CN106635539A - Antibacterial skin-moisturizing soap and preparation method thereof - Google Patents
Antibacterial skin-moisturizing soap and preparation method thereof Download PDFInfo
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- CN106635539A CN106635539A CN201611073071.XA CN201611073071A CN106635539A CN 106635539 A CN106635539 A CN 106635539A CN 201611073071 A CN201611073071 A CN 201611073071A CN 106635539 A CN106635539 A CN 106635539A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/18—Water-insoluble compounds
Abstract
The invention discloses an antibacterial skin-moisturizing soap. The prepared soap comprises the following raw materials in parts by weight: 30-40 parts of fresh aloe, 15-20 parts of fresh purslane, 10-16 parts of herba houttuyniae, 8-12 parts of common andrographis herb, 4-8 parts of juniper berries, 6-10 parts of eucalyptus globulus, 1-3 parts of picrasma quassioides, 4-8 parts of mahonia bealei roots, 6-12 parts of Chinese galls, 3-7 parts of coptis chinensis, 4-6 parts of prepared liquorice, 4-6 parts of titanium dioxide/activated carbon composite particles, 1-3 parts of rose essential oil and 220-250 parts of a soap base; the titanium dioxide/activated carbon composite particles are prepared by carbonizing, pickling and crushing electrospunbite nanometer particles/titanium dioxide fibers. The soap can effectively inhibit and kill a variety of pathogenic bacteria while removing stains, is mild in formula and can play roles in moisturizing and protecting skin while cleaning the skin.
Description
Technical field
The invention belongs to field of hygiene products, and in particular to a kind of antibacterial fancy soap for moistening skin and preparation method thereof.
Background technology
Perfumed soap is one of skin, hair washing and nursing article, is a kind of indispensable daily washing product, and it is with fat
Sour sodium and other surfaces activating agent are primary raw material, addition quality improver and appearance modifying agents, are made after machine-shaping
Product, be a kind of daily necessities.People can trace back to B.C. Italy using the history of perfumed soap.From the eighties
Start, China gradually starts to widely use perfumed soap.In prospect of Chinese washing products, fragrant soap still has certain market demand, especially
In vast rural area and outlying district, people wash one's face, to take a shower still be accustomed to and use perfumed soap, in populous China, condition from every side
Consider, perfumed soap, soap are no fleeting product, corresponding development should be obtained and improved.In over nearly more than 10 year
State's synthetic detergent is annual still with 8% speed increase.So the articles for washing of China is particularly various synthetic detergent products
Still have an optimistic view of in foreseeable future.However, with the improvement of people's living standards, the enhancing of health perception, for perfumed soap,
People have no longer only been merely to pursue good this characteristic of washing clean effect, and the perfumed soap with bactericidal effect is then more by popular blue or green
Look at, and the not strong shortcoming of existing perfumed soap generally existing sterilizing ability, in the market the perfumed soap one with certain bactericidal effect
As alkalescence it is relatively strong, Long-Time Service can pass through machinery and chemical action wash away the angling confluent monolayer cells of skin surface, promote cell division
Hyperplasia, damages to skin.
The content of the invention
It is an object of the invention to overcome prior art not enough, there is provided a kind of antibacterial fancy soap for moistening skin and preparation method thereof, should
Perfumed soap can effectively suppress to kill various pathogenic bacteria while spot is removed, and it is gentle to fill a prescription, can be in the same of cleaning skin
When, play effect of moistening skin-care.
To achieve these goals, the technical scheme that the present invention is provided is as follows：
A kind of antibacterial fancy soap for moistening skin, the raw material and its parts by weight for making the perfumed soap be：Aloe fresh goods 30-40 part, horse
Bitterroot fresh goods 15-20 part, cordate houttuynia 10-16 parts, Herba Andrographitis 8-12 parts, needle juniper fruit 4-8 parts, blue gum 6-10 parts, quassia 1-3 parts,
Mahonia bealei root 4-8 parts, Chinese gall 6-12 parts, coptis 3-7 parts, honey-fried licorice root 4-6 parts, compound of Titanium dioxide/active carbon
Grain 4-6 parts, Rosa Damascana 1-3 parts, soap base 220-250 parts；Described Titanium dioxide/active carbon composite particles are received by electrospinning Enteromorpha
Rice grain/titania fiber Jing carbonizations, pickling, crushing are obtained.
Preferably, the raw material and its parts by weight for making the perfumed soap be：35 parts of aloe fresh goods, 17 parts of purslane fresh goods,
13 parts of cordate houttuynia, 10 parts of Herba Andrographitis, 6 parts of needle juniper fruit, 8 parts of blue gum, 2 parts of quassia, 6 parts of mahonia bealei root, 9 parts of Chinese gall,
5 parts of the coptis, 5 parts of honey-fried licorice root, 5 parts of Titanium dioxide/active carbon composite particles, 2 parts of Rosa Damascana, 233 parts of soap base.
