CN106675720A - Nano copper lubricated micro-emulsification cutting solution - Google Patents

Nano copper lubricated micro-emulsification cutting solution Download PDF

Info

Publication number
CN106675720A
CN106675720A CN201611157432.9A CN201611157432A CN106675720A CN 106675720 A CN106675720 A CN 106675720A CN 201611157432 A CN201611157432 A CN 201611157432A CN 106675720 A CN106675720 A CN 106675720A
Authority
CN
China
Prior art keywords
solution
deionized water
stirring
micro
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611157432.9A
Other languages
Chinese (zh)
Inventor
江海涛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Original Assignee
Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Runda Metal Antirust Auxiliary Co Ltd filed Critical Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority to CN201611157432.9A priority Critical patent/CN106675720A/en
Publication of CN106675720A publication Critical patent/CN106675720A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/05—Metals; Alloys
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/081—Inorganic acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/042—Sulfate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/02—Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C10N2050/011—Oil-in-water

Abstract

The invention discloses a nano copper lubricated micro-emulsification cutting solution prepared from the following raw materials: refined mineral oil, ammonium lauryl sulfate, coconut monoethanol amide, polyoxyethylene fatty acid, undecanedioic acid, triglyceride sulfide, diethanolamine, petroleum sodium sulfonate, sodium chloride, propanetriol, cetanol, a defoaming agent, copper sulfate pentahydrate, polystyrene sulfonic acid, ammonium persulfate, an appropriate amount of aniline, an appropriate amount of ethylenediamine tetraacetic acid, an appropriate amount of sodium hypophosphite, an appropriate amount of methanol, and an appropriate amount of deionized water. The prepared micro-emulsification cutting solution according to the invention does not contain substances harmful to the environment and human health, has excellent processability, strong universality, excellent antirust performance, corrosion resistance and wear resistance, and a long service life, and has a high price/performance ratio and is worthy of promotion compared with like products.

