CN106582575A - Adsorbing agent used for sewage treatment and preparation method thereof - Google Patents

Adsorbing agent used for sewage treatment and preparation method thereof Download PDF

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Publication number
CN106582575A
CN106582575A CN201611256345.9A CN201611256345A CN106582575A CN 106582575 A CN106582575 A CN 106582575A CN 201611256345 A CN201611256345 A CN 201611256345A CN 106582575 A CN106582575 A CN 106582575A
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Prior art keywords
parts
mixture
added
cellulose
adsorbent
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CN201611256345.9A
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应璐超
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Yuyao Hart Food Co Ltd
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Yuyao Hart Food Co Ltd
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Priority to CN201611256345.9A priority Critical patent/CN106582575A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229Compounds of Fe
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12Naturally occurring clays or bleaching earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/165Natural alumino-silicates, e.g. zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/286Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof

Abstract

The invention discloses an adsorbing agent used for sewage treatment. The adsorbing agent is composed of, by weight, 2-6 parts of loofash sponge, 4-9 parts of straw, 1.5-5 parts of wood chips, 15-24 parts of attapulgite, 0.5-3 parts of ferric sulfate, 3-8 parts of soybean meal, 5-10 parts of silica gel, 8-15 parts of montmorillonite, 4-10 parts of zeolite, 10-18 parts of ion exchange resin, 0.5-6 parts of humic acid, 2-8 parts of cellulose and 0.5-2.5 parts of chloramphenicol. The invention further discloses a preparation method of the adsorbing agent. All the components achieve a synergistic effect, the treatment effect on kinds of waste is good, the adsorbing treatment effect on sewage containing nitrate and nitrite is also good, harmful components in the sewage can be adsorbed, the treatment cost of the sewage is lowered, secondary pollution is avoided, and the using effect is good.

