Methods 0.000 claims abstract description 8
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 34
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 32
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 241000276489 Merlangius merlangus Species 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- -1 poly- ammonia Ester Chemical class 0.000 claims description 6
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000006210 lotion Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 238000003384 imaging method Methods 0.000 abstract description 3
- 239000003973 paint Substances 0.000 abstract description 3
- 230000003678 scratch resistant effect Effects 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 53
- 239000003292 glue Substances 0.000 description 32
- 238000007639 printing Methods 0.000 description 20
- 239000002904 solvent Substances 0.000 description 13
- 239000007787 solid Substances 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000000758 substrate Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000693 micelle Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000009288 screen filtration Methods 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000007790 scraping Methods 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CZFMLDUNXATLOW-XKZIYDEJSA-N (5z)-5-[[3-(2-hydroxyethoxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1COCCO CZFMLDUNXATLOW-XKZIYDEJSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920005692 JONCRYL® Polymers 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention belongs to paint fields, disclose a kind of air brushing coating for adapting to Latex ink, including 20 ~ 25 parts of powdered whitings, 4 ~ 6 parts of silica, 20 ~ 40 parts of styrene-acrylic emulsions, 20 ~ 40 parts of polyaminoester emulsions, 0.3 ~ 0.8 part of polyvinyl alcohol, 8 ~ 12 parts of wear-resistance microspheres, 0.04~0.06 part of wetting agent.The invention also discloses the preparation methods of air brushing coating.Air brushing coating of the invention adapts to a variety of print media, and imaging is persistently, environmentally friendly, and it is good that scratch-resistant scratches performance.
Description
Technical field
The invention belongs to paint field, specifically a kind of air brushing coating and preparation method thereof for adapting to Latex ink.
Background technique
Main ink type on existing market has solvent-based inks, water-based ink, UV ink.Solvent-based inks can be right
Substrate is corroded, and many substrates are suitable for, but due to containing solvent inside its ink, causes adverse effect to environment.It is aqueous
Ink is environmentally friendly, but weather resistance is inadequate, usually makees outer indoor printing use, since inadequate waterproof usually also needs pair
Consumptive material carries out mounting film, increases process and cost.
LATEX ink is a kind of latex type ink, and colorant substrate, resin and latex auxiliary agent based on its paint ink are matched
Side, it has the advantages that solvent-based inks adapt to the diversity and image durability of print media, while having water-based ink again
The characteristics of to the low damage and the feature of environmental protection of equipment is a functional ink for representing the following printing inkjet direction.
Compared with UV ink, the advantage of Latex ink is mainly reflected in several aspects:
One: UV print screen ink droplet sense is obvious, exists simultaneously UV spot generally existing in industry, influences image quality.UV
The reason of spot formation: the ink that UV is printed needs the time of an of short duration levelling, reuses UV lamp irradiation solidification.Cause
It is to be moved with print head, while inkjet printing is all multiple-pass printing for UV lamp, so will appear UV spot.It is printed by improving
Pass number can improve, but cost and efficiency can be sacrificed.Latex ink then not similar problem.
Two: environmental protection: HP Latex uses natural emulsion, and ink is environmentally protective, obtains the states such as green guardian, Northern Europe white swan
The top environmental certification in border can be widely applied in the high industry of the environmental requirements such as fitting-up, wallpaper mural painting.Either beat
During print, or print the finished product completed, all not any peculiar smell.The ink of UV can all have the smell of comparison stimulus,
The picture that printing is completed in time also can persistently volatilize irritating smell.
Three: printing effect
1, HP Latex print head (heat foamable) nozzle quantity is the 2 times or more of UV print head (minute-pressure electricity)；
2, HP Latex print head ratio UV print head is light (inertia is small), can move faster；
3, HP Latex print head is not corrosion-resistant, cannot be used in UV, Weak solvent, in solvent-based inks；
4, HP Latex ink cured needs to heat, and has a heating device and complicated algorithm control, and UV, Weak solvent, molten
Agent ink apparatus does not have such function.
Due to above, it will determine that the print speed of HP Latex can be faster than UV.
