CN106622311A - Preparation method of silver phosphate photocatalyst with capillary action - Google Patents
Preparation method of silver phosphate photocatalyst with capillary action Download PDFInfo
- Publication number
- CN106622311A CN106622311A CN201611224852.4A CN201611224852A CN106622311A CN 106622311 A CN106622311 A CN 106622311A CN 201611224852 A CN201611224852 A CN 201611224852A CN 106622311 A CN106622311 A CN 106622311A
- Authority
- CN
- China
- Prior art keywords
- silver
- preparation
- threads
- capillary action
- phosphate photocatalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 title claims abstract description 11
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229940019931 silver phosphate Drugs 0.000 title claims abstract description 8
- 229910000161 silver phosphate Inorganic materials 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000002242 deionisation method Methods 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 3
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract description 2
- 238000004065 wastewater treatment Methods 0.000 abstract description 2
- 244000062175 Fittonia argyroneura Species 0.000 abstract 2
- 238000002791 soaking Methods 0.000 abstract 2
- 229920005594 polymer fiber Polymers 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 238000009941 weaving Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003933 environmental pollution control Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NDYNABNWLRVCDO-UHFFFAOYSA-N phosphoric acid silver Chemical compound [Ag].P(O)(O)(O)=O NDYNABNWLRVCDO-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/58—Fabrics or filaments
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a preparation method of a silver phosphate photocatalyst with capillary action. The preparation method comprises the following steps: 1) soaking silver threads with diameter of 0.1-2.0mm in 30% hydrogen peroxide by mass for 5-10min, taking out and washing with deionized water for 3-5 times; and soaking in 1-20% phosphoric acid solution by mass for 20-40min, taking out and washing with deionized water for 3-5 times; and 2) spinning threads from the treated 2-4 strands of silver threads and 6-10 strands of polymer fiber, and weaving cloth from the threads to obtain a silver phosphate photocatalyst with capillary action. Given the hydrophilcity and woolen yarn characteristic of fiber, a film is formed on the surface, and organic pollutants are thoroughly degraded under solar radiation. The preparation method disclosed by the invention is applicable to an unpowered organic wastewater treatment system.
Description
Technical field
The present invention relates to the exploitation of novel environmental pollution control material, more particularly to a kind of there is capillarity silver orthophosphate light to urge
Agent preparation method.
Background technology
Catalyst carrier, also known as carrier, is one of composition of loaded catalyst.Catalytic active component is supported on carrier table
On face, carrier is mainly used in supporting active component, makes catalyst have specific physical behavior, and carrier itself does not typically have
There is catalysis activity.Majority carrier is the product in Catalyst, and conventional has alumina support, silica-gel carrier, carried by active carbon
Body and some natural products such as float stone, diatomite etc..Commonly use " active component title-container name " to show loaded catalyst
Composition, the such as vanadium oxide-diatomite catalyst of the nickel-alumina catalyst of hydrogenation, oxidation.By the side such as ion exchange
Formula introduces interlamination region some compounds, forms the other pillar of molecular level, made by a class aperture it is big, new point of distribution rule
The horizontal composite of son, the characteristics of with absorption, conversion organic molecule.Hydrotalcite is wide in variety, the adjustability of pillar compound, changes
Clay material pore size, adsorption property after property etc. can artificially be controlled by, therefore can be entered according to the difference of purposes
Prepared by row material, have wide application prospects in numerous areas such as petrochemical industry, environmental protection.
Carrier can make made by catalyst there is suitable shape, size and mechanical strength, to meet industrial reactor
Operation is required;Carrier can be such that active component is dispersed on carrier surface, obtain higher specific surface area, improve unit mass activity
The catalytic efficiency of component.
Photochemical catalyst is applied as a kind of new environment-friendly treatment method in organic pollution decomposition etc. is processed.