Description

A kind of adsorbent for sewage disposal and preparation method thereof
Technical field
The present invention relates to field of environment protection, specifically a kind of adsorbent for sewage disposal.
Background technology
The activity of the mankind can be such that substantial amounts of industry, agricultural and domestic refuse enters in water, be contaminated water.The whole world The sewage that there are about billion cubic meter more than 4200 every year enters rivers,lakes and seas, pollutes the fresh water of 5.5 tcms, and this is equivalent to complete More than the 14% of ball runoff volume.China has 82% people to drink shallow well and river, and wherein severe water pollution antibacterial exceedes Sanitary standard accounts for 75%, by the drinking water population about 1.6 hundred million of Organic Pollution.For a long time, people think always originally Water is safety and sanitation.But, because water pollution, tap water of today can not be health.Tap water is only capable of adopting The methods such as precipitation, filtration, chlorination, by river or subsoil water drinkable water is simply processed into.Tap water chlorination can be effective Kill except pathogenic bacteria, while can also produce more halogenated hydrocarbon compound, the content of these chlorinated organics is multiplied, and is to cause people Class suffers from the maximum root of various human primary gastrointestinal cancers.The composition of municipal pollution is sufficiently complex, in contaminated waters outside removing heavy metals, also contains There are the Harmful Residues such as a lot of pesticide, chemical fertilizer, detergent, even boiling tap water, what above-mentioned residue still drove does not go, And the concentration of nuisance is increased in boil water, the content of the dissolved oxygen for being beneficial to health is reduced, and make nitrous The carcinogen such as hydrochlorate and chloroform increases.
Heavy metal is to cause a class noxious substance of water pollution, and micro heavy metal can produce poisonous effect, a huge sum of money It is many-sided, multi-level to belong to the harm to health, and its toxicological effect is mainly manifested in many such as reduction resistance of human body Aspect.Heavy metal is all non-reduced type noxious substance, can ultimately cause people along food chain or food web by bio-absorbable, accumulation Volume is tired out and chronic poisoning.Heavy Metals in Waters pollution monitoring is always the focus of Research of Environmental Sciences with preventing and treating.People are continuous Ground exploitation, the methods and techniques for improving improvement heavy metal wastewater thereby, generate such as Physical, chemical method, biochemical process process Method, but current method does not reach the expection of people.
The content of the invention
It is an object of the invention to provide a kind of adsorbent for sewage disposal, to solve above-mentioned background technology in propose Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of adsorbent for sewage disposal, is made up of following raw material according to weight portion:Retinervus Luffae Fructuss 2-6 parts, straw 4-9 Part, wood flour 1.5-5 parts, attapulgite 15-24 parts, iron sulfate 0.5-3 parts, analysis for soybean powder 3-8 part, silica gel 5-10 parts, montmorillonite 8- 15 parts, zeolite 4-10 parts, ion exchange resin 10-18 parts, humic acid 0.5-6 parts, cellulose 2-8 parts and chloromycetin 0.5-2.5 Part.
As further scheme of the invention:Straw is using corn straw, soybean stalk, broomcorn straw and wheat stalk One or several mixture.
As further scheme of the invention:Cellulose is using methylcellulose and the one or two kinds of of Microcrystalline Cellulose Mixture, silica gel using the one or two kinds of of macro porous silica gel and silochrom mixture.
The preparation method of the adsorbent for sewage disposal, comprises the following steps that:
Step one, Retinervus Luffae Fructuss, straw, silica gel, ion exchange resin and wood flour is put in pulverizer and is crushed to particle diameter not More than 1mm, the first mixture is obtained;
Step 2,1-2 hours are calcined by montmorillonite and zeolite under 700-850 degree Celsius, and room is naturally cooled to after calcining Temperature and be ground into 80-150 mesh powder, obtain the second mixture;
Step 3, iron sulfate, analysis for soybean powder and humic acid are added in the deionized water of gross weight 3-6 times, in heating-up temperature To be stirred mixing under 45-70 degree Celsius, speed of agitator is 750-900rpm, and mixing time is 10-15 minutes, obtains first Mixed solution;
Step 4, cellulose is added in the first mixed solution, is added while stir, until stirring, is obtained Second mixed solution;
Step 5, the first mixture and the second mixture are added in the second mixed solution, are 50-65 degree Celsius in temperature Under carry out ultrasonic agitation 20-45 minute, then be added thereto to attapulgite and chloromycetin stirs, homogeneous mixture solotion is entered The process of row freezing gel, is dried in a nitrogen environment and crushes, you can obtain finished product.
As further scheme of the invention:The whipping temp of step 4 is 30-42 degree Celsius, and mixing speed is 180- 300rpm, the baking temperature of step 5 is 40-54 degree Celsius.
Compared with prior art, the invention has the beneficial effects as follows:The raw material sources of the present invention are extensive, preparation process is simple, Low production cost, it is adaptable to large-scale industrial production;Each component plays synergism in the present invention, for the place of various wastes Reason effect is good, while the adsorption treatment effect of the sewage containing NO3-N and NO2-N is also showed preferably, can be by sewage In harmful components absorption, reduce cost of sewage disposal, it is to avoid secondary pollution, using effect is good.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of adsorbent for sewage disposal, is made up of following raw material according to weight portion:2 parts of Retinervus Luffae Fructuss, 4 parts of straw, 1.5 parts of wood flour, 15 parts of attapulgite, 0.5 part of iron sulfate, 3 parts of analysis for soybean powder, 5 parts of silica gel, 8 parts of montmorillonite, 4 parts of zeolite, ion are handed over Change 0.5 part of 10 parts of resin, 0.5 part of humic acid, 2 parts of cellulose and chloromycetin.Straw is using the mixed of corn straw and broomcorn straw Compound.
The preparation method of the adsorbent for sewage disposal, comprises the following steps that:
Step one, Retinervus Luffae Fructuss, straw, silica gel, ion exchange resin and wood flour is put in pulverizer and is crushed to particle diameter and is 0.6mm, obtains the first mixture;
Step 2, montmorillonite and zeolite are calcined 1 hour under 720 degrees Celsius, naturally cool to after calcining room temperature and 80 mesh powder are ground into, the second mixture is obtained;
Step 3, iron sulfate, analysis for soybean powder and humic acid are added in the deionized water of 4 times of gross weight, are in heating-up temperature Mixing is stirred under 50 degrees Celsius, speed of agitator is 750rpm, and mixing time is 12 minutes, obtains the first mixed solution;
Step 4, cellulose is added in the first mixed solution, is added while stir, until stirring, is obtained Second mixed solution;
Step 5, the first mixture and the second mixture are added in the second mixed solution, in the case where temperature is for 50 degrees Celsius Carry out ultrasonic agitation 20 minutes, then be added thereto to attapulgite and chloromycetin stirs, homogeneous mixture solotion is carried out cold Freeze Gel Treatment, be dried in a nitrogen environment and crush, you can obtain finished product.
