CN106690577A - Composite nanofiltration anti-haze antibiotic inhibition mask based on grapheme oxide and preparing method - Google Patents
Composite nanofiltration anti-haze antibiotic inhibition mask based on grapheme oxide and preparing method Download PDFInfo
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- CN106690577A CN106690577A CN201710038463.0A CN201710038463A CN106690577A CN 106690577 A CN106690577 A CN 106690577A CN 201710038463 A CN201710038463 A CN 201710038463A CN 106690577 A CN106690577 A CN 106690577A
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
- A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
- A41D13/1107—Protective face masks, e.g. for surgical use, or for use in foul atmospheres characterised by their shape
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
- A41D31/265—Electrically protective, e.g. preventing static electricity or electric shock using layered materials
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
- A41D31/305—Antimicrobial, e.g. antibacterial using layered materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Filtering Materials (AREA)
Abstract
The invention discloses a composite nanofiltration anti-haze antibiotic inhibition mask based on grapheme oxide. The mask comprises a mask body which is formed by sequentially stacking an anti-static processing layer, a grapheme oxide/silica/polymer composite nanometer filter core layer, an anion fiber non-woven fabric layer and an antibacterial layer from outside to inside. The outer exposed surface of the anti-static processing layer is provided with symmetrical fixing buckles, and a resistance band is detachably connected with the fixing buckles, and the mask body is bonded through hot-press to form the mask with a stereo breathing space. The polypropylene nonwoven fabric is loaded with the core filtration material made of the grapheme oxide/silica/polymer composite nanometer filter core layer, the anion fiber non-woven, the antibacterial layer by the method of the electrostatic spinning, the outermost layer of the propylene nonwoven fabric is treated by antistatic electricity. The anti-haze antibiotic inhibition face mask has the advantages of being high in efficiency of filtering away PM2.5 haze and good in permeability. The mask also has the functions of releasing negative ions to breath, resisting bacteria, low temperature far infrared and ultraviolet ray and the like.
Description
Technical field
The present invention relates to haze-proof mask technical field, the anti-haze of more particularly to a kind of composite nanometer filter based on graphene oxide
Antibacterial bacteriostatic mouth mask and preparation method.
Background technology
In recent years, the owning amount of China's automobile rapidly increases and industrialized high speed development, causes air quality to deteriorate, mist
Haze day duration is more and more long, continues haze weather and causes extremely serious influence to human health and daily life,
And thus trigger various diseases, including:The respiratory diseases such as asthma, respiratory tract infection, pulmonary infection, the body to people is good for
Health, colony particularly weaker to immunity such as children and the elderlys, causes extremely serious influence.
City poisonous particles source:Vehicle exhaust, is discharge fine particle " major criminal " using the car of diesel oil, is used
Although the compact car discharge of gasoline is gaseous contaminant, such as nitrogen oxides etc. runs into the greasy weather, is also easily converted to two
Secondary particulate pollutant, aggravates haze;The waste gas of industrial production discharge, such as metallurgical, kiln and boiler, electromechanical manufacturing industry, also
A large amount of Automobile Service spray paintings, the waste gas of production of construction materials kiln burning and exhausting;Airborne dust that construction site and road traffic are produced etc., can all add
Heavy fog haze, PM2.5 is commonly called as haze, is also called fine particle, one of index paid close attention to the most as existing social stage people,
It can be suspended in air long period, its in atmosphere content concn it is higher, it is more serious just to represent air pollution, therefore, open
It is one of effective measure to send out filtering material high performance.
Method of electrostatic spinning is the new development of chemical fibre conventional solution dry spinning and melt spinning, is current nanofiber
Topmost method is manufactured Deng superfine fibre.There is obvious difference with traditional method, it is by polymer solution or melt band
Upper thousands of to up to ten thousand volt high-pressure electrostatics.The core of this technology is to make electrically charged Polymer Solution or melt in electrostatic field
Flowing and deformation, when electric field force is sufficiently large, polymer drop can overcome surface tension to form injection thread.Then steamed through solvent
Hair or melt cooling and solidify and obtain fibrous material, therefore this process is referred to as electrostatic spinning.Existing Static Spinning nanometer film
Material, especially electrostatic spinning fiber film low intensity, and the electrospinning film shortage economy of high areal density is prepared, therefore using simple
Its optimum filtration effect is unable to reach when nano-sized membrane is used as filtering material and feature is poor.Knitted additionally, non-with routine
Make fiber filtering to compare, electrostatic spinning nano fiber film is very low for the mechanical strength of the filtering material of base material, therefore, by nanofiber
It is compound with non-weaving cloth, can both ensure the mechanical strength and filtering property of filtrate, can also reduce production cost.
