CN106592895A - Weather-proof adhesive sticker type polyvinyl chloride wallpaper - Google Patents

Weather-proof adhesive sticker type polyvinyl chloride wallpaper Download PDF

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Publication number
CN106592895A
CN106592895A CN201611049766.4A CN201611049766A CN106592895A CN 106592895 A CN106592895 A CN 106592895A CN 201611049766 A CN201611049766 A CN 201611049766A CN 106592895 A CN106592895 A CN 106592895A
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CN
China
Prior art keywords
layer
chloride wallpaper
weather
polrvinyl chloride
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611049766.4A
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Chinese (zh)
Inventor
徐诚
徐洪
蒋晓璐
陈向荣
颜华红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG GREEN NEW MATERIALS CO Ltd
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ZHEJIANG GREEN NEW MATERIALS CO Ltd
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Priority to CN201611049766.4A priority Critical patent/CN106592895A/en
Publication of CN106592895A publication Critical patent/CN106592895A/en
Pending legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552Fatigue strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses weather-proof adhesive sticker type polyvinyl chloride wallpaper which comprises a polyvinyl chloride wallpaper layer. An anti-fouling surface layer and an adhesive sticker layer adhere to the two sides of the polyvinyl chloride wallpaper layer correspondingly. The anti-fouling surface layer is formed by an outer protecting layer, a functional layer and a bonding layer through co-extrusion, and the thickness ratio of the outer protecting layer to the functional layer to the bonding layer is 1:3:1, the outer protecting layer is fluorine-containing polymer, the functional layer is a mixture of fluorine-containing polymer, hot melt glue and a functional assistant with the proportion being 20-100:0-60:0.5-20, and the bonding layer is a mixture of fluorine-containing polymer and hot melt glue with the proportion being 0-40:60-100. The anti-fouling surface layer is connected with the polyvinyl chloride wallpaper layer through the bonding layer in a hot pressed mode. The adhesive sticker layer comprises a pressure-sensitive adhesive layer and a release paper layer. The adhesive sticker layer is connected with the polyvinyl chloride wallpaper layer through the pressure-sensitive adhesive layer in a bonded mode. The weather-proof adhesive sticker type polyvinyl chloride wallpaper has the advantages of being high in fouling resistance, chemically inert, high in abrasion resistance, environmentally friendly, weather-proof and convenient to install.

Description

A kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper
Technical field
The present invention relates to a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper.
Background technology
Polrvinyl chloride wallpaper is widely used house decorative material, and because which has, color is various, pattern is abundant, price is fitted Preferably so as to which there is in designing indoors incomparable advantage.Existing wallpaper single function, often only has attractive, decorative work( Can, use for a long time, the phenomenon such as colour fading, dirty, abrasion, the time limit of its service life well below building easily occur.Again more Change wallpaper, it may appear that indoor VOC it is exceeded it is unhealthful, the problems such as increase cost, cause inconvenience to the user.
The content of the invention
In order to solve above technical problem, the present invention provides a kind of wear-resisting and easy to use weather-proof non-drying adhesive type of resistant and gathers Vinyl chloride wallpaper.
A kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present invention, including polrvinyl chloride wallpaper layer, the polrvinyl chloride Wallpaper layer both sides are stained with antifouling surface layer and non-drying glue layer respectively, and the antifouling surface layer is 1 by thickness ratio:3:1 external protection, Functional layer and tack coat are co-extruded, and the external protection is fluorine-containing polymer, and the functional layer is fluorine-containing polymer, PUR With functional aid with 20~100:0~60:0.5~20 ratio is mixed, and the tack coat is fluorine-containing polymer and heat Melten gel is with 0~40:60~100 ratio is mixed;The antifouling surface layer passes through tack coat and the polrvinyl chloride wallpaper layer Bonding is connected;The non-drying glue layer includes pressure-sensitive adhesive layer and off-style paper layer, and the non-drying glue layer is poly- with described by pressure-sensitive adhesive layer The bonding of vinyl chloride wallpaper layer is connected.