Preferably, described Titanium dioxide/active carbon composite particles are obtained by following methods：
(1) Enteromorpha nanometer dry powder is prepared：The cleaning of Enteromorpha fresh goods removes the impurity such as the grains of sand, and Jing natural air dryings or freeze-drying are obtained
Dry product, gained dry product ultramicro grinding to powder and micron it is last be placed in ball grinder carry out high-energy ball milling post-drying obtain Enteromorpha nanometer do
Powder；
(2) spinning precursor liquid is prepared：Prepare containing tetrabutyl titanate, the Enteromorpha nanometer dry powder of gained in step (1), anhydrous
Ethanol, the high molecular polymer for being dissolved in ethanol, the uniform suspension of organic acid are used as spinning precursor liquid；
(3) electrospinning preparation tunica fibrosa：Spinning precursor liquid obtained by step (2) adds the liquid storage mechanism of electrostatic spinning apparatus
In, spinning nozzle connection high-voltage power cathode, collector connection high voltage power supply negative pole, adjusting spinning voltage and spinning distance is carried out
Electrostatic spinning, spinning precursor liquid forms tunica fibrosa and is preparation tunica fibrosa in the presence of electric field force on collector；
(4) high-temperature heat treatment：Preparation fibre film Jing high-temperature heat treatments under anoxic or oxygen-free environment of gained make in step (3)
Enteromorpha nanometer dry powder is carbonized to obtain activated carbon, and the high molecular polymer and remnants that the process is eliminated in prepared tunica fibrosa simultaneously is molten
Agent, obtains Enteromorpha activated carbon/dioxide composite nanofiber film；
(5) pickling impurity removal：By sample Jing molar concentrations 5mol/L obtained by step (4) under the constant temperature that temperature is 60 DEG C
Salt acid soak is taken out sample from acid solution with removing impurity for 10 hours, then is soaked in deionized water every 2 hours more
Change and once soak the deionized water of sample, and test the ph values of the deionized water for soaking sample, to soaked sample go from
When sub- water is neutral, sample is taken out to be placed in 60 DEG C of baking ovens and is dried；
(6) pulverized particles：Drying sample Jing ultramicro grindings obtained by step (5) to 2000 mesh powder are obtained into titanium dioxide
Titanium/activated carbon composite particles.
In order to while effective decontamination, safely and effectively play a part of to suppress to kill pathogenic bacteria, the perfumed soap of the present invention
In with the addition of Titanium dioxide/active carbon composite particles, the photocatalysis antibacterial material with titanium dioxide as representative is that have weight at present
Want the inorganic antiseptic of researching value and wide DEVELOPMENT PROSPECT.Titanium dioxide has photocatalytic effect, and being excited by light makes valence band
To conduction band, the electronics that is excited in conduction band has strong reproducibility, and the hole of valence band has strong oxidability for electron transition, from
And can play a part of to kill suppression bacterium.By containing tetrabutyl titanate, Enteromorpha nanometer dry powder, absolute ethyl alcohol, be dissolved in ethanol
High molecular polymer, preparation tunica fibrosa obtained in the spinning precursor liquid method of electrostatic spinning of organic acid be TiO2/ high molecular polymerization
The tunica fibrosa that thing/Enteromorpha nano particle (Enteromorpha nanometer dry powder) composite nano fiber is constituted, wherein Enteromorpha nano particle is uniformly embedding
In TiO2In/high molecular polymer composite nano fiber, the preparation fibre film of gained is under anoxic or oxygen free condition at the high warms of Jing
Reason, makes Enteromorpha nano particle be carbonized into the activated carbon nano particle of porous, and heat treatment process is eliminated in prepared tunica fibrosa simultaneously
High molecular polymer and residual solvent, be uniformly embedded with the polycrystalline Titanium dioxide/active carbon of Enteromorpha activated carbon nano particle
Nano fibrous membrane, then through the Titanium dioxide/active carbon composite particles obtained by pickling impurity removal, ultramicro grinding, combine titanium dioxide
The advantage performance of titanium and Enteromorpha activated carbon, Enteromorpha activated carbon granule has preferable suction-operated, can effectively improve the perfumed soap
Clean effect, while improve the sterilization effect of titanium dioxide by this adsorption effect, and by electrostatic spinning technique and ultra micro
The composite particles of micro/nano level obtained in crushing technology have larger specific surface area, can fill with skin during washing
Tap is touched, and improves decontamination and bactericidal effect, and the Enteromorpha activated carbon granule that composite particles are embedded with is carbonized by Enteromorpha nano particle
To the activated carbon granule of nano-scale, the adsorption capacity of absorbent charcoal material because its hole has absorption potential, be by carbon molecule with
The gravitation of adsorbed molecule and formed, aperture is less, and absorption potential is stronger, and the adsorption capacity of absorbent charcoal material is stronger, therefore
Compared to Enteromorpha activated carbon obtained in commonsense method, the hole of the activated carbon granule of this Nano grade is less, with higher
Adsorption capacity, can effectively strengthen composite suction-operated, and the preparation method of the composite particles is simpler, and product property is superior,
And coastal waters Enteromorpha resource is taken full advantage of, turn waste into wealth.This composite particles are uniformly distributed in the perfumed soap of the present invention so that fragrant
Soap in the case where formula is gentle, with preferable decontamination bacteria-eliminating efficacy.On the other hand, in order to further improve the anti-of the perfumed soap
Bacterium fungistatic effect, adds Chinese medicine antibacterial composition, in making the Chinese medicine material medicine of the perfumed soap simultaneously in the perfumed soap of the present invention：
Aloe：Heat-clearing cool liver, rushes down lower desinsection.Hydroxy kind, anthraquinone derivatives such as aloe-emodin contained by it etc. is organic
Tool more than active component is killed, presses down skin surface bacterial action, and complex polysaccharide and organic acid are natural moisturizing elements, can supplement skin
The moisture lost in skin, repairs Skin Cell.
