CN106671388A - Wood-plastic decorative board high in moisture resistance - Google Patents
Wood-plastic decorative board high in moisture resistance Download PDFInfo
- Publication number
- CN106671388A CN106671388A CN201611004021.6A CN201611004021A CN106671388A CN 106671388 A CN106671388 A CN 106671388A CN 201611004021 A CN201611004021 A CN 201611004021A CN 106671388 A CN106671388 A CN 106671388A
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- moisture resistance
- wood
- decorative board
- plastic decorative
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/10—Properties of the layers or laminate having particular acoustical properties
- B32B2307/102—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to the technical field of wood-plastic composite boards and particularly relates to a wood-plastic decorative board high in moisture resistance. The wood-plastic decorative board high in moisture resistance comprises a core layer and a decorative layer. The core layer is made of prepreg. The prepreg is made of the following raw materials comprising sulfonated amino-formaldehyde resin, pinus elliottii rosin, carbonized softwood pulp, waxy corn starch, ash calcium powder, ardealite, dihydrocumic acid, acrylic fiber pulp, coal ash floating beads, diphenylamine, Fischer-tropsch wax, calcium stearate, terephthaloyl chloride and an accelerant. Compared with the prior art, the wood-plastic decorative board high in moisture resistance has the advantages that materials having multiple properties cooperate, so that the structure stability is high after forming, the wood-plastic decorative board high in moisture resistance is good in aging resistance, corrosion resistance, sound insulation effect, heat preservation effect, flame retardant effect and mechanical property, the moisture resistance is greatly improved under the corresponding strength, and the wood-plastic decorative board high in moisture resistance is suitable for suspended ceiling engineering and buildings in southern cities wherein the plum rain season exists, capable of guaranteeing the construction quality and the service life period of the buildings and remarkable in economic benefit.
Description
Technical field
The invention belongs to wood-plastic clad plate technical field, and in particular to a kind of strong wood-plastic decorative board of moisture resistance.
Background technology
Wood-plastic composite panel is one kind mainly by timber(Lignose, plant cellulose)Based on material and thermoplasticity it is high
Molecular material(Plastics)With processing aid etc., after being well mixed again the heating extrusion molding of Jing die apparatus and made by high-tech it is green
Colour circle protects new decorative material, has the performance and feature of timber and plastics concurrently, is the NEW TYPE OF COMPOSITE material that can substitute timber and plastics
Material, with expanding economy, the improvement of people's living standards, people have higher wanting to the speed and quality of Decoration Industry
Ask, wood-plastic composite panel compare common wood loss it is low, be not required to paint or water paint coating process, easy construction, price be adapted to,
Long service life, maintenance cost is low, therefore is increasingly liked by masses, and existing wood-plastic composite panel has had stronger anti-
It is aqueous, but many areas in south can be moister for a long time in rainy season, and at this moment, part wood-plastic clad plate is it is possible that inhale
Situations such as wet, softening, deformation, therefore have larger requirement to moisture resistance.
The content of the invention
The purpose of the present invention is for existing problem, there is provided a kind of strong wood-plastic decorative board of moisture resistance.
The present invention is achieved by the following technical solutions:A kind of strong wood-plastic decorative board of moisture resistance, including sandwich layer and dress
Decorations layer, its center core layer is made up of prepreg, and the prepreg is made up of the raw material of following weight portion:Sulfonated amino resin 15-20 parts,
Slash pine rosin 13-15 parts, carbonization softwood pulp 5-8 parts, waxy corn starch 2-6 parts, sierozem power 3-6 parts, ardealite 6-10
Part, dihydrocumic acid 4-6 parts, acrylic fibers pulp 2-4 parts, fly ash float 3-5 parts, diphenylamines 0.2-0.4 parts, Fischer-Tropsch wax 2-3 parts,
Calcium stearate 0.7-1.5 parts, paraphthaloyl chloride 0.1-0.3 parts, accelerator 0.2-0.5 parts;
Waxy corn starch using it is front its water content is adjusted to 42% after, sealing and balancing 5-8 minute, be subsequently placed in Microwave Frequency
Rate is cooled to room temperature to process 20 seconds in the microwave device of 350-400MHz, and drying and crushing to particle diameter is 200-400nm.