Description

A kind of Nanometer Copper lubricates micro-emulsion cutting fluid
Technical field
The present invention relates to micro-emulsion cutting fluid technical field, more particularly to a kind of Nanometer Copper lubrication micro-emulsion cutting fluid.
Background technology
Metalworking fluid is supplementary material important in process of metal working, its Main Function be cool down, lubricate, cleaning and Antirust.It is divided into two big class according to medium condition：Oil type and aqua type cutting fluid, the main component of oil type cutting fluid is typically Mineral oil（Also there are vegetable oil or other synthetic materials）, and add oil-soluble antirust agent, oiliness improver and the extreme pressure containing active element Lubricant blending is formed, and compares water-base cutting fluid, and the greasy property and rustless property of oil base cutting fluid preferably, but have easily product Oil generation mist, the shortcomings of easily catch fire, water-base cutting fluid is used after with substantial amounts of water concentrated solution is diluted, because not with generation The shortcoming of oil smoke and initiation fire, the specific heat capacity of water is big, and thermal conductivity is high, and heat of vaporization is big, is very excellent coolant, cut and into This is cheap, and the cleaning by degreasing after processing in addition is also fairly simple.Microemulsion is that one kind is between emulsion and Synthesis liquid and simultaneous The cutting fluid of the excellent performance of tool emulsion lubrication and Synthesis liquid clarity, cost is relatively low, is that the main of following working fluid is sent out Exhibition direction.With economic fast development, the processing of various iron and steel and aluminium alloy is also developed rapidly, and at present the country is in iron and steel and aluminum The lubrication aspect metalworking fluid research of alloy is less, mainly based on import, China's research work starting in this respect It is later, and be concentrated mainly in materials processing molding, the problem to the lubrication in machining and in terms of anticorrosion is paid attention to not It is enough.Recently as the emergence of new processing equipment, processing conditionss are increasingly harsh, metalworking fluid it is also proposed higher Requirement.
Fu Qiaolian exists《Additive is in microemulsion to the research of aluminum/steel Lubrication Properties》Rub for aluminum-steel in one text Wipe the problem that pair is difficult to lubricate, the liquid based on aqueouss microemulsion, systematic research chlorine system, phosphorus system, sulfur system, esters and The big class lubricating additive of polyethers five is in microemulsion to steel-steel frictional pair, the lubrication property of aluminum-steel-steel pair.Research is sent out The maximum nonseizure load of existing microemulsion is relevant with the species of additive and consumption, wherein the lubricant effect to steel-steel frictional pair It is that response values of the polysulfide LZ5340L in aqueous microemulsion is best, maximum nonseizure load value is when addition is 5% 1118N, next to that chlorinated aliphatic acids DA8527, sulfuration triglyceride RC2411 also have preferable greasy property；In microemulsified It is that sulfur system additive RC2411 is best to the friction lubricating effect of aluminum-steel to the friction lubricating result of aluminum-steel in liquid, when When its concentration is 4%, the wear extent of aluminum pin only has 0.1mg, and LZ5340L when addition is 4%, also only have by the wear extent of aluminum pin 0.2mg.Find that sulfur system's additive has preferably lubrication to steel-steel frictional pair and aluminum-steel-steel pair after series of experiments Performance, preliminary analyses is carried out to its mechanism and thinks that sulfur system additive can form the sulfide film of one layer of densification in metal surface, is reduced Shear stress, plays lubrication.Can be effective although author's systematic research adds sulfur base lubricant in microemulsion Raising cutting fluid greasy property, but as processing device becomes more diversified, requirement of the people to micro-emulsion cutting fluid is got over Come higher, anti-corrosion and service life problem are a key factors having to take into account that in the cutting fluid course of processing, therefore right Micro-emulsion cutting fluid must be modified the cutting fluid to obtaining and can improve the surface quality of working (machining) efficiency and workpiece, while Extend the service life of cutter and cutting fluid itself, reduce processing cost, obtain optimum economic benefit and be only current research heat Point.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of Nanometer Copper lubricates micro-emulsion cutting fluid.
The present invention is achieved by the following technical solutions：
