CN106634736B - A kind of rapid curing installation glue - Google Patents
A kind of rapid curing installation glue Download PDFInfo
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- CN106634736B CN106634736B CN201611245234.8A CN201611245234A CN106634736B CN 106634736 B CN106634736 B CN 106634736B CN 201611245234 A CN201611245234 A CN 201611245234A CN 106634736 B CN106634736 B CN 106634736B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of rapid curings to install glue, belongs to adhesive material technical field.In order to solve the problems, such as that existing adhesive speed is slow, a kind of rapid curing installation glue is provided, which is characterized in that rapid curing installation glue includes the parts by weight of following component：Styrene-butadiene-styrene：10~12；Coumarone indene resin：1.0~2.0；Cyclic olefin copolymer：2.0~2.5；Modified C9 Petropols：20~25；Poly- ɑ-ethyl styrene：1.2~1.5；Polyvinyl alcohol：0.1~0.5；Filler：30~35；Auxiliary agent：15~20.The present invention can effectively realize the ability quickly bonded, while but also with the effect of high bond strength and shear strength.
Description
Technical field
The present invention relates to a kind of rapid curings to install glue, belongs to adhesive material technical field.
Background technique
Adhesive is usually widely used in the industries such as timber, furniture, advertisement, and the market space is huge.Currently, traditional gluing
Agent is the all-purpose adhesive using solvent type and aqua type mostly, and solvent type all-purpose adhesive mainly has SBS class all-purpose adhesive and neoprene ten thousand
It can glue.Have due to the SBS (styrene-butadiene-styrene) in SBS all-purpose adhesive and between many polymer preferably
Compatibility and be easy the various features such as modified, be also very applicable for preparing adhesive.In addition, SBS elastomer can also be more
Kind of weak polar solvent is dissolved, have the characteristics that preparation process simply, high solids content, be readily made environmental-protection type adhesive, mesh
It is preceding by the common concern of people, it is very common in actual use；But the existing most cohesive force of SBS adhesive is bad,
Especially in the bonding for outdoor objects such as Billboards, it is not easy occur falling off the problem short with service life very much.Such as
Chinese patent (Authorization Notice No.：CN101503605B a kind of SBS universal glue sizing agent and preparation method thereof, the solid) are disclosed
It is omnipotent to be made of following quality group at the raw material of number, environmentally friendly solvent：60 parts；Oxidation modification SBS：17 parts；Terpene resin：8
Part；Petropols：3 parts；Rosin：5 parts；Filler：1 part：2 parts of antifreezing agent：Plasticizer：3 parts, preparation method is by will be above-mentioned
The raw material of ratio is mixed after being completely dissolved in environmentally friendly solvent, and obtained solution is controlled in 30 DEG C of viscosity below
Between 300-500cps, then, filtering obtains corresponding product.Although the product, itself have environmentally friendly and easy to use etc.
Feature, still, its adhesion strength is bad when using outdoors and shear strength is poor, so that jelly be made to need to be punched after bonding
Reinforce etc.；And solidification bonding is relatively slow, the defects of being unfavorable for quick-binding.
Summary of the invention
The present invention is directed to the above defect existing in the prior art, provides a kind of rapid curing installation glue, solves the problems, such as
It is how to realize rapid curing and the high performance of adhesion strength.
The purpose of the present invention is what is be achieved by the following technical programs, a kind of rapid curing installation glue, feature exists
In the quick glue includes the parts by weight of following component：
Styrene-butadiene-styrene：10~12；Coumarone indene resin：1.0~2.0；Cyclic olefin copolymer：
2.0~2.5；Modified C9 Petropols：20~25；Poly- ɑ-ethyl styrene：1.2~1.5；Polyvinyl alcohol：0.1~0.5；It fills out
Material：30~35；Auxiliary agent：15~25.
Rapid curing installation glue of the present invention, can be with styrene-by the way that coumarone indene resin and modified C9 Petropols is added
Preferable synergistic effect is formed between butadiene-styrene copolymer (SBS), is conducive to be grafted onto modified C9 Petropols
Grafting is formed on SBS, makes adhesive that there is good adhesion strength performance；Meanwhile poly- ɑ-ethyl styrene and polyethylene is added
The purpose of alcohol is to make to be less prone to phenomena such as falling off to improve the shear strength performance after gluing knot, to realize without another
It is outer to carry out punching the operation such as fixed, improve the convenience of operation.On the other hand, in cyclic olefin copolymer and poly- ɑ-ethylo benzene
Under the collective effect of ethylene, the adhesive speed of this quick glue can be improved, make to achieve the effect that quickly to tie, and can also be simultaneous simultaneously
Has high shear strength effect.