Used as further improvement of these options, the sulfonation degree of the sulfonated amino resin is 16.5-18%.
As further improvement of these options, the model FUJICURE FXR1020/1081 of the accelerator.
Used as further improvement of these options, the decorative layer is made by the mixing of kaolin, wollastonite in powder and sepiolite
Into mixed weight ratio is 5:4:2.
Used as further improvement of these options, the preparation method of the sandwich layer is comprised the following steps:
(1)By the mixing of sulfonated amino resin, slash pine rosin, sierozem power and ardealite, mix under conditions of 95-100 DEG C, dry
The mixed powder that particle diameter is 60-80 μm is ground to form after dry;
(2)By acrylic fibers pulp, carbonization softwood pulp, diphenylamines and dihydrocumic acid, insulated and stirred 3- under conditions of 35-40 DEG C
4 hours, obtain mixed serum;
(3)Mixed serum and mixed powder are mixed, is stirred 15-20 minutes under conditions of 600-800 rev/min, be cooled to often
Temperature, adds surplus stock, is sufficiently mixed, and by double screw extruder melt blending, extrusion molding, obtains final product.
The present invention has compared to existing technology advantages below:The material of multiple performance mutually acts synergistically in the present invention, into
Structural stability is high after type, maintains preferable Ageing-resistant corrosion-resistant effect property, and sound insulation, insulation, flame retardant effect, mechanical property compared with
It is good, while also substantially increasing the moisture resistance under respective strengths, it is adaptable to which furred ceiling engineering has the city of plum rain season in south
In city's building, it is ensured that Construction Quality and service life, remarkable in economical benefits.
Specific embodiment
Embodiment 1
A kind of strong wood-plastic decorative board of moisture resistance, including sandwich layer and decorative layer, its center core layer is made up of prepreg, the prepreg by
The raw material of following weight portion is made:15 parts of sulfonated amino resin, 15 parts of slash pine rosin, 5 parts of softwood pulp of carbonization, waxy corn
6 parts of starch, 3 parts of sierozem power, 10 parts of ardealite, 4 parts of dihydrocumic acid, 4 parts of acrylic fibers pulp, 3 parts of fly ash float, diphenylamines
0.2 part, 2 parts of Fischer-Tropsch wax, 1.5 parts of calcium stearate, 0.1 part of paraphthaloyl chloride, 0.5 part of accelerator;
Waxy corn starch using it is front its water content is adjusted to 42% after, sealing and balancing 6 minutes is subsequently placed in microwave frequency
To process 20 seconds in the microwave device of 350MHz, room temperature is cooled to, drying and crushing to particle diameter is 300nm.
Wherein, the sulfonation degree of the sulfonated amino resin is 18%;Model FUJICURE of the accelerator
FXR1020/1081;The decorative layer is mixed by kaolin, wollastonite in powder and sepiolite, and mixed weight ratio is 5:4:2.
Wherein, the preparation method of the sandwich layer is comprised the following steps:
(1)By the mixing of sulfonated amino resin, slash pine rosin, sierozem power and ardealite, mix under conditions of 95-100 DEG C, dry
The mixed powder that particle diameter is 60-80 μm is ground to form after dry;
(2)By acrylic fibers pulp, carbonization softwood pulp, diphenylamines and dihydrocumic acid, insulated and stirred 3- under conditions of 35-40 DEG C
4 hours, obtain mixed serum;
(3)Mixed serum and mixed powder are mixed, is stirred 15-20 minutes under conditions of 600-800 rev/min, be cooled to often
Temperature, adds surplus stock, is sufficiently mixed, and by double screw extruder melt blending, extrusion molding, obtains final product.