But nanometer chicken catalyst material has the shortcomings that its is intrinsic i.e. during use:Easily reunite, it is therefore desirable to be carried on load
Body surface face is obtaining optimal using effect.There is a problem of separating difficulty after catalytic action, if to be separated clean, need Jing
Multiple steps are crossed, is wasted time and energy.
The content of the invention
The purpose of the present invention be to overcome the shortcomings of prior art in photocatalyst technology, there is provided one kind have capillary
Effect silver phosphate photocatalyst preparation method.
The technical solution used in the present invention is in turn include the following steps:
1) silver wire of a diameter of 0.1~2.0mm is dipped in into 5~10min of hydrogen peroxide that mass concentration is 30%, taking-up spends
Ionized water rinse 3~5 times, then be dipped in mass concentration be 1%~20% phosphoric acid solution in 20~40min, take out, use
Deionization is washed 3~5 times;
2) by process after 2~4 bursts of silver wires and 6~10 strands of macromolecular fibres be woven into line, then these lines with being woven into
Cloth, that is, obtain with capillarity silver phosphate photocatalyst.
It is an advantage of the invention that:Using silver wire after its surface forms oxide layer, then and phosphatase reaction, form phosphoric acid
Silver.The silver wire and macromolecular fibre that are loaded with silver orthophosphate are spun into after line and are made into cloth again, you can using the hydrophily and hair of fiber
Line characteristic, on its surface film, the thorough degradable organic pollutant under solar radiation are formed.The present invention is suitable for be had with motorless
Machine Waste Water Treatment.
Specific embodiment
3 embodiments of the present invention are provided further below:
Embodiment 1
The silver wire of a diameter of 2.0mm is dipped in into the hydrogen peroxide 10min that mass concentration is 30%, deionized water is taken out and is rinsed
5 times, then be dipped in mass concentration be 20% phosphoric acid solution in 40min, take out, be washed with deionized water 5 times;After processing
4 bursts of silver wires and 10 strands of macromolecular fibres be woven into line, then these lines are obtained with capillarity phosphoric acid with cloth is woven into
Silver-colored photochemical catalyst.
By the 100cm2Levels of catalysts is laid at the 3cm of pending water surface top, and one end level hangs down the contact water surface,
Automatically by capillarity automatic wetting catalyst surface, under sunlight, pollutant decomposes accessing pending water, divides after 2 days
COD in analysis accessing pending water, degradation rate is 95.3%.
Embodiment 2
The silver wire of a diameter of 0.1mm is dipped in into the hydrogen peroxide 5min that mass concentration is 30%, deionized water is taken out and is rinsed 3
Time, then be dipped in mass concentration be 1% phosphoric acid solution in 20min, take out, be washed with deionized water 3 times;After process
2 bursts of silver wires and 6 strands of macromolecular fibres are woven into line, then these lines are obtained with capillarity silver orthophosphate with cloth is woven into
Photochemical catalyst.
By the 100cm2Levels of catalysts is laid at the 3cm of pending water surface top, and one end level hangs down the contact water surface,
Automatically by capillarity automatic wetting catalyst surface, under sunlight, pollutant decomposes accessing pending water, divides after 2 days
COD in analysis accessing pending water, degradation rate is 96.7%.
Embodiment 3
The silver wire of a diameter of 0.6mm is dipped in into the hydrogen peroxide 10min that mass concentration is 30%, deionized water is taken out and is rinsed
5 times, then be dipped in mass concentration be 10% phosphoric acid solution in 30min, take out, be washed with deionized water 5 times;After processing
4 bursts of silver wires and 8 strands of macromolecular fibres be woven into line, then these lines are obtained with capillarity phosphoric acid with cloth is woven into
Silver-colored photochemical catalyst.
By the 100cm2Levels of catalysts is laid at the 3cm of pending water surface top, and one end level hangs down the contact water surface,
Automatically by capillarity automatic wetting catalyst surface, under sunlight, pollutant decomposes accessing pending water, divides after 2 days
COD in analysis accessing pending water, degradation rate is 93.5%.