The product of embodiment 1 is added into the sewage containing hydrargyrum and lead, after adsorption treatment, the mercury content of sewage is reduced to 0.006mg/L, the content of lead is reduced to 0.01mg/L.
Embodiment 2
A kind of adsorbent for sewage disposal, is made up of following raw material according to weight portion:3.5 parts of Retinervus Luffae Fructuss, straw 7 Part, 4 parts of wood flour, 19 parts of attapulgite, 2 parts of iron sulfate, 6 parts of analysis for soybean powder, 7 parts of silica gel, 11 parts of montmorillonite, 7 parts of zeolite, ion are handed over Change 1.5 parts of 14 parts of resin, 3 parts of humic acid, 5 parts of cellulose and chloromycetin.Cellulose adopts methylcellulose, silica gel to adopt macropore Silica gel.
The preparation method of the adsorbent for sewage disposal, comprises the following steps that:
Step one, Retinervus Luffae Fructuss, straw, silica gel, ion exchange resin and wood flour is put in pulverizer and is crushed to particle diameter and is 0.4mm, obtains the first mixture;
Step 2, montmorillonite and zeolite are calcined 1.5 hours under 780 degrees Celsius, and room temperature is naturally cooled to after calcining simultaneously And 120 mesh powder are ground into, obtain the second mixture;
Step 3, iron sulfate, analysis for soybean powder and humic acid are added in the deionized water of 5 times of gross weight, are in heating-up temperature Mixing is stirred under 60 degrees Celsius, speed of agitator is 830rpm, and mixing time is 13 minutes, obtains the first mixed solution;
Step 4, cellulose is added in the first mixed solution, is added while stir, until stirring, is obtained Second mixed solution;
Step 5, the first mixture and the second mixture are added in the second mixed solution, in the case where temperature is for 60 degrees Celsius Carry out ultrasonic agitation 30 minutes, then be added thereto to attapulgite and chloromycetin stirs, homogeneous mixture solotion is carried out cold Freeze Gel Treatment, be dried in a nitrogen environment and crush, you can obtain finished product.
The product of embodiment 2 is added to into the sewage containing NO3-N and NO2-N, after adsorption treatment, sewage NO3-N and NO2-N content is reduced to 0.01mg/L.
Embodiment 3
A kind of adsorbent for sewage disposal, is made up of following raw material according to weight portion:6 parts of Retinervus Luffae Fructuss, 8 parts of straw, 5 parts of wood flour, 22 parts of attapulgite, 3 parts of iron sulfate, 7 parts of analysis for soybean powder, 9 parts of silica gel, 14 parts of montmorillonite, 10 parts of zeolite, ion exchange 2.5 parts of 18 parts of resin, 6 parts of humic acid, 8 parts of cellulose and chloromycetin.Straw adopts corn straw, soybean stalk, broomcorn straw With the mixture of wheat stalk.Cellulose adopts macro porous silica gel using methylcellulose and the mixture of Microcrystalline Cellulose, silica gel With the mixture of silochrom.
The preparation method of the adsorbent for sewage disposal, comprises the following steps that:
Step one, Retinervus Luffae Fructuss, straw, silica gel, ion exchange resin and wood flour is put in pulverizer and is crushed to particle diameter and is 0.8mm, obtains the first mixture;
Step 2, montmorillonite and zeolite are calcined 2 hours under 820 degrees Celsius, naturally cool to after calcining room temperature and 140 mesh powder are ground into, the second mixture is obtained;
Step 3, iron sulfate, analysis for soybean powder and humic acid are added in the deionized water of 6 times of gross weight, are in heating-up temperature Mixing is stirred under 70 degrees Celsius, speed of agitator is 880rpm, and mixing time is 14 minutes, obtains the first mixed solution;
Step 4, cellulose is added in the first mixed solution, is added while stirring, whipping temp is 36 Celsius Degree, mixing speed is 240rpm, until stirring, obtains the second mixed solution;
Step 5, the first mixture and the second mixture are added in the second mixed solution, in the case where temperature is for 62 degrees Celsius Carry out ultrasonic agitation 38 minutes, then be added thereto to attapulgite and chloromycetin stirs, homogeneous mixture solotion is carried out cold Freeze Gel Treatment, be dried and crush under 45 degrees Celsius in a nitrogen environment, you can obtain finished product.
The product of embodiment 3 is added into the sewage of chlorinated organics, after adsorption treatment, the chlorinated organics of sewage Content reaches national effluent-disposal standard.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be in other specific forms realized.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that for clarity those skilled in the art should Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of adsorbent for sewage disposal, it is characterised in that be made up of according to weight portion following raw material:Retinervus Luffae Fructuss 2-6 Part, straw 4-9 parts, wood flour 1.5-5 parts, attapulgite 15-24 parts, iron sulfate 0.5-3 parts, analysis for soybean powder 3-8 part, silica gel 5-10 Part, montmorillonite 8-15 parts, zeolite 4-10 parts, ion exchange resin 10-18 parts, humic acid 0.5-6 parts, cellulose 2-8 parts and chlorine Mycin 0.5-2.5 parts.
2. the adsorbent for sewage disposal according to claim 1, it is characterised in that the straw adopts corn stalk One or several mixture of stalk, soybean stalk, broomcorn straw and wheat stalk.
3. the adsorbent for sewage disposal according to claim 1 and 2, it is characterised in that the cellulose adopts first The mixture of the one or two kinds of of base cellulose and Microcrystalline Cellulose, silica gel using macro porous silica gel and silochrom one kind or The mixture that two kinds of person.
4. a kind of preparation method of the adsorbent for sewage disposal as described in claim 1-3 is arbitrary, it is characterised in that tool Body step is as follows:
Step one, Retinervus Luffae Fructuss, straw, silica gel, ion exchange resin and wood flour is put in pulverizer and is crushed to particle diameter and is not more than 1mm, obtains the first mixture;
Step 2,1-2 hours are calcined by montmorillonite and zeolite under 700-850 degree Celsius, and room temperature is naturally cooled to after calcining simultaneously And 80-150 mesh powder is ground into, obtain the second mixture;
Step 3, iron sulfate, analysis for soybean powder and humic acid are added in the deionized water of gross weight 3-6 times, are 45- in heating-up temperature Mixing is stirred under 70 degrees Celsius, speed of agitator is 750-900rpm, and mixing time is 10-15 minutes, obtains the first mixing Solution;
Step 4, cellulose is added in the first mixed solution, is added while stir, until stirring, obtains second Mixed solution;
Step 5, the first mixture and the second mixture are added in the second mixed solution, are entered in the case where temperature is for 50-65 degree Celsius Row ultrasonic agitation 20-45 minute, then it is added thereto to attapulgite and chloromycetin stirs, homogeneous mixture solotion is carried out cold Freeze Gel Treatment, be dried in a nitrogen environment and crush, you can obtain finished product.
5. the preparation method of the adsorbent for sewage disposal according to claim 4, it is characterised in that the step 4 Whipping temp be 30-42 degree Celsius, mixing speed is 180-300rpm, and the baking temperature of step 5 is 40-54 degree Celsius.
CN201611256345.9A 2016-12-30 2016-12-30 Adsorbing agent used for sewage treatment and preparation method thereof Pending CN106582575A (en)