Further, the fluorine-containing polymer is fluorinated ethylene propylene (FEP), ethylene-tetrafluoroethylene, politef-perfluor Propyl vinyl ether, Kynoar, politef, politef-perfluoro methyl vinyl ether, polyethylene chlorine trifluoro second One or more in alkene, polychlorotrifluoroethylene, politef-hexafluoropropene-vinylidene fluoride.
Further, the functional aid include ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer, One or more in light stabilizer or antistatic additive.
Further, the PUR includes modified polypropene acid resin, polyethylene vinyl acetate resin, polyethylene One or more in polyvinyl butyral resin or polyamide-based PUR.
Further, the pressure-sensitive adhesive layer is acrylic pressure-sensitive adhesivee, silicone pressure sensitive adhesive or polyurethaness pressure sensitive adhesive In one kind made by pressure-sensitive adhesive layer.
The fluorine-containing polymer molecule interchain arrangement that external protection is used in the application is tight, has stronger hydrogen bond again, therefore has Have outside good chemical resistance, heat-resisting quantity, oxidative resistance, weatherability, resistance to x radiation x performance, also with piezoelectricity, The properties such as dielectricity, pyroelectricity, for herein as outermost external protection have it is excellent it is weather-proof, wear-resisting, It is antifouling to be difficult trace effect.
In the application functional layer due to add functional aid have include uvioresistant, high tenacity, antioxygen, resist cold, electrostatic, The functions such as light and heat stability, add different functionalities auxiliary agent to make it have difference in functionality as the case may be;While functional layer With transitional function, which is mainly the mixing material of fluorine-containing polymer and hot melt gum resin, is essentially for transition fluorine-containing high poly- The tack coat of the external protection of thing and essentially PUR, such as lacks the functional layer of transition, and external protection and tack coat can not be very Good compatible, easily layering departs from.
The tack coat of the application includes PUR, and selectively mixes a small amount of external protection material fluorine-containing polymer, uses In the being connected property of co-extrusion with functional layer is improved, PUR is used to bond polrvinyl chloride wallpaper, at a temperature of 130~170 DEG C Realize bonding.
The non-drying glue layer of the application is pasted on surface of wall to be pasted for weather-proof non-drying adhesive type polrvinyl chloride wallpaper, makes Release paper need to only be removed by the used time, you can be directly covered on body of wall to be pasted by pressure-sensitive adhesive layer, practical and convenient, without the need for special messenger Gluing is pasted again, it is adaptable to general population, substantially increases degree easy to use.
A kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present invention has the advantages that:
1st, resistance to soiling is strong:It is difficult to oil smoke, oiliness pen and ink etc. to remove spot easy cleaning, and time restriction is not received, when polluting long Between after be still easily cleaned;
2nd, chemical inertness:The acid-base solution of PH1~14 is resistant to, insoluble in organic solvents such as alcohol, aldehyde, benzene;
3rd, high-wearing feature:Compared with conventional polyvinyl chloride wallpaper, its abrasion resistance properties is improved more than 30%;
4th, the feature of environmental protection:The film has excellent barrier property, can intercept the VOC of base material release, have High barrier, close to zero percent of pass and VOC burst size itself is very low, is conventional polyvinyl chloride wallpaper Below one thousandth;
5th, weatherability:The weatherability and light aging resisting property of the polrvinyl chloride wallpaper so as to indoors on external wall Widely use, life was to more than 15 years;
6th, it is easy for installation:During use, removing release paper can paste, and construct simple and convenient, match somebody with somebody glue without the need for special messenger, without dirt Dye, improves degree easy to use.
7th, applied range:It is applicable to various base materials:Plank base material, plastic basis material, metal base etc.;
Description of the drawings
Fig. 1 is a kind of structural representation of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Embodiment 1
As shown in Figure 1, a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present embodiment, including lower shrinkage type polrvinyl chloride Wallpaper substrate layer 1 and antifouling surface layer, antifouling surface layer are 1 by thickness ratio:3:1 external protection 2,4 co-extrusion of functional layer 3 and tack coat Form, external protection 2 is fluorine-containing polymer Kynoar and politef with 100:3 ratio is mixed, functional layer 3 It is Kynoar, modified polypropene acid resin and ultraviolet absorber with 80:20:0.5 ratio is mixed, tack coat 4 It is Kynoar and modified polypropene acid resin with 20:80 ratio is mixed;Antifouling surface layer by tack coat 4 one Side is connected with 1 hot melt adhesive of lower shrinkage type polrvinyl chloride wallpaper substrate layer, non-drying glue layer include acrylic pressure-sensitive adhesivee layer 5 and from Type ply of paper 6, non-drying glue layer are connected with the bonding of polrvinyl chloride wallpaper layer 1 by acrylic pressure-sensitive adhesivee layer 5.
