CN106634722B - A kind of aqueous laminated adhesive and preparation method thereof - Google Patents
A kind of aqueous laminated adhesive and preparation method thereof Download PDFInfo
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- CN106634722B CN106634722B CN201611146339.8A CN201611146339A CN106634722B CN 106634722 B CN106634722 B CN 106634722B CN 201611146339 A CN201611146339 A CN 201611146339A CN 106634722 B CN106634722 B CN 106634722B
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- deionized water
- monomer emulsions
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- 239000000853 adhesive Substances 0.000 title claims abstract description 31
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- 239000003999 initiator Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 12
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims abstract description 10
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000178 monomer Substances 0.000 claims description 60
- 239000000839 emulsion Substances 0.000 claims description 45
- 238000003756 stirring Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 12
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 238000004132 cross linking Methods 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 238000011010 flushing procedure Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical group OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000872 buffer Substances 0.000 claims description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical group CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims 4
- 229920000126 latex Polymers 0.000 claims 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 238000004806 packaging method and process Methods 0.000 abstract description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052737 gold Inorganic materials 0.000 abstract description 4
- 239000010931 gold Substances 0.000 abstract description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 3
- 238000004049 embossing Methods 0.000 abstract description 3
- 238000004945 emulsification Methods 0.000 abstract description 3
- 239000003292 glue Substances 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000032798 delamination Effects 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 241000276489 Merlangius merlangus Species 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 abstract 1
- -1 polypropylene Polymers 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a kind of aqueous laminated adhesive and preparation method thereof, the raw material of the aqueous laminated adhesive includes deionized water, butyl acrylate, methacrylic acid, acryllic acid di-isooctyl, Diacetone Acrylamide, adipic acid dihydrazide, tert-butyl hydroperoxide, initiator, initiator.The present invention prepares appearance milky white liquid with blue floodlight by pre-emulsification technology, viscosity 15-25 second, solid content 48%-55%, film forming matter be it is colorless and transparent, pH is in 7.0-9.0.Aqueous laminated adhesive of the invention has good coating performance and stronger lid powder ability, and gloss is bright-coloured after overlay film, not blistering, not delamination, especially to carrying out deep hitting convex, deep embossing and having excellent tolerance after the printing of gold and silver paper jam litho ink.Solve the quality problems of many printing packaging enterprises glue film absciss layer common in wine box, box for moon-cake are made, whiting.
Description
Technical field
The present invention relates to film coating technique field, especially a kind of aqueous laminated adhesive and preparation method thereof.
Background technique
After the print of printing packaging industry in process, the brightness of printed matter is can be improved in overlay film, is enhanced water resistance, is provided more
Good visual effect.In recent years, paper covers glue and is widely used, and is mainly used in wine box packaging, casket packaging, essence
Fill books etc..Paper overlay film is to be covered the plastic films such as polypropylene (BOPP), terylene (PET) and paper printed matter using adhesive
It is combined, to greatly improve the performances such as printed matter appearance and water proof anti-soil.And aqueous paper plastic laminated adhesive used in it has
There is the features such as nontoxic, tasteless, pollution-free, easy to apply, at low cost, has obtained quick application.It also needs after printing overlay film at it
Surface carries out other process, and the concave-convex, full page of hitting of such as gold stamping, local UV silk-screen, font and pattern embosses deeply, wherein with wine box,
Box for moon-cake and tea caddy are that the packing articles of representative mostly use greatly the printing of gold and silver paper jam, overlay film, even more to printing coated with film into
Row thermal shock is convex, deep embossing, it is desirable that film and paper not absciss layer do not whiten, can require adhesive force and mechanical resistant processability higher.Mesh
Before, aqueous paper plastic laminated adhesive is difficult to meet the requirements in the market.