Embodiment 2
A kind of strong wood-plastic decorative board of moisture resistance, including sandwich layer and decorative layer, its center core layer is made up of prepreg, the prepreg by
The raw material of following weight portion is made:20 parts of sulfonated amino resin, 13 parts of slash pine rosin, 5 parts of softwood pulp of carbonization, waxy corn
2 parts of starch, 6 parts of sierozem power, 6 parts of ardealite, 6 parts of dihydrocumic acid, 2 parts of acrylic fibers pulp, 5 parts of fly ash float, diphenylamines 0.4
Part, 3 parts of Fischer-Tropsch wax, 1.5 parts of calcium stearate, 0.1 part of paraphthaloyl chloride, 0.4 part of accelerator;
Waxy corn starch using it is front its water content is adjusted to 42% after, sealing and balancing 6 minutes is subsequently placed in microwave frequency
To process 20 seconds in the microwave device of 380MHz, room temperature is cooled to, drying and crushing to particle diameter is 400nm.
Remainder is in the same manner as in Example 1.
Embodiment 3
A kind of strong wood-plastic decorative board of moisture resistance, including sandwich layer and decorative layer, its center core layer is made up of prepreg, the prepreg by
The raw material of following weight portion is made:18 parts of sulfonated amino resin, 14 parts of slash pine rosin, 6 parts of softwood pulp of carbonization, waxy corn
4 parts of starch, 5 parts of sierozem power, 8 parts of ardealite, 5 parts of dihydrocumic acid, 4 parts of acrylic fibers pulp, 4 parts of fly ash float, diphenylamines 0.3
Part, 3 parts of Fischer-Tropsch wax, 1.2 parts of calcium stearate, 0.2 part of paraphthaloyl chloride, 0.3 part of accelerator;
Waxy corn starch using it is front its water content is adjusted to 42% after, sealing and balancing 8 minutes is subsequently placed in microwave frequency
To process 20 seconds in the microwave device of 350MHz, room temperature is cooled to, drying and crushing to particle diameter is 200nm.
Remainder is in the same manner as in Example 1.
The impact strength of decorative panel is 1.5KJ/ ㎡ or so in the present invention, in order to prove the present invention in the strong wood of moisture resistance
The performance design contrast test of plastic decorative board, test method is wood of the impact strength for 1.5KJ/ ㎡ or so for taking conventional method
Plastic decorative board cuts into the bar shaped plank that length and width specification is 300mm × 50mm, and as a control group, putting it into relative humidity is
98%th, temperature is in 40 DEG C of chamber, to ride upon on case inner support, and 15mm is taken per side, middle hanging, is kept in casing
Stationary temperature and humidity, then at 2,4,6 hours measured its sagging size respectively, and testing result is as follows:
Table 1
Sagging size(mm) | 2 hours | 4 hours | 6 hours |
Embodiment 1 | 0 | 1.2 | 2.3 |
Embodiment 2 | 0 | 1.5 | 2.6 |
Embodiment 3 | 0 | 1.3 | 2.4 |
Control group | 1.4 | 3.8 | 8.7 |
The moisture-resisting decoration board humidity resistance prepared in the present invention is can be seen that by data in table 1 higher, and with stronger power
Intensity is learned, decorative panel prepared in the present invention is used for into furred ceiling engineering or in there is the urban architecture of plum rain season in south, can
To ensure Construction Quality and service life.
Claims (5)
1. the strong wood-plastic decorative board of a kind of moisture resistance, it is characterised in that including sandwich layer and decorative layer, its center core layer is by prepreg system
Into the prepreg is made up of the raw material of following weight portion:Sulfonated amino resin 15-20 parts, slash pine rosin 13-15 parts, carbonization
Softwood pulp 5-8 parts, waxy corn starch 2-6 parts, sierozem power 3-6 parts, ardealite 6-10 parts, dihydrocumic acid 4-6 parts, acrylic fibers
Pulp 2-4 parts, fly ash float 3-5 parts, diphenylamines 0.2-0.4 parts, Fischer-Tropsch wax 2-3 parts, calcium stearate 0.7-1.5 parts, to benzene
Dimethyl chloride 0.1-0.3 parts, accelerator 0.2-0.5 parts;
Waxy corn starch using it is front its water content is adjusted to 42% after, sealing and balancing 5-8 minute, be subsequently placed in Microwave Frequency
Rate is cooled to room temperature to process 20 seconds in the microwave device of 350-400MHz, and drying and crushing to particle diameter is 200-400nm.
2. a kind of as claimed in claim 1 strong wood-plastic decorative board of moisture resistance, it is characterised in that the sulphur of the sulfonated amino resin
Change degree is 16.5-18%.
3. a kind of as claimed in claim 1 strong wood-plastic decorative board of moisture resistance, it is characterised in that the model of the accelerator
FUJICURE FXR1020/1081。
4. the as claimed in claim 1 strong wood-plastic decorative board of a kind of moisture resistance, it is characterised in that the decorative layer by kaolin,
Wollastonite in powder and sepiolite are mixed, and mixed weight ratio is 5:4:2.
5. a kind of as claimed in claim 1 strong wood-plastic decorative board of moisture resistance, it is characterised in that the preparation method bag of the sandwich layer
Include following steps:
(1)By the mixing of sulfonated amino resin, slash pine rosin, sierozem power and ardealite, mix under conditions of 95-100 DEG C, dry
The mixed powder that particle diameter is 60-80 μm is ground to form after dry;
(2)By acrylic fibers pulp, carbonization softwood pulp, diphenylamines and dihydrocumic acid, insulated and stirred 3- under conditions of 35-40 DEG C
4 hours, obtain mixed serum;
(3)Mixed serum and mixed powder are mixed, is stirred 15-20 minutes under conditions of 600-800 rev/min, be cooled to often
Temperature, adds surplus stock, is sufficiently mixed, and by double screw extruder melt blending, extrusion molding, obtains final product.
Priority Applications (1)
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CN201611004021.6A CN106671388A (en) | 2016-11-15 | 2016-11-15 | Wood-plastic decorative board high in moisture resistance |
Applications Claiming Priority (1)
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CN201611004021.6A CN106671388A (en) | 2016-11-15 | 2016-11-15 | Wood-plastic decorative board high in moisture resistance |
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CN106671388A true CN106671388A (en) | 2017-05-17 |
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CN201611004021.6A Pending CN106671388A (en) | 2016-11-15 | 2016-11-15 | Wood-plastic decorative board high in moisture resistance |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186754A (en) * | 2006-11-16 | 2008-05-28 | 滨州华晨新型建材有限公司 | Method for producing macromolecule composite wood-plastic material by utilizing crop straw |
CN102470544A (en) * | 2009-06-30 | 2012-05-23 | 新西兰森林研究所有限公司 | Method for producing wood fibre-plastics composite products |
WO2015169647A1 (en) * | 2014-05-09 | 2015-11-12 | Akzenta Paneele + Profile Gmbh | Method for producing a decorated wall or floor panel |
CN105133813A (en) * | 2015-07-06 | 2015-12-09 | 安徽以诺木塑板材科技有限公司 | Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor |
CN105504577A (en) * | 2015-12-17 | 2016-04-20 | 绵阳立新科技发展有限公司 | Wood-plastic composite material |
CN105504853A (en) * | 2016-02-03 | 2016-04-20 | 中国地质大学(北京) | Novel wood-plastic composite material |
-
2016
- 2016-11-15 CN CN201611004021.6A patent/CN106671388A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101186754A (en) * | 2006-11-16 | 2008-05-28 | 滨州华晨新型建材有限公司 | Method for producing macromolecule composite wood-plastic material by utilizing crop straw |
CN102470544A (en) * | 2009-06-30 | 2012-05-23 | 新西兰森林研究所有限公司 | Method for producing wood fibre-plastics composite products |
WO2015169647A1 (en) * | 2014-05-09 | 2015-11-12 | Akzenta Paneele + Profile Gmbh | Method for producing a decorated wall or floor panel |
CN105133813A (en) * | 2015-07-06 | 2015-12-09 | 安徽以诺木塑板材科技有限公司 | Environmental friendly, wear resistant and sound-absorbing double-layer-structure waterproof wood-plastic floor |
CN105504577A (en) * | 2015-12-17 | 2016-04-20 | 绵阳立新科技发展有限公司 | Wood-plastic composite material |
CN105504853A (en) * | 2016-02-03 | 2016-04-20 | 中国地质大学(北京) | Novel wood-plastic composite material |
Non-Patent Citations (2)
Title |
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中国木材流通协会编: "《中国市场木材及木制品采购指南》", 31 March 2006, 中国轻工业出版社 * |
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Application publication date: 20170517 |