Embodiment 2
As shown in Figure 1, a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present embodiment, including flame retardant type polrvinyl chloride wall Paper base material layer 1 and antifouling surface layer, antifouling surface layer are 1 by thickness ratio:3:1 external protection 2, functional layer 3 and 4 co-extrusion of tack coat and It is fluorine-containing polymer Kynoar and politef with 100 into, external protection 2:5 ratio is mixed, and functional layer 3 is Kynoar, polyethylene vinyl acetate and ultraviolet absorber, toughener are with 60:40:0.5:10 ratios are mixed, bonding Layer 4 is polyethylene vinyl acetate resin;Antifouling surface layer is by the side of tack coat 4 and flame retardant type polrvinyl chloride wallpaper substrate layer 1 Hot melt adhesive is connected;Non-drying glue layer includes silicone pressure-sensitive adhesive layer 5 and off-style paper layer 6, and non-drying glue layer passes through silicone pressure Quick glue-line 5 is connected with the bonding of polrvinyl chloride wallpaper layer 1.
Embodiment 3
As shown in Figure 1, a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present embodiment, including flame retardant type polrvinyl chloride wall Paper base material layer 1 and antifouling surface layer, antifouling surface layer are 1 by thickness ratio:3:1 external protection 2, functional layer 3 and 4 co-extrusion of tack coat and It is fluorine-containing polymer Kynoar and politef with 100 into, external protection 2:3 ratio is mixed, and functional layer 3 is Kynoar, modified polypropene acid resin and ultraviolet absorber are with 80:20:0.5 ratio is mixed, and tack coat 4 is Polyvinyl butyral resin;Antifouling surface layer is viscous with the hot melt of flame retardant type polrvinyl chloride wallpaper substrate layer 1 by the side of tack coat 4 Close and be connected;Non-drying glue layer includes polyurethaness pressure-sensitive adhesive layer 5 and off-style paper layer 6, and non-drying glue layer passes through polyurethaness pressure-sensitive adhesive layer 5 It is connected with the bonding of polrvinyl chloride wallpaper layer 1.
Embodiment 4
As shown in Figure 1, a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of the present embodiment, including lower shrinkage type polrvinyl chloride Wallpaper substrate layer 1 and antifouling surface layer, antifouling surface layer are 1 by thickness ratio:3:1 external protection 2,4 co-extrusion of functional layer 3 and tack coat Form, external protection 2 is fluorine-containing polymer Kynoar and politef with 100:1 ratio is mixed, functional layer 3 It is Kynoar, ultraviolet absorber, heat stabilizer light, stabilizer with 100:0.5:3:0.5 ratio is mixed, tack coat 4 is Kynoar and polyamide-based PUR with 10:90 ratio is mixed;Side of the antifouling surface layer by tack coat 4 It is connected with 1 hot melt adhesive of lower shrinkage type polrvinyl chloride wallpaper substrate layer;Non-drying glue layer includes polyurethaness pressure-sensitive adhesive layer 5 and release Ply of paper 6, non-drying glue layer are connected with the bonding of polrvinyl chloride wallpaper layer 1 by polyurethaness pressure-sensitive adhesive layer 5.
The technical specification result of above example is as shown in table 1 below:
1 embodiment technical specification testing result table of table
Above example quality testing experimental standard is as follows:
1st, stability:The decorating film of 150 ㎜ × 150 ㎜ is attached on the aluminium sheet of 200 ㎜ × 200 ㎜, is carved at its center The cross of one 100 ㎜ × 100 ㎜, after placing 48 hours at 65 DEG C, maximal clearance≤0.3 ㎜ of cross.Execution standard GB/ T2423.2-2008。
2nd, weatherability:With the test machine of daylight charcoal element arc light lamp-based, under irradiation in more than 300 hours, decorating film is without change Change
3rd, low-temperature impact resistance:At a temperature of 0 DEG C, the steel ball of 100g is freely fallen from 125 ㎜ height, impact thick 1.0 The decorating film applied on ㎜ aluminium sheets, decorating film crack-free is without coming off.
4th, wearability:5000 are gone round and round a millstone using wear test machine (taber abraser, abrasion wheels CS-17,1.0 ㎏ of weight) Turn, decorating film superficial makings is unchanged
Execution standard:GB/T 1768-2006
5th, drug resistance, solvent resistance:The flushing of Jing water, Ran Hou after specimen surface drips following medicine, watch or clock glass lid 6h 24h observation surface conditions are placed under room temperature;Petroleum ether, ethanol, n- acetic acid, cresol, ammonia, hydrochloric acid (10%), Caustic soda (10%): It is unchanged
6th, chemical-resistant:After decorating film is attached to aluminium sheet upper 72 hour, it is soaked in following chemicals:
7th, stain resistance:After following material contact 24h, with observing surface condition after neutral detergent or alcohol wipe:
(1) and vinegar, coffee, soy sauce, tomato sauce, Fructus Citri Limoniae juice, wine, cola, black tea, yogurt, Xi Shui (1%), soda, After formalin, milk, hydrochloric acid (10%), ethanol (50%), domestic ammonia, saline (1%) material contact 24h, with Surface condition is observed after property detergent or alcohol wipe, speckle is not stayed;
(2) aqueouss signature pen, wax crayon can be washed away with ethanol.
8th, fire protecting performance:Execution standard:TB/T3237-2010
Scope:Flammability, smokiness, toxicity
Index:Oxygen index (OI) (%) >=28
Flammability level:A
After burning, harmful gas concentration and smoke density index meet table 3 in TB/T3237-2010, table 4 and require
9th, environmental-protecting performance:Meet TB/T 3139-2006《Rolling stock built-in material and room air limits of harmful substances》 In " structural material limits of harmful substances "
Above quality measurements are as shown in table 2:
2 embodiment quality measurements table of table
Data above shows to have using a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper of above example following beneficial Effect:
1st, resistance to soiling is strong:It is difficult to oil smoke, oiliness pen and ink etc. to remove spot easy cleaning, and time restriction is not received, when polluting long Between after be still easily cleaned;
2nd, chemical inertness:The acid-base solution of PH1~14 is resistant to, insoluble in organic solvents such as alcohol, aldehyde, benzene;
3rd, high-wearing feature:Compared with conventional polyvinyl chloride wallpaper, its abrasion resistance properties is improved more than 30%;
4th, the feature of environmental protection:The film has excellent barrier property, can intercept the VOC of base material release, have High barrier, close to zero percent of pass and VOC burst size itself is very low, is conventional polyvinyl chloride wallpaper Below one thousandth;
5th, weatherability:The weatherability and light aging resisting property of the polrvinyl chloride wallpaper so as to indoors on external wall Widely use, life was to more than 15 years;
6th, it is easy for installation:During use, removing release paper can paste, and using simple, paste without the need for special messenger's gluing special messenger, carry High degree easy to use.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper, it is characterised in that:Including polrvinyl chloride wallpaper layer, the polrvinyl chloride Wallpaper layer both sides are stained with antifouling surface layer and non-drying glue layer respectively, and the antifouling surface layer is 1 by thickness ratio:3:1 external protection, Functional layer and tack coat are co-extruded, and the external protection is fluorine-containing polymer, and the functional layer is fluorine-containing polymer, PUR With functional aid with 20~100:0~60:0.5~20 ratio is mixed, and the tack coat is fluorine-containing polymer and heat Melten gel is with 0~40:60~100 ratio is mixed;The antifouling surface layer passes through tack coat and the polrvinyl chloride wallpaper layer Bonding is connected;The non-drying glue layer includes pressure-sensitive adhesive layer and off-style paper layer, and the non-drying glue layer is poly- with described by pressure-sensitive adhesive layer The bonding of vinyl chloride wallpaper layer is connected.