Latex ink is suitble to indoor and outdoor to use, environmentally friendly using water as ink solvent, for the adaptability of consumptive material
Extensively, good weatherability, the advantages of combining various inks, the welcome by market.This coating is provided simultaneously with into membrane structure and micropore
Structure can quickly absorb ink, and for printing very dark-toned part, the stereovision that can also do well, image has
Very high vividness, image stabilization and clarity can match high-precision printing since coating material is very fine and smooth.Due to
Coating also has good waterproof performance and scraping and wiping resistance performance, this coating is outdoor indoors to be can be used, and use scope is wide, this painting
Layer can be applied to different media up, such as non-woven paper, printing paper, PP class, PET class, dry goods.
Since releasing Latex resin ink-jet printer from Hewlett-Packard, Latex can replace solvent-based inks and UV solidification
Ink is used for exterior durability advertising and printing.Latex ink printed has been applied on some media, such as art paper, PE
On material, PVC mantle, though its clarity be not it is very high, market segment can receive.And it is situated between for some more demanding printings
Matter, such as stationery, PP, PET film, due to not having coating to receive ink, printing effect is bad, and clarity is not high, and color is not fresh enough
Gorgeous, demand is unable to satisfy.
Currently without the coating of the Latex ink specifically for HP, the patent application No. is 201410126558.4 be
Compatible Latex ink printed on the basis of exploitation Weak solvent coating, due to the composition and ink-jet of Weak solvent ink and Latex ink
Amount is different, and thickness needed for Weak solvent coating does not need so thick coating for Latex printing at 20 microns or more,
It is a kind of waste of cost.
Summary of the invention
The object of the present invention is to provide a kind of air brushing coatings for adapting to Latex ink, this coating can be applied to different
On substrate, it is bright-coloured lasting to be showed by Latex ink printed, rub resistance, the effect of waterproof.
It is a further object of the present invention to provide the preparation methods of the air brushing coating.
One of in order to achieve the above objectives, the invention adopts the following technical scheme:
A kind of air brushing coating adapting to Latex ink, according to parts by weight, including 20 ~ 25 parts of powdered whitings, 4 ~ 6 parts
Silica, 20 ~ 40 parts of styrene-acrylic emulsions, 20 ~ 40 parts of polyaminoester emulsions, 0.3 ~ 0.8 part of polyvinyl alcohol, 8 ~ 12 parts of wear-resistance microspheres,
0.04~0.06 part of wetting agent.
Including 23 parts of powdered whitings, 5 parts of silica, 30 parts of styrene-acrylic emulsions, 30 further, according to parts by weight,
Part polyaminoester emulsion, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting agent.
Further, the powdered whiting requires partial size to account for 95% or more less than 2 microns.
Powdered whiting can play the role of absorbing ink, and powdered whiting has the performance of covering, forms coating
Opacity, while high glaze is kept, such Bulk coat is apparently opaque and maintains higher glossiness.Heavy carbon
Sour calcium must be 95 ranks (partial size accounts for 95% less than 2 microns) or more, and otherwise printing effect is not fine and smooth enough, has and bites phenomenon
Further, the Kong Rong of the silica is greater than 1.8mL/g, and average grain diameter is at 3 microns or less.
Silica is a kind of loose porous substance, has big Kong Rong, and unique gap structure can absorb ink
Moisture in water, indiffusion are come, to make ink quickly in conjunction with coating.
Further, the Tg value of the styrene-acrylic emulsion is -18 DEG C.
Further, the Tg value of the polyaminoester emulsion is 25 DEG C.
Styrene-acrylic emulsion has splendid initial stage water-resistance and excellent adhesive force, coating can be promoted closely to tie with substrate
It closes.
Polyaminoester emulsion has good filming performance, is conducive to the film forming of coating when coating, and stain resistance is strong, resists
Yellow, long-term indoor and outdoor use, and picture is kept not influenced by the moisture of environment, impurity.
Due to the styrene-acrylic emulsion and polyaminoester emulsion relatively low using glass transition temperature, when Latex ink printed, printing
Machine is in warm-up mode, and the temperature of machine makes both lotions that soft state be presented, is conducive to coating in conjunction with ink, makes
Ink and coating adhesion-tight are obtained, is not easily disconnected from out.
Further, the wear-resistance microspheres are 15 ~ 20 microns of partial size, the polythene wax emulsion (polyethylene that fusing point is 140 DEG C
Wax microballoon is dispersed in water)；Polyethylene wax fusing point increases generally at 90 ~ 120 DEG C, as molecular weight increases, and 140 DEG C belong to height
Fusing point.
Wear-resistance microspheres are added, are to make coating waterproof to save cold lamination film, while there is certain scraping and wiping resistance performance, it is resistance to
It is big to grind microspherulite diameter, is conducive to picture and is exposed to outside scratch resistance, scrapes, will not be worn with 300 times pictures of brush brush.
Further, the wetting agent is BYK 333, TEGO wet KL 245, Tao Shi X405 or surfynol 440.
Wetting agent is the overall flow and spreading property in order to reinforce coating.
Polyvinyl alcohol is the viscosity in order to adjust glue, while enhancing the filming performance of coating, and preferred polyvinyl alcohol is
PVA BM-1 can also use other types, 88% or more alcoholysis degree.
A method of preparing above-mentioned air brushing coating, comprising the following steps:
Polyvinyl alcohol and water are mixed under S1, room temperature, 85 DEG C of heat preservation 1h is then heated to, is cooled to 40 DEG C, mistake
Filter stands defoaming, obtains poly-vinyl alcohol solution；
Powdered whiting is added to the water under S2, stirring condition, silica is then added, be subsequently added into styrene-acrylic emulsion and
Polyaminoester emulsion adds the poly-vinyl alcohol solution of S1, is eventually adding wear-resistance microspheres and wetting agent, and filtering stands defoaming.
The invention has the following advantages:
1, the diversity of print media is adapted to.Coating can be applied to different substrates up, as PP, PET, PE, printing paper,
Non-woven paper, dry goods.
2, image durability: Glass Transition Temperature of Latex used in the coating is low, and polymer segment is soft under room temperature, can
Adhere to well with Latex ink；The lotion anti-aging property that coating is used is strong, and the pigment and resin in ink use for a long time
All there is no problem, and imaging frame stabilization is lasting, outer indoors can use.
3, environmentally friendly, air brushing figure layer of the invention does not have the smell of solvent when matching printing with Latex ink, to setting
It is standby not injure, either in print procedure, or print the finished product completed, all not any peculiar smell.
4, scratch-resistant scuffing performance is good, since coating uses the big wear-resistance microspheres of partial size, when scraping generation, and microballoon energy
Enough energy for absorbing impact, coating are not in scratch.
Specific embodiment
The present invention is described further combined with specific embodiments below.
In following embodiment, number refers both to parts by weight；Powdered whiting is raw for Foshan City South Sea close friend's powder Co., Ltd
The MYJ-98 of production；Silica is the SD640 of Beijing Spaceflight Sai De Powder Material Technology Co., Ltd.'s production；Styrene-acrylic emulsion is BASF
The Joncryl 2640 of production；Polyaminoester emulsion is the U57 of ShangHai SiSheng polymer Materials Co., Ltd's production；Polyvinyl alcohol is
The BM-1 of SINOPEC Sichuan Vinylon Factory production；Wear-resistance microspheres be Hai Mingsi speciality chemical company (ELEMENTIS
SPECIALTIES) the slip-ayd SL300 produced；Wetting agent is BYK 333, the wet KL 245 of TEGO company production, makes pottery
The surfynol 440 of the X405 Air products company production of family name company production.
Embodiment 1
A kind of air brushing coating adapting to Latex ink, dry glue ratio are as follows: 23 parts of powdered whitings, 5 parts of silica, 30
Part styrene-acrylic emulsion, 30 parts of polyaminoester emulsions, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting agent.
The solid content of powdered whiting is 72%, and the solid content of silica is 100%, and the solid content of styrene-acrylic emulsion is
48.50%, the solid content of polyaminoester emulsion is 50%, and the solid content of poly-vinyl alcohol solution is 15%, and wear-resistance microspheres solid content is 30%,
The solid content of wetting agent is 100%.
According to the above solid content, dry glue each component is converted into raw material dosage when S2 feeds intake: 30 parts of water, 31.94 parts of weights
Matter calcium carbonate, 5 parts of silica, 61.86 parts of styrene-acrylic emulsions, 60 parts of polyaminoester emulsions, 3.333 parts of polyvinyl alcohol, 33.33 parts it is resistance to
Grind microballoon, 0.05 part of wetting agent.