Electrostatic spinning nano fiber diameter is thin, specific surface area big, is shown by this fibroplastic non-weaving cloth excellent
Absorption property, can be used as adsorbing medium, cladding activated carbon, biocide etc., with these fiber applications in mouth mask or air mistake
Filter membrane, can efficiently filter and the pernicious gas in air of degrading.
To hide haze pollution, mouth mask turns into the first-selected article of common citizen.But, mouth mask product in the market is big
Part can not filter PM2.5, and the test result of the Chinese Consumers' Association in 2014 shows that only only a few external product reaches
Removal efficiency requirement, and these product major parts be for industrial production is designed, comfortableness, aesthetic property be difficult to meet it is civilian will
Ask, on the one hand wearer can cause the inside and outside exchange velocity of air slower when being carried out air-breathing and being exhaled using these mouth masks, make
Into the sensation that wearer's supply is not enough, another aspect expiration gas residence time on the inside of mouth mask is long, and humidity is larger, influences face
Skin health.
The content of the invention
For defect present in prior art or deficiency, the present invention innovatively proposes a kind of based on graphene oxide
The anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter and preparation method, the obtained composite nanometer filter based on graphene oxide of the preparation method
Anti- haze antibacterial bacteriostatic mouth mask, not only filters the efficiency high of anti-haze PM2.5, and good permeability, is also breathed with anion releasing
The function such as pure and fresh, antibacterial bacteriostatic, pure and fresh, Low Temperature Far Infrared, uvioresistant.
The technical proposal of the invention is realized in this way:
A kind of anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including mask body, the mask body
Compression trace is provided with periphery, the mask body is from outside to inside successively by antistatic treatment layer, graphene oxide/titanium dioxide
Silicon/high molecular polymer composite Nano filter core layer, negative-ion fiber nonwoven layer, antibacterial bacteriostatic layer order are formed by stacking, described
Symmetrical clip is provided with the outside exposed surface of antistatic treatment layer, detachable with clip is connected with elastic band,
Nose support is provided with the lateral surface of the antibacterial bacteriostatic layer of upper position in the middle of the mask body, position is provided with the downside of nose support
Aluminum strip between antistatic treatment layer and graphene oxide/silica/high molecular polymer composite Nano filter core layer.
Preferably, a folding edge tracking arranged along its vertical center line, the folding are provided with the mask body
Edge tracking forms one with the aluminum strip for outwardly opening has the mouth mask of three-dimensional breathing space.
Preferably, position corresponding with mouth in human body face or nose in the mask body is provided with outlet valve, described
It is provided with outlet valve for limiting particle debris into the catch on the inside of mouth mask.
The invention discloses a kind of preparation method of the anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, bag
Include following steps:
(1)Nonwoven polypropylene fabric base material is laid on the metal plate of inner ground, the surface density of the nonwoven polypropylene fabric is 30-
75g/㎡;
(2)By graphene oxide, nano silicon with 4 in reaction vessel:3 ratio mixing, the 10- under the conditions of non-neutral
80 DEG C of stirring reaction 1-15h, obtain graphene oxide/silica composite;
(3)Graphene oxide/silica composite, high molecular polymer are dissolved in solvent, are stirred to being completely dissolved, obtained
To spinning solution, the mass percent concentration of the spinning solution is 5-20wt%;
(4)By step(3)Obtained spinning solution is added in syringe pump, controls ambient humidity for 20-60%, and environment temperature is
20-50 DEG C, syringe pump is set to be connected by pipeline with spinning head, spinning head is placed in tiling the metal plate of nonwoven polypropylene fabric
Top, spinning head is 15-35cm with the spacing of metal plate, and high-tension electricity is applied between spinning head and metal plate, makes to pass through
Pipeline reaches the spinning solution in spinning head from syringe pump, and graphene oxide/titanium dioxide is sprayed with the flow of 0.1-3.5mL/h
Silicon/high molecular polymer composite nano fiber, graphene oxide/silica/high molecular polymer composite nano fiber landing
On the nonwoven polypropylene fabric base material on metal plate surface, graphene oxide/silica/high score that polypropylene fibre is spun on cloth base material is collected
Sub- composite nano-polymers fiber, obtains graphene oxide/silica/high molecular polymer composite nanometer film filter layer material
Material;
(5)To load the polypropylene fibre of graphene oxide/silica/high molecular polymer composite nanometer film filtering layer material without
Spin cloth base material to be removed from metal plate, another layer of nonwoven polypropylene fabric is compound in and has loaded graphene oxide/silica/height
On the nonwoven polypropylene fabric base material of Molecularly Imprinted Polymer composite nanometer film filtering layer material, nonwoven polypropylene fabric/graphene oxide/bis- are formed
Silica/high molecular polymer composite nanometer film filtering material;
(6)By step(5)Obtained nonwoven polypropylene fabric/graphene oxide/silica/high molecular polymer composite nanometer film
Filtering material is put into vacuum drying chamber after standing 1.5-2.5h, and temperature setting is 10-30 DEG C, after standing 10-15h again after drying,
Obtain graphene oxide/silica/high molecular polymer composite Nano filter core layer;
(7)Successively by antistatic treatment layer, graphene oxide/silica/high molecular polymer composite Nano filter core layer, negative
After ion fiber nonwoven layer, antibacterial bacteriostatic layer order are overlapped, by periphery heat pressure adhesive, mask body is obtained, in the mouth mask
A folding edge tracking arranged along its vertical center line is suppressed on body;
(8)By step(7)Nose support is installed on the lateral surface of the antibacterial bacteriostatic layer of upper position in the middle of obtained mask body, anti-
Symmetrical clip is installed on the outside exposed surface of Electrostatic Treatment layer, is installed on the downside of nose support positioned at antistatic treatment layer and oxygen
Aluminum strip between graphite alkene/silica/high molecular polymer composite Nano filter core layer, the folding edge tracking with outwardly open
Aluminum strip form one there is the mouth mask of three-dimensional breathing space.