Claims (1)
1. it is a kind of that there is capillarity silver phosphate photocatalyst preparation method, it is characterized in that in turn including the following steps:
1) silver wire of a diameter of 0.1~2.0mm is dipped in into 5~10min of hydrogen peroxide that mass concentration is 30%, taking-up deionization
Water rinse 3~5 times, then be dipped in mass concentration be 1%~20% phosphoric acid solution in 20~40min, take out, spend from
Son washing 3~5 times;
2) by process after 2~4 bursts of silver wires and 6~10 strands of macromolecular fibres be woven into line, then these lines with cloth is woven into, i.e.,
Obtain with capillarity silver phosphate photocatalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611224852.4A CN106622311B (en) | 2016-12-27 | 2016-12-27 | One kind having capillarity silver phosphate photocatalyst preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611224852.4A CN106622311B (en) | 2016-12-27 | 2016-12-27 | One kind having capillarity silver phosphate photocatalyst preparation method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106622311A true CN106622311A (en) | 2017-05-10 |
CN106622311B CN106622311B (en) | 2019-03-22 |
Family
ID=58832890
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611224852.4A Active CN106622311B (en) | 2016-12-27 | 2016-12-27 | One kind having capillarity silver phosphate photocatalyst preparation method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106622311B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108325542A (en) * | 2018-02-02 | 2018-07-27 | 华北理工大学 | A kind of netted Ag/Ag3PO4The synthetic method of/AgCl composite photocatalyst materials |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101087893A (en) * | 2004-11-15 | 2007-12-12 | 米德尔塞克斯银有限公司 | Fabric structure comprising silver-germanium-copper alloy |
CN102535145A (en) * | 2011-12-16 | 2012-07-04 | 吴江市利达上光制品有限公司 | Novel antibacterial anti-mite wool textile and manufacturing method thereof |
CN103272622A (en) * | 2013-06-20 | 2013-09-04 | 南京信息工程大学 | Preparation method of silver phosphate photocatalyst |
CN103721731A (en) * | 2014-01-21 | 2014-04-16 | 南京信息工程大学 | Novel silver phosphate photocatalyst and preparation method thereof |
CN104047114A (en) * | 2014-06-17 | 2014-09-17 | 李文博 | Nano-silver antibacterial melt-blown non-woven fabric and production method thereof |
CN104862953A (en) * | 2015-04-28 | 2015-08-26 | 常州纺织服装职业技术学院 | Method for depositing nano-silver on cellulose fabric through one step |
CN105217749A (en) * | 2015-07-03 | 2016-01-06 | 何素梅 | Absorption carrier of a kind of loading nano silvery and preparation method thereof |
CN105289497A (en) * | 2015-11-25 | 2016-02-03 | 甘李 | High nanometer sliver loading active carbon and preparation method thereof |
CN105776410A (en) * | 2016-03-28 | 2016-07-20 | 朱连文 | Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof |
-
2016
- 2016-12-27 CN CN201611224852.4A patent/CN106622311B/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101087893A (en) * | 2004-11-15 | 2007-12-12 | 米德尔塞克斯银有限公司 | Fabric structure comprising silver-germanium-copper alloy |
CN102535145A (en) * | 2011-12-16 | 2012-07-04 | 吴江市利达上光制品有限公司 | Novel antibacterial anti-mite wool textile and manufacturing method thereof |
CN103272622A (en) * | 2013-06-20 | 2013-09-04 | 南京信息工程大学 | Preparation method of silver phosphate photocatalyst |
CN103721731A (en) * | 2014-01-21 | 2014-04-16 | 南京信息工程大学 | Novel silver phosphate photocatalyst and preparation method thereof |
CN104047114A (en) * | 2014-06-17 | 2014-09-17 | 李文博 | Nano-silver antibacterial melt-blown non-woven fabric and production method thereof |
CN104862953A (en) * | 2015-04-28 | 2015-08-26 | 常州纺织服装职业技术学院 | Method for depositing nano-silver on cellulose fabric through one step |