Air brushing coating glue is prepared according to the following steps:
S1, configuration poly-vinyl alcohol solution: weighing polyethylene alcohol and water, (dosage of water is to obtain the polyvinyl alcohol containing 15% admittedly
Solution is advisable), it first adds water in glue pot under room temperature, slow turn on agitator, mixing speed reaches 200r/min, then slowly
Slowly BM-1 micelle is added in glue pot, be kept stirring and started to warm up, until keeping the temperature 1 hour after being raised to 85 DEG C, led to afterwards cold
But 40 DEG C are water-cooled to, 200 mesh filter screen filtrations are spare after standing defoaming 24 hours；
S2, raw material is weighed in proportion, water is first added in glue pot, open blender, make 700 ~ 800r/ of its revolving speed
Powdered whiting is added in min while stirring, stirs 10min, adds silica, stirs 10min, reduces revolving speed extremely later
Styrene-acrylic emulsion and polyaminoester emulsion is added in 400 ~ 500r/min while stirring, stirs 20min, is slow added into prepared by S1
Poly-vinyl alcohol solution stirs 20min, adds wear-resistance microspheres and wetting agent, stir 30min together, later with 300 mesh filter screens
Filtering, it is spare after standing defoaming 24 hours.
Embodiment 2
A kind of air brushing coating adapting to Latex ink, dry glue ratio are as follows: 20 parts of powdered whitings, 4 parts of silica, 21
Part styrene-acrylic emulsion, 22 parts of polyaminoester emulsions, 0.3 part of polyvinyl alcohol, 8 parts of wear-resistance microspheres, 0.04 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to the following steps:
S1, configuration poly-vinyl alcohol solution: weighing polyethylene alcohol and water, (dosage of water is to obtain the polyvinyl alcohol containing 15% admittedly
Solution is advisable), it first adds water in glue pot under room temperature, slow turn on agitator, mixing speed reaches 200r/min, then slowly
Slowly BM-1 micelle is added in glue pot, be kept stirring and started to warm up, until keeping the temperature 1 hour after being raised to 85 DEG C, led to afterwards cold
But 40 DEG C are water-cooled to, 200 mesh filter screen filtrations are spare after standing defoaming 24 hours；
S2, raw material is weighed in proportion, water is first added in glue pot, open blender, make 700 ~ 800r/ of its revolving speed
Powdered whiting is added in min while stirring, stirs 10min, adds silica, stirs 10min, reduces revolving speed extremely later
Styrene-acrylic emulsion and polyaminoester emulsion is added in 400 ~ 500r/min while stirring, stirs 20min, is slow added into prepared by S1
Poly-vinyl alcohol solution stirs 20min, adds wear-resistance microspheres and wetting agent, stir 30min together, later with 300 mesh filter screens
Filtering, it is spare after standing defoaming 24 hours.
Embodiment 3
A kind of air brushing coating adapting to Latex ink, dry glue ratio are as follows: 25 parts of powdered whitings, 6 parts of silica, 40
Part styrene-acrylic emulsion, 39 parts of polyaminoester emulsions, 0.7 part of polyvinyl alcohol, 11 parts of wear-resistance microspheres, 0.06 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to the following steps:
S1, configuration poly-vinyl alcohol solution: weighing polyethylene alcohol and water, (dosage of water is to obtain the polyvinyl alcohol containing 15% admittedly
Solution is advisable), it first adds water in glue pot under room temperature, slow turn on agitator, mixing speed reaches 200r/min, then slowly
Slowly BM-1 micelle is added in glue pot, be kept stirring and started to warm up, until keeping the temperature 1 hour after being raised to 85 DEG C, led to afterwards cold
But 40 DEG C are water-cooled to, 200 mesh filter screen filtrations are spare after standing defoaming 24 hours；
S2, raw material is weighed in proportion, water is first added in glue pot, open blender, make 700 ~ 800r/ of its revolving speed
Powdered whiting is added in min while stirring, stirs 10min, adds silica, stirs 10min, reduces revolving speed extremely later
Styrene-acrylic emulsion and polyaminoester emulsion is added in 400 ~ 500r/min while stirring, stirs 20min, is slow added into prepared by S1
Poly-vinyl alcohol solution stirs 20min, adds wear-resistance microspheres and wetting agent, stir 30min together, later with 300 mesh filter screens
Filtering, it is spare after standing defoaming 24 hours.