Preferably, the step(3)In high molecular polymer be polyacrylonitrile, Kynoar, polyurethane, poly- carbonic acid
In ester, PET, nylon, poly butyric ester, poly butyric valeric acid copolyesters any one or it is several
Kind.
Preferably, the step(3)In solvent be water, ethanol, dichloromethane, chloroform, N, N- dimethyl formyls
Any one or a few in amine, methyl alcohol, ethanol, formic acid, acetic acid.
Preferably, the step(2)Middle graphene oxide, the mixed proportion of silicon source are 4:3.
Preferably, the step(4)In high pressure piezoelectric voltage be 20-50KV.
Preferably, the step(7)In antistatic treatment layer base material be nonwoven polypropylene fabric, negative-ion fiber non-woven fabrics
The base material of layer and antibacterial bacteriostatic layer is regenerated celulose fibre non-woven fabrics.
Preferably, the step(6)In the filter of obtained graphene oxide/silica/high molecular polymer composite Nano
The filter efficiency of sandwich layer is 96%-99.66%.
Compared with prior art, the beneficial effects of the present invention are:
The invention discloses a kind of anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide and preparation method, the preparation
Mouth mask obtained in method, including antistatic treatment layer, be attached with antistatic additive, can reach the effect for refusing haze.
Graphene oxide/silica/high molecular polymer composite Nano filter core layer, therein, graphene oxide/dioxy
SiClx is combined, and Graphene has the functions, titanium dioxide such as the excellent, uvioresistant of excellent Low Temperature Far Infrared, antibacterial bacteriostatic, absorption property
Silicon has the functions such as excellent anion releasing, antibacterial bacteriostatic, uvioresistant.Graphene oxide is lyophobic dust, in Static Spinning base
It is easy to reunite in the high polymeric solutions such as material PAN, PU, PVDF, silica is combined with graphene oxide, can both improves oxidation stone
Dispersiveness of the black alkene in polyblend, while graphene oxide, the anion releasing of silica, antibacterial suppression can be played
The synergy of the functions such as bacterium, Low Temperature Far Infrared, absorption, uvioresistant.
Negative-ion fiber nonwoven layer, using anion function fiber, the anion of release has purify air, refreshes oneself awake
Brain, promotes human body oxygen-containing, the function of fresh air.
Antibacterial bacteriostatic layer, using chitin or bamboo fibre functional fibre, with the function such as antibacterial bacteriostatic, pro-skin be comfortable.
The present invention by folding edge tracking that one set in mask body is arranged along its vertical center line with outwards beat
The aluminum strip opened forms one has the mouth mask of three-dimensional breathing space, it is ensured that wearer's mouth, nasal respiration are smooth;With human body in mask body
Mouth or the corresponding position of nose are provided with outlet valve in face, and the air-flow of human body respiration is discharged from breather valve, prevents the heat of exhalation
Air-flow in human body suction body, will not be conducive to again, and people's is healthy.
The anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide of the invention, can effective haze
Pernicious gas in the air such as PM2.5 and vehicle exhaust, anion releasing, breath freshening;The preparation method is simple to operate, technique
Equipment operation is convenient, and raw materials used valency is cheap, is conducive to industrialization, can obtain extensive use.
Brief description of the drawings
Fig. 1 is the structural representation of lateral surface of the present invention;
Fig. 2 is the structural representation of medial surface of the present invention;
Fig. 3 is the structural representation of the electrostatic spinning apparatus that preparation method of the present invention is related to;
Reference:
1st, mask body;2nd, trace is compressed;3rd, clip;4th, elastic band;5th, nose support;6th, aluminum strip;7th, edge tracking is folded;8th, outlet valve;
9th, catch;10th, antistatic treatment layer;11st, antibacterial bacteriostatic layer;12nd, syringe pump;13rd, spinning head;14th, high-tension electricity;15th, polypropylene fibre without
Spin cloth;16th, metal plate.
Specific embodiment
With reference to specific embodiment, technical scheme is clearly and completely described, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
A kind of anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including mask body 1, the mouth mask sheet
Compression trace 2 is provided with the periphery of body 1, the mask body 1 is from outside to inside successively by antistatic treatment layer 10, graphite oxide
Alkene/silica/high molecular polymer composite Nano filter core layer, the order of negative-ion fiber nonwoven layer, antibacterial bacteriostatic layer 11 are folded
Conjunction is formed, and symmetrical clip 3 is provided with the outside exposed surface of the antistatic treatment layer 10, detachable with clip 3
Be connected with elastic band 4, the middle upper position of the mask body 1 antibacterial bacteriostatic layer 11 lateral surface on be provided with nose support
5, it is provided with to be combined positioned at antistatic treatment layer 10 and graphene oxide/silica/high molecular polymer in the downside of nose support 5 and receives
Aluminum strip 6 between rice filter core layer;A folding edge tracking 7 arranged along its vertical center line, institute are provided with the mask body 1
State mouth mask of the formation of aluminum strip 6 one with three-dimensional breathing space for folding edge tracking 7 and outwardly opening;With people in the mask body 1
Mouth or the corresponding position of nose are provided with outlet valve 8, the outlet valve 8 and are provided with to enter for limiting particle debris in honorable portion
Catch 9 on the inside of inlet shroud.
Embodiment 1:
The invention also discloses a kind of preparation method of the anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including
Following steps:
(1)By surface density for the nonwoven polypropylene fabric base material of 30g/ ㎡ is laid on the metal plate 16 of inner ground;
(2)By graphene oxide, nano silicon with 4 in reaction vessel:3 ratio mixing, 10 under the conditions of non-neutral
DEG C stirring reaction 1h, obtains graphene oxide/silica composite;
(3)It is 5 by high molecular polymer polyacrylonitrile, graphene oxide/silica composite mixed proportion:4 are dissolved in first
Alcohol, ethanol mixed proportion are 3:In 1 solvent, stir to being completely dissolved, obtain spinning solution, the mass percent of spinning solution
Concentration is 8wt%;
(4)By step(3)Obtained spinning solution is added in syringe pump 12, and it is 20% to control ambient humidity, and environment temperature is 20
DEG C, syringe pump 12 is connected by pipeline with spinning head 13, spinning head 13 is placed in tiling has the metal of nonwoven polypropylene fabric 15 flat
The top of plate 16, spinning head 13 is 15cm with the spacing of metal plate 16, is applied between spinning head 13 and metal plate 16
The high-tension electricity 14 of 20KV, makes to reach the spinning solution in spinneret 13 from syringe pump 12 by pipeline, with the flow of 0.1mL/h
Spray graphene oxide/silica/polyacrylonitrile nanofiber, graphene oxide/silica/polyacrylonitrile nanofiber
Drop on the base material of nonwoven polypropylene fabric 15 on the surface of metal plate 16, collect graphene oxide/dioxy that polypropylene fibre is spun on cloth base material
SiClx/polyacrylonitrile nanofiber, obtains graphene oxide/silica/polyacrylonitrile composite nanometer film filtering layer material;
(5)The nonwoven polypropylene fabric base that graphene oxide/silica/polyacrylonitrile composite nanometer film filters layer material will have been loaded
Material is removed from metal plate 16, another layer of nonwoven polypropylene fabric is compound in and has loaded graphene oxide/silica/polypropylene
On the nonwoven polypropylene fabric base material of nitrile composite nanometer film filtering layer material, formation nonwoven polypropylene fabric/graphene oxide/silica/
Polyacrylonitrile composite nanometer film filtering material;
(6)By step(5)Obtained nonwoven polypropylene fabric/graphene oxide/silica/polyacrylonitrile composite nanometer film filter material
Material is put into vacuum drying chamber after standing 1.5h, and temperature setting is 10 DEG C, after standing 10h again after drying, obtains graphene oxide/bis-
Silica/polyacrylonitrile composite Nano filter core layer, obtained graphene oxide/silica/polyacrylonitrile composite Nano filter core
The filter efficiency of layer is 96%-99.66%;
(7)Successively by antistatic treatment layer 10, graphene oxide/silica/polyacrylonitrile composite Nano filter core layer, anion
After fiber non-woven layer of cloth, the order of antibacterial bacteriostatic layer 11 are overlapped, by periphery heat pressure adhesive, mask body 1 is obtained, in the mouth mask sheet
A folding edge tracking 7 arranged along its vertical center line is suppressed on body 1;
(8)By step(7)Nose support 5 is installed on the lateral surface of the antibacterial bacteriostatic layer 11 of the middle upper position of obtained mask body 1,
Symmetrical clip 3 is installed on the outside exposed surface of antistatic treatment layer 10, is installed positioned at antistatic place in the downside of nose support 5
Aluminum strip 6 between reason layer 10 and graphene oxide/silica/polyacrylonitrile composite Nano filter core layer, the folding edge tracking 7 with
The aluminum strip 6 for outwardly opening forms one has the mouth mask of three-dimensional breathing space.
Embodiment 2:
The invention also discloses a kind of preparation method of the anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including
Following steps:
(1)By surface density for 50g/ ㎡ nonwoven polypropylene fabric base materials are laid on the metal plate 16 of inner ground;
(2)By graphene oxide, nano silicon with 4 in reaction vessel:3 ratio mixing, 40 under the conditions of non-neutral
DEG C stirring reaction 8h, obtains graphene oxide/silica composite;
(3)It is 5 by high molecular polymer Kynoar, graphene oxide/silica composite mixed proportion:4 are dissolved in
Formic acid, acetic acid mixed proportion are 3:In 1 solvent, stir to being completely dissolved, obtain spinning solution, the mass percent of spinning solution
Concentration is 15wt%;
(4)By step(3)Obtained spinning solution is added in syringe pump 12, and it is 35% to control ambient humidity, and environment temperature is 30
DEG C, syringe pump 12 is connected by pipeline with spinning head 13, spinning head 13 is placed in tiling has the metal of nonwoven polypropylene fabric 15 flat
The top of plate 16, spinning head 13 is 25cm with the spacing of metal plate 16, is applied between spinning head 13 and metal plate 16
35KV high-tension electricities 14, make to reach the spinning solution in spinning head 13 from syringe pump 12 by pipeline, are sprayed with the flow of 2mL/h
Graphene oxide/silica/polyvinylidene fluoride nanometer fiber, graphene oxide/silica/polyvinylidene fluoride nanometer fiber
Drop on the nonwoven polypropylene fabric base material on the surface of metal plate 16, collect graphene oxide/titanium dioxide that polypropylene fibre is spun on cloth base material
Silicon/polyvinylidene fluoride nanometer fiber, obtains graphene oxide/silica/Kynoar composite nanometer film filtering layer material;
(5)The nonwoven polypropylene fabric that graphene oxide/silica/Kynoar composite nanometer film filters layer material will have been loaded
Base material is removed from metal plate 16, another layer of nonwoven polypropylene fabric is compound in and has loaded graphene oxide/silica/poly- inclined
On the nonwoven polypropylene fabric base material of PVF composite nanometer film filtering layer material, nonwoven polypropylene fabric/graphene oxide/titanium dioxide is formed
Silicon/Kynoar composite nanometer film filtering material;
(6)By step(5)Obtained nonwoven polypropylene fabric/graphene oxide/silica/Kynoar composite Nano membrane filtration
Vacuum drying chamber is put into after material left 2h, temperature setting is 20 DEG C, after standing 12h again after drying, obtains graphene oxide/bis-
Silica/Kynoar composite Nano filter core layer, obtained graphene oxide/silica/Kynoar composite Nano
The filter efficiency of filter core layer is 96%-99.66%;
(7)Successively by antistatic treatment layer 10, graphene oxide/silica/Kynoar composite Nano filter core layer, bear from
After subbundle nonwoven layer, the order of antibacterial bacteriostatic layer 11 are overlapped, by periphery heat pressure adhesive, mask body 1 is obtained, in the mouth mask
A folding edge tracking 7 arranged along its vertical center line is suppressed on body 1;
(8)By step(7)Nose support 5 is installed on the lateral surface of the antibacterial bacteriostatic layer 11 of the middle upper position of obtained mask body 1,
Symmetrical clip 3 is installed on the outside exposed surface of antistatic treatment layer 10, is installed positioned at antistatic place in the downside of nose support 5
Aluminum strip 6 between reason layer 10 and graphene oxide/silica/Kynoar composite Nano filter core layer, the folding edge tracking 7
Forming one with the aluminum strip 6 for outwardly opening has the mouth mask of three-dimensional breathing space.