A kind of Nanometer Copper lubricates micro-emulsion cutting fluid, is made up of the raw material of following weight portion：Refined mineral oil 18-22, ten Dialkyl group ammonium sulfate 12-15, fatty monoethanol amide 4-5, polyoxyethylene carboxylate 6-8, DC11 2- 3rd, triglyceride 4-5, diethanolamine 3-4, petroleum sodium sulfonate 3-5, Sodium Chloride 2.2-2.5, glycerol 0.6-0.8, whale are vulcanized Ceryl alcohol 2.8-3.5, defoamer 0.05-0.1, copper sulphate pentahydrate 8.5-9, polystyrolsulfon acid 32-35, Ammonium persulfate. 11-13, benzene Appropriate amine, appropriate ethylenediaminetetraacetic acid, appropriate sodium hypophosphite, appropriate methanol, appropriate deionized water.
A kind of Nanometer Copper lubricates micro-emulsion cutting fluid, is made up of following concrete steps：
（1）The solution of 0.1mol/L is made in the dissolving of copper sulphate pentahydrate deionized water, ethylenediaminetetraacetic acid stirring is added molten Solution A is made after solution, solution B, wherein ethylenediaminetetraacetic acid and five water sulphuric acid are made in the dissolving of sodium hypophosphite deionized water The concentration ratio of copper is 1:4, the mol ratio of sodium hypophosphite and copper sulphate pentahydrate is 2.4:1, A, B solution are respectively placed in into 50 DEG C In thermostat water bath, magnetic stirring apparatuss solution A, then solution B is poured slowly in A, it is 2 to adjust pH value, starts agitator heating Make it keep isothermal reaction 4-6h to 70 DEG C, after question response terminates, product is washed to neutrality repeatedly, then washed with dehydrated alcohol Wash, place sedimentation, then with the anti-oxidation of soaked in absolute ethyl alcohol, filter, drying for standby；
（2）The solution that mass fraction is 10% is made in the dissolving of polystyrolsulfon acid deionized water, by step（1）The product of preparation Thing is added in polystyrolsulfon acid solution, and Deca aniline then proceedes to ultrasonic vibration 2h after ultrasonic disperse is uniform, it is fully dispersed after In being placed in 25 DEG C of constant temperature blender with magnetic force, wherein aniline and step（1）The product quality ratio of preparation is 2-3:1, add 5% Ammonium persulfate. make it fully react 5-6h, reaction carries out sucking filtration after terminating, and is then washed repeatedly with methanol and deionized water successively Wash up to filtrate clarification, solidss are placed in 60 DEG C of vacuum drying oven and dry 24h, it is standby after grinding；
(3) refined mineral oil is added in reaction vessel, petroleum sodium sulfonate, spermaceti is sequentially added when being heated with stirring to 60-65 DEG C Alcohol, ammonium lauryl sulfate, fatty monoethanol amide, polyoxyethylene carboxylate, often add a kind of material stirring equal A kind of material under can adding after even, then adds DC11, and stirring and dissolving is uniform to obtain oil-based system；
（4）Add deionized water to be heated to 70-80 DEG C in a reservoir, be added slowly with stirring Sodium Chloride and glycerol is fully stirred Mix dissolving, be stirring evenly and then adding into step (2) preparation product ultrasonic disperse it is uniform aqueous phase system；
（5）During aqueous phase system to be added slowly to the oil-based system stirred with 200-300r/min rotating speeds in the case where being kept for 60-70 DEG C, treat Controlling reaction temperature is 40-50 DEG C after aqueous phase system completion of dropwise addition, adds defoamer to obtain basic concentrated solution, in the concentrated solution Remaining leftover materials is added to be tuned into mother solution, deionized water is diluted to the micro-emulsion cutting fluid that concentration is 10%.
It is an advantage of the invention that：Polyaniline has synthesis material scratch resistance with low cost, excellent, pitting corrosion resistant performance etc. excellent Point, can form the polyaniline film of even compact on the surface of iron and steel and aluminium alloy, play good antiseptic and rustproof effect, but It is that its dissolubility in general organic solvent is poor, it is therefore desirable to which it is doped improves its dissolubility, and polyaniline has Host's ability of excellent capture nanoparticle, inorganic nano-particle co-doped that can be active with some effectively improves it Dissolubility and anti-corrosion capability, nano-metallic copper powder has that shearing force is low, heat conductivity is good, ductility is good, the low characteristic of fusing point, in profit Good lubrication antifriction function can be played in lubricating oil, but is applied directly in water-base cutting fluid to be easily polymerized and be not easy point Dissipate, it is impossible to reach excellent anti-attrition and friction reducing effect, the present invention is embedded in poly- using large-sized polystyrolsulfon acid counter ion