CN108911575A - A kind of energy conservation and environmental protection novel floor material and preparation method thereof - Google Patents
A kind of energy conservation and environmental protection novel floor material and preparation method thereof Download PDFInfo
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- CN108911575A CN108911575A CN201810831291.7A CN201810831291A CN108911575A CN 108911575 A CN108911575 A CN 108911575A CN 201810831291 A CN201810831291 A CN 201810831291A CN 108911575 A CN108911575 A CN 108911575A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/006—Waste materials as binder
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
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- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of energy conservation and environmental protection novel floor materials, are related to flooring material field, the raw material including following parts by weight meter：8-15 parts of waste polyethylene plastic, 12-18 parts of waste phenolic resin, 22-28 parts of waste polyurethane foamed plastics, 8-15 parts of modified bamboo powdered carbon, manioc waste 30-42 parts modified, 4-9 parts of negative ion powder, 8-15 parts of wollastonite powder, 12-18 parts of expanded perlite, 15-22 parts of quartz sand, 5-10 parts of precipitated calcium carbonate, 12-18 parts of nano aluminium oxide, 4-8 parts of plasticizer, 1.2-1.8 parts of antioxidant and 1.4-2.2 parts of anti ultraviolet agent；Flooring material of the present invention, by the cooperation humidification of other raw materials, has good anti-folding and anti-pressing, thermal coefficient low using waste plastic and manioc waste as raw material, good heat insulating, raw material sources are extensive, and production cost is low, waste in life is recycled simultaneously, it is environmentally protective.
Description
Technical field
The present invention relates to flooring material fields, and in particular to a kind of energy conservation and environmental protection novel floor material and preparation method thereof.
Background technique
Timber floor is from nineteen ninety-five till now after development in more than 20 years, and ground decoration effect warmth is naturally, solid resistance to
With in the traditional understanding of people, timber floor is exactly a kind of floor decorative material, other than material pattern, as not having
What considers reference, and with the raising of people's quality of the life, people are when choosing the floor decorative materials such as floor, other than stressing
It sees, timber floor, which lacks waterproofness, crack resistance and durability, also has become focus of attention.
Pure wooden floor is very poor on the durability of wetness and sunlight, and humidity enables floor expand, and after parching and can receive
Contracting causes the gap between floor to expand, and wearability is weaker, makes floor embrittlement, and flexibility, which weakens, influences service life and glossiness,
And the common disadvantage of always these materials is kept the temperature, while wood floors cause a large amount of trees felling to destroy ecological environments.Therefore
More and more composition floors replace Wood-plastic floor now.
Chinese patent CN1285449A discloses a kind of super-high wear-resistant and water soak resistance Strong floor and its manufacturing method,
Its wearing layer is manufactured gummed paper layer, decorations with melamine resin pure wood pulp paper of the dipping containing 5~30% corundum
Surface layer is so that melamine resin is impregnated containing the paper that 30~35% titanium dioxide needle and hardwood pulp form and is made
At gummed paper layer, sandwich layer is to impregnate twig wood pulp paper and manufactured gummed paper layer with phenolic resin.Above-mentioned technology makes laminated board exist
Wearability or corrosion resistance, crack resistance etc. are improved, but due to preparation method complexity, in actual production also
It is not used widely.
Chinese patent CN103275416A discloses a kind of Wood-plastic floor, including base layer, the material packet of the base layer
PVC powder, plasticizer, Plant Powder and stabilizer are included, repressed method is made, and preparation method is simple, but the flame retardant property of material is not
Enough excellent, there are some potential safety problemss.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of energy conservation and environmental protection novel floor material and its preparations
Method, flooring material of the present invention, by the cooperation humidification of other raw materials, have good using waste plastic and manioc waste as raw material
Anti-folding and anti-pressing well, thermal coefficient are low, and good heat insulating, raw material sources are extensive, and production cost is low, while recycling life
Middle waste, it is environmentally protective.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
8-15 parts of waste polyethylene plastic, 22-28 parts of waste polyurethane foamed plastics, changes 12-18 parts of waste phenolic resin
Property 8-15 parts of bamboo charcoal powder, modified manioc waste 30-42 parts, 4-9 parts of negative ion powder, 8-15 parts of wollastonite powder, expanded perlite 12-18
Part, 15-22 parts of quartz sand, 5-10 parts of precipitated calcium carbonate, 12-18 parts of nano aluminium oxide, 4-8 parts of plasticizer, antioxidant 1.2-
1.8 parts and anti ultraviolet agent 1.4-2.2 parts.
