CN106592229A - Cashmere fabric anti-pilling finishing liquor containing modified sericin and preparation method of finishing liquor - Google Patents
Cashmere fabric anti-pilling finishing liquor containing modified sericin and preparation method of finishing liquor Download PDFInfo
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- CN106592229A CN106592229A CN201611044380.4A CN201611044380A CN106592229A CN 106592229 A CN106592229 A CN 106592229A CN 201611044380 A CN201611044380 A CN 201611044380A CN 106592229 A CN106592229 A CN 106592229A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic System
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Abstract
The invention discloses cashmere fabric anti-pilling finishing liquor containing modified sericin and a preparation method of the finishing liquor. The finishing liquor is prepared from, by weight, 24-48 parts of modified sericin, 11-25 parts of SXA-amino silicone elastomer, 12-26 parts of protease, 8-15 parts of sodium chloride, 3-11 parts of keratin, 5-21 parts of polyethylene wax emulsion, 4-16 parts of magnesium sulfate, 4-15 parts of zinc chloride and 3-11 parts of hydrogen peroxide. The cashmere fabric anti-pilling finishing liquor containing modified sericin can form a protective film on the surface of cashmere fabric aiming at the characteristics of the cashmere fabric, and the cashmere fabric is prevented from pilling; the cashmere fabric anti-pilling finishing liquor containing modified sericin does not affect the hand feeling, elasticity, dyeing fastness and gloss of the fabric.
Description
Technical field
The invention belongs to field of textiles, it is related to a kind of textile finishing liquid, more particularly to it is a kind of containing modified sericin
Fleece fabrics Anti-Pilling Finishes liquid and preparation method thereof.
Background technology
Balling-up is that the fiber that fabric face exposes is tangled the bead to be formed by friction, and its prerequisite for being formed is fabric table
There is loose superfluous random fibre end where close fabric face in face.Fabric pilling mechanism is as follows：Fabric is being worn and is being made
With during, many fiber ends are present in the fibre end of fabric face or close fabric face by external force band to fabric table
Face, the fiber of these exposed ends is subject to the effect of external force friction brushing to be easy to mutually tangle together, forms fluffing.What is continued
During dress and use, these snarly fibers by rotating friction force and linear friction power due to being combined simultaneously
Act on and form little ball top；Acting on the frictional force on bead further can pull out the fiber being connected with bead from fabric,
Simultaneously these fibers are drawn into bead as new fiber end from wide range around so that bead becomes big and becomes tight.After
After the continuous rubbing action by external force, relative intensity fibroplastic spherolite less than normal is easily worn away when being acted on by external force.
Its pilling situation of the fabric of different fiber species compositions is different.In general natural fiber, except wool fabric
Outward, pilling phenomenon is seldom produced, this is determined by the structural behaviour of natural fiber itself；The pure spinning of synthetic fibers is mixed
In yarn fabric, because synthetic fibers surface is smooth, cohesive force is little between fiber, and fiber is beaten with respect to strong team, and elongation is also big, adds fiber
Resistance to torsional fatigue itself, bending resistance fatigue and wearability are good so that these fibers are after external force is undergone, it is easy to skid off fabric face
Mutually tangle to form bead.Carry out both at home and abroad cashmere sweater Anti-Pilling Finishes research it is all less, and do not obtain effective research
Achievement.Main cause has：Mainly produce the country of cashmere in the world, including China, Iran, Mongolia, Turkey etc. a few
Country, these countries do not obtain obvious achievement to the achievement that the Anti-Pilling Finishes of fleece fabrics are studied；
Advanced country in the world, the such as U.S., Germany, Britain, France, the production of state of Japan cashmere it is less, it is to sheep
The research of the Anti-Pilling Finishes technology of fleecy sweatshirt is also less.Retrieved by computer networking, not yet find to have in the world it is special with regard to
Article in terms of cashmere sweater Anti-Pilling Finishes technical research is delivered and patent application, does not also occur excellent resisting on international market
Ball cashmere sweater product.
Domestic each big-and-middle-sized cashmere sweater production enterprise, such as Inner Mongol Erdos cashmere group, Xinjiang Tianshan wool manufacturing
The business organizations such as Co., Ltd, Beijing Snow-Lotus Cashmere Ltd person skilled carries out improving the anti-fluffing of cashmere sweater and rises
The Primary Study of ball finishing technique, research, but do not carry out system and comprehensively study, do not obtain fruitful progress yet.