Between aniline molecule chain, intermolecular interaction force is reduced, the unadulterated sulfonic acid in another aspect polystyrolsulfon acid Group water soluble, plays the effect of grafting solubilising, using chemical syntheses method by polyaniline in-situ preparation in Nanometer Copper Surface so as to there is good dispersibility and stability in water-base cutting fluid, the function such as its heat conduction, wear-resisting, antifriction is improved, this Micro-emulsion cutting fluid prepared by invention is general with excellent processing characteristics without the material being harmful to environmental and human health impacts Property strong, excellent antirust, anti-corrosion and wearability, long service life compares cost performance high, is worthy to be popularized in like product.
Specific embodiment
A kind of Nanometer Copper lubricates micro-emulsion cutting fluid, by following weight portion（Kilogram）Raw material make：Refined mineral Oil 18, ammonium lauryl sulfate 12, fatty monoethanol amide 4, polyoxyethylene carboxylate 6, DC11 2, Sulfuration triglyceride 4, diethanolamine 3, petroleum sodium sulfonate 3, Sodium Chloride 2.2, glycerol 0.6, spermol 2.8, defoamer 0.05th, copper sulphate pentahydrate 8.5, polystyrolsulfon acid 32, Ammonium persulfate. 11, appropriate aniline, appropriate ethylenediaminetetraacetic acid, secondary phosphorous Sour sodium is appropriate, appropriate methanol, appropriate deionized water.
A kind of Nanometer Copper lubricates micro-emulsion cutting fluid, is made up of following concrete steps：
（1）The solution of 0.1mol/L is made in the dissolving of copper sulphate pentahydrate deionized water, ethylenediaminetetraacetic acid stirring is added molten Solution A is made after solution, solution B, wherein ethylenediaminetetraacetic acid and five water sulphuric acid are made in the dissolving of sodium hypophosphite deionized water The concentration ratio of copper is 1:4, the mol ratio of sodium hypophosphite and copper sulphate pentahydrate is 2.4:1, A, B solution are respectively placed in into 50 DEG C In thermostat water bath, magnetic stirring apparatuss solution A, then solution B is poured slowly in A, it is 2 to adjust pH value, starts agitator heating Make it keep isothermal reaction 4h to 70 DEG C, after question response terminates, product is washed to neutrality repeatedly, then washed with dehydrated alcohol Wash, place sedimentation, then with the anti-oxidation of soaked in absolute ethyl alcohol, filter, drying for standby；
（2）The solution that mass fraction is 10% is made in the dissolving of polystyrolsulfon acid deionized water, by step（1）The product of preparation Thing is added in polystyrolsulfon acid solution, and Deca aniline then proceedes to ultrasonic vibration 2h after ultrasonic disperse is uniform, it is fully dispersed after In being placed in 25 DEG C of constant temperature blender with magnetic force, wherein aniline and step（1）The product quality ratio of preparation is 2:1, add 5% Ammonium persulfate. makes it fully react 5h, and reaction carries out sucking filtration after terminating, then straight with methanol and deionized water cyclic washing successively To filtrate clarification, solidss are placed in 60 DEG C of vacuum drying oven and dry 24h, it is standby after grinding；
(3) refined mineral oil is added in reaction vessel, sequentially add when being heated with stirring to 60 DEG C petroleum sodium sulfonate, spermol, Ammonium lauryl sulfate, fatty monoethanol amide, polyoxyethylene carboxylate, after often adding a kind of material stirring uniform A kind of material under can adding, then adds DC11, and stirring and dissolving is uniform to obtain oil-based system；
（4）Add deionized water to be heated to 70 DEG C in a reservoir, be added slowly with stirring Sodium Chloride and glycerol is sufficiently stirred for Dissolving, be stirring evenly and then adding into step (2) preparation product ultrasonic disperse it is uniform aqueous phase system；
（5）During aqueous phase system to be added slowly to the oil-based system stirred with 200r/min rotating speeds in the case where being kept for 60 DEG C, water phase body is treated It is that controlling reaction temperature is 40 DEG C after completion of dropwise addition, adds defoamer to obtain basic concentrated solution, in the concentrated solution remaining is added Leftover materials are tuned into mother solution, and deionized water is diluted to the micro-emulsion cutting fluid that concentration is 10%.
Performance test is carried out to micro-emulsion cutting fluid prepared by embodiment, it is as a result as follows：
Storage stability：Without discoloration, without layering；Defoaming（mL•10-1min-1）：＜ 2；Corrosion testing（55 ± 2 DEG C, cast iron/ h）：＞ 48；Corrosion testing（55 ± 2 DEG C, aluminum/h）：＞ 12；Rust-preventing characteristic is tested（Cast iron, h）＞ 48；It is maximum without seizing negative and（N）： 911；Wear resistence（N）：＞ 57.

