CN106634661A - Weather-proof film for plastic floor - Google Patents
Weather-proof film for plastic floor Download PDFInfo
- Publication number
- CN106634661A CN106634661A CN201611049760.7A CN201611049760A CN106634661A CN 106634661 A CN106634661 A CN 106634661A CN 201611049760 A CN201611049760 A CN 201611049760A CN 106634661 A CN106634661 A CN 106634661A
- Authority
- CN
- China
- Prior art keywords
- fluorine
- plastic floor
- proof film
- weather
- containing polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
- C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a weather-proof film for a plastic floor. The weather-proof film is formed by an outer protection layer, a function layer and an adhesion layer of which the thickness ratio is 1 to 3 to 1 through co-extrusion, wherein the outer protection layer is prepared from a fluorine-containing high polymer; the function layer is prepared from 20 to 100 parts of fluorine-containing high polymer, 0 to 60 parts of hot melt glue and 0.5 to 20 parts of functional aid; the adhesion layer is prepared from 0 to 40 parts of fluorine-containing high polymer and 60 to 100 parts of hot melt glue. The weather-proof film for the plastic floor, disclosed by the invention, has the characteristics of strong stain resistance, chemical inertness, high wear resistance, environment friendliness, weather resistance and universality.
Description
Technical field
The present invention relates to a kind of plastic floor Weather-proof film.
Background technology
The motive force of development in fluoro-containing copolymer film market comes from the application of continuous expansion.Additionally, fluoro-containing copolymer film
Constantly increase with the development of the compatible and multilayer coating film technology of other films, and medicine and medicine trade demand, also promote
Its market scale expands rapidly.The blockade on new techniques of fluorine-containing special membrane processing industry and industry threshold are all higher, in order to break related state
The technology barriers of family, promote the fluorine resin development of China and meet the market demand, need to segment market, and by breakthrough
Innovative technology is guiding market development.The application expands the application of fluoropolymer membrane to plastic floor.
Plastic floor is popular a kind of novel light body floor decorative material in the world today, also referred to as " light body ground
Material ".It is a kind of very popular product of Japan and Korea S in American-European and Asia, fashionable foreign countries initially enter Chinese city from the beginning of the eighties
, so far big and medium-sized cities at home have obtained universal accreditation, using widely, such as family, hospital, school, do
The various places such as public building, factory, public place, supermarket, business, stadiums.But existing plastic floor organic volatile gas compared with
It is many, maintenance is inconvenient, easily stain the defects such as trace intolerant to chemical reagent such as the tincture of iodine, limits the range of application of plastic floor.
The content of the invention
In order to solve above technical problem, the present invention provides a kind of weather-proof wear-resisting plastic floor Weather-proof film.
A kind of plastic floor Weather-proof film of the present invention, including thickness ratio is 1:3:1 external protection, functional layer and bonding
Layer is co-extruded, and the external protection is fluorine-containing polymer, and the functional layer is fluorine-containing polymer, PUR and functional aid
With 20～100:0～60:0.5～20 ratio is mixed, and the tack coat is fluorine-containing polymer and PUR with 0～40:
60～100 ratio is mixed.
Further, including thickness ratio be 1:3:1 external protection, functional layer and tack coat are co-extruded, the outer guarantor
Sheath is fluorine-containing polymer, and the functional layer is fluorine-containing polymer and functional aid with 90～100:0.5～20 ratio is mixed
Conjunction is formed, and the tack coat is fluorine-containing polymer and PUR with 0～40:60～100 ratio is mixed.
Further, the fluorine-containing polymer is fluorinated ethylene propylene, ethylene-tetrafluoroethylene, polytetrafluoroethylene (PTFE)-perfluor
Propyl vinyl ether, Kynoar, polytetrafluoroethylene (PTFE), polytetrafluoroethylene (PTFE)-perfluoro methyl vinyl ether, polyethylene chlorine trifluoro second
One or more in alkene, polychlorotrifluoroethylene, polytetrafluoroethylene (PTFE)-hexafluoropropene-vinylidene fluoride.
Further, the functional aid include ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer,
One or more in light stabilizer or antistatic additive.
Further, the random copolymer of the PUR including modified polypropene acid resin, copolyamide and ethene,
One kind in polyethylene vinyl acetate resin, polyvinyl butyral resin, polyamide-based PUR or TPO PUR
Or it is several.
The fluorine-containing polymer molecule interchain arrangement that external protection is used in the application is tight, there is stronger hydrogen bond again, therefore has
Have outside good chemical resistance, heat-resisting quantity, oxidative resistance, weatherability, the radiance of resistance to ray, also with piezoelectricity,
The properties such as dielectricity, pyroelectricity, for herein as outermost external protection have it is excellent it is weather-proof, wear-resisting,
It is antifouling to be difficult trace effect.