The content of the invention
The purpose of the present invention is：In order to overcome the defect of prior art, obtaining one kind prevents fleece fabrics balling-up, and can
Ensure its feel, elasticity, dye firm and coloured light etc., the invention provides a kind of fleece fabrics containing modified sericin is anti-
Balling-up dressing liquid and preparation method thereof.
Technical scheme：A kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, by following components by weight
Number proportioning is made：24～48 parts of modified sericin, 11～25 parts of SXA- amodimethicones elastomer, 12～26 parts of protease,
8～15 parts of sodium chloride, 3～11 parts of keratin, 5～21 parts of Tissuemat E breast, 4～16 parts of magnesium sulfate, 4～15 parts of zinc chloride, mistake
3～11 parts of hydrogen oxide.
Preferably, the fleece fabrics Anti-Pilling Finishes liquid containing modified sericin by following components by weight
Proportioning is made：39 parts of modified sericin, 21 parts of SXA- amodimethicones elastomer, 21 parts of protease, 12 parts of sodium chloride, keratin
7 parts, Tissuemat E breast 13 parts, 12 parts of magnesium sulfate, 11 parts of zinc chloride, 6 parts of hydrogen peroxide.
A kind of preparation method of the fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, comprises the steps of：
(1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, is placed in after drying in ether and is soaked 22～50 hours, cocoon shell
It is 1 with the mass ratio of ether:3～6, distilled water is cleaned, dried；Be placed in again in absolute ethyl alcohol soak 12～35 hours, cocoon shell with
The mass ratio of absolute ethyl alcohol is 1:2～5, distilled water is cleaned, dried；
(2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 1～5% sodium carbonate liquor, is boiled 30～70 minutes,
Collect crude extract；
(3) silk gum is refined：Silk gum crude extract is placed in bag filter, bag filter is placed in ultra-pure water under room temperature, every 5
Change water once within～12 hours, polyethylene glycol, magnetic agitation 35～70 minutes are added in the silk gum solution after dialysis；
(4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1～1.7 mixing, is placed in autoclaving
Pot in, 121 DEG C, 0.12～0.16MPa process 0.6～1.4 hour；
(5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E breast, magnesium sulfate,
Zinc chloride and hydrogen peroxide are added in modified silk gum solution, 25～45 DEG C of stirring reactions 1.5～5 hours.
Preferably, step (1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, immersion 42 in ether is placed in after drying little
When, cocoon shell is 1 with the mass ratio of ether:5, distilled water is cleaned, dried；Be placed in again in absolute ethyl alcohol soak 30 hours, cocoon shell with
The mass ratio of absolute ethyl alcohol is 1:4, distilled water is cleaned, dried.
Preferably, step (2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 3.5% sodium carbonate liquor, 55 are boiled
Minute, collect crude extract.
Preferably, step (3) silk gum is refined：Silk gum crude extract is placed in bag filter, is placed in bag filter under room temperature super
In pure water, water was changed once every 8 hours, polyethylene glycol, magnetic agitation 50 minutes are added in the silk gum solution after dialysis.
Preferably, step (4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1.3 mixing, are placed in
In high-pressure sterilizing pot, 121 DEG C, 0.14MPa process 1.1 hours.
Preferably, step (5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E
Breast, magnesium sulfate, zinc chloride and hydrogen peroxide are added in modified silk gum solution, 38 DEG C of stirring reactions 4 hours.
Beneficial effect：(1) the fleece fabrics Anti-Pilling Finishes liquid energy containing modified sericin of the present invention is enough directed to
The characteristics of fleece fabrics, layer protecting film is formed on its surface, prevent its balling-up；(2) it is of the present invention containing modified silk gum egg
White fleece fabrics Anti-Pilling Finishes liquid does not affect feel, elasticity, dyefastness and the gloss of fabric itself.
Specific embodiment
Embodiment 1
A kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, by following components proportioning system by weight
Into：It is 24 parts of modified sericin, 11 parts of SXA- amodimethicones elastomer, 12 parts of protease, 8 parts of sodium chloride, 3 parts of keratin, poly-
5 parts of ethylene waxes breast, 4 parts of magnesium sulfate, 4 parts of zinc chloride, 3 parts of hydrogen peroxide.
A kind of preparation method of the fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, comprises the steps of：
(1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, immersion 22 hours, cocoon shell and second in ether are placed in after drying
The mass ratio of ether is 1:3, distilled water is cleaned, dried；It is placed in again in absolute ethyl alcohol and soaks 12 hours, the matter of cocoon shell and absolute ethyl alcohol
Amount is than being 1:2, distilled water is cleaned, dried；
(2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 1% sodium carbonate liquor, is boiled 30 minutes, collection is slightly carried
Liquid；
(3) silk gum is refined：Silk gum crude extract is placed in bag filter, bag filter is placed in ultra-pure water under room temperature, every 5
Hour changes water once, and polyethylene glycol, magnetic agitation 35 minutes are added in the silk gum solution after dialysis；
(4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1 mixing, in being placed in high-pressure sterilizing pot,
121 DEG C, 0.12MPa process 0.6 hour；
(5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E breast, magnesium sulfate,
Zinc chloride and hydrogen peroxide are added in modified silk gum solution, 25 DEG C of stirring reactions 1.5 hours.
Embodiment 2
A kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, by following components proportioning system by weight
Into：It is 39 parts of modified sericin, 21 parts of SXA- amodimethicones elastomer, 21 parts of protease, 12 parts of sodium chloride, Keratin 7 part, poly-
13 parts of ethylene waxes breast, 12 parts of magnesium sulfate, 11 parts of zinc chloride, 6 parts of hydrogen peroxide.
A kind of preparation method of the fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, comprises the steps of：
(1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, immersion 42 hours, cocoon shell and second in ether are placed in after drying
The mass ratio of ether is 1:5, distilled water is cleaned, dried；It is placed in again in absolute ethyl alcohol and soaks 30 hours, the matter of cocoon shell and absolute ethyl alcohol
Amount is than being 1:4, distilled water is cleaned, dried；
(2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 3.5% sodium carbonate liquor, is boiled 55 minutes, collect thick
Extract；
(3) silk gum is refined：Silk gum crude extract is placed in bag filter, bag filter is placed in ultra-pure water under room temperature, every 8
Hour changes water once, and polyethylene glycol, magnetic agitation 50 minutes are added in the silk gum solution after dialysis；
(4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1.3 mixing, are placed in high-pressure sterilizing pot
In, 121 DEG C, 0.14MPa process 1.1 hours；
(5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E breast, magnesium sulfate,
Zinc chloride and hydrogen peroxide are added in modified silk gum solution, 38 DEG C of stirring reactions 4 hours.
Embodiment 3
A kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, by following components proportioning system by weight
Into：48 parts of modified sericin, 25 parts of SXA- amodimethicones elastomer, 26 parts of protease, 15 parts of sodium chloride, 1 part of Keratin 1,
21 parts of Tissuemat E breast, 16 parts of magnesium sulfate, 15 parts of zinc chloride, 11 parts of hydrogen peroxide.
A kind of preparation method of the fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, comprises the steps of：
(1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, immersion 50 hours, cocoon shell and second in ether are placed in after drying
The mass ratio of ether is 1:6, distilled water is cleaned, dried；It is placed in again in absolute ethyl alcohol and soaks 35 hours, the matter of cocoon shell and absolute ethyl alcohol
Amount is than being 1:5, distilled water is cleaned, dried；
(2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 5% sodium carbonate liquor, is boiled 70 minutes, collection is slightly carried
Liquid；
(3) silk gum is refined：Silk gum crude extract is placed in bag filter, bag filter is placed in ultra-pure water under room temperature, every
Change water once within 12 hours, polyethylene glycol, magnetic agitation 70 minutes are added in the silk gum solution after dialysis；
(4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1.7 mixing, are placed in high-pressure sterilizing pot
In, 121 DEG C, 0.16MPa process 1.4 hours；
(5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E breast, magnesium sulfate,
Zinc chloride and hydrogen peroxide are added in modified silk gum solution, 45 DEG C of stirring reactions 5 hours.
The fleece fabrics Anti-Pilling Finishes liquid containing modified sericin prepared to embodiment 1～3 detects,
As a result it is as shown in the table：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Warp-wise balling-up quantity/ | 45 | 32 | 38 |
| Broadwise balling-up quantity/ | 46 | 34 | 38 |
Claims (8)
1. a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin, it is characterised in that by following components by weight
Number proportioning is made：24～48 parts of modified sericin, 11～25 parts of SXA- amodimethicones elastomer, 12～26 parts of protease,
8～15 parts of sodium chloride, 3～11 parts of keratin, 5～21 parts of Tissuemat E breast, 4～16 parts of magnesium sulfate, 4～15 parts of zinc chloride, mistake
3～11 parts of hydrogen oxide.
2. a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 1, its feature exists
In being made up of following components proportioning by weight：39 parts of modified sericin, 21 parts of SXA- amodimethicones elastomer, albumen
21 parts of enzyme, 12 parts of sodium chloride, Keratin 7 part, 13 parts of Tissuemat E breast, 12 parts of magnesium sulfate, 11 parts of zinc chloride, 6 parts of hydrogen peroxide.
3. the preparation method of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin described in claim 1, its
It is characterised by, comprises the steps of：
(1) cocoon shell pretreatment：Cocoon shell is cleaned using distilled water, immersion 22～50 hours, cocoon shell and second in ether are placed in after drying
The mass ratio of ether is 1:3～6, distilled water is cleaned, dried；Be placed in again in absolute ethyl alcohol soak 12～35 hours, cocoon shell with it is anhydrous
The mass ratio of ethanol is 1:2～5, distilled water is cleaned, dried；
(2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 1～5% sodium carbonate liquor, is boiled 30～70 minutes, collected
Crude extract；
(3) silk gum is refined：Silk gum crude extract is placed in bag filter, bag filter is placed in ultra-pure water under room temperature, every 5～12
Hour changes water once, and polyethylene glycol, magnetic agitation 35～70 minutes are added in the silk gum solution after dialysis；
(4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1～1.7 mixing, is placed in high-pressure sterilizing pot
In, 121 DEG C, 0.12～0.16MPa process 0.6～1.4 hour；
(5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E breast, magnesium sulfate, chlorination
Zinc and hydrogen peroxide are added in modified silk gum solution, 25～45 DEG C of stirring reactions 1.5～5 hours.
4. the preparation side of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 3
Method, it is characterised in that step (1) cocoon shell is pre-processed：Cocoon shell is cleaned using distilled water, immersion 42 in ether is placed in after drying little
When, cocoon shell is 1 with the mass ratio of ether:5, distilled water is cleaned, dried；Be placed in again in absolute ethyl alcohol soak 30 hours, cocoon shell with
The mass ratio of absolute ethyl alcohol is 1:4, distilled water is cleaned, dried.
5. the preparation side of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 3
Method, it is characterised in that step (2) silk gum is slightly extracted：Pretreated cocoon shell is placed in 3.5% sodium carbonate liquor, 55 are boiled
Minute, collect crude extract.
6. the preparation side of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 3
Method, it is characterised in that step (3) silk gum is refined：Silk gum crude extract is placed in bag filter, is placed in bag filter under room temperature ultrapure
In water, water was changed once every 8 hours, polyethylene glycol, magnetic agitation 50 minutes are added in the silk gum solution after dialysis.
7. the preparation side of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 3
Method, it is characterised in that step (4) silk gum is modified：Silk gum and sodium acid carbonate in mass ratio 1 after will be refined:1.3 mixing, are placed in
In high-pressure sterilizing pot, 121 DEG C, 0.14MPa process 1.1 hours.
8. the preparation side of a kind of fleece fabrics Anti-Pilling Finishes liquid containing modified sericin according to claim 3
Method, it is characterised in that step (5) finished product：By SXA- amodimethicone elastomers, protease, sodium chloride, keratin, Tissuemat E
Breast, magnesium sulfate, zinc chloride and hydrogen peroxide are added in modified silk gum solution, 38 DEG C of stirring reactions 4 hours.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611044380.4A CN106592229A (en) | 2016-11-24 | 2016-11-24 | Cashmere fabric anti-pilling finishing liquor containing modified sericin and preparation method of finishing liquor |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611044380.4A CN106592229A (en) | 2016-11-24 | 2016-11-24 | Cashmere fabric anti-pilling finishing liquor containing modified sericin and preparation method of finishing liquor |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227618A (en) * | 2017-06-28 | 2017-10-03 | 常州美帛纺织品有限公司 | A kind of wool fabric antipilling finishing agent |
| CN112981938A (en) * | 2021-04-20 | 2021-06-18 | 浙江工业职业技术学院 | Oxidized and keratin cashmere after-finishing liquid and finishing method |
Citations (4)
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Application publication date: 20170426 |