Purslane：It is cold in nature, sweet acid；Enter the heart, liver, spleen, large intestine channel.With hygroscopic is antipruritic, it is clearing heat for detumescence, clearing heat and detoxicating,
Li Shui dries, and dissipates blood detumescence, dust-collection sterilization, anti-inflammatory analgetic, the effect of blood-stanching and blood-cooling.Purslane is to shigella dysenteriae, typhoid bacillus
There is stronger inhibitory action with Escherichia coli, can be used for the auxiliary treatment of various inflammation, have the title of " natural antibiotics ", while
Purslane is also rich in vitamin C, and vitamin C has the good antioxidation can be with whitening nourishes rough skin.
Cordate houttuynia：Cold nature, bitter, energy drop-down of trembling with fear, pungent with dissipating bind, main return lung Jing is good at removing summer-heat lung heat, while and having
There is the carbuncle apocenosis that disappears, can treat the hot carbuncle lung of phlegm, pectoralgia coughs that vomiting of pus and blood is stench and the disease such as phlegm-heat cough.Additionally due to it was both
Can be clearing heat and detoxicating, can disappear carbuncle apocenosis again, so and be usually used in the diseases such as surgery ulcerative carbuncle pyogenic infections and then treat, decanoy acetaldehyde is to golden yellow Portugal
Grape sugar ball bacterium, staphylococcus albus, shigella dysenteriae, pseudomonas aeruginosa, proteus, paracolon, Grain-positive brood cell
Bacillus etc. has certain inhibitory action, and stronger to staphylococcus inhibitory action；
Herba Andrographitis：It is clearing heat and detoxicating, cool blood detumescence.Control acute bacillary dysentery, gastroenteritis, flu, epidemic meningitis, tracheitis, pneumonia, one hundred days
Cough, pulmonary tuberculosis, lung abscess, cholecystitis, hypertension, nosebleed epistaxis, oropharynx swells and ache, boil carbuncle swells, scald, venomous snake bite, punching
Contained neoandrographolide is clinically excellent compared with chloramphenicol and furazolidone to the curative effect of bacillary dysentery in lotus, and is had no side effect
And toxicity, in vitro test, Herba Andrographitis water decoction and from the coarse crystallization wherein isolated, leptospiral some types are had
Suppress or killing action, decoction has certain inhibitory action to pneumococcus, first streptococcus and micrococcus catarrhalis；
Needle juniper fruit：Antibacterial, convergence, promotion scab, purify, sterilizing, sharp nerve, desinsection, midwifery；Cure mainly pore obstruction, skin
Skin is scorching, flow soup eczema, chronic eczema and swelling；
Blue gum：Taste micro-pungent, slight bitter, it is mild-natured.Dispelling wind is antipyretic, and inhibiting bacteria and diminishing inflammation, anti-corrosion is antipruritic.For prevent influenza,
Meningococal meningitis, controls the infection of the upper respiratory tract, sphagitis, bronchitis, pneumonia, Acute and chronic pyelonephritis, enteritis, dysentery
Disease, filariasis；Burn and scald, cellulitis, mastitis, furuncle, erysipelas, paddy-field dermatitis, skin eczema, the ringworm of the foot, skin are controlled in external application
Sterilization；
Quassia：Nature and flavor bitter cold, with the effect of heat-clearing, clearing damp, removing toxic substances, for anemopyretic cold, abscess of throat, under diarrhoea
Dysentery, eczema, boil, venomous snake bite, quassia is natural with antibacterial action, the quassia product of unprocessed mistake, shigella dysenteriae, typhoid fever
Bacillus, hepatitis B can not survive completely；
Mahonia bealei root：Heat-clearing, eliminating dampness, removing toxic substances, main cough with lung heat, jaundice is had loose bowels, dysentery, red eye, swell pain, sore
Ulcer, eczema is scalded；
Chinese gall：Cold in nature, taste is sour, puckery, main the effects such as with fall fire of astringing the lung, relieving diarrhea with astringents, arrest sweating hemostasis, hygroscopic sore
The diseases such as chronic cough of deficiency lung, protracted dysentery and diarrhea, hemorrhoid blood of having blood in stool, carbuncle sore tumefacting virus, skin moisture fester are controlled, Chinese gall decoction is to Staphylococcus aureus
Bacterium, beta hemolytic streptococcus, pneumococcus, Pseudomonas aeruginosa, shigella dysenteriae, bacillus anthracis, corynebacterium diphtheriae, Escherichia coli, wound
Cold and paratyphosum Bacterium etc. has obvious antibacterial and bactericidal action；
The coptis：Heat-clearing and damp-drying drug, purging intense heat and detonicating, desinsection is antipruritic, for damp and hot feeling of fullness, vomits acid regurgitation, rush down dysentery, jaundice, hyperpyrexia
Coma, heart-fire hyperactivity, dysphoria and insomnia, blood-head tells nosebleed, hot eyes, toothache is quenched one's thirst, carbuncle swells furunculosis；Eczema, wet sore, duct stream are controlled outward
Purulence, the coptis has stronger antibacterial and anti-inflammation functions, double to staphylococcus aureus, hemolytic streptococcus, pneumococcus, meningitis
Coccus, shigella dysenteriae, bacillus anthracis etc. have good inhibiting effect；
Honey-fried licorice root：Containing various chemical compositions such as glycyrrhizin, enoxolone, licorice polysaccharide, with anti-inflammatory and resistance state
Reagentia, can adjust body's immunity, antitumor and analgesic effect, therefore the primary efficacy of honey-fried licorice root is and middle emergency,
Moistening lung, removing toxic substances, coordinating the drug actions of a prescription.