In the application functional layer due to add functional aid have include uvioresistant, high tenacity, antioxygen, resist cold, electrostatic,
The functions such as light and heat stability, add as the case may be different functionalities auxiliary agent to make it have difference in functionality；While functional layer
With transitional function, it is mainly the mixing material of fluorine-containing polymer and hot melt gum resin, is essentially for transition fluorine-containing high poly-
The tack coat of the external protection of thing and essentially PUR, such as lacks the functional layer of transition, and external protection and tack coat can not be very
Good compatible, easily layering departs from.
The tack coat of the application includes PUR, and selectively mixes a small amount of external protection material fluorine-containing polymer, uses
In the being connected property of co-extrusion with functional layer is improved, PUR is used to bond the plastic floor of plastic cement, polypropylene or polyethylene material,
Bonding is capable of achieving at a temperature of 100～170 DEG C.
A kind of plastic floor of the present invention is had the advantages that with Weather-proof film：
1st, resistance to soiling is strong：It is difficult to oil smoke, oiliness pen and ink etc. to remove spot easy cleaning, and time restriction is not received, when polluting long
Between after be still easily cleaned；
2nd, chemical inertness：The acid-base solution of PH1～14 is resistant to, insoluble in organic solvents such as alcohol, aldehyde, benzene；
3rd, high-wearing feature：Compared with pvc material decorating film, its abrasion resistance properties is improved more than 30%；
4th, the feature of environmental protection：The film has excellent barrier property, can intercept the VOC of base material release, has
High barrier, is conventional polyvinyl chloride decoration material close to zero percent of pass and VOC burst size itself is very low
Below the one thousandth of material；
5th, weatherability：The weatherability and light aging resisting property of the film so as to which out of doors building is widely used, life
To more than 15 years；
6th, popularity：Can bond with metal and nonmetallic materials, various base materials can be played a very good protection, prolong
The service life of long substrate.
7th, safe anti-slipping：Anti-skidding grade reaches world lead level, and surface friction factor is more than 0.5.
Description of the drawings
Fig. 1 is a kind of structural representation of plastic floor Weather-proof film of the invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Embodiment 1
As shown in Figure 1, a kind of plastic floor Weather-proof film of the present embodiment, including thickness ratio is 1:3:1 external protection
1st, functional layer 2 and tack coat 3 are co-extruded, and external protection 1 is fluorine-containing polymer Kynoar and polytetrafluoroethylene (PTFE) with 100:3
Ratio mix, functional layer 2 be Kynoar, polyacrylics and functional aid with 60:30:10.5 ratio
Example is mixed, and functional aid is with 0.5 with ultraviolet absorber and toughener:10 ratio is mixed, tack coat 3 be containing
Fluorine high polymer Kynoar and modified polypropene acid resin are with 60:40 ratios are mixed；The plastic floor of the present embodiment
Can be connected with PVC flooring layer hot melt adhesive by tack coat 3 with Weather-proof film.
Embodiment 2
As shown in Figure 1, a kind of plastic floor Weather-proof film of the present embodiment, including thickness ratio is 1:3:1 external protection
1st, functional layer 2 and tack coat 3 are co-extruded, and external protection 1 is fluorine-containing polymer Kynoar and polytetrafluoroethylene (PTFE) with 100:
10 ratio is mixed, and functional layer 2 is Kynoar, polyacrylics and functional aid with 80:20:1 ratio
Example is mixed, and functional aid is with 0.5 with antioxidant and toughener:0.5 ratio is mixed, and tack coat 3 is poly- second
Alkene-vinyl acetate resin；The plastic floor Weather-proof film of the present embodiment can be by tack coat 3 and polypropylene floor layer hot melt adhesive
It is connected.
Embodiment 3
As shown in Figure 1, a kind of plastic floor Weather-proof film of the present embodiment, including thickness ratio is 1:3:1 external protection
1st, functional layer 2 and tack coat 3 are co-extruded, and external protection 1 is fluorine-containing polymer Kynoar, and functional layer 2 is polyvinylidene fluoride
Alkene and functional aid are with 90:10 ratio is mixed, and functional aid is with 2 with ultraviolet absorber and toughener:8 ratio
Example is mixed, and tack coat 3 is Kynoar and polyvinyl butyral resin with 10:90 ratio is mixed；This reality
Applying the plastic floor Weather-proof film of example can be connected by tack coat 3 with vinyl floors layer hot melt adhesive.
Embodiment 4
As shown in Figure 1, a kind of plastic floor Weather-proof film of the present embodiment, including thickness ratio is 1:3:1 outer protection
Layer 1, functional layer 2 and tack coat 3 is co-extruded, external protection 1 be fluorine-containing polymer polychlorotrifluoroethylene and polytetrafluoroethylene (PTFE) with
100:5 ratio is mixed, and functional layer 2 is polychlorotrifluoroethylene and functional aid with 82:8 ratio is mixed, work(
Energy property auxiliary agent is with 2 with ultraviolet absorber and toughener:6 ratio is mixed, and tack coat 3 is the nothing of copolyamide and ethene
Rule copolymer；The plastic floor Weather-proof film of the present embodiment can be connected by tack coat 3 with rubber floor covering layer hot melt adhesive.