In above-mentioned rapid curing installation glue, preferably, also containing 0.02~0.04 weight in rapid curing installation
Measure the ammonium salt of part.It can promote being modified for SBS and play the role of snap action and reach cured, the addition of ammonium salt can be played
The effect of surface active improves the compatibility of each raw material, is conducive to improve the strength character after bonding.As further excellent
Choosing, the ammonium salt are mixed selected from one or both of alkyl dimethyl benzyl ammonium salt and ammonium metatungstate.As further
It is preferred that mixture of the ammonium salt for alkyl dimethyl benzyl ammonium salt and ammonium metatungstate, and the ammonium metatungstate：Alkyl dimethyl
The mass ratio of benzyl ammonium salt is 1：0.2~0.4.The present inventor has found in the course of the research, when alkyl dimethyl benzyl ammonium salt and
Ammonium metatungstate is added simultaneously and the shear strength after bonding is improved clearly, and can be realized the ability quickly bonded, base
It can make shear strength that there is preferable cohesive force later in bonding on this, be especially bonding timber and stainless steel material
When, the effect of bonding is more preferable.
In above-mentioned rapid curing installation glue, preferably, the cyclic olefin copolymer passes through with by double-heptene list
Body and vinyl monomer are polymerized.The cyclic olefin copolymer, that is, cyclic olefin copolymer TOPAS.Purpose is to improve
Its compatibility between SBS improves the adhesive speed of glue, realizes the effect of rapid curing bonding.
In above-mentioned rapid curing installation glue, preferably, also containing 0.01~0.03 weight in rapid curing installation
Measure the polytetrahydrofuran diol of part.It can play and bond not fastness caused by preventing adhesive from mothization occurring after use
Problem is more advantageous to it in outdoor utility, and can guarantee the intensity and service life of viscosity.
In above-mentioned rapid curing installation glue, preferably, the filler is selected from titanium dioxide, calcium carbonate and precipitated calcium carbonate
One or more of.Be conducive to the level of solids for improving glue and the strength character after bonding.
In above-mentioned rapid curing installation glue, the auxiliary agent is selected from one of antifreezing agent, anti-aging agent and film forming agent or several
Kind.Purpose is the ability of the antifreeze ability and uvioresistant irradiation in order to improve glue, improves anti-aging property, further increases bonding
Strength character afterwards.
In conclusion compared with prior art, the present invention having the following advantages that：
1. rapid curing installation glue by being added coumarone indene resin and modified C9 petroleum tree in SBS basis material simultaneously
Rouge, and the common synergistic effect of poly- ɑ-ethyl styrene and polyvinyl alcohol is combined, after can be realized bonding there is height to glue intensity
With the effect of shear strength.
2. rapid curing installation glue, can by mixing cyclic olefin copolymer and poly- ɑ-ethyl styrene collective effect
Adhesive speed is effectively improved, makes to realize the ability quickly bonded, while but also with the effect of high bond strength and shear strength.
3. rapid curing installation glue passes through while being added alkyl dimethyl benzyl ammonium salt and ammonium metatungstate passes through more into one
The raising shear strength performance of step and the ability of adhesive speed.
Specific embodiment
Below by specific embodiment, the technical solutions of the present invention will be further described, but the present invention is simultaneously
It is not limited to these embodiments.
Embodiment 1
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：10；
Coumarone indene resin：1.0；
Cyclic olefin copolymer：2.5, wherein cyclic olefin copolymer by by double-heptene monomer and vinyl monomer into
Row is polymerized；
Modified C9 Petropols：25；
Poly- ɑ-ethyl styrene：1.5；
Polyvinyl alcohol：0.1；
Filler titanium dioxide：30, wherein the mesh number of titanium dioxide is 2000 mesh；
Auxiliary agent antifreeze glycol：18；
Coalescents alcohol ester 12：2.0.
Rapid curing installation glue can be prepared by the following method to obtain：
Raw material is weighed according to the parts by weight of following ingredient, is added in mixing agitator, suitable environment-friendly type is added
Solvent such as methyl acetate etc. stirs to after being completely dissolved, is filtered to remove a small amount of particle object such as insoluble impurity, obtains corresponding fast
Fast glue.
Embodiment 2
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：12；
Coumarone indene resin：2.0；
Cyclic olefin copolymer：2.0, wherein cyclic olefin copolymer by by double-heptene monomer and vinyl monomer into
Row is polymerized；
Modified C9 Petropols：20；Wherein, modified C9 Petropols are butyl acrylate modification C9 Petropols, i.e., logical
Butyl acrylate grafting is crossed to be modified to obtain corresponding modified C9 Petropols；
Poly- ɑ-ethyl styrene：1.5；
Polyvinyl alcohol：0.5；
Filler light calcium carbonate powder：35, wherein the mesh number of precipitated calcium carbonate is 2000 mesh；
Auxiliary agent antifreeze glycol：10；
Anti-aging agent：5.0, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：1.0.
That the preparation method is the same as that of Example 1 is consistent for the quick glue of the present embodiment specific, and which is not described herein again.
Embodiment 3
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：11；
Coumarone indene resin：1.5；
Cyclic olefin copolymer：2.2, wherein cyclic olefin copolymer is cyclic olefin copolymer TOPAS；
Modified C9 Petropols：23；
Wherein, modified C9 Petropols are to add hydrogen C9 Petropols, i.e., obtain being modified C9 stone accordingly by hydrogenation modification
Oleoresin；
Poly- ɑ-ethyl styrene：1.3；
Polyvinyl alcohol：0.2；
Filler light calcium carbonate powder：32, wherein the mesh number of precipitated calcium carbonate is 3000 mesh；
Auxiliary agent antifreeze glycol：10；
Anti-aging agent：10, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：1.5.
That the preparation method is the same as that of Example 1 is consistent for the quick glue of the present embodiment specific, and which is not described herein again.
Embodiment 4
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：10；
Coumarone indene resin：1.6；
Cyclic olefin copolymer：2.3, wherein cyclic olefin copolymer is cyclic olefin copolymer TOPAS；
Modified C9 Petropols：21；
Wherein, modified C9 Petropols are to add hydrogen C9 Petropols, i.e., obtain being modified C9 stone accordingly by hydrogenation modification
Oleoresin；
Poly- ɑ-ethyl styrene：1.2；
Polyvinyl alcohol：0.4；
Filler light calcium carbonate powder：32, wherein the mesh number of precipitated calcium carbonate is 3000 mesh；
Auxiliary agent antifreeze glycol：15；
Anti-aging agent：3.0, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：1.0；
Alkyl dimethyl benzyl ammonium salt：0.02.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 5
The quick glue of the present embodiment at be grouped as substantially with embodiment 4 it is consistent, difference was only that using ammonium metatungstate generation
For alkyl dimethyl benzyl ammonium salt, and the additional amount of ammonium metatungstate is 0.04, other at being grouped as and weight ratio is identical, this
In repeat no more.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 6
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：11；
Coumarone indene resin：1.8；
Cyclic olefin copolymer：2.0, wherein cyclic olefin copolymer is cyclic olefin copolymer TOPAS；
Modified C9 Petropols：22；
Wherein, modified C9 Petropols are butyl acrylate modification C9 Petropols, i.e., by butyl acrylate be grafted into
Row modification obtains being modified C9 Petropols accordingly；
Poly- ɑ-ethyl styrene：1.3；
Polyvinyl alcohol：0.3；
Filler-calcium carbonate powder：30；
Wherein, the mesh number of calcium carbonate powder is 2000 mesh；
Auxiliary agent antifreeze glycol：9.0；
Anti-aging agent：10, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：1.5；
Alkyl dimethyl benzyl ammonium salt：0.01；
Ammonium metatungstate：0.02.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 7
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：12；
Coumarone indene resin：1.9；
Cyclic olefin copolymer：2.1, wherein cyclic olefin copolymer is cyclic olefin transparent resin APL6015T；
Modified C9 Petropols：23；
Wherein, modified C9 Petropols are butyl acrylate modification C9 Petropols, i.e., by butyl acrylate be grafted into
Row modification obtains being modified C9 Petropols accordingly；
Poly- ɑ-ethyl styrene：1.2；
Polyvinyl alcohol：0.4；
Filler titanium dioxide powder：31；
Wherein, the mesh number of titanium dioxide powder is 2000 mesh；
Auxiliary agent antifreeze glycol：14；
Anti-aging agent：5.0, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：1.0；
Alkyl dimethyl benzyl ammonium salt：0.012；
Ammonium metatungstate：0.02.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 8
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：10；
Coumarone indene resin：1.8；
Cyclic olefin copolymer：2.4, wherein cyclic olefin copolymer is cyclic olefin copolymer TOPAS；
Modified C9 Petropols：20；Wherein, modified C9 Petropols are to add hydrogen C9 Petropols, that is, pass through hydrogenation modification
It obtains being modified C9 Petropols accordingly；
Poly- ɑ-ethyl styrene：1.2；
Polyvinyl alcohol：0.1；
Filler titanium dioxide powder：20；
Wherein, the mesh number of titanium dioxide powder is 2000 mesh；
Filler light calcium carbonate powder：15, wherein the mesh number of light calcium carbonate powder is 2000；
Auxiliary agent antifreeze glycol：15；
Anti-aging agent：8.0, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：2.0；Alkyl dimethyl benzyl ammonium salt：0.01；
Ammonium metatungstate：0.02；
Polytetrahydrofuran diol：0.01.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 9
The quick glue of the present embodiment at be grouped as substantially with embodiment 8 it is consistent, difference is only that using polytetrahydrofuran
The additional amount of glycol is 0.03, and other at being grouped as and weight ratio is identical, which is not described herein again.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
Embodiment 10
The rapid curing installation glue of the present embodiment includes the parts by weight of following component：
Styrene-butadiene-styrene (SBS)：11；
Coumarone indene resin：2.0；
Cyclic olefin copolymer：2.1, wherein cyclic olefin copolymer is cyclic olefin copolymer TOPAS；
Modified C9 Petropols：20；Wherein, modified C9 Petropols are to add hydrogen C9 Petropols, that is, pass through hydrogenation modification
It obtains being modified C9 Petropols accordingly；
Poly- ɑ-ethyl styrene：1.1；
Polyvinyl alcohol：0.3；
Filler titanium dioxide powder：40,
Wherein, the mesh number of titanium dioxide powder is 2000 mesh；
Auxiliary agent antifreeze glycol：13；
Anti-aging agent：10, wherein anti-aging agent such as irgasfos 168 etc.；
Coalescents alcohol ester 12：2.0；
Alkyl dimethyl benzyl ammonium salt：0.012；
Ammonium metatungstate：0.02；
Polytetrahydrofuran diol：0.03.