Preferably, the raw material including following parts by weight meter：10-13 parts of waste polyethylene plastic, waste phenolic resin 14-16
Part, 24-26 parts of waste polyurethane foamed plastics, 10-13 parts of modified bamboo powdered carbon, modified manioc waste 34-38 parts, negative ion powder 5-8
Part, 10-13 parts of wollastonite powder, 14-16 parts of expanded perlite, 17-20 parts of quartz sand, 6-9 parts of precipitated calcium carbonate, nano aluminium oxide
14-16 parts, 5-7 parts of plasticizer, 1.4-1.6 parts of antioxidant and 1.6-1.9 parts of anti ultraviolet agent.
Preferably, the raw material including following parts by weight meter：12 parts of waste polyethylene plastic, is given up at 15 parts of waste phenolic resin
Abandon 25 parts of polyurethane foam plastics, 12 parts of modified bamboo powdered carbon, modified 36 parts of manioc waste, 7 parts of negative ion powder, 12 parts of wollastonite powder, swollen
15 parts of swollen perlite, 19 parts of quartz sand, 8 parts of precipitated calcium carbonate, 15 parts of nano aluminium oxide, 6 parts of plasticizer, 1.5 parts of antioxidant
With 1.8 parts of anti ultraviolet agent.
Preferably, the modification bamboo charcoal powder, preparation method thereof is taking-up after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution
Filtrate is washed to neutrality, is calcined 4-6 hours under 400-450 degrees Celsius, places and ground in ball mill, cross 400-500 mesh.
Preferably, the manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 4-5；
(b) manioc waste is placed in 100-110 degrees Celsius of dryer and is dried to water content lower than 2%, step (a) system is added
In the silane coupling agent -ol solution obtained, it is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, is put into 100-110
Degree Celsius dryer in dry to constant weight, be put into pulverizer and crush, cross 150-300 mesh.
Preferably, the mass ratio of the manioc waste and silane coupling agent is 100:3-5.
Preferably, the plasticizer is o-phthalic acid dibutyl ester, epoxidized soybean oil, dibutyl phthalate and lemon
One or more of sour tributyl mixing composition.
Preferably, the antioxidant is β-((3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester, β-
One of (3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester and three (2,4- di-tert-butyl-phenyl) phosphites
Or several combinations.
Preferably, the anti ultraviolet agent is 2-hydroxy-4-n-octoxybenzophenone, 2- hydroxyl -4- methoxyl group hexichol first
Ketone, 2- (2- hydroxyl -3,5- di-tert-butyl-phenyl) -5- chlorobenzotriazole and 2- (2- hydroxyl -5- (1,1,3,3- tetramethyl butyl)
Phenyl) one or more of benzotriazole combines.
A kind of preparation method of energy conservation and environmental protection novel floor material is also disclosed in the present invention, specifically, including following step
Suddenly：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, 60-70 degrees Celsius is warming up to, with 800-1000 revs/min of speed
Degree mixing 30-40 minutes, obtains mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 145-152 degrees Celsius of hot pressing temperature, hot pressing time 6-
It is 12 minutes, cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
The present invention has following beneficial effect：
(1) flooring material of the present invention is using waste plastic and manioc waste as raw material, by the cooperation humidification of other raw materials,
Low with good anti-folding and anti-pressing, thermal coefficient, good heat insulating, raw material sources are extensive, and production cost is low, while recycling benefit
It is environmentally protective with waste in life.
(2) manioc waste makes the waste generated in alcoholic fermentation, after modification, as flooring material raw material, tool
There are good corrosion resistance and weatherability, while the stretch-resistance and mechanical tenacity of waste plastic can be improved.
(3) negative ion powder and modified bamboo powdered carbon are added in the present invention, and there is good antibiotic property, can adsorb in air
Harmful substance purifies air, environmentally protective, and the bamboo charcoal powder after leading to peracid treatment and high-temperature process, the specific surface area of enhancing improves
The adsorption capacity and detergent power of bamboo charcoal powder.