The quality measurements of above example are as shown in the table：
Data above shows to be had the advantages that with Weather-proof film using a kind of plastic floor of above example：
1st, resistance to soiling is strong：It is difficult to oil smoke, oiliness pen and ink etc. to remove spot easy cleaning, and time restriction is not received, when polluting long
Between after be still easily cleaned；
2nd, chemical inertness：The acid-base solution of PH1～14 is resistant to, insoluble in organic solvents such as alcohol, aldehyde, benzene；
3rd, high-wearing feature：Compared with pvc material decorating film, its abrasion resistance properties is improved more than 30%；
4th, the feature of environmental protection：The film has excellent barrier property, can intercept the VOC of base material release, has
High barrier, close to zero percent of pass and VOC burst size itself is very low；
5th, weatherability：The weatherability and light aging resisting property of the film so as to which out of doors building is widely used, life
To more than 15 years；
6th, popularity：Can bond with metal and nonmetallic materials, various base materials can be played a very good protection, prolong
The service life of long substrate.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of plastic floor Weather-proof film, it is characterised in that：It is 1 including thickness ratio:3:1 external protection, functional layer and viscous
Knot layer is co-extruded, and the external protection is fluorine-containing polymer, and the functional layer is helped for fluorine-containing polymer, PUR and feature
Agent is with 20～100:0～60:0.5～20 ratio is mixed, and the tack coat is fluorine-containing polymer and PUR with 0～
40:60～100 ratio is mixed.
2. a kind of plastic floor Weather-proof film according to claim 1, it is characterised in that：It is 1 including thickness ratio:3:1
External protection, functional layer and tack coat are co-extruded, and the external protection is fluorine-containing polymer, and the functional layer is fluorine-containing high poly-
Thing and functional aid are with 90～100:0.5～20 ratio is mixed, and the tack coat is fluorine-containing polymer and PUR
With 0～40:60～100 ratio is mixed.
3. a kind of plastic floor Weather-proof film according to claim 1 and 2, it is characterised in that：The fluorine-containing polymer is
Fluorinated ethylene propylene, ethylene-tetrafluoroethylene, polytetrafluoroethylene (PTFE)-perfluoro propyl vinyl ether, Kynoar, polytetrafluoroethyl-ne
Alkene, polytetrafluoroethylene (PTFE)-perfluoro methyl vinyl ether, polyethylene chlorotrifluoroethylene, polychlorotrifluoroethylene, polytetrafluoroethylene (PTFE)-hexafluoro
One or more in propylene-vinylidene fluoride.
4. a kind of plastic floor Weather-proof film according to claim 1 and 2, it is characterised in that：The functional aid bag
Include one or more in ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer, light stabilizer or antistatic additive.
5. a kind of plastic floor Weather-proof film according to claim 1 and 2, it is characterised in that：The PUR includes changing
Random copolymer, polyethylene vinyl acetate resin, the polyvinyl alcohol contracting fourth of property polyacrylics, copolyamide and ethene
One or more in urea formaldehyde or polyamide-based PUR.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611049760.7A CN106634661A (en) | 2016-11-24 | 2016-11-24 | Weather-proof film for plastic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611049760.7A CN106634661A (en) | 2016-11-24 | 2016-11-24 | Weather-proof film for plastic floor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634661A true CN106634661A (en) | 2017-05-10 |
Family
ID=58812902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611049760.7A Pending CN106634661A (en) | 2016-11-24 | 2016-11-24 | Weather-proof film for plastic floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106634661A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109880361A (en) * | 2019-02-24 | 2019-06-14 | 成都市水泷头化工科技有限公司 | A kind of heat-insulated, moisture-proof, wear-resisting compound imitated wood floor board and preparation method |
| WO2019196343A1 (en) * | 2018-04-12 | 2019-10-17 | 安徽森泰木塑集团股份有限公司 | Outdoor floor and preparation process therefor |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105196778A (en) * | 2015-10-15 | 2015-12-30 | 浙江歌瑞新材料有限公司 | Decorative film |
-
2016
- 2016-11-24 CN CN201611049760.7A patent/CN106634661A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105196778A (en) * | 2015-10-15 | 2015-12-30 | 浙江歌瑞新材料有限公司 | Decorative film |
Non-Patent Citations (1)
| Title |
|---|
| 彭康珍: "《新型塑料建材》", 31 May 2000, 广东科技出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019196343A1 (en) * | 2018-04-12 | 2019-10-17 | 安徽森泰木塑集团股份有限公司 | Outdoor floor and preparation process therefor |
| US11131100B2 (en) | 2018-04-12 | 2021-09-28 | Anhui Sentai Wpc Group Share Co., Ltd | Outdoor laminate floor and a manufacturing technique thereof |
| CN109880361A (en) * | 2019-02-24 | 2019-06-14 | 成都市水泷头化工科技有限公司 | A kind of heat-insulated, moisture-proof, wear-resisting compound imitated wood floor board and preparation method |
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Application publication date: 20170510 |