Summary of the invention
In view of the above problems, the object of the present invention is to provide a kind of aqueous laminated adhesives and preparation method thereof.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of aqueous laminated adhesive, including following raw material by weight:
The monomer emulsions A, including following raw material by weight:
The monomer emulsions B, including following raw material by weight:
The monomer emulsions C, including following raw material by weight:
Monomer emulsions B 95-98%
Initiator 0.3-1%
Deionized water 1-4%.
Preferably, the crosslinking agent is adipic dihydrazide.
Preferably, the initiator is ammonium persulfate or potassium peroxydisulfate.
Preferably, the auxiliary agent is one of emulsifier, buffer, defoaming agent, coalescing agent, wetting agent or more
Kind.
It is further preferred that the emulsifier is Cops-1.
It is further preferred that the coalescing agent is alcohol ester 12.
Preferably, the cross-linking monomer is hydroxy-ethyl acrylate, Diacetone Acrylamide, acrylamide, methylol third
One of acrylamide, glycidyl methacrylate and phosphate function monomer are a variety of.
Preferably, the acrylic monomer is methacrylic acid, butyl acrylate, Isooctyl acrylate monomer, third
One of e pioic acid methyl ester is a variety of.
Preferably, the regulator is lauryl mercaptan.
Further preferably, the monomer emulsions A, including following raw material by weight:
The preparation method of above-mentioned aqueous laminated adhesive, comprising the following steps:
(1) deionized water is added in reaction kettle 1, low whipping speed is that emulsifier is added under 1000-1100rmp, stirs 5-
After 7min, successively at the uniform velocity addition deionized water, cross-linking monomer, acrylic monomer, styrene obtain after mixing
Monomer emulsions A, it is spare；
(2) initiator is added in reaction kettle 2, adds deionized water dissolving, and regulator and partial process is then added
Monomer emulsions A is prepared in step (1), is uniformly mixed, obtains monomer emulsions B, spare；
(3) initiator is added in reaction kettle 3, adds deionized water dissolving, and process step (2) preparation of half is then added
Obtained monomer emulsions B is uniformly mixed, obtains monomer emulsions C, spare；
(4) water is added into reaction kettle 4, low whipping speed is after emulsifier is added under 900-1000rmp, to begin to warm up；
(5) temperature rises to 70-72 DEG C, and sodium bicarbonate and flushing water is added, and after being continuously heating to 78-80 DEG C, is added remaining
Monomer emulsions A stops heating, and after reacting 2-3min, initiator for reaction 30-40min is added；
(6) remaining monomer emulsions B and monomer emulsions C is successively at the uniform velocity added dropwise, rear insulation reaction 1-1.5h is added dropwise；
(7) after completion of the reaction, it is cooled to 75-77 DEG C, tert-butyl hydroperoxide and sodium formaldehyde sulfoxylate is added, reacts 40-50min
Afterwards, it is cooled to 65-67 DEG C, defoaming agent, the wetting agent, coalescing agent being pre-mixed is added, after stirring 30-40min, is cooled to
50-55 DEG C, continues to stir 10-15min, ammonium hydroxide is added, make PH≤7.0, stir 30-40min, crosslinking agent is then added, stir
Uniformly,
(8) viscosity is adjusted to 15-25 seconds (25 DEG C), solid content 48%-55%, with 200 mesh filter bag mistakes with deionized water
Filter encapsulating.
Preferably, the total time that monomer emulsions B and monomer emulsions C is added dropwise in the step (6) is 4-5 hours.