Claims (2)

1. a kind of Nanometer Copper lubricates micro-emulsion cutting fluid, it is characterised in that be made up of the raw material of following weight portion：Refined ore deposit Thing oil 18-22, ammonium lauryl sulfate 12-15, fatty monoethanol amide 4-5, polyoxyethylene carboxylate 6-8, ten One carbon dicarboxylic acid 2-3, sulfuration triglyceride 4-5, diethanolamine 3-4, petroleum sodium sulfonate 3-5, Sodium Chloride 2.2-2.5, the third three Alcohol 0.6-0.8, spermol 2.8-3.5, defoamer 0.05-0.1, copper sulphate pentahydrate 8.5-9, polystyrolsulfon acid 32-35, over cure Sour ammonium 11-13, appropriate aniline, appropriate ethylenediaminetetraacetic acid, appropriate sodium hypophosphite, appropriate methanol, appropriate deionized water.
2. according to claim 1 a kind of Nanometer Copper lubricates micro-emulsion cutting fluid, it is characterised in that by following concrete steps system Prepare into：
（1）The solution of 0.1mol/L is made in the dissolving of copper sulphate pentahydrate deionized water, ethylenediaminetetraacetic acid stirring is added molten Solution A is made after solution, solution B, wherein ethylenediaminetetraacetic acid and five water sulphuric acid are made in the dissolving of sodium hypophosphite deionized water The concentration ratio of copper is 1:4, the mol ratio of sodium hypophosphite and copper sulphate pentahydrate is 2.4:1, A, B solution are respectively placed in into 50 DEG C In thermostat water bath, magnetic stirring apparatuss solution A, then solution B is poured slowly in A, it is 2 to adjust pH value, starts agitator heating Make it keep isothermal reaction 4-6h to 70 DEG C, after question response terminates, product is washed to neutrality repeatedly, then washed with dehydrated alcohol Wash, place sedimentation, then with the anti-oxidation of soaked in absolute ethyl alcohol, filter, drying for standby；
（2）The solution that mass fraction is 10% is made in the dissolving of polystyrolsulfon acid deionized water, by step（1）The product of preparation Thing is added in polystyrolsulfon acid solution, and Deca aniline then proceedes to ultrasonic vibration 2h after ultrasonic disperse is uniform, it is fully dispersed after In being placed in 25 DEG C of constant temperature blender with magnetic force, wherein aniline and step（1）The product quality ratio of preparation is 2-3:1, add 5% Ammonium persulfate. make it fully react 5-6h, reaction carries out sucking filtration after terminating, and is then washed repeatedly with methanol and deionized water successively Wash up to filtrate clarification, solidss are placed in 60 DEG C of vacuum drying oven and dry 24h, it is standby after grinding；
(3) refined mineral oil is added in reaction vessel, petroleum sodium sulfonate, spermaceti is sequentially added when being heated with stirring to 60-65 DEG C Alcohol, ammonium lauryl sulfate, fatty monoethanol amide, polyoxyethylene carboxylate, often add a kind of material stirring equal A kind of material under can adding after even, then adds DC11, and stirring and dissolving is uniform to obtain oil-based system；
（4）Add deionized water to be heated to 70-80 DEG C in a reservoir, be added slowly with stirring Sodium Chloride and glycerol is fully stirred Mix dissolving, be stirring evenly and then adding into step (2) preparation product ultrasonic disperse it is uniform aqueous phase system；
（5）During aqueous phase system to be added slowly to the oil-based system stirred with 200-300r/min rotating speeds in the case where being kept for 60-70 DEG C, treat Controlling reaction temperature is 40-50 DEG C after aqueous phase system completion of dropwise addition, adds defoamer to obtain basic concentrated solution, in the concentrated solution Remaining leftover materials is added to be tuned into mother solution, deionized water is diluted to the micro-emulsion cutting fluid that concentration is 10%.
CN201611157432.9A 2016-12-15 2016-12-15 Nano copper lubricated micro-emulsification cutting solution Pending CN106675720A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611157432.9A CN106675720A (en) 2016-12-15 2016-12-15 Nano copper lubricated micro-emulsification cutting solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611157432.9A CN106675720A (en) 2016-12-15 2016-12-15 Nano copper lubricated micro-emulsification cutting solution