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CN108217776A (en) * 2018-02-08 2018-06-29 朱佳琪 It is a kind of to be used to handle medicament at water source of chemical contamination and preparation method thereof
CN108609752A (en) * 2018-05-21 2018-10-02 泉州万利得节能科技有限公司 A kind of new green environment protection scale inhibition filtrate and preparation method thereof
CN108862500A (en) * 2018-06-01 2018-11-23 王玲 A kind for the treatment of agent and preparation method thereof for administering sanitary sewage
CN110170303A (en) * 2019-06-10 2019-08-27 陕西科技大学 A kind of heavy-metal adsorption material and its preparation method and application
CN111498947A (en) * 2020-04-22 2020-08-07 罗来飞 Treating agent for halogen-containing compound sewage and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108217776A (en) * 2018-02-08 2018-06-29 朱佳琪 It is a kind of to be used to handle medicament at water source of chemical contamination and preparation method thereof
CN108609752A (en) * 2018-05-21 2018-10-02 泉州万利得节能科技有限公司 A kind of new green environment protection scale inhibition filtrate and preparation method thereof
CN108862500A (en) * 2018-06-01 2018-11-23 王玲 A kind for the treatment of agent and preparation method thereof for administering sanitary sewage
CN110170303A (en) * 2019-06-10 2019-08-27 陕西科技大学 A kind of heavy-metal adsorption material and its preparation method and application
CN111498947A (en) * 2020-04-22 2020-08-07 罗来飞 Treating agent for halogen-containing compound sewage and preparation method thereof

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