Embodiment 3:
The invention also discloses a kind of preparation method of the anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including
Following steps:
(1)75g/ ㎡ nonwoven polypropylene fabric base materials are laid on the metal plate 16 of inner ground;
(2)By graphene oxide, nano silicon with 4 in reaction vessel:3 ratio mixing, 80 under the conditions of non-neutral
DEG C stirring reaction 15h, obtains graphene oxide/silica composite;
(3)It is 5 by high molecular polymer polyurethane, graphene oxide/silica composite mixed proportion:4 be dissolved in formic acid,
Acetic acid mixed proportion is 3:In 1 solvent, stir to being completely dissolved, obtain spinning solution, the mass percent concentration of spinning solution
It is 20wt%;
(4)By step(3)Obtained spinning solution is added in syringe pump 12, and it is 60% to control ambient humidity, and environment temperature is 50
DEG C, syringe pump 12 is connected by pipeline with spinning head 13, spinning head 13 is placed in tiling has the metal of nonwoven polypropylene fabric 15 flat
The top of plate 16, spinning head 13 is 35cm with the spacing of metal plate 16, is applied between spinning head 13 and metal plate 16
50KV high-tension electricities 14, make to reach the spinning solution in spinning head 13 from syringe pump 12 by pipeline, are sprayed with the flow of 3.5mL/h
Go out graphene oxide/silica/polyurethane nanofiber, graphene oxide/silica/polyurethane nanofiber is dropped to
On the nonwoven polypropylene fabric base material on the surface of metal plate 16, graphene oxide/silica/poly- ammonia that polypropylene fibre is spun on cloth base material is collected
Ester nanofiber, obtains graphene oxide/silica/polyurethane composite nanometer film filtering layer material;
(5)The nonwoven polypropylene fabric base material that graphene oxide/silica/polyurethane composite nanometer film filters layer material will have been loaded
Removed from metal plate 16, another layer of nonwoven polypropylene fabric be compound in have loaded graphene oxide/silica/polyurethane multiple
Close on the nonwoven polypropylene fabric base material of nano-film filtration layer material, form nonwoven polypropylene fabric/graphene oxide/silica/poly- ammonia
Ester composite nanometer film filtering material;
(6)By step(5)Obtained nonwoven polypropylene fabric/graphene oxide/silica/polyurethane composite nanometer film filtering material
Vacuum drying chamber is put into after standing 2.5h, temperature setting is 30 DEG C, after standing 15h again after drying, obtains graphene oxide/dioxy
SiClx/polyurethane composite Nano filter core layer, the mistake of obtained graphene oxide/silica/polyurethane composite Nano filter core layer
Filter efficiency is 96%-99.66%;
(7)It is successively that antistatic treatment layer 10, graphene oxide/silica/polyurethane composite Nano filter core layer, anion is fine
After dimension nonwoven layer, the order of antibacterial bacteriostatic layer 11 are overlapped, by periphery heat pressure adhesive, mask body 1 is obtained, in the mask body
A folding edge tracking 7 arranged along its vertical center line is suppressed on 1;
(8)By step(7)Nose support 5 is installed on the lateral surface of the antibacterial bacteriostatic layer 11 of the middle upper position of obtained mask body 1,
Symmetrical clip 3 is installed on the outside exposed surface of antistatic treatment layer 10, is installed positioned at antistatic place in the downside of nose support 5
Aluminum strip 6 between reason layer 10 and graphene oxide/silica/polyurethane composite Nano filter core layer, the folding edge tracking 7 with to
The aluminum strip 6 of outer opening forms one has the mouth mask of three-dimensional breathing space.
The preferred embodiment of invention is the foregoing is only, is not intended to limit the invention, it is all in spirit of the invention
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (10)
1. a kind of anti-haze antibacterial bacteriostatic mouth mask of composite nanometer filter based on graphene oxide, including mask body, it is characterised in that institute
State and be provided with the periphery of mask body compression trace, the mask body is from outside to inside successively by antistatic treatment layer, oxidation stone
Black alkene/silica/high molecular polymer composite Nano filter core layer, negative-ion fiber nonwoven layer, antibacterial bacteriostatic layer order are folded
Conjunction is formed, and is provided with symmetrical clip on the outside exposed surface of the antistatic treatment layer, the company detachable with clip
Elastic band is connected to, nose support is provided with the lateral surface of the antibacterial bacteriostatic layer of upper position in the middle of the mask body, in nose support
Downside is provided with positioned at antistatic treatment layer and graphene oxide/silica/high molecular polymer composite Nano filter core layer
Between aluminum strip.
2. the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 1, it is characterised in that
Be provided with a folding edge tracking arranged along its vertical center line in the mask body, the folding edge tracking with outwardly open
Aluminum strip forms one has the mouth mask of three-dimensional breathing space.
3. the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 1, it is characterised in that
The position corresponding with mouth in human body face or nose is provided with outlet valve in the mask body, and use is provided with the outlet valve
In the catch that limitation particle debris enter on the inside of mouth mask.