Embodiment 4
A kind of air brushing coating adapting to Latex ink, dry glue ratio are as follows: 22 parts of powdered whitings, 5 parts of silica, 28
Part styrene-acrylic emulsion, 32 parts of polyaminoester emulsions, 0.6 part of polyvinyl alcohol, 9 parts of wear-resistance microspheres, 0.05 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to the following steps:
S1, configuration poly-vinyl alcohol solution: weighing polyethylene alcohol and water, (dosage of water is to obtain the polyvinyl alcohol containing 15% admittedly
Solution is advisable), it first adds water in glue pot under room temperature, slow turn on agitator, mixing speed reaches 200r/min, then slowly
Slowly BM-1 micelle is added in glue pot, be kept stirring and started to warm up, until keeping the temperature 1 hour after being raised to 85 DEG C, led to afterwards cold
But 40 DEG C are water-cooled to, 200 mesh filter screen filtrations are spare after standing defoaming 24 hours；
S2, raw material is weighed in proportion, water is first added in glue pot, open blender, make 700 ~ 800r/ of its revolving speed
Powdered whiting is added in min while stirring, stirs 10min, adds silica, stirs 10min, reduces revolving speed extremely later
Styrene-acrylic emulsion and polyaminoester emulsion is added in 400 ~ 500r/min while stirring, stirs 20min, is slow added into prepared by S1
Poly-vinyl alcohol solution stirs 20min, adds wear-resistance microspheres and wetting agent, stir 30min together, later with 300 mesh filter screens
Filtering, it is spare after standing defoaming 24 hours.
Performance test
Emboss wallpaper: the paper base of wallpaper is non-woven paper, first the two is combined with non-woven paper and cloth with composite glue, so
After carry out surface embossed, then with the air brushing coating glue of 20# bar coating Examples 1, coating weight exists in 20 ~ 25g/M2, machine speed
30M/min, dry glue is in 11G or so, and cutting is packed later.
Two generation wallpapers: the difference of two generation wallpapers and embossing wallpaper is not emboss this procedure.The paper base of wallpaper is nonwoven
Paper first combines the two with non-woven paper and cloth with composite glue, then with the air brushing coating adhesive of 20# bar coating Examples 2
Water, coating weight is in 20 ~ 25g/M2, and machine speed is in 30M/min, and dry glue is in 10G or so, and cutting is packed later.
Latex printing paper: having lamination PE on printing paper paper base, in the face the PE air brushing coating adhesive of 20# bar coating Examples 3
Water, coating weight is in 20 ~ 25g/M2, and machine speed is in 30M/min, and cutting is packed later.
Composite glue is mixed by acrylic resin (Tg:-7 DEG C) with aluminium hydroxide, and acrylic resin plays bonded fabric
With the effect of non-woven paper, aluminium hydroxide plays the role of fireproof, and the two dry glue ratio is between 70:30 ~ 60:40.
It is printed using HP L26500, effect is as shown in the table:
Lab colour model tri- elements of a, b by illumination (L) and in relation to color form.L indicates illumination, is equivalent to bright
Degree, a indicate the range from carmetta to green, and b indicates the range from yellow to blue.When the codomain of L is by 0 to 100, L=50,
Be equivalent to 50% it is black；The codomain of a and b be all by+127 to -128, wherein+127a is exactly carmetta, be transitioned into gradually -
Green is reformed into when 128a；Same principle ,+127b are yellow, and -128b is blue.All colors are just with these three values
Interaction variation is formed, for example, the Lab value of one piece of color is L=100, a=30, b=0, this block color is exactly pink.
As can be known from the above table, the performance indexes (glossiness, whiteness, color density, LAB value etc.) after the printing of air brushing coating
It is excellent.
Embossing wallpaper, two generation wallpapers, Latex printing paper (are being equivalent in 70 DEG C of baking ovens bakings respectively and are using 2 outdoors for 10 days
Year), after tested, glossiness, LAB value, colour gamut etc. are without significant changes, it was demonstrated that imaging is lasting.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Belong to those skilled in the art in the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of, all answers
It is included within the scope of the present invention.Therefore, protection scope of the present invention should be subject to the protection scope in claims.
Claims (6)
1. a kind of air brushing coating for adapting to Latex ink, which is characterized in that according to parts by weight, including 20~25 parts of heavy carbons
Sour calcium, 4~6 parts of silica, 20~40 parts of styrene-acrylic emulsions, 20~40 parts of polyaminoester emulsions, 0.3~0.8 part of polyvinyl alcohol, 8
~12 parts of wear-resistance microspheres, 0.04~0.06 part of wetting agent；The powdered whiting require partial size less than 2 microns account for 95% with
On；The Tg value of the styrene-acrylic emulsion is -18 DEG C；The Tg value of the polyaminoester emulsion is 25 DEG C.