Preferably, the weight ratio of the monomer emulsions A of addition is in the monomer emulsions A and step (5) being added in step (2)
24-25:1。
The present invention is with butyl acrylate, methacrylic acid, acryllic acid di-isooctyl, Diacetone Acrylamide etc. for monomer
Lotion, the active group carboxyl using water as decentralized medium, using seed pre-emulsification semi-continuous process, when emulsion film forming, in polymer
Reaction is crosslinked with hydroxyl and is solidified, and is formed macromolecular network structure, is enhanced the performance of its withstanding mechanical machining deformation.System
Standby obtained aqueous laminated adhesive appearance is milky white liquid with blue floodlight, and viscosity was at 15-25 seconds, solid content 48%-
55%, film forming matter be it is colorless and transparent, pH is in 7.0-9.0.Aqueous laminated adhesive of the present invention has good coating performance and stronger
Lid powder ability, gloss is bright-coloured after overlay film, not blistering, not delamination, especially to carried out after the printing of gold and silver paper jam litho ink it is deep hit it is convex,
Deep embossing has excellent tolerance.Solve many printing packaging enterprises glue film absciss layer common in wine box, box for moon-cake are made, general
White quality problems.And aqueous laminated adhesive user of the invention makes, to environment, normal temperature cure pollution-free by adhesive material
Or hot pressing, adhesive strength height, stability is good, and storage period is long.Synthetic method of the invention has easy to operate, preparation efficiency
High feature.
Specific embodiment
Further terminate the present invention combined with specific embodiments below, but embodiment be not used to make the present invention it is any
The restriction of form.
The raw material and its weight of the aqueous laminated adhesive of embodiment 1-3 are as shown in table 1 below:
Table 1 is the raw material and weight of the aqueous laminated adhesive of embodiment 1-3
The preparation method of above-mentioned aqueous laminated adhesive, comprising the following steps:
(1) it prepares monomer emulsions A: deionized water 1 being added in reaction kettle 1, low whipping speed is that emulsification is added under 1100rmp
After stirring 5-7min, deionized water 2, hydroxy-ethyl acrylate, methacrylic acid, acrylic acid fourth is successively at the uniform velocity added in agent Cops-1
Then ester styrene is added and is pre-mixed the Diacetone Acrylamide and Isooctyl acrylate monomer of dissolution, after mixing, spend from
Sub- water 3 carries out shower, obtains monomer emulsions A, spare；
(2) prepare monomer emulsions B: ammonium persulfate is added in reaction kettle 2, adds deionized water dissolving, is then added 12
Monomer emulsions A is prepared in the process step (1) of alkyl hydrosulfide and 620kg, is uniformly mixed, obtains monomer emulsions B, spare；
(3) prepare monomer emulsions C: ammonium persulfate is added in reaction kettle 3, adds deionized water dissolving, half is then added
The monomer emulsions B that is prepared of process step (2), be uniformly mixed, obtain monomer emulsions C, it is spare；
(4) water is added into reaction kettle 4, low whipping speed is after emulsifier Cops-1 is added under 900rmp, to begin to warm up；
(5) temperature rises to 70 DEG C, and sodium bicarbonate and flushing water is added, and after being continuously heating to 78 DEG C, remaining monomer cream is added
Liquid A, etc. temperature when returning to 77 DEG C, stop heating, ammonium persulfate be added after constant 2-3min, react 30min；
(6) after reaction after 20min, remaining monomer emulsions B and monomer emulsions C is successively at the uniform velocity added dropwise, control is total
Time for adding 4 hours, rear insulation reaction 1h is added dropwise；
(7) after insulation reaction, 75 DEG C are cooled to, tert-butyl hydroperoxide and sodium formaldehyde sulfoxylate is added, after reacting 40min,
65 DEG C are cooled to, defoaming agent 8034A, wetting agent 400, the coalescing agent alcohol ester 12 being pre-mixed is added, stirs 30min
Afterwards, 50 DEG C are cooled to, continues to stir 10min, ammonium hydroxide is added, adjust PH≤7.0, after stirring 30min, adipic acid two is then added
Hydrazides stirs evenly,
(8) viscosity is adjusted to 15-25 seconds (25 DEG C), with 200 mesh sock filtration encapsulatings with deionized water.
Embodiment 4
The aqueous laminated adhesive of embodiment 1-3 is tested for the property, the result is shown in tables 2
It is measured according to following national standard
The measurement of 2793 adhesive non-volatile content of GB/T
The measurement of 2794 adhesive viscosity of GB/T
GB/T 11175-2002 synthetic resin emulsion test method
The pH value of 14518 adhesive of GB/T measures
The aqueous laminated adhesive the performance test results of 2 embodiment 1-3 of table
Claims (4)
1. a kind of aqueous laminated adhesive, which is characterized in that be made of following raw material by weight:
Wherein, the monomer emulsions A is made of following raw material by weight:
Wherein, the monomer emulsions B is made of following raw material by weight:
Wherein, the monomer emulsions C is made of following raw material by weight:
Monomer emulsions B 95-98%
Initiator 0.3-1%
Deionized water 1-4%；
The preparation method of the aqueous laminated adhesive the following steps are included:
(1) deionized water is added in reaction kettle 1, low whipping speed is that emulsifier is added under 1000-1100rmp, stirs 5-7min
Afterwards, successively at the uniform velocity addition deionized water, cross-linking monomer, acrylic monomer, styrene obtain monomer after mixing
Latex A, it is spare；
(2) initiator is added in reaction kettle 2, adds deionized water dissolving, and regulator and partial process step is then added
(1) monomer emulsions A is prepared, is uniformly mixed, obtains monomer emulsions B, it is spare；
(3) initiator is added in reaction kettle 3, adds deionized water dissolving, and the process step (2) that half is then added is prepared
Monomer emulsions B, be uniformly mixed, obtain monomer emulsions C, it is spare；
(4) water is added into reaction kettle 4, low whipping speed is after emulsifier is added under 900-1000rmp, to begin to warm up；
(5) temperature rises to 70-72 DEG C, and sodium bicarbonate and flushing water is added, after being continuously heating to 78-80 DEG C, remaining monomer is added
Latex A stops heating, and after reacting 2-3min, initiator for reaction 30-40min is added；
(6) remaining monomer emulsions B and monomer emulsions C is successively at the uniform velocity added dropwise, the total time of dropwise addition is 4-5 hours, is added dropwise
Insulation reaction 1-1.5h afterwards；
(7) after insulation reaction, it is cooled to 75-77 DEG C, tert-butyl hydroperoxide and sodium formaldehyde sulfoxylate is added, reacts 40-50min
Afterwards, it is cooled to 65-67 DEG C, the auxiliary agent being pre-mixed is added, after stirring 30-40min, 50-55 DEG C is cooled to, continues to stir
Ammonium hydroxide is added in 10-15min, makes PH≤7.0, stirs 30-40min, crosslinking agent is then added, stirs evenly,
(8) viscosity is adjusted to being 15-25 seconds in 25 DEG C of tests with deionized water, solid content 48%-55%, with 200 mesh filter bags
Filter encapsulating；
The cross-linking monomer is hydroxy-ethyl acrylate and Diacetone Acrylamide；
The acrylic monomer is methacrylic acid, butyl acrylate and Isooctyl acrylate monomer；
The regulator is lauryl mercaptan；The auxiliary agent is emulsifier, buffer, defoaming agent, coalescing agent, moistens
One of agent is a variety of.
2. aqueous laminated adhesive according to claim 1, which is characterized in that the crosslinking agent is adipic dihydrazide.
3. aqueous laminated adhesive according to claim 1, which is characterized in that the initiator is ammonium persulfate or persulfuric acid
Potassium.