All taste bulk drug compatibilities are proper, and sharing can play stronger broad-spectrum sterilization effect, effectively kill and suppress all kinds of pathogenic
Bacterium, raw material the effective elements of the medicine and Titanium dioxide/active carbon composite particles collective effect, can play good bactericidal effect
Really, meanwhile, the complex polysaccharide and organic acid that aloe is rich in is again natural moisturizing element, can supplement the moisture of loss in skin, is repaiied
Multiple Skin Cell, the multivitamin being rich in purslane is effective antioxidant, with the effect for nourishing skin whitening, is made
Obtaining perfumed soap of the invention can play the effect of moistening skin-care while stain removal bactericidal.
Preferably, described step (1) prepares Enteromorpha nanometer dry powder：The cleaning of Enteromorpha fresh goods is removed after the impurity such as the grains of sand, cold
Lyophilized dry dry product, gained dry product ultramicro grinding is last to 500 mesh powder and microns, and gained micron powder is placed in ball grinder to be carried out
High-energy ball milling, wherein zirconia ball:Micron powder:The mass ratio of water is 8:4:1,2000 revs/min of rotating speed, Ball-milling Time 4 is little
When, gained powder is placed in 60 DEG C of baking ovens dries to obtain Enteromorpha nanometer dry powder.
Preferably, described step (2) prepares spinning precursor liquid：3.4g tetrabutyl titanates are added with 2g sulfosalicylic acids
In 9ml absolute ethyl alcohols, magnetic agitation adds the Enteromorpha nanometer dry powder obtained by 2.2g steps (1), magnetic force to stir after being well mixed within 1 hour
Mix 1 hour, be configured to suspension A；3.5g polyvinylpyrrolidones are added in 9ml absolute ethyl alcohols, and magnetic agitation mixing in 2 hours is equal
It is even to obtain solution B；After suspension A and solution B are mixed into magnetic agitation 40 minutes, ultrasonic vibration 10 minutes, after ultrasonic vibration again
Magnetic agitation 30 minutes, then ultrasonic vibration 10 minutes again, obtain final product uniform suspension for spinning precursor liquid.
Preferably, the spinning voltage in described step (3) electrospinning preparation tunica fibrosa is 22kV, and spinning distance is 18cm,
The spinning time is 15 minutes.
Preferably, described step (4) high-temperature heat treatment：The preparation fibre film of gained is placed in tube furnace in step (3),
Under nitrogen atmosphere, 500 DEG C are warming up to 3 DEG C/min, after being incubated 1 hour, are cooled to room temperature and take out sample, obtain final product Enteromorpha activity
Charcoal/dioxide composite nanofiber film.
The invention also discloses the preparation method of described antibacterial fancy soap for moistening skin, comprises the following steps：
1) cordate houttuynia, Herba Andrographitis, needle juniper fruit, blue gum, quassia, mahonia bealei root, Chinese gall, the coptis, honey-fried licorice root powder
50 mesh powder are broken to, the water for adding 5 times of mixed-powder gross mass multiple soaks 30 minutes, is cooked by slow fire 1 hour, crosses 200 mesh mistakes
Filter screen, takes filtrate, and the water that 4 times of mixed-powder gross mass is added again soaks 1 hour, is cooked by slow fire 1 hour, crosses 200 mesh and filters
Net, takes filtrate, merge filtrate twice be cooled to 60 ± 2 DEG C it is standby；
2) aloe, purslane clean after add step 1) gained filtrate mixing squeeze the juice after cross 200 mesh filter screen filtrations must filter
Liquid, gained filtrate dry to relative density for 1.25 ± 0.02 (60 DEG C) thick paste, gained thick paste be cooled to 55 ± 2 DEG C it is standby；
3) step 2) obtained by thick paste mix with Titanium dioxide/active carbon composite particles, Rosa Damascana, add soap base in,
Stir, Jing cooling shapings obtain final product antibacterial fancy soap for moistening skin.