2. a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper according to claim 1, it is characterised in that:It is described fluorine-containing high poly- Thing be fluorinated ethylene propylene (FEP), ethylene-tetrafluoroethylene, politef-perfluoro propyl vinyl ether, Kynoar, poly- four Fluorothene, politef-perfluoro methyl vinyl ether, polyethylene chlorotrifluoroethylene, polychlorotrifluoroethylene, politef- One or more in hexafluoropropene-vinylidene fluoride.
3. a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper according to claim 1, it is characterised in that:The feature is helped Agent includes the one kind or several in ultraviolet absorber, toughener, antioxidant, cold-resistant agent, heat stabilizer, light stabilizer or antistatic additive Kind.
4. a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper according to claim 1, it is characterised in that:The PUR bag Include in modified polypropene acid resin, polyethylene vinyl acetate resin, polyvinyl butyral resin or polyamide-based PUR One or more.
5. a kind of weather-proof non-drying adhesive type polrvinyl chloride wallpaper according to claim 1, it is characterised in that:The pressure-sensitive adhesive layer The pressure-sensitive adhesive layer made by the one kind in acrylic pressure-sensitive adhesivee, silicone pressure sensitive adhesive or polyurethaness pressure sensitive adhesive.
CN201611049766.4A 2016-11-24 2016-11-24 Weather-proof adhesive sticker type polyvinyl chloride wallpaper Pending CN106592895A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085997A (en) * 2017-12-05 2018-05-29 苏州固泰新材股份有限公司 A kind of weather-proof antifouling wallpaper and preparation method thereof
CN108485545A (en) * 2018-03-13 2018-09-04 昆山市聚光装饰材料有限公司 The preparation method of house ornamentation PVC wallpaper
CN109306246A (en) * 2018-10-11 2019-02-05 广东福美新材料科技有限公司 A kind of shock proof automatically cleaning impregnated paper and preparation method thereof

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JPH0679835A (en) * 1991-07-31 1994-03-22 Yamagata Three M Kk Interior decorative material
CN203331515U (en) * 2013-05-25 2013-12-11 甘春丽 Anti-fouling light-dimming heat-insulating film
CN203385883U (en) * 2013-08-15 2014-01-08 江苏特森特新材料科技有限公司 Reflecting film with protective layer
CN204530326U (en) * 2015-02-06 2015-08-05 中山荣思东数码科技有限公司 One repeatedly can move environmental protection wall paper structure
CN105196778A (en) * 2015-10-15 2015-12-30 浙江歌瑞新材料有限公司 Decorative film

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0679835A (en) * 1991-07-31 1994-03-22 Yamagata Three M Kk Interior decorative material
CN203331515U (en) * 2013-05-25 2013-12-11 甘春丽 Anti-fouling light-dimming heat-insulating film
CN203385883U (en) * 2013-08-15 2014-01-08 江苏特森特新材料科技有限公司 Reflecting film with protective layer
CN204530326U (en) * 2015-02-06 2015-08-05 中山荣思东数码科技有限公司 One repeatedly can move environmental protection wall paper structure
CN105196778A (en) * 2015-10-15 2015-12-30 浙江歌瑞新材料有限公司 Decorative film

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085997A (en) * 2017-12-05 2018-05-29 苏州固泰新材股份有限公司 A kind of weather-proof antifouling wallpaper and preparation method thereof
CN108485545A (en) * 2018-03-13 2018-09-04 昆山市聚光装饰材料有限公司 The preparation method of house ornamentation PVC wallpaper
CN109306246A (en) * 2018-10-11 2019-02-05 广东福美新材料科技有限公司 A kind of shock proof automatically cleaning impregnated paper and preparation method thereof
CN109306246B (en) * 2018-10-11 2023-12-01 广东福美新材料科技有限公司 Impact-resistant self-cleaning impregnated paper and preparation method thereof

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Application publication date: 20170426