Publications (1)

Publication Number Publication Date
CN106675720A true CN106675720A (en) 2017-05-17

Family

ID=58868963

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611157432.9A Pending CN106675720A (en) 2016-12-15 2016-12-15 Nano copper lubricated micro-emulsification cutting solution

Country Status (1)

Country Link
CN (1) CN106675720A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112280608A (en) * 2019-07-23 2021-01-29 富兰克科技（深圳）股份有限公司 Application of nano-copper in cutting fluid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277900A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 High-antiwear cutting fluid
CN104789311A (en) * 2015-04-22 2015-07-22 青岛承天伟业机械制造有限公司 Multifunctional cutting liquid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104277900A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 High-antiwear cutting fluid
CN104789311A (en) * 2015-04-22 2015-07-22 青岛承天伟业机械制造有限公司 Multifunctional cutting liquid

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
赵炳桢等: "《现代刀具设计与应用》", 30 September 2014, 国防工业出版社 *
马贤智等: "《实用机械加工手册》", 28 February 2015, 辽宁科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112280608A (en) * 2019-07-23 2021-01-29 富兰克科技（深圳）股份有限公司 Application of nano-copper in cutting fluid

Similar Documents

Publication Publication Date Title
CN105001964A (en) Microemulsified cutting fluid
CN104164283A (en) Microemulsion metal cutting fluid
CN102676277A (en) Water soluble antirusting fluid, and preparation method and using method thereof
CN104877749B (en) Vermicular cast iron processing water-base cutting fluid and its dilution
Reeves et al. Advancements in eco-friendly lubricants for tribological applications: Past, present, and future
CN102876435B (en) Semisynthetic metal cutting fluid with trimethylolpropane oleate serving as base oil and preparation method of semisynthetic metal cutting fluid
CN102311864A (en) Cutting fluid special for NC machine tools
CN111378520A (en) MoS-containing2Water soluble trace amount lubricating liquid
CN107541328A (en) Aqueous cutting fluid that can be recycled without discharge and preparation method thereof
CN106590907A (en) Graphene-containing metal cutting fluid and preparation method thereof
CN106675739A (en) Emulsified-titanium-dioxide-added photocatalytic bactericidal microemulsified cutting fluid
CN105623809A (en) Synthetic ester environment-friendly type aluminum alloy cutting emulsified oil and preparing method thereof
CN102604723A (en) Lubricating grease composition and preparation method thereof
CN103555392A (en) Ionic liquid-containing micro-emulsified metal cutting fluid, and preparation method and application thereof
CN104120017B (en) Water-base cutting fluid of the strong good antirust property of a kind of penetration and preparation method thereof
CN106675720A (en) Nano copper lubricated micro-emulsification cutting solution
CN101948711B (en) Water-soluble cutting fluid and preparation method thereof
CN106675722A (en) Modified-clay-modified microemulsion cutting fluid
CN106635355A (en) Pectin-modified micro-emulsion cutting fluid
CN106675721A (en) Micro-emulsion cutting fluid added with plant ash
CN106675740A (en) Micro emulsion cutting fluid for hard and brittle material processing
CN106635336A (en) Wear-resistant and pressure-resistant nanometer diamond microemulsion cutting fluid
CN102876438A (en) Finishing solution and preparation method thereof
CN103351937B (en) Water-soluble cutting fluid and preparation method thereof
CN108441310A (en) A kind of intermetallic composite coating semi-synthetic cutting fluid and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170517

RJ01 Rejection of invention patent application after publication