Beneficial effects of the present invention are：The invention provides a kind of antibacterial fancy soap for moistening skin and preparation method thereof, the perfumed soap energy
It is enough effectively to suppress to kill various pathogenic bacteria while spot is removed, and it is gentle to fill a prescription, and can rise while cleaning skin
To effect of moistening skin-care.Specifically：
(1) pathogenic bacteria, the perfume (or spice) of the present invention are killed in order to while effective decontamination, safely and effectively play a part of suppression
Titanium dioxide/active carbon composite particles are with the addition of in soap, the photocatalysis antibacterial material with titanium dioxide as representative is that have at present
Important research is worth the inorganic antiseptic with wide DEVELOPMENT PROSPECT.Titanium dioxide has photocatalytic effect, and being excited by light makes valency
Having electronic transits to conduction band, and the electronics that is excited in conduction band has strong reproducibility, and the hole of valence band has strong oxidability,
Suppress bacterium such that it is able to play a part of to kill.By containing tetrabutyl titanate, Enteromorpha nanometer dry powder, absolute ethyl alcohol, be dissolved in second
Preparation tunica fibrosa is TiO obtained in the high molecular polymer of alcohol, the spinning precursor liquid method of electrostatic spinning of organic acid2/ polyphosphazene polymer
The tunica fibrosa that compound/Enteromorpha nano particle (Enteromorpha nanometer dry powder) composite nano fiber is constituted, wherein Enteromorpha nano particle is uniform
It is embedded in TiO2In/high molecular polymer composite nano fiber, the high warms of preparation fibre film Jing under anoxic or oxygen free condition of gained
Process, make Enteromorpha nano particle be carbonized into the activated carbon nano particle of porous, heat treatment process eliminates prepared tunica fibrosa simultaneously
In high molecular polymer and residual solvent, be uniformly embedded with many crystal titanium dioxide/activity of Enteromorpha activated carbon nano particle
Carbon nanofibers film, then through the Titanium dioxide/active carbon composite particles obtained by pickling impurity removal, ultramicro grinding, combine dioxy
Change the advantage performance of titanium and Enteromorpha activated carbon, Enteromorpha activated carbon granule has preferable suction-operated, can effectively improve the perfume
The clean effect of soap, while improving the sterilization effect of titanium dioxide by this adsorption effect, and by electrostatic spinning technique and surpasses
The composite particles of micro/nano level have larger specific surface area obtained in Crushing of Ultrafine technology, can during washing with skin
It is fully contacted, improves decontamination and bactericidal effect, the Enteromorpha activated carbon granule that composite particles are embedded with is carbonized by Enteromorpha nano particle
The activated carbon granule of nano-scale is obtained, the adsorption capacity of absorbent charcoal material, because its hole has absorption potential, is by carbon molecule
Formed with the gravitation of adsorbed molecule, aperture is less, and absorption potential is stronger, and the adsorption capacity of absorbent charcoal material is stronger, because
, compared to Enteromorpha activated carbon obtained in commonsense method, the hole of the activated carbon granule of this Nano grade is less, with higher for this
Adsorption capacity, can effectively strengthen composite suction-operated, the preparation method of the composite particles is simpler, and product property is excellent
More, and coastal waters Enteromorpha resource is taken full advantage of, is turned waste into wealth.This composite particles are uniformly distributed in the perfumed soap of the present invention, are made
Perfumed soap is obtained in the case where formula is gentle, with preferable decontamination bacteria-eliminating efficacy.
(2) in order to further improve the antibacterial bacteriostatic effect of the perfumed soap, add Chinese medicine in the perfumed soap of the present invention simultaneously and resist
Bacterium composition, all taste bulk drug compatibilities are proper, and sharing can play stronger broad-spectrum sterilization effect, effectively kill and suppress all kinds of pathogenic
Bacterium, raw material the effective elements of the medicine and Titanium dioxide/active carbon composite particles collective effect, can play good bactericidal effect
Really, meanwhile, the complex polysaccharide and organic acid that aloe is rich in is again natural moisturizing element, can supplement the moisture of loss in skin, is repaiied
Multiple Skin Cell, the multivitamin being rich in purslane is effective antioxidant, with the effect for nourishing skin whitening, is made
Obtaining perfumed soap of the invention can play the effect of moistening skin-care while stain removal bactericidal.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
Apply the specific material proportion described by example, process conditions and its result be merely to illustrate the present invention and should not also without limitation on
The present invention described in detail in claims.
Titanium dioxide/active carbon composite particles used in following examples are obtained by following methods：
(1) Enteromorpha nanometer dry powder is prepared：The cleaning of Enteromorpha fresh goods is removed after the impurity such as the grains of sand, and freeze-drying obtains dry product, gained
Dry product ultramicro grinding is last to 500 mesh powder and microns, and gained micron powder is placed in ball grinder carries out high-energy ball milling, wherein aoxidizing
Zirconium ball:Micron powder:The mass ratio of water is 8:4:1,2000 revs/min of rotating speed, Ball-milling Time 4 hours, gained powder is placed in 60
Enteromorpha nanometer dry powder is dried to obtain in DEG C baking oven；
(2) spinning precursor liquid is prepared：3.4g tetrabutyl titanates are added in 9ml absolute ethyl alcohols with 2g sulfosalicylic acids, magnetic force
Stirring adds the Enteromorpha nanometer dry powder obtained by 2.2g steps (1), magnetic agitation 1 hour to be configured to suspended after being well mixed within 1 hour
Liquid A；3.5g polyvinylpyrrolidones are added in 9ml absolute ethyl alcohols, and magnetic agitation is well mixed to obtain solution B in 2 hours；By suspension
A and solution B mixed magnetic agitation after 40 minutes, ultrasonic vibration 10 minutes, magnetic agitation 30 minutes again after ultrasonic vibration, then
Again ultrasonic vibration 10 minutes, obtain final product uniform suspension for spinning precursor liquid；
(3) electrospinning preparation tunica fibrosa：Spinning precursor liquid obtained by step (2) adds the liquid storage mechanism of electrostatic spinning apparatus
In, spinning nozzle connection high-voltage power cathode, collector connection high voltage power supply negative pole, adjusting spinning voltage and spinning distance is carried out
Electrostatic spinning, spinning precursor liquid forms tunica fibrosa as preparation tunica fibrosa in the presence of electric field force on collector, wherein, spin
Filament voltage is 22kV, and spinning distance is 18cm, and the spinning time is 15 minutes；
(4) high-temperature heat treatment：The preparation fibre film of gained is placed in tube furnace in step (3), in a nitrogen atmosphere, with 3 DEG C/
Minute is warming up to 500 DEG C, after insulation 1 hour, is cooled to room temperature and takes out sample, obtains final product that Enteromorpha activated carbon/titanium dioxide is compound to be received
Rice tunica fibrosa；
(5) pickling impurity removal：By sample Jing molar concentrations 5mol/L obtained by step (4) under the constant temperature that temperature is 60 DEG C
Salt acid soak is taken out sample from acid solution with removing impurity for 10 hours, then is soaked in deionized water every 2 hours more
Change and once soak the deionized water of sample, and test the ph values of the deionized water for soaking sample, to soaked sample go from
When sub- water is neutral, sample is taken out to be placed in 60 DEG C of baking ovens and is dried；
(6) pulverized particles：Drying sample Jing ultramicro grindings obtained by step (5) to 2000 mesh powder are obtained into titanium dioxide
Titanium/activated carbon composite particles.
Embodiment 1
A kind of antibacterial fancy soap for moistening skin, the raw material and its parts by weight for making the perfumed soap be：30 parts of aloe fresh goods, dent
15 parts of amaranth fresh goods, 10 parts of cordate houttuynia, 8 parts of Herba Andrographitis, 4 parts of needle juniper fruit, 6 parts of blue gum, 1 part of quassia, 4 parts of mahonia bealei root,
6 parts of Chinese gall, 3 parts of the coptis, 4 parts of honey-fried licorice root, 4 parts of Titanium dioxide/active carbon composite particles, 1 part of Rosa Damascana, 220 parts of soap base.
The preparation method of the perfumed soap is comprised the following steps：
1) cordate houttuynia, Herba Andrographitis, needle juniper fruit, blue gum, quassia, mahonia bealei root, Chinese gall, the coptis, honey-fried licorice root powder
50 mesh powder are broken to, the water for adding 5 times of mixed-powder gross mass multiple soaks 30 minutes, is cooked by slow fire 1 hour, crosses 200 mesh mistakes
Filter screen, takes filtrate, and the water that 4 times of mixed-powder gross mass is added again soaks 1 hour, is cooked by slow fire 1 hour, crosses 200 mesh and filters
Net, takes filtrate, merge filtrate twice be cooled to 60 ± 2 DEG C it is standby；
2) aloe, purslane clean after add step 1) gained filtrate mixing squeeze the juice after cross 200 mesh filter screen filtrations must filter
Liquid, gained filtrate dry to relative density for 1.25 ± 0.02 (60 DEG C) thick paste, gained thick paste be cooled to 55 ± 2 DEG C it is standby；
3) step 2) obtained by thick paste mix with Titanium dioxide/active carbon composite particles, Rosa Damascana, add soap base in,
Stir, Jing cooling shapings obtain final product antibacterial fancy soap for moistening skin.
Embodiment 2
A kind of antibacterial fancy soap for moistening skin, the raw material and its parts by weight for making the perfumed soap be：40 parts of aloe fresh goods, purslane
20 parts of fresh goods, 16 parts of cordate houttuynia, 12 parts of Herba Andrographitis, 8 parts of needle juniper fruit, 10 parts of blue gum, 3 parts of quassia, 8 parts of mahonia bealei root,
12 parts of Chinese gall, 7 parts of the coptis, 6 parts of honey-fried licorice root, 6 parts of Titanium dioxide/active carbon composite particles, 3 parts of Rosa Damascana, soap base 250
Part.
The preparation method of the perfumed soap of embodiment 2 is same as Example 1.
Embodiment 3
A kind of antibacterial fancy soap for moistening skin, the raw material and its parts by weight for making the perfumed soap be：35 parts of aloe fresh goods, purslane
17 parts of fresh goods, 13 parts of cordate houttuynia, 10 parts of Herba Andrographitis, 6 parts of needle juniper fruit, 8 parts of blue gum, 2 parts of quassia, 6 parts of mahonia bealei root, five
9 parts of gall nut, 5 parts of the coptis, 5 parts of honey-fried licorice root, 5 parts of Titanium dioxide/active carbon composite particles, 2 parts of Rosa Damascana, 233 parts of soap base.
The preparation method of the perfumed soap of embodiment 3 is same as Example 1.
The antibacterial tests of embodiment 4
With Escherichia coli, staphylococcus aureus agent as bacterial classification, anti-microbial property survey is carried out to sample using concussion flask method
Examination, the anti-microbial property of sample is evaluated by bacteriostasis rate, and testing result see the table below.
| Commercially available conventional toilet soaps | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Effective time/h | 2 | 10 | 10.5 | 11 |
| Escherichia coli inhibiting rate/% | <50 | 93 | 93 | 96 |
| Staphylococcus aureus inhibiting rate/% | <50 | 95 | 97 | 98 |
As seen from the above table, compared with commercially available conventional toilet soaps, the perfumed soap of the present invention has notable fungistatic effect.