CN105217749A (en) * | 2015-07-03 | 2016-01-06 | 何素梅 | Absorption carrier of a kind of loading nano silvery and preparation method thereof |
CN105289497A (en) * | 2015-11-25 | 2016-02-03 | 甘李 | High nanometer sliver loading active carbon and preparation method thereof |
CN105776410A (en) * | 2016-03-28 | 2016-07-20 | 朱连文 | Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
成都印钞公司编: "《现代金银分析》", 31 August 2006, 冶金工业出版社 * |
马建锋等: "活性炭纤维负载Ag3PO4光催化剂的可见光催化性能", 《常州大学学报(自然科学版)》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108325542A (en) * | 2018-02-02 | 2018-07-27 | 华北理工大学 | A kind of netted Ag/Ag3PO4The synthetic method of/AgCl composite photocatalyst materials |
CN108325542B (en) * | 2018-02-02 | 2020-12-08 | 华北理工大学 | Net-shaped Ag/Ag3PO4Synthetic method of/AgCl composite photocatalytic material |
Also Published As
Publication number | Publication date |
---|---|
CN106622311B (en) | 2019-03-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108355717A (en) | A kind of preparation method of cellulose/BiOBr composite photocatalyst materials | |
CN101880961A (en) | Series modified nano titanium dioxide photo-catalyst textile finishing agent and preparation method | |
CN113198473B (en) | Transition metal oxide Fenton catalyst and preparation method and application thereof | |
CN101584996B (en) | Manufacturing method of netted catalyst for degrading organic pollutant in wastewater by photocatalysis | |
CN107999062A (en) | Activated carbon fiber loaded Ag/TiO2The preparation method and application of composite catalyzing material | |
CN111250171B (en) | Preparation method of acrylic fiber-based photocatalytic material | |
CN110180513A (en) | Titanium dioxide-graphene oxide composite sponge and its preparation method and application | |
CN106512988B (en) | A kind of molecular sieve carried type MnO2- ZnO ozone catalyst and preparation method thereof | |
CN106622311B (en) | One kind having capillarity silver phosphate photocatalyst preparation method | |
CN113976078A (en) | Sisal fiber-based biomass activated carbon and preparation method and application thereof | |
CN102517887A (en) | Method for preparing silicon protective in-situ deposition photocatalytic functional textile | |
CN101829603B (en) | Preparation method of beta-iron oxide hydroxides loaded resin and application thereof in photocatalysis | |
CN114481623B (en) | Anti-mosquito fabric and preparation method thereof | |
CN105923695A (en) | Photocatalyst active carbon floating sphere and preparation method thereof | |
CN111957320B (en) | Supported catalyst filter fiber for catalytic degradation of pollutants in water, and preparation and application thereof | |
CN110152644A (en) | A kind of active carbon fiber fabrics are the rGO/Mg (OH) of carrier2Photo catalysis reactor | |
CN110902847B (en) | Production process of carbon fiber ecological grass | |
CN112062157B (en) | Preparation method of tungsten trioxide with inverse opal structure and application of tungsten trioxide in photo-Fenton catalysis | |
CN108117142A (en) | Compound BiOI carbon cloths of a kind of flexibility large area TaON nanometer stick arrays and preparation method thereof | |
CN102441385A (en) | Method for preparing metal modified active carbon fibers and removing methylene blue in water | |
CN108855215A (en) | A kind of photocatalytic fiber preparation method for pollution of estuary object of degrading | |
CN107115858A (en) | MoO3/CeO2/Al2O3The method of tri compound nanofiber degraded indoor formaldehyde | |
CN106521764A (en) | Nanometer self-cleaning shell fabric and preparing method thereof | |
CN108126726B (en) | Flexible large-area Ta3N5Nano-rod array carbon fiber cloth and preparation method thereof | |
CN109231483A (en) | A kind of method of photocatalysis coupled microbe filter integral process Phenol-Containing Wastewater Treatment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |