CN106590960B - A kind of alkaline foam cleaning agent for washing foodstuff dirt and preparation method thereof, application - Google Patents
A kind of alkaline foam cleaning agent for washing foodstuff dirt and preparation method thereof, application Download PDFInfo
- Publication number
- CN106590960B CN106590960B CN201611085955.7A CN201611085955A CN106590960B CN 106590960 B CN106590960 B CN 106590960B CN 201611085955 A CN201611085955 A CN 201611085955A CN 106590960 B CN106590960 B CN 106590960B
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- amine oxide
- foam cleaning
- dirt
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims abstract description 99
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 70
- 238000005406 washing Methods 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229930182470 glycoside Natural products 0.000 claims abstract description 23
- 150000001412 amines Chemical class 0.000 claims abstract description 20
- 239000002738 chelating agent Substances 0.000 claims abstract description 19
- 150000002338 glycosides Chemical class 0.000 claims abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 13
- -1 alkyl dimethyl amine oxide Chemical compound 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 27
- 238000010790 dilution Methods 0.000 claims description 20
- 239000012895 dilution Substances 0.000 claims description 20
- 238000005187 foaming Methods 0.000 claims description 16
- 235000013305 food Nutrition 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002689 soil Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000003760 tallow Substances 0.000 claims description 6
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical class OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical group CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 3
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 claims description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 16
- 238000012360 testing method Methods 0.000 description 28
- 230000001376 precipitating effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 239000008233 hard water Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- MLFIYYDKLNZLAO-UHFFFAOYSA-N 2-aminoethane-1,1-diol Chemical compound NCC(O)O MLFIYYDKLNZLAO-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000012488 sample solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 244000137852 Petrea volubilis Species 0.000 description 2
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 235000014103 egg white Nutrition 0.000 description 2
- 210000000969 egg white Anatomy 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 2
- AQFWNELGMODZGC-UHFFFAOYSA-N o-ethylhydroxylamine Chemical compound CCON AQFWNELGMODZGC-UHFFFAOYSA-N 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 239000010773 plant oil Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- 239000010963 304 stainless steel Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/365—Organic compounds containing phosphorus containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/42—Application of foam or a temporary coating on the surface to be cleaned
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of alkaline foam cleaning agents for washing foodstuff dirt, it is calculated according to mass percent, the alkalinity foam cleaning agent includes component: sodium hydroxide 4%~7%, chelating agent 1%~3%, thickener 0.5%~10%, amine oxide 5~15%, glycoside nonionic surfactant 5~10%, isopropanol 1~5% and pure water 50%~82%.The present invention also provides the applications of the method for preparing the alkalinity foam cleaning agent and the alkalinity foam cleaning agent.Alkalinity foam cleaning agent foam is stable, wall built-up ability is strong, cleaning efficiency is high, dirt-removing power is strong for this.
Description
Technical field
The present invention relates to chemical more particularly to a kind of imitating with colloid for cleaning food industrial equipment surface
The alkaline foam cleaning agent of fruit and its preparation.
Background technique
In recent years, the food-safe property in countries in the world requires constantly to increase.In food processing process, the cleaning of food machinery
Property has a major impact the safety of food.Food machinery usually generates oily dirt, burnt dirt in process of production.Cleaning is handle
The dirt of factory and process equipment removes, these dirts are stored in food contacting surface, and required nutrition is provided for bacterial growth
Substance.All surfaces to be cleaned are not cleaned or cleaning is not thorough, and disinfection cannot reach good result.Therefore, oily dirt,
Burnt dirt is removed not in time to have an adverse effect to product quality.
Foam cleaning is to be added to foam cleaning agent in water in proportion, and solution is sufficiently mixed by compressed air in mixer
Make its foaming after conjunction, then the cleaning solution after foaming is sprayed to the surface of substrate, cleaning solution by outlet hose and spray gun
After being kept for sufficient time of contact with dirt, dirt is handled by dispersion, absorption, dissolution, package mode, makes dirt and object table
Face is completely separated, then is rinsed with clear water and can be easy to remove by the dirt in easily exfoliated state, provides cleaning significantly
Efficiency.
Therefore, it is necessary to provide the alkalinity bubble that a kind of foam is stable, wall built-up ability is strong, cleaning efficiency is high, dirt-removing power is strong
Foam cleaning agent.
Summary of the invention
One of the objects of the present invention is to provide a kind of foam stabilization, wall built-up ability is strong, cleaning efficiency is high, dirt-removing power is strong
The alkaline foam cleaning agent for washing foodstuff dirt,.
To realize the purpose, the present invention provides a kind of alkaline foam cleaning agent for washing foodstuff dirt, according to quality
Percentage calculates, and the alkalinity foam cleaning agent includes following components: sodium hydroxide 4%~7%；Chelating agent 1%~3%；Increase
Thick dose 0.5%~10%；Amine oxide 5%~15%；Glycoside nonionic surfactant 5%~10%；Isopropanol 1%~
5%；And pure water 50%~82%.
Preferably, the chelating agent is 2- phosphonobutane -1,2,4- tricarboxylic acids, or including aminotrimethylenephosphonic acid, two
At least one of hexene triamine pentamethylene phosphonic acids and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulphur
At least one of acid-acrylate terpolymer.
Preferably, the thickener is one of polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthan gum
Or mixtures thereof.
Preferably, the amine oxide is the mixture of alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide,
Middle alkyl is the alkyl chain of C8~C20.Alkyl dimethyl amine oxide/alkyl dihydroxy ethyl amine oxide has relative to alkyl amine oxide
There is lower CMC value, it is easier to form micella.The molecular weight of thickener is big, generates high molecular association in aqueous solution,
Increase solution viscosity.Alkyl dimethyl amine oxide/alkyl dihydroxy ethyl amine oxide is used in compounding with thickener, make its compared with
Solution viscosity with higher can still be made under low concentration, i.e., viscosity increases after alkaline foam cleaning agent dilution.
Preferably, the alkyl dimethyl amine oxide is dodecyldimethylamine oxide, the oxidation of dodecyldimethylamine base
Or mixtures thereof one of amine, cetyl dimethyl amine oxide；The alkyl dihydroxy ethyl amine oxide is octadecyl two
Or mixtures thereof one of ethoxy amine oxide, Cocoalkyl dihydroxy ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
Preferably, the glycoside nonionic surfactant is C8~C10 alkyl glycosides surfactant.
The alkaline foam as described above for being used for washing foodstuff dirt is prepared another object of the present invention is to provide a kind of
The method of cleaning agent, the preparation method include:
(1) by the amount weigh respectively thickener, pure water, amine oxide, glycoside nonionic surfactant, chelating agent,
Isopropanol and sodium hydroxide；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glycoside nonionic surfactant is added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) sodium hydroxide is added, stirring and dissolving is uniform.
Isopropanol, which is added, after dissolution thickener can reduce solution viscosity, stir evenly conducive to solution, then add oxidation
Amine, glycoside nonionic surfactant, solution still keep low viscosity, add chelating agent, are eventually adding sodium hydroxide, because
The addition of sodium hydroxide has heat release.
Another object of the present invention is to provide a kind of application of alkaline foam cleaning agent, steeped using alkalinity as described above
Foam cleaning agent carrys out washing foodstuff dirt, and it is 2%~4% that the alkaline foam cleaning agent, which is first diluted to mass fraction, then will be dilute
The alkaline foam cleaning agent after releasing foams in food soil surface.It is finally cleaned using clear water, removes food soil and alkali
Property foam cleaning agent.
The prior art is compared, and the present invention relates to the alkaline foam cleaning agent with colloid effect, its advantages include:
(1) the alkalinity foam cleaning agent viscosity is low, and viscosity increases after dilution.The addition of isopropanol can reduce alkaline foam
The viscosity of cleaning agent, convenient for product production, filling and use when pump formulated product；When in use by alkaline foam cleaning agent
Dilution, the viscosity reduction of isopropanol are acted on and being reduced, and dilution fluid viscosity increases, and considerably increase product foam stability.Published increasing
In thick system, such as addition cationic surfactant, colloidal magnesium aluminum silicate, polysaccharide and sodium chloride, under these formula systems
The phenomenon that increasing product dilution fluid viscosity cannot be reached.The present invention is compounded using certain thickener with amine oxide, herein
Other substances such as isopropanol are added under formula system has the viscosity that can reduce product, while there is dilution fluid viscosity to increase
Effect.
(2) dosage is saved.The alkalinity foam cleaning agent can be foamed by foamed system in cleaned material surface, due to foam
There is certain mobility, cleaning agent is enable to penetrate into gap or the groove of food soil Non-smooth surface, prevent corner or spot as yet untouched by a clean-up campaign, saves
The dosage of cleaning agent, provides cleaning efficiency.
(3) foam is stable, wall built-up ability is strong.Glycoside nonionic surfactant is compounded with amine oxide, enhances alkalinity
The foaming capacity and foam stability of foam cleaning agent.Influencing the stable principal element with wall built-up ability of foam is that alkaline foam is clear
The viscosity of the viscosity of lotion dilution, alkaline foam cleaning agent dilution is higher, and boundary layer drain age velocity is slower after foaming, interface
Tension is lower, and foam is more lasting；The viscosity of another alkalinity foam cleaning agent dilution is higher, and gas-premeable is with regard to low, durable lather
Property also enhances.Foam is stable, wall built-up ability is strong, keeps it longer with surface to be cleaned dirt time of contact, has superior clear
Wash effect.
(4) cleaning capacity is strong.Chelating agent is selected as compounding for organic phosphine series and organic carboxyl acid series, organic phosphine in formula
Serial chelating agent has good chelating, lower bound inhibition and distortion of lattice effect.Scaling salt class in water can be prevented to form scale, it is special
It is not the formation of calcium carbonate scale, is particularly suitable for winter severe cold area.Organic carboxyl acid series chelating agent is due to point in copolymer
Contain strong acid, weak acid and non-ionic group in subchain simultaneously, it be suitable for high temperature, high pH, it is high firmly with it is high-alkali under the conditions of use, it is right
The deposition of iron oxide, calcium phosphate, trbasic zinc phosphate and calcium carbonate in water has excellent inhibiting effect.The two is used in compounding
Better effect effectively can prevent scale from being formed, and inhibit soil redeposition；With the fatty acid in grease soap can occur for sodium hydroxide
Change reaction and form fatty acid salt, while glycoside nonionic surfactant has the function of wetting, solubilising and high bubble, it can be fast
Speed reduces the surface tension of aqueous solution, facilitates the removing of dirt, while its solubilization can make the dirt after saponification readily soluble
Yu Shui prevents redeposition.
Detailed description of the invention
Fig. 1 is the effect picture after the alkaline foam cleaning agent foaming of the present invention.
Fig. 2 is the effect picture after comparative example foaming.
Specific embodiment
The several different most preferred embodiments of the present invention are illustrated below with reference to the accompanying drawings.
The present invention is intended to provide a kind of alkaline foam cleaning agent for washing foodstuff dirt, according to mass percentage
It calculates, the alkalinity foam cleaning agent includes following components: sodium hydroxide 4%~7%；Chelating agent 1%~3%；Thickener 0.5%
~10%；Amine oxide 5~15%；Glycoside nonionic surfactant 5~10%；Isopropanol 1~5%；And pure water 50%
~82%.
Wherein, the chelating agent be 2- phosphonobutane -1,2,4- tricarboxylic acids, or including aminotrimethylenephosphonic acid, two oneself
At least one of alkene triamine pentamethylene phosphonic acids and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulfonic acid-
At least one of acrylate terpolymer.
The thickener is one of polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthan gum or its mixing
Object.
The amine oxide is the mixture of alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide, and wherein alkyl is
The alkyl chain of C8~C20.The alkyl dimethyl amine oxide is dodecyldimethylamine oxide, the oxidation of dodecyldimethylamine base
Or mixtures thereof one of amine, cetyl dimethyl amine oxide；The alkyl dihydroxy ethyl amine oxide is octadecyl two
Or mixtures thereof one of ethoxy amine oxide, Cocoalkyl dihydroxy ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
The glycoside nonionic surfactant is C8~C10 alkyl glycosides surfactant.
The method for the alkaline foam cleaning agent of washing foodstuff dirt as described above is prepared the present invention also provides a kind of,
The preparation method includes:
(1) by the amount weigh respectively thickener, pure water, amine oxide, glycoside nonionic surfactant, chelating agent,
Isopropanol and sodium hydroxide；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glycoside nonionic surfactant is added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) sodium hydroxide is added, stirring and dissolving is uniform.
The present invention also provides a kind of applications of alkaline foam cleaning agent, are come using alkaline foam cleaning agent as described above clear
Food soil is washed, it is 2%~4% that the alkaline foam cleaning agent, which is first diluted to mass fraction, then by the alkali after dilution
Property foam cleaning agent foaming in food soil surface.It is finally cleaned using clear water, removes food soil and alkaline foam cleaning agent.
Embodiment one
1. taking polyacrylamide 5g, it is uniformly dissolved with 500g water；
2. isopropanol 40g is added thereto, it is uniformly dissolved；
3. it is separately added into dodecyl amine oxide 20g thereto, tallow alkyl dihydroxy ethyl amine oxide 60g, alkyl glycosides
Class surfactant 50g, stirring and dissolving are uniform；
4. amino trident phosphonic acids 20g is added thereto, stirring and dissolving is uniform；
5. sodium hydroxide 50g is added thereto, stirring and dissolving is uniform；Detection is qualified.
Embodiment two
1. taking polyvinyl alcohol 20g, it is uniformly dissolved with 700g water；
2. isopropanol 10g is added thereto, it is uniformly dissolved；
3. it is separately added into tetradecyldimethylamine oxide 50g thereto, tallow alkyl dihydroxy ethyl amine oxide 100g, alkane
Base glycoside surfactant 100g, stirring and dissolving are uniform；
4. hydroxy ethylidene phosphonic acids 10g is added thereto, stirring and dissolving is uniform；
5. sodium hydroxide 70g is added thereto, stirring and dissolving is uniform；Detection is qualified.
Embodiment three
1. taking sodium carboxymethylcellulose 100g, it is uniformly dissolved with 820g water；
2. isopropanol 50g is added thereto, it is uniformly dissolved；
3. it is separately added into Cocoalkyl dihydroxy ethyl amine oxide 30g thereto, tallow alkyl dihydroxy ethyl amine oxide 100g,
Alkyl glycosides surfactant 60g, stirring and dissolving are uniform；
3. addition 2- phosphonobutane -1,2,4- tricarboxylic acids 30g, stirring and dissolving are uniform thereto；
5. sodium hydroxide 70g is added thereto, stirring and dissolving is uniform；Detection is qualified.
Comparative example
The composition of conventional alkaline foam cleaning agent is as follows:
Below by the effect for testing alkaline foam cleaner and comparative experiments example more of the invention.
The test of 1 foam stability: foaming properties are according to " surfactant detergent test method " (GB/T 13173-
2008) prescriptive procedure carries out, and is measured using Roche foam meter.Foam is high when test measures sample initial foam height and 30min
Degree, is compared to observe the foam performance and foam stability of Examples 1 to 3, while with comparative example product.
The foaming properties of Examples 1 to 3 and comparative experimental example are measured, experimental result is as follows:
The alkaline foam cleaning agent foaming properties measurement result of table 1
As known from Table 1, the foam of alkaline foam cleaning agent of the invention is more stable compared with comparative example.
2 viscosity tests: detergent viscosimetric analysis is according to " surfactant and detergent rotary viscosity design determining liquid product
Viscosity " (GB/T 15357-2014) method carry out.
Viscosimetric analysis uses NDJ-8SN rotational viscometer, and determination condition is No. 2 rotors, revolving speed 60r/min, experiment knot
Fruit is as follows:
The alkaline foam cleaning agent viscosity experiment result of table 2
As known from Table 2, the viscosity after alkaline foam cleaning agent of the invention dilution increases, and the viscosity of comparative example becomes
Change less, or even reduces.
3 hard water resistance tests: the preparation of hard water is according to " preparation of calcium hardness water known to surfactant " (GB/T 6367-
2012) method is prepared.It weighs 16.7g anhydrous calcium chloride and 24.7g magnesium sulfate prepares 10L, about 2500mg/L hard water.When use
It is diluted to different hardness water.The water of different hardness is prepared, then alkaline cleaner is diluted to concentration is used with hard water, tests
Its stability in hard water energy.
The stability in hard water energy of Examples 1 to 3 and comparative experimental example the results show that the alkaline cleaner of Examples 1 to 3 it is dilute
When to release concentration be 4%, it is 250mg/L~625mg/ that the alkaline foam cleaning agent with antifreezing effect developed, which can tolerate hardness,
The hard water of L；The resistance to hard water ability of comparative example is poor.
The resistance to hard water experimental result of the alkaline foam cleaning agent of table 3
| Hardness | 250mg/L | 375mg/L | 500mg/L | 625mg/L |
| Embodiment 1 | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating |
| Embodiment 2 | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating |
| Embodiment 3 | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating | It is transparent, without precipitating |
| Comparative example | It is muddy, without precipitating | Muddiness has precipitating | Muddiness has precipitating | Muddiness has precipitating |
4. detergency test: alkaline foam colloid cleaning agent detergency measurement is according to " food items and industrial equipment alkali
Property cleaning agent " (QBT 4314-2012) method carry out.
The preparation of 4.1 test pieces
Test steels piece is 304 stainless steel substrates, and specification is 50mm × 25mm × 4mm.First use 180# sand paper by the table of test piece
Face is polished, then bright by the polishing of parallel ridge orientation with 200# sand paper, is deposited in be washed in drier.It is clamped with tweezers
The test piece that absorbent cotton has been polished successively scrubs in acetone and dehydrated alcohol, is placed on clean filter paper, is blotted with filter paper, is put
It is stand-by after dry 4h in drier.
The preparation of 4.2 hard water
It weighs 16.7g anhydrous calcium chloride and 24.7g magnesium sulfate prepares 10L, about 2500mg/L hard water.1L is taken to fill when use
It is 250mg/L hard water to 10L.
The preparation of 4.3 sample solutions
Sample solution is prepared using concentration by product with 250mg/L hard water, to test.
The preparation of 4.4 artificial dirts
By butter: lard: refined plant oil: glycerin monostearate: sugar aqueous solution: egg white presses 16:16:3.2:30:
2.8 ratio is prepared, this is artificial dirt.
Butter, lard, refined plant oil, glycerin monostearate are mixed in beaker, set heat value 180 on electric furnace
DEG C, stirring keeps this temperature to stir 10min, then beaker is moved to magnetic stirrer, is cooled to 60 DEG C, and it is molten that syrup is added
Liquid, egg white are uniformly mixed.It is ready-to-use.
The preparation of 4.5 dirty pieces
It is one group by the test piece three pieces polished and cleaned, prepares three groups altogether, weighing, quality is at this time with m0It indicates.
Weighed test piece is sandwiched on film airing stand one by one, shelf should be clipped in test piece more than 20mm line, by film airing stand
It sets and prepares to defile in enamel tray, temperature of defiling is 60 DEG C.When dirt is maintained at 60 DEG C, one by one by test piece together with clip from the piece that dries in the air
It is removed on frame；Hand-held clip immerses test piece in greasy dirt to once 1~2s along 20mm, slowly takes out, to drip speed under greasy dirt
After slack-off, extension is returned on original film airing stand, primary to prepare dirty piece.After dirt solidification, dirty piece is removed with filter paper or absorbent cotton
The extra dirt in dirty piece bottom edge and two avris is wiped, after hanging 4h at room temperature, accurate weighing is defiled the quality m of test piece1.This
When each dirty piece extension dirt amount should ensure that in 0.3g~0.5g.
4.6 test procedure
Sample solution is poured into stainless steel water bath, is heated to (80 ± 2) DEG C, constant temperature is kept.The pendulum of adjustment pendulum washing machine
Washing frequency is (30 ± 2) DEG C secondary/min (being back and forth 1 time), at this time clips the test piece of the known amount of defiling with the clip of pendulum washing machine,
Pay attention to being clipped in test piece more than 20mm line, test piece is totally immersed into detergent solution and impregnates 1min, starting pendulum washing machine, pendulum is washed
13min takes out rapidly test piece, hangs the 3h that dries in the air and test piece is weighed, and quality is m at this time2。
4.7 results calculate
Detergency D is expressed as a percentage, and is calculated as follows:
D (100%)=(m1-m2)/(m1-m0)×100
In formula: m0--- test piece quality before defiling, unit are gram (g)；
m1--- test piece quality after defiling, unit are gram (g)；
m2--- test piece quality after cleaning, unit are gram (g).
For the 4.8 antifreeze alkaline cleaner differences of experiment using detergency under concentration, experimental result is as follows:
The alkaline foam cleaning agent detergency experimental result of table 4
As shown in Table 4, the detergency of alkaline bubble face cleaning agent of the invention is up to 93% or more, compared with the decontamination of comparative example
Ability is strong.
5. foaming test: Examples 1 to 3 being proportionally diluted to 2% using solution, will be produced using mobile foaming machine
Product foam is sprayed on body surface.For the wall built-up performance of test product, 1 square metre of stainless steel plate is vertically hung on wall, it will
Bubble jet thereon, observes the wall built-up situation and stability of foam.Meanwhile using same procedure by comparative example sample foams
It is sprayed on stainless steel plate, is compared.
Examples 1 to 3 alkalinity foam cleaning agent and comparative example sample are subjected to foaming experiment, observe foam stability
And wall built-up ability.The results show that the foam of Examples 1 to 3 is relatively steady when cleaning agent foam is sprayed on stainless steel surface 5min
Fixed, wall built-up ability is strong, and the foam of comparative experimental example starts to rupture, and starts to glide, specifically as shown in Fig. 1~2.
The prior art is compared, and the present invention relates to the alkaline foam cleaning agent with colloid effect, its advantages include:
(1) the alkalinity foam cleaning agent viscosity is low, and viscosity increases after dilution.The addition of isopropanol can reduce alkaline foam
The viscosity of cleaning agent, convenient for product production, filling and use when pump formulated product；When in use by alkaline foam cleaning agent
Dilution, the viscosity reduction of isopropanol are acted on and being reduced, and dilution fluid viscosity increases, and considerably increase product foam stability.Published increasing
In thick system, such as addition cationic surfactant, colloidal magnesium aluminum silicate, polysaccharide and sodium chloride, under these formula systems
The phenomenon that increasing product dilution fluid viscosity cannot be reached.The present invention is compounded using certain thickener with amine oxide, herein
Other substances such as isopropanol are added under formula system has the viscosity that can reduce product, while there is dilution fluid viscosity to increase
Effect.
(2) dosage is saved.The alkalinity foam cleaning agent can be foamed by foamed system in cleaned material surface, due to foam
There is certain mobility, cleaning agent is enable to penetrate into gap or the groove of food soil Non-smooth surface, prevent corner or spot as yet untouched by a clean-up campaign, saves
The dosage of cleaning agent, provides cleaning efficiency.
(3) foam is stable, wall built-up ability is strong.Glycoside nonionic surfactant is compounded with amine oxide, enhances alkalinity
The foaming capacity and foam stability of foam cleaning agent.Influencing the stable principal element with wall built-up ability of foam is that alkaline foam is clear
The viscosity of the viscosity of lotion dilution, alkaline foam cleaning agent dilution is higher, and boundary layer drain age velocity is slower after foaming, interface
Tension is lower, and foam is more lasting；The viscosity of another alkalinity foam cleaning agent dilution is higher, and gas-premeable is with regard to low, durable lather
Property also enhances.Foam is stable, wall built-up ability is strong, keeps it longer with surface to be cleaned dirt time of contact, has superior clear
Wash effect.
(4) cleaning capacity is strong.Chelating agent is selected as compounding for organic phosphine series and organic carboxyl acid series, organic phosphine in formula
Serial chelating agent has good chelating, lower bound inhibition and distortion of lattice effect.Scaling salt class in water can be prevented to form scale, it is special
It is not the formation of calcium carbonate scale, is particularly suitable for winter severe cold area.Organic carboxyl acid series chelating agent is due to point in copolymer
Contain strong acid, weak acid and non-ionic group in subchain simultaneously, it be suitable for high temperature, high pH, it is high firmly with it is high-alkali under the conditions of use, it is right
The deposition of iron oxide, calcium phosphate, trbasic zinc phosphate and calcium carbonate in water has excellent inhibiting effect.The two is used in compounding
Better effect effectively can prevent scale from being formed, and inhibit soil redeposition；With the fatty acid in grease soap can occur for sodium hydroxide
Change reaction and form fatty acid salt, while glycoside nonionic surfactant has the function of wetting, solubilising and high bubble, it can be fast
Speed reduces the surface tension of aqueous solution, facilitates the removing of dirt, while its solubilization can make the dirt after saponification readily soluble
Yu Shui prevents redeposition.
Above disclosed is only presently preferred embodiments of the present invention, cannot limit the right of the present invention with this certainly
Range, therefore according to equivalent variations made by scope of the present invention patent, it is still within the scope of the present invention.
Claims (5)
1. a kind of alkaline foam cleaning agent for washing foodstuff dirt, which is characterized in that it is calculated according to mass percent, it is described
Alkaline foam cleaning agent includes following components:
The amine oxide be alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide mixture, wherein alkyl for C8~
The alkyl chain of C20, the thickener be one of polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthan gum or its
Mixture, the chelating agent are 2- phosphonobutane -1,2,4- tricarboxylic acids, or including aminotrimethylenephosphonic acid, two hexene triamines
At least one of pentamethylene phosphonic acids and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulfonic-acrylic
At least one of ester terpolymer.
2. being used for the alkaline foam cleaning agent of washing foodstuff dirt as described in claim 1, which is characterized in that the alkyl two
Methyl oxidation amine is dodecyldimethylamine oxide, in tetradecyldimethylamine oxide, cetyl dimethyl amine oxide
Or mixtures thereof one kind；The alkyl dihydroxy ethyl amine oxide is octadecyl dihydroxy ethyl amine oxide, Cocoalkyl dihydroxy
Or mixtures thereof one of ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
3. being used for the alkaline foam cleaning agent of washing foodstuff dirt as described in claim 1, which is characterized in that the glycoside
Nonionic surfactant is C8~C10 alkyl glycosides surfactant.
4. a kind of side for preparing the alkaline foam cleaning agent as claimed in any one of claims 1 to 3 for washing foodstuff dirt
Method, which is characterized in that the preparation method includes:
(1) thickener, pure water, amine oxide, glycoside nonionic surfactant, chelating agent, isopropyl are weighed respectively by the amount
Alcohol and sodium hydroxide；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glycoside nonionic surfactant is added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) sodium hydroxide is added, stirring and dissolving is uniform.
5. carrying out washing foodstuff dirt using alkaline foam cleaning agent as claimed in any one of claims 1 to 3, which is characterized in that
The alkaline foam cleaning agent is diluted to mass fraction 2%~4%, by the alkaline foam cleaning agent foaming after dilution in
Food soil surface.
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| CN114686321B (en) * | 2022-04-28 | 2024-07-02 | 陕西汉隆清洁科技有限公司 | Low-foam environment-friendly efficient CIP alkaline cleaning agent for food processing and preparation method thereof |
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