Embodiment 5：
The perfumed soap of the embodiment of the present invention 3 is issued at random into 100 bit test persons to use, experimenter's day is washed one's hands using the perfumed soap
3 times, use time is three months.After three months, 60% experimenter's hand skin situation has clear improvement, and hand skin becomes
Delicate, hair pore shrinkage；29% experimenter's hand skin situation makes moderate progress, and skin starts to become soft, flexible；11%
Experimenter's skin is not improved；All experimenters are there is skin quality variation or allergic symptom.Test result indicate that this
The perfumed soap of invention can play the effect of moistening skin-care.
Illustrative embodiments listed above are only not to technical scheme described in the invention for understanding that the present invention is used
Restriction, about the those of ordinary skill in field, on the basis of technical scheme described in claim, various changes can also be made
Change or deform, the change or deformation of all equivalents all should be covered within the claims of the present invention.The present invention is not
Part is described in detail in detail, the known technology of those skilled in the art of the present technique is.
Claims (8)
1. a kind of antibacterial fancy soap for moistening skin, it is characterised in that the raw material and its parts by weight for making the perfumed soap be：Aloe fresh goods
30-40 parts, purslane fresh goods 15-20 part, cordate houttuynia 10-16 parts, Herba Andrographitis 8-12 parts, needle juniper fruit 4-8 parts, blue gum 6-10 parts,
Quassia 1-3 parts, mahonia bealei root 4-8 parts, Chinese gall 6-12 parts, coptis 3-7 parts, honey-fried licorice root 4-6 parts, titanium dioxide/work
Property charcoal composite particles 4-6 parts, Rosa Damascana 1-3 parts, soap base 220-250 parts；Described Titanium dioxide/active carbon composite particles by
Electrospinning Enteromorpha Nano granule/titanium dioxide fiber Jing carbonizations, pickling, crushing are obtained.
2. a kind of antibacterial fancy soap for moistening skin as claimed in claim 1, it is characterised in that make the raw material and its weight of the perfumed soap
Number is：35 parts of aloe fresh goods, 17 parts of purslane fresh goods, 13 parts of cordate houttuynia, 10 parts of Herba Andrographitis, 6 parts of needle juniper fruit, 8 parts of blue gum is bitter
2 parts of wood, 6 parts of mahonia bealei root, 9 parts of Chinese gall, 5 parts of the coptis, 5 parts of honey-fried licorice root, Titanium dioxide/active carbon composite particles 5
Part, 2 parts of Rosa Damascana, 233 parts of soap base.
3. a kind of antibacterial fancy soap for moistening skin as claimed in claim 1, it is characterised in that described Titanium dioxide/active carbon is combined
Particle is obtained by following methods：
(1) Enteromorpha nanometer dry powder is prepared：The cleaning of Enteromorpha fresh goods removes the impurity such as the grains of sand, and Jing natural air dryings or freeze-drying must be done
Product, gained dry product ultramicro grinding to last being placed in ball grinder of powder and micron carries out high-energy ball milling post-drying and obtains Enteromorpha nanometer dry powder；
(2) spinning precursor liquid is prepared：Prepare Enteromorpha nanometer dry powder, anhydrous second containing gained in tetrabutyl titanate, step (1)
Alcohol, the high molecular polymer for being dissolved in ethanol, the uniform suspension of organic acid are used as spinning precursor liquid；
(3) electrospinning preparation tunica fibrosa：Spinning precursor liquid obtained by step (2) is added in the liquid storage mechanism of electrostatic spinning apparatus, is spun
Silk shower nozzle connection high-voltage power cathode, collector connection high voltage power supply negative pole, adjusting spinning voltage and spinning distance carries out electrostatic
Spinning, spinning precursor liquid forms tunica fibrosa and is preparation tunica fibrosa in the presence of electric field force on collector；
(4) high-temperature heat treatment：Preparation fibre film Jing high-temperature heat treatments under anoxic or oxygen-free environment of gained make Enteromorpha in step (3)
Nanometer dry powder is carbonized to obtain activated carbon, and the process eliminates high molecular polymer and residual solvent in prepared tunica fibrosa, obtains simultaneously
Enteromorpha activated carbon/dioxide composite nanofiber film；
(5) pickling impurity removal：By the hydrochloric acid of sample Jing molar concentrations 5mol/L obtained by step (4) under the constant temperature that temperature is 60 DEG C
Immersion is taken out sample from acid solution with removing impurity for 10 hours, then is soaked in deionized water every replacing one in 2 hours
The deionized water of secondary immersion sample, and the ph values of the deionized water for soaking sample are tested, to the deionized water for soaking sample
For neutrality when, by sample take out be placed in 60 DEG C of baking ovens dry；
(6) pulverized particles：Drying sample Jing ultramicro grindings obtained by step (5) to 2000 mesh powder are obtained into titanium dioxide/work
Property charcoal composite particles.
4. a kind of antibacterial fancy soap for moistening skin as claimed in claim 3, it is characterised in that described step (1) prepares Enteromorpha nanometer
Dry powder：The cleaning of Enteromorpha fresh goods is removed after the impurity such as the grains of sand, and freeze-drying obtains dry product, and gained dry product ultramicro grinding is to 500 mesh microns
After powder, gained micron powder is placed in ball grinder carries out high-energy ball milling, wherein zirconia ball:Micron powder:The quality of water
Than for 8:4:1,2000 revs/min of rotating speed, Ball-milling Time 4 hours, gained powder is placed in 60 DEG C of baking ovens dries to obtain Enteromorpha nanometer
Dry powder.
5. a kind of antibacterial fancy soap for moistening skin as claimed in claim 3, it is characterised in that described step (2) prepares spinning forerunner
Liquid：3.4g tetrabutyl titanates are added in 9ml absolute ethyl alcohols with 2g sulfosalicylic acids, and magnetic agitation is added after being well mixed within 1 hour
Enteromorpha nanometer dry powder obtained by 2.2g steps (1), magnetic agitation 1 hour is configured to suspension A；3.5g polyvinylpyrrolidones
In adding 9ml absolute ethyl alcohols, magnetic agitation is well mixed to obtain solution B in 2 hours；By suspension A and solution B mixing magnetic agitation 40
After minute, ultrasonic vibration 10 minutes, magnetic agitation 30 minutes again after ultrasonic vibration, then ultrasonic vibration 10 minutes again, i.e.,
It is spinning precursor liquid to obtain uniform suspension.
6. a kind of antibacterial fancy soap for moistening skin as claimed in claim 5, it is characterised in that described step (3) electrospinning preparation fiber
Spinning voltage in film is 22kV, and spinning distance is 18cm, and the spinning time is 15 minutes.
7. a kind of antibacterial fancy soap for moistening skin as claimed in claim 3, it is characterised in that described step (4) high-temperature heat treatment：Step
Suddenly the preparation fibre film of gained is placed in tube furnace in (3), in a nitrogen atmosphere, with 3 DEG C/min 500 DEG C is warming up to, and insulation 1 is little
Shi Hou, is cooled to room temperature and takes out sample, obtains final product Enteromorpha activated carbon/dioxide composite nanofiber film.
8. the preparation method of a kind of antibacterial fancy soap for moistening skin as any one of claim 1-7, it is characterised in that include with
Lower step：
1) cordate houttuynia, Herba Andrographitis, needle juniper fruit, blue gum, quassia, mahonia bealei root, Chinese gall, the coptis, honey-fried licorice root are crushed to
50 mesh powder, the water for adding 5 times of mixed-powder gross mass multiple soaks 30 minutes, is cooked by slow fire 1 hour, crosses 200 mesh screen packs,
Filtrate is taken, the water that 4 times of mixed-powder gross mass is added again soaks 1 hour, is cooked by slow fire 1 hour, crosses 200 mesh screen packs, takes
Filtrate, merge twice filtrate be cooled to 60 ± 2 DEG C it is standby；
2) aloe, purslane clean after add step 1) gained filtrate mixing squeeze the juice after cross 200 mesh filter screen filtrations obtain filtrate, institute
Filtrate dry to relative density for 1.25 ± 0.02 (60 DEG C) thick paste, gained thick paste be cooled to 55 ± 2 DEG C it is standby；
3) step 2) obtained by thick paste mix with Titanium dioxide/active carbon composite particles, Rosa Damascana, add soap base in, stirring
Uniformly, Jing cooling shapings obtain final product antibacterial fancy soap for moistening skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611073071.XA CN106635539A (en) | 2016-11-29 | 2016-11-29 | Antibacterial skin-moisturizing soap and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611073071.XA CN106635539A (en) | 2016-11-29 | 2016-11-29 | Antibacterial skin-moisturizing soap and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106635539A true CN106635539A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611073071.XA Withdrawn CN106635539A (en) | 2016-11-29 | 2016-11-29 | Antibacterial skin-moisturizing soap and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642611A (en) * | 2013-12-10 | 2014-03-19 | 王淳 | Active carbon soap |
| CN103783080A (en) * | 2014-01-24 | 2014-05-14 | 北京林业大学 | Antibacterial active carbon nano composite material and preparation method thereof |
| CN103896268A (en) * | 2014-04-08 | 2014-07-02 | 山东大学 | Method for preparing multistage-aperture activated carbon with high specific surface area |
| CN105502392A (en) * | 2015-12-29 | 2016-04-20 | 山东大学 | Preparation method of micropore-developed activated carbon |
-
2016
- 2016-11-29 CN CN201611073071.XA patent/CN106635539A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642611A (en) * | 2013-12-10 | 2014-03-19 | 王淳 | Active carbon soap |
| CN103783080A (en) * | 2014-01-24 | 2014-05-14 | 北京林业大学 | Antibacterial active carbon nano composite material and preparation method thereof |
| CN103896268A (en) * | 2014-04-08 | 2014-07-02 | 山东大学 | Method for preparing multistage-aperture activated carbon with high specific surface area |
| CN105502392A (en) * | 2015-12-29 | 2016-04-20 | 山东大学 | Preparation method of micropore-developed activated carbon |
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Application publication date: 20170510 |