Specifically the preparation method is the same as that of Example 1 for the quick glue of the present embodiment unanimously, and which is not described herein again.
It randomly selects the corresponding quick glue that above-described embodiment obtains and carries out corresponding performance test, specific test result is as follows
Shown in table 1：
Table 1：
Wherein, the initial shear strength in above-mentioned table 1 refers to the shear strength performance after solidifying 30 minutes, and maximum shear is strong
Degree refers to the shear strength performance after solidifying 24 hours.Meanwhile from curing rate it can also be seen that quick glue of the invention is viscous
It can achieve the effect that be fully cured after 30 minutes after knot, and also there is preferable shear strength performance after hardening,
Just illustrate that quick glue of the invention has the effect of that adhesive speed is fast.
In addition, quick gluing knot of the invention is carried out durothermic test, the results showed that quick glue of the invention it is resistance to
Warm range is wider, and preferable adhesive property is able to maintain between -20 DEG C -80 DEG C, under conditions of 80 DEG C after 72 hours, not
It was found that there is obscission.And when carrying out temperature tolerance test, quick glue of the invention can store 3 between -20 DEG C~80 DEG C
Year or more remain unchanged matter, have preferable service life.
Specific embodiment described in the present invention only illustrate the spirit of the present invention by way of example.The neck of technology belonging to the present invention
The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method
In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
It is skilled to this field although present invention has been described in detail and some specific embodiments have been cited
For technical staff, as long as it is obvious for can making various changes or correct without departing from the spirit and scope of the present invention.
Claims (5)
1. a kind of rapid curing installs glue, which is characterized in that the quick glue includes the parts by weight of following component：
Styrene-butadiene-styrene：10~12；Coumarone indene resin：1.0~2.0；Cyclic olefin copolymer：2.0
~2.5；Modified C9 Petropols：20~25；Poly- ɑ-ethyl styrene：1.2~1.5；Polyvinyl alcohol：0.1~0.5；Fill out grain：30
~35；Auxiliary agent：15~25；Ammonium salt：0.02~0.04, the ammonium salt is selected from ammonium metatungstate；Or the ammonium salt is selected from alkyl two
The mixture of methylbenzylammonium salt and ammonium metatungstate, and the ammonium metatungstate：The mass ratio of alkyl dimethyl benzyl ammonium salt is 1：
0.5~0.6.
2. rapid curing installs glue according to claim 1, which is characterized in that the cyclic olefin copolymer passes through will be bicyclic
Heptene monomer and vinyl monomer are polymerized.
3. rapid curing installs glue according to claim 1, which is characterized in that also contain 0.01~0.03 in the quick glue
The polytetrahydrofuran diol of parts by weight.
4. according to claim 1 rapid curing install glue, which is characterized in that it is described fill out grain-by-grain seed selection from titanium dioxide, calcium carbonate and
One or more of precipitated calcium carbonate.
5. according to claim 1 rapid curing install glue, which is characterized in that the auxiliary agent be selected from antifreezing agent, anti-aging agent and
One or more of film forming agent.
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| CN201611245234.8A CN106634736B (en) | 2016-12-29 | 2016-12-29 | A kind of rapid curing installation glue |
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| CN201611245234.8A CN106634736B (en) | 2016-12-29 | 2016-12-29 | A kind of rapid curing installation glue |
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| CN106634736B true CN106634736B (en) | 2018-11-16 |
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