4. the system of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim any one of 1-3
Preparation Method, it is characterised in that comprise the following steps:
(1)Nonwoven polypropylene fabric base material is laid on the metal plate of inner ground, the surface density of the nonwoven polypropylene fabric is 30-
75g/㎡;
(2)By graphene oxide, nano silicon with 4 in reaction vessel:3 ratio mixing, the 10- under the conditions of non-neutral
80 DEG C of stirring reaction 1-15h, obtain graphene oxide/silica composite;
(3)Graphene oxide/silica composite, high molecular polymer are dissolved in solvent, are stirred to being completely dissolved, obtained
To spinning solution, the mass percent concentration of the spinning solution is 5-20wt%;
(4)By step(3)Obtained spinning solution is added in syringe pump, controls ambient humidity for 20-60%, and environment temperature is
20-50 DEG C, syringe pump is set to be connected by pipeline with spinning head, spinning head is placed in tiling the metal plate of nonwoven polypropylene fabric
Top, spinning head is 15-35cm with the spacing of metal plate, and high-tension electricity is applied between spinning head and metal plate, makes to pass through
Pipeline reaches the spinning solution in spinning head from syringe pump, and graphene oxide/titanium dioxide is sprayed with the flow of 0.1-3.5mL/h
Silicon/high molecular polymer composite nano fiber, graphene oxide/silica/high molecular polymer composite nano fiber landing
On the nonwoven polypropylene fabric base material on metal plate surface, graphene oxide/silica/high score that polypropylene fibre is spun on cloth base material is collected
Sub- composite nano-polymers fiber, obtains graphene oxide/silica/high molecular polymer composite nanometer film filter layer material
Material;
(5)To load the polypropylene fibre of graphene oxide/silica/high molecular polymer composite nanometer film filtering layer material without
Spin cloth base material to be removed from metal plate, another layer of nonwoven polypropylene fabric is compound in and has loaded graphene oxide/silica/height
On the nonwoven polypropylene fabric base material of Molecularly Imprinted Polymer composite nanometer film filtering layer material, nonwoven polypropylene fabric/graphene oxide/bis- are formed
Silica/high molecular polymer composite nanometer film filtering material;
(6)By step(5)Obtained nonwoven polypropylene fabric/graphene oxide/silica/high molecular polymer composite nanometer film
Filtering material is put into vacuum drying chamber after standing 1.5-2.5h, and temperature setting is 10-30 DEG C, after standing 10-15h again after drying,
Obtain graphene oxide/silica/high molecular polymer composite Nano filter core layer;
(7)Successively by antistatic treatment layer, graphene oxide/silica/high molecular polymer composite Nano filter core layer, negative
After ion fiber nonwoven layer, antibacterial bacteriostatic layer order are overlapped, by periphery heat pressure adhesive, mask body is obtained, in the mouth mask
A folding edge tracking arranged along its vertical center line is suppressed on body;
(8)By step(7)Nose support is installed on the lateral surface of the antibacterial bacteriostatic layer of upper position in the middle of obtained mask body,
Antistatic treatment layer outside exposed surface on symmetrical clip is installed, installed on the downside of nose support positioned at antistatic treatment layer and
Aluminum strip between graphene oxide/silica/high molecular polymer composite Nano filter core layer, the folding edge tracking is beaten with outwards
The aluminum strip opened forms one has the mouth mask of three-dimensional breathing space.
5. the preparation method of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 4,
It is characterized in that:The step(3)In high molecular polymer for polyacrylonitrile, Kynoar, polyurethane, makrolon,
Any one or a few in PET, nylon, poly butyric ester, poly butyric valeric acid copolyesters.
6. the preparation method of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 4,
It is characterized in that:The step(3)In solvent be water, ethanol, dichloromethane, chloroform, N, N- dimethylformamides,
Any one or a few in methyl alcohol, ethanol, formic acid, acetic acid.
7. the preparation method of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 4,
It is characterized in that:The step(2)Middle graphene oxide, the mixed proportion of nano silicon are 4:3.
8. the preparation method of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 4,
It is characterized in that:The step(4)In high pressure piezoelectric voltage be 20-50KV.
9. the preparation method of the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to claim 4,
It is characterized in that:The step(7)In antistatic treatment layer base material be nonwoven polypropylene fabric, negative-ion fiber nonwoven layer and
The base material of antibacterial bacteriostatic layer is regenerated celulose fibre non-woven fabrics.
10. the anti-haze antibacterial bacteriostatic mouth mask of the composite nanometer filter based on graphene oxide according to any one of claim 4-9
Preparation method, it is characterised in that:The step(6)In obtained graphene oxide/silica/high molecular polymer be combined
The filter efficiency of nanometer filter core layer is 96%-99.66%.
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107981444A (en) * | 2018-01-02 | 2018-05-04 | 山东省圣泉生物质石墨烯研究院 | A kind of antibacterial oxygenation mask and preparation method thereof |
CN108043112A (en) * | 2017-12-14 | 2018-05-18 | 江苏工程职业技术学院 | A kind of automobile-used antibacterial air-filtering material containing graphene oxide composite material and preparation method thereof |
CN108049032A (en) * | 2017-11-24 | 2018-05-18 | 湖州织里创塑塑料科技有限公司 | A kind of preparation method of the non-woven fabrics with strong negative ion releasing function |
CN109954329A (en) * | 2017-12-25 | 2019-07-02 | 中国科学院上海硅酸盐研究所 | A kind of anti-haze filtering layer material of plant fiber self-supporting graphene and its preparation method and application |
CN110819001A (en) * | 2019-10-23 | 2020-02-21 | 南京长三角绿色发展研究院有限公司 | Flame-retardant antibacterial composite polypropylene filter material and preparation method thereof |
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WO2021197482A1 (en) * | 2020-04-03 | 2021-10-07 | King's Flair Innovative Marketing Limited | Novel filter material, face mask comprising the same and method of making the same |
CN113638130A (en) * | 2021-08-23 | 2021-11-12 | 无锡市鸿庆无纺布有限公司 | Multipurpose environment-friendly sterilization type multilayer filtering non-woven fabric and preparation method thereof |
WO2022015269A1 (en) * | 2020-07-17 | 2022-01-20 | Yorukogullari Ertugrul | A mask that provides thermochemical disinfection and is capable of storing energy |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN203152561U (en) * | 2013-03-27 | 2013-08-28 | 安徽理工大学 | Sterilization and dust prevention mask |
CN104083946A (en) * | 2014-06-27 | 2014-10-08 | 上海洁晟环保科技有限公司 | Antibacterial gauze mask filter and preparation method thereof, and antibacterial gauze mask |
CN204409659U (en) * | 2015-02-27 | 2015-06-24 | 济宁利特纳米技术有限责任公司 | A kind of mouth mask filter core for purifying PM2.5 |
CN204908034U (en) * | 2015-07-24 | 2015-12-30 | 浙江衢州南核特种劳动防护用品科技有限公司 | Expiratory valve and take foldable protective facial mask of valve |
CN105455254A (en) * | 2016-01-08 | 2016-04-06 | 清华大学 | Nanofiber mouth mask capable of effectively blocking PM0.3 and rich in nanometer antibacterial ingredients |
CN205214282U (en) * | 2015-12-08 | 2016-05-11 | 沈阳联锦科技有限公司 | Mask |
CN205597203U (en) * | 2016-05-13 | 2016-09-28 | 浙江海洋大学 | Graphite alkene gauze mask |
-
2017
- 2017-01-19 CN CN201710038463.0A patent/CN106690577B/en not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN203152561U (en) * | 2013-03-27 | 2013-08-28 | 安徽理工大学 | Sterilization and dust prevention mask |
CN104083946A (en) * | 2014-06-27 | 2014-10-08 | 上海洁晟环保科技有限公司 | Antibacterial gauze mask filter and preparation method thereof, and antibacterial gauze mask |
CN204409659U (en) * | 2015-02-27 | 2015-06-24 | 济宁利特纳米技术有限责任公司 | A kind of mouth mask filter core for purifying PM2.5 |
CN204908034U (en) * | 2015-07-24 | 2015-12-30 | 浙江衢州南核特种劳动防护用品科技有限公司 | Expiratory valve and take foldable protective facial mask of valve |
CN205214282U (en) * | 2015-12-08 | 2016-05-11 | 沈阳联锦科技有限公司 | Mask |
CN105455254A (en) * | 2016-01-08 | 2016-04-06 | 清华大学 | Nanofiber mouth mask capable of effectively blocking PM0.3 and rich in nanometer antibacterial ingredients |
CN205597203U (en) * | 2016-05-13 | 2016-09-28 | 浙江海洋大学 | Graphite alkene gauze mask |
Non-Patent Citations (7)
Title |
---|
刘迎云等: "《南方某尾矿库区空气颗粒物质量浓度及重金属污染特征》", 《2014中国环境科学学会学术年会》 * |
孔庆强等: "《石墨烯改性聚丙烯腈基纳米炭纤维的制备及其性能》", 《新型炭材料》 * |
曲丽君等: "《部分石墨烯复合纤维与制品的研发》", 《纺织学报》 * |
李栋等: "《静电纺丝法制备RGO/PU纳米复合纤维的研究》", 《聚氨酯工业》 * |
梁红培等: "《电纺制备明胶/壳聚糖/羟基磷灰石/氧化石墨烯抗菌复合纳米纤维的研究》", 《无机材料学报》 * |
王亮等: "《氧化石墨烯/二氧化硅复合材料对铀(Ⅵ)的吸附性能》", 《中国有色金属学报》 * |
覃小红等: "《静电纺丝中基布的静电性能对纺丝的影响研究》", 《产业用纺织品》 * |
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US11130087B2 (en) | 2019-10-23 | 2021-09-28 | Nanjing Yrd Eco Development Ri Co., Ltd. | Flame-retardant antibacterial composite polypropylene filter material and preparation method thereof |
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