(4) nano aluminium oxide is added in the present invention as fire retardant has good flame retardant effect, while can be filled into
The compactness of reinforcing material in the gap of material improves the structural stability and mechanical property of material.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
8 parts of waste polyethylene plastic, 12 parts of waste phenolic resin, 22 parts of waste polyurethane foamed plastics, modified bamboo powdered carbon 8
Part, modified 30 parts of manioc waste, 4 parts of negative ion powder, 8 parts of wollastonite powder, 12 parts of expanded perlite, 15 parts of quartz sand, precipitated calcium carbonate 5
Part, 12 parts of nano aluminium oxide, 4 parts of plasticizer, 1.2 parts of antioxidant and 1.4 parts of anti ultraviolet agent.
Modification bamboo charcoal powder, preparation method thereof is after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution, to take out and wash filtrate extremely
Neutrality is calcined 4-6 hours under 400 degrees Celsius, is placed and is ground in ball mill, and 400 meshes are crossed.
Manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 4；
(b) manioc waste is placed in 100 degrees Celsius of dryers and is dried to water content lower than 2%, it is obtained that step (a) is added
It in silane coupling agent -ol solution, is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, is put into 100 degrees Celsius
It dries in dryer to constant weight, is put into pulverizer and crushes, cross 150 meshes.
The mass ratio of manioc waste and silane coupling agent is 100:3.
Plasticizer is o-phthalic acid dibutyl ester.
Antioxidant is β-((3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.
Anti ultraviolet agent is 2-hydroxy-4-n-octoxybenzophenone.
The preparation method of energy conservation and environmental protection novel floor material in the present embodiment specifically includes the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, is warming up to 60 degrees Celsius, mix 30 with 800 revs/min of speed
Minute, obtain mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 145 degrees Celsius of hot pressing temperature, hot pressing time 6 minutes,
It is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
Embodiment 2
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
15 parts of waste polyethylene plastic, 18 parts of waste phenolic resin, 28 parts of waste polyurethane foamed plastics, modified bamboo powdered carbon
15 parts, modified 42 parts of manioc waste, 9 parts of negative ion powder, 15 parts of wollastonite powder, 18 parts of expanded perlite, 22 parts of quartz sand, lightweight carbonic acid
10 parts of calcium, 18 parts of nano aluminium oxide, 8 parts of plasticizer, 1.8 parts of antioxidant and 2.2 parts of anti ultraviolet agent.
Modification bamboo charcoal powder, preparation method thereof is after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution, to take out and wash filtrate extremely
Neutrality is calcined 6 hours under 450 degrees Celsius, is placed and is ground in ball mill, and 500 meshes are crossed.
Preferably, the manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 4-5；
(b) manioc waste is placed in 110 degrees Celsius of dryers and is dried to water content lower than 2%, it is obtained that step (a) is added
It in silane coupling agent -ol solution, is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, is put into 110 degrees Celsius
It dries in dryer to constant weight, is put into pulverizer and crushes, cross 300 meshes.
The mass ratio of manioc waste and silane coupling agent is 100:5.
Plasticizer is epoxidized soybean oil.
Antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester.
Anti ultraviolet agent is ESCALOL 567.
The preparation method of energy conservation and environmental protection novel floor material in the present embodiment specifically includes the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, is warming up to 70 degrees Celsius, mix 40 with 1000 revs/min of speed
Minute, obtain mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 152 degrees Celsius of hot pressing temperature, hot pressing time 12 minutes,
It is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
Embodiment 3
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
10 parts of waste polyethylene plastic, 14 parts of waste phenolic resin, 24 parts of waste polyurethane foamed plastics, modified bamboo powdered carbon
10 parts, modified 34 parts of manioc waste, 5 parts of negative ion powder, 10 parts of wollastonite powder, 14 parts of expanded perlite, 17 parts of quartz sand, lightweight carbonic acid
6 parts of calcium, 14 parts of nano aluminium oxide, 5 parts of plasticizer, 1.4 parts of antioxidant and 1.6 parts of anti ultraviolet agent.
Modification bamboo charcoal powder, preparation method thereof is after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution, to take out and wash filtrate extremely
Neutrality is calcined 5 hours under 420 degrees Celsius, is placed and is ground in ball mill, and 450 meshes are crossed.
Manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 5；
(b) manioc waste is placed in 105 degrees Celsius of dryers and is dried to water content lower than 2%, it is obtained that step (a) is added
It in silane coupling agent -ol solution, is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, is put into 105 degrees Celsius
It dries in dryer to constant weight, is put into pulverizer and crushes, cross 200 meshes.
The mass ratio of manioc waste and silane coupling agent is 100:4.
Plasticizer is dibutyl phthalate.
Antioxidant is three (2,4- di-tert-butyl-phenyl) phosphites.
Anti ultraviolet agent is 2- (2- hydroxyl -3,5- di-tert-butyl-phenyl) -5- chlorobenzotriazole.
The preparation method of energy conservation and environmental protection novel floor material in the present embodiment specifically includes the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, is warming up to 65 degrees Celsius, mix 38 with 900 revs/min of speed
Minute, obtain mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 148 degrees Celsius of hot pressing temperature, hot pressing time 10 minutes,
It is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
Embodiment 4
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
13 parts of waste polyethylene plastic, 16 parts of waste phenolic resin, 26 parts of waste polyurethane foamed plastics, modified bamboo powdered carbon
13 parts, modified 38 parts of manioc waste, 8 parts of negative ion powder, 13 parts of wollastonite powder, 16 parts of expanded perlite, 20 parts of quartz sand, lightweight carbonic acid
9 parts of calcium, 16 parts of nano aluminium oxide, 7 parts of plasticizer, 1.6 parts of antioxidant and 1.9 parts of anti ultraviolet agent.
Modification bamboo charcoal powder, preparation method thereof is after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution, to take out and wash filtrate extremely
Neutrality is calcined 4.8 hours under 440 degrees Celsius, is placed and is ground in ball mill, and 420 meshes are crossed.
Manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 4.5；
(b) manioc waste is placed in 109 degrees Celsius of dryers and is dried to water content lower than 2%, it is obtained that step (a) is added
It in silane coupling agent -ol solution, is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, is put into 106 degrees Celsius
It dries in dryer to constant weight, is put into pulverizer and crushes, cross 250 meshes.
Preferably, the mass ratio of the manioc waste and silane coupling agent is 100:3.5.
Plasticizer is tributyl citrate.
Antioxidant is β-((3,5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.
Anti ultraviolet agent is 2- (2- hydroxyl -5- (1,1,3,3- tetramethyl butyl) phenyl) benzotriazole.
The preparation method of energy conservation and environmental protection novel floor material in the present embodiment specifically includes the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, is warming up to 68 degrees Celsius, mix 38 with 950 revs/min of speed
Minute, obtain mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 151 degrees Celsius of hot pressing temperature, hot pressing time 10 minutes,
It is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
Embodiment 5
A kind of energy conservation and environmental protection novel floor material, the raw material including following parts by weight meter：
12 parts of waste polyethylene plastic, 15 parts of waste phenolic resin, 25 parts of waste polyurethane foamed plastics, modified bamboo powdered carbon
12 parts, modified 36 parts of manioc waste, 7 parts of negative ion powder, 12 parts of wollastonite powder, 15 parts of expanded perlite, 19 parts of quartz sand, lightweight carbonic acid
8 parts of calcium, 15 parts of nano aluminium oxide, 6 parts of plasticizer, 1.5 parts of antioxidant and 1.8 parts of anti ultraviolet agent.
Modification bamboo charcoal powder, preparation method thereof is after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution, to take out and wash filtrate extremely
Neutrality is calcined 5.5 hours under 440 degrees Celsius, is placed and is ground in ball mill, and 470 meshes are crossed.
Manioc waste preparation method is as follows：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly and is configured to silane coupling agent -ol
Solution adds suitable glacial acetic acid to adjust solution pH value to 4.8；
(b) manioc waste is placed in 100-110 degrees Celsius of dryer and is dried to water content lower than 2%, step (a) system is added
In the silane coupling agent -ol solution obtained, it is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, it is Celsius to be put into 105
It dries in the dryer of degree to constant weight, is put into pulverizer and crushes, cross 280 meshes.
The mass ratio of manioc waste and silane coupling agent is 100:4.6.
Plasticizer is o-phthalic acid dibutyl ester.
Antioxidant is β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester.
Anti ultraviolet agent is 2-hydroxy-4-n-octoxybenzophenone.
The preparation method of energy conservation and environmental protection novel floor material in the present embodiment specifically includes the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and anti-
Ultraviolet dose of mixing is added to the mixer and is stirred, and obtains material 1；
(2) material 1 and other surplus stocks are mixed, is warming up to 68 degrees Celsius, mix 38 with 900 revs/min of speed
Minute, obtain mixed material；
(3) will mixed material be added mold in carry out it is hot-forming, 147 degrees Celsius of hot pressing temperature, hot pressing time 10 minutes,
It is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
Comparative example 1：Modified manioc waste is substituted with common manioc waste, remaining raw material is identical as preparation method and embodiment 1；
Flooring material made from energy conservation and environmental protection novel floor material made from embodiment 1-5 and comparative example 1 is subjected to performance
Test, as a result such as the following table 1：
In conclusion the present invention has the following advantages that：
(1) flooring material of the present invention is using waste plastic and manioc waste as raw material, by the cooperation humidification of other raw materials,
Low with good anti-folding and anti-pressing, thermal coefficient, good heat insulating, raw material sources are extensive, and production cost is low, while recycling benefit
It is environmentally protective with waste in life.
(2) manioc waste makes the waste generated in alcoholic fermentation, after modification, as flooring material raw material, tool
There are good corrosion resistance and weatherability, while the stretch-resistance and mechanical tenacity of waste plastic can be improved.
(3) negative ion powder and modified bamboo powdered carbon are added in the present invention, and there is good antibiotic property, can adsorb in air
Harmful substance purifies air, environmentally protective, and the bamboo charcoal powder after leading to peracid treatment and high-temperature process, the specific surface area of enhancing improves
The adsorption capacity and detergent power of bamboo charcoal powder.
(4) nano aluminium oxide is added in the present invention as fire retardant has good flame retardant effect, while can be filled into
The compactness of reinforcing material in the gap of material improves the structural stability and mechanical property of material.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of energy conservation and environmental protection novel floor material, which is characterized in that the raw material including following parts by weight meter：Waste polyethylene modeling
8-15 parts of material, 22-28 parts of waste polyurethane foamed plastics, 8-15 parts of modified bamboo powdered carbon, is modified 12-18 parts of waste phenolic resin
30-42 parts of manioc waste, 4-9 parts of negative ion powder, 8-15 parts of wollastonite powder, 12-18 parts of expanded perlite, 15-22 parts of quartz sand, lightweight
5-10 parts of calcium carbonate, 12-18 parts of nano aluminium oxide, 4-8 parts of plasticizer, 1.2-1.8 parts of antioxidant and anti ultraviolet agent 1.4-2.2
Part.
2. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the original including following parts by weight meter
Material：10-13 parts of waste polyethylene plastic, 14-16 parts of waste phenolic resin, 24-26 parts of waste polyurethane foamed plastics, modified bamboo
10-13 parts of powdered carbon, manioc waste 34-38 parts modified, 5-8 parts of negative ion powder, 10-13 parts of wollastonite powder, 14-16 parts of expanded perlite,
17-20 parts of quartz sand, 6-9 parts of precipitated calcium carbonate, 14-16 parts of nano aluminium oxide, 5-7 parts of plasticizer, 1.4-1.6 parts of antioxidant
With 1.6-1.9 parts of anti ultraviolet agent.
3. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the original including following parts by weight meter
Material：12 parts of waste polyethylene plastic, 15 parts of waste phenolic resin, 25 parts of waste polyurethane foamed plastics, 12 parts of modified bamboo powdered carbon,
Modified 36 parts of manioc waste, 7 parts of negative ion powder, 12 parts of wollastonite powder, 15 parts of expanded perlite, 19 parts of quartz sand, precipitated calcium carbonate 8
Part, 15 parts of nano aluminium oxide, 6 parts of plasticizer, 1.5 parts of antioxidant and 1.8 parts of anti ultraviolet agent.
4. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that modified bamboo powdered carbon preparation side
Method is to take out after being put into bamboo charcoal and impregnating 5 hours in glacial acetic acid solution and wash filtrate to neutrality, under 400-450 degrees Celsius
Calcining 4-6 hours is placed and is ground in ball mill, and 400-500 mesh is crossed.
5. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the manioc waste preparation method is such as
Under：
(a) by silane coupling agent and ethyl alcohol according to 1:10 mass ratio mixing, stirs evenly that be configured to silane coupling agent -ol molten
Liquid adds suitable glacial acetic acid to adjust solution pH value to 4-5；
(b) manioc waste is placed in 100-110 degrees Celsius of dryer and is dried to water content lower than 2%, it is obtained that step (a) is added
It in silane coupling agent -ol solution, is uniformly mixed, is warming up to 78 degrees Celsius, ultrasonic activation 2 hours, it is Celsius to be put into 100-110
It dries in the dryer of degree to constant weight, is put into pulverizer and crushes, cross 150-300 mesh.
6. energy conservation and environmental protection novel floor material according to claim 5, which is characterized in that the manioc waste and silane coupled
The mass ratio of agent is 100:3-5.
7. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the plasticizer is O-phthalic
One or more of sour dibutyl ester, epoxidized soybean oil, dibutyl phthalate and tributyl citrate mixing composition.
8. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the antioxidant be β-((3,
5- di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester, β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol
One or more of ester and three (2,4- di-tert-butyl-phenyl) phosphites combine.
9. energy conservation and environmental protection novel floor material according to claim 1, which is characterized in that the anti ultraviolet agent is 2- hydroxyl
Base -4- oxy-octyl benzophenone, ESCALOL 567,2- (2- hydroxyl -3,5- di-tert-butyl-phenyl) -5-
One or more of chlorobenzotriazole and 2- (2- hydroxyl -5- (1,1,3,3- tetramethyl butyl) phenyl) benzotriazole combine.
10. a kind of preparation method of such as described in any item energy conservation and environmental protection novel floor materials of claim 1-9, feature exist
In including the following steps：
(1) by waste polyethylene plastic, waste phenolic resin, waste polyurethane foamed plastics, plasticizer, antioxidant and uvioresistant
Agent mixing, which is added to the mixer, to be stirred, and material 1 is obtained；
(2) material 1 and other surplus stocks are mixed, is warming up to 60-70 degrees Celsius, it is mixed with 800-1000 revs/min of speed
It closes 30-40 minutes, obtains mixed material；
(3) mixed material is added in mold carry out it is hot-forming, 145-152 degrees Celsius of hot pressing temperature, hot pressing time 6-12 point
Clock, it is cooling to set room temperature, it conserves to get energy conservation and environmental protection novel floor material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810831291.7A CN108911575A (en) | 2018-07-26 | 2018-07-26 | A kind of energy conservation and environmental protection novel floor material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810831291.7A CN108911575A (en) | 2018-07-26 | 2018-07-26 | A kind of energy conservation and environmental protection novel floor material and preparation method thereof |
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| CN108911575A true CN108911575A (en) | 2018-11-30 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109736540A (en) * | 2019-02-28 | 2019-05-10 | 扬州富铭新材料有限公司 | A kind of environment-friendly type floor and its production method |
| CN111305508A (en) * | 2020-02-18 | 2020-06-19 | 微山宏瑞电力科技有限公司 | Moisture-resistant self-disinfection environment-friendly sound insulation floor and manufacturing method thereof |
| CN111980187A (en) * | 2019-05-24 | 2020-11-24 | 北京仁创科技集团有限公司 | Sand plastic plate with functional assembly |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107265998A (en) * | 2017-06-22 | 2017-10-20 | 合肥励仙电力工程有限公司 | A kind of floor of energy-conserving and environment-protective and preparation method thereof |
-
2018
- 2018-07-26 CN CN201810831291.7A patent/CN108911575A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107265998A (en) * | 2017-06-22 | 2017-10-20 | 合肥励仙电力工程有限公司 | A kind of floor of energy-conserving and environment-protective and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109736540A (en) * | 2019-02-28 | 2019-05-10 | 扬州富铭新材料有限公司 | A kind of environment-friendly type floor and its production method |
| CN111980187A (en) * | 2019-05-24 | 2020-11-24 | 北京仁创科技集团有限公司 | Sand plastic plate with functional assembly |
| CN111980187B (en) * | 2019-05-24 | 2022-03-22 | 北京仁创科技集团有限公司 | Sand plastic plate with functional assembly |
| CN111305508A (en) * | 2020-02-18 | 2020-06-19 | 微山宏瑞电力科技有限公司 | Moisture-resistant self-disinfection environment-friendly sound insulation floor and manufacturing method thereof |
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