4. a kind of preparation method of aqueous laminated adhesive of any of claims 1-3, which is characterized in that including following step
It is rapid:
(1) deionized water is added in reaction kettle 1, low whipping speed is that emulsifier is added under 1000-1100rmp, stirs 5-7min
Afterwards, successively at the uniform velocity addition deionized water, cross-linking monomer, acrylic monomer, styrene obtain monomer after mixing
Latex A, it is spare；
(2) initiator is added in reaction kettle 2, adds deionized water dissolving, and regulator and partial process step is then added
(1) monomer emulsions A is prepared, is uniformly mixed, obtains monomer emulsions B, it is spare；
(3) initiator is added in reaction kettle 3, adds deionized water dissolving, and the process step (2) that half is then added is prepared
Monomer emulsions B, be uniformly mixed, obtain monomer emulsions C, it is spare；
(4) water is added into reaction kettle 4, low whipping speed is after emulsifier is added under 900-1000rmp, to begin to warm up；
(5) temperature rises to 70-72 DEG C, and sodium bicarbonate and flushing water is added, after being continuously heating to 78-80 DEG C, remaining monomer is added
Latex A stops heating, and after reacting 2-3min, initiator for reaction 30-40min is added；
(6) remaining monomer emulsions B and monomer emulsions C is successively at the uniform velocity added dropwise, the total time of dropwise addition is 4-5 hours, is added dropwise
Insulation reaction 1-1.5h afterwards；
(7) after insulation reaction, it is cooled to 75-77 DEG C, tert-butyl hydroperoxide and sodium formaldehyde sulfoxylate is added, reacts 40-50min
Afterwards, it is cooled to 65-67 DEG C, the auxiliary agent being pre-mixed is added, after stirring 30-40min, 50-55 DEG C is cooled to, continues to stir
Ammonium hydroxide is added in 10-15min, makes PH≤7.0, stirs 30-40min, crosslinking agent is then added, stirs evenly,
(8) viscosity is adjusted to being 15-25 seconds in 25 DEG C of tests with deionized water, solid content 48%-55%, with 200 mesh filter bags
Filter encapsulating.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107189723A (en) * | 2017-06-07 | 2017-09-22 | 宜昌金海科技股份有限公司 | Waterborne dry-type laminated adhesive and preparation method thereof |
| CN107699169A (en) * | 2017-11-14 | 2018-02-16 | 福建友谊胶粘带集团有限公司 | A kind of adhesive and its processing technology for being used for white OPP adhesive tapes thoroughly |
| CN109370487A (en) * | 2018-09-13 | 2019-02-22 | 广东星宇耐力新材料股份有限公司 | A kind of universal aluminizer composite adhesive and preparation method thereof for gold and silver paper jam |
| CN112172366A (en) * | 2020-09-30 | 2021-01-05 | 襄阳和顺发彩色印刷有限公司 | Printing process of green environment-friendly color box |
| CN113073494A (en) * | 2021-04-12 | 2021-07-06 | 东莞市冠力胶业有限公司 | Environment-friendly plastic replacement water gel |
| CN113249063B (en) * | 2021-05-20 | 2022-11-04 | 东莞市冠力胶业有限公司 | Water-based plastic substitute and preparation method thereof |
| CN114214004B (en) * | 2021-12-23 | 2022-11-18 | 河南省科学院高新技术研究中心 | Composite acrylic resin hot melt adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102140320A (en) * | 2010-08-19 | 2011-08-03 | 北京高盟新材料股份有限公司 | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof |
| CN103205224A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Acrylate emulsion laminating adhesive, and preparation method and application thereof |
| CN104263292A (en) * | 2014-09-03 | 2015-01-07 | 台州学院 | Water-based laminated adhesive and preparation method thereof |
| CN105482745A (en) * | 2015-12-04 | 2016-04-13 | 常德市雄鹰科技有限责任公司 | Aqueous dry lamination adhesive and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102140320A (en) * | 2010-08-19 | 2011-08-03 | 北京高盟新材料股份有限公司 | Water-based polyacrylic emulsion laminating adhesive and preparation method thereof |
| CN103205224A (en) * | 2012-08-30 | 2013-07-17 | 湖北航天化学技术研究所 | Acrylate emulsion laminating adhesive, and preparation method and application thereof |
| CN104263292A (en) * | 2014-09-03 | 2015-01-07 | 台州学院 | Water-based laminated adhesive and preparation method thereof |
| CN105482745A (en) * | 2015-12-04 | 2016-04-13 | 常德市雄鹰科技有限责任公司 | Aqueous dry lamination adhesive and preparation method thereof |
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