2. air brushing coating according to claim 1, which is characterized in that according to parts by weight, including 23 parts of powdered whitings,
5 parts of silica, 30 parts of styrene-acrylic emulsions, 30 parts of polyaminoester emulsions, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting
Agent.
3. air brushing coating according to claim 1 or 2, which is characterized in that the Kong Rong of the silica is greater than 1.8mL/
G, average grain diameter is at 3 microns or less.
4. air brushing coating according to claim 1 or 2, which is characterized in that the wear-resistance microspheres be 15~20 microns of partial size,
The polythene wax emulsion that fusing point is 140 DEG C.
5. air brushing coating according to claim 1 or 2, which is characterized in that the wetting agent is BYK 333, TEGO wet
KL 245, Tao Shi X405 or surfynol 440.
6. a kind of method for preparing air brushing coating of any of claims 1 or 2, which comprises the following steps:
Polyvinyl alcohol and water are mixed under S1, room temperature, then heat to 85 DEG C of heat preservation 1h, is cooled to 40 DEG C, filtering is quiet
Defoaming is set, poly-vinyl alcohol solution is obtained；
Powdered whiting is added to the water under S2, stirring condition, silica is then added, is subsequently added into styrene-acrylic emulsion and poly- ammonia
Ester lotion adds the poly-vinyl alcohol solution of S1, is eventually adding wear-resistance microspheres and wetting agent, and filtering stands defoaming.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710538345.6A CN107325654B (en) | 2017-07-04 | 2017-07-04 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
| PCT/CN2017/094300 WO2019006786A1 (en) | 2017-07-04 | 2017-07-25 | Inkjet coating for adapting to latex ink and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710538345.6A CN107325654B (en) | 2017-07-04 | 2017-07-04 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
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| CN107325654A CN107325654A (en) | 2017-11-07 |
| CN107325654B true CN107325654B (en) | 2019-07-30 |
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| WO (1) | WO2019006786A1 (en) |
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| CN108948908B (en) * | 2018-05-30 | 2020-06-19 | 广东艺都科技有限公司 | Foaming spray-painting material and preparation method thereof |
| CN109251596A (en) * | 2018-07-31 | 2019-01-22 | 安徽鼎兴纺织科技有限公司 | A kind of water-soluble coating material adapting to Latex ink |
| CN113389084B (en) * | 2021-06-17 | 2022-08-26 | 广东希贵光固化材料有限公司 | Melamine impregnated paper body paper printing ink-absorbing coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1727203A (en) * | 2004-07-26 | 2006-02-01 | 富士胶片株式会社 | Recording medium, ink composition and recording method using the same |
| CN102796431A (en) * | 2012-09-13 | 2012-11-28 | 惠州艺都影像科技有限公司 | Label film paint and manufacturing method thereof |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP1714792A1 (en) * | 2005-03-28 | 2006-10-25 | Konica Minolta Holdings, Inc. | Inkjet recording medium and method for producing the same |
| US7641947B2 (en) * | 2006-05-26 | 2010-01-05 | Hewlett-Packard Development Company, L.P. | Stackable inkjet recording material |
| US8361572B2 (en) * | 2009-10-30 | 2013-01-29 | Hewlett-Packard Development Company, L.P. | Coated medium for inkjet printing |
| EP2596169A1 (en) * | 2010-07-23 | 2013-05-29 | International Paper Company | Coated printable substrates providing higher print quality and resolution at lower ink usage |
| EP3079913A4 (en) * | 2013-12-13 | 2017-02-15 | Hewlett-Packard Development Company, L.P. | Printable recording media |
| CN104369565B (en) * | 2014-03-31 | 2017-04-05 | 营口科玫数码影像材料有限公司 | A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof |
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2017
- 2017-07-04 CN CN201710538345.6A patent/CN107325654B/en not_active Withdrawn - After Issue
- 2017-07-25 WO PCT/CN2017/094300 patent/WO2019006786A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1727203A (en) * | 2004-07-26 | 2006-02-01 | 富士胶片株式会社 | Recording medium, ink composition and recording method using the same |
| CN102796431A (en) * | 2012-09-13 | 2012-11-28 | 惠州艺都影像科技有限公司 | Label film paint and manufacturing method thereof |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
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| WO2019006786A1 (en) | 2019-01-10 |
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