CN106567073A - Material coil of selective plating and relevant method - Google Patents
Material coil of selective plating and relevant method Download PDFInfo
- Publication number
- CN106567073A CN106567073A CN201510646050.1A CN201510646050A CN106567073A CN 106567073 A CN106567073 A CN 106567073A CN 201510646050 A CN201510646050 A CN 201510646050A CN 106567073 A CN106567073 A CN 106567073A
- Authority
- CN
- China
- Prior art keywords
- coat
- metal
- coating
- matrix
- material volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Abstract
The invention discloses a material coil of selective metal plating, and relates to an example execution mode of the material coil for selective metal plating and a method of the material coil for selective metal plating. In the example execution mode, the material coil comprises a matrix, and insulating ink is on the matrix; a catalyst coating is arranged in the position, not at the insulating ink part, on the matrix; and the catalyst coating can be prepared, and one or more catalytic surfaces applicable to metal electroless deposition are provided for the matrix, so that a metal plating can be formed on the catalyst coating through electroless deposition while the insulating ink is not plated with the metal plating.
Description
Technical field
The disclosure relates generally to the material volume and correlation technique of selective plating.
Background technology
This part provides the background information relevant with the disclosure, and it is not necessarily prior art.
Metal deposition material is currently used for manufacture various electronic products.For example, plating fabric can be used for manufacture electromagnetism do
Disturb (EMI) shield and other purposes.
The content of the invention
First aspect present invention provides a kind of material volume, and it is included：Matrix；Insulation inks in described matrix；And institute
State and there is no catalyst coat at the insulation inks on matrix.
In the material volume of first aspect present invention：Described matrix includes one or more insulated parts and one or more platings
Cover part；The insulation inks are in the pattern for defining one or more of insulated parts in described matrix；Described one
Individual or multiple coating sections defined by the region in the pattern of the insulation inks without printing or with the area coincidence；And
And one or more of coating sections include the catalyst coat, the catalyst coat is configured to be provided to described matrix
For one or more catalytic surfaces of metal electroless.
The material volume of first aspect present invention is additionally included on the catalyst coat electroless deposition without being plated on
The coat of metal in insulation inks is stated, so as to the insulation inks are without the coat of metal.
The material volume of first aspect present invention also includes one or more following layers：It is arranged at least described coat of metal
Electro deposition；And/or the antioxidant coating that is arranged at least described coat of metal and/or wear-resistant coating；And/or arrange
Water-based polyurethane coating at least described coat of metal, the water-based polyurethane coating suppresses in bending or flexing when institute
State the rupture or peeling of the coat of metal；And/or the anticorrosive painting of benzotriazole (BTA) being arranged at least described coat of metal
Layer.
In the material volume of first aspect present invention：The insulation inks include silicone ink；The catalyst coat bag
Nitrile polymer containing butadiene and palladium；And described matrix includes polyester taffeta fabric.
Second aspect present invention additionally provides a kind of material volume of selective plating, and it includes：Matrix；In described matrix
Insulation inks；There is no the catalyst coat at the insulation inks in described matrix；With the metal on the catalyst coat
Coating.
In the material volume of the selective plating of second aspect present invention：The coat of metal electroless deposition is in the catalyst
Without being plated in the insulation inks in coating, so as to the insulation inks are without the coat of metal.
In the material volume of the selective plating of second aspect present invention：Described matrix include one or more insulated parts and
One or more coating sections；The figure that define one or more of insulated parts of the insulation inks in described matrix
In case；One or more of coating sections by without printing insulation inks pattern in region define or with this
Area coincidence；And one or more of coating sections include the catalyst coat.
The material volume of the selective plating of second aspect present invention also includes：The electricity being arranged at least described coat of metal
Solution coating；And/or the antioxidant coating that is arranged at least described coat of metal and/or wear-resistant coating；And/or be arranged on to
Water-based polyurethane coating on few coat of metal, the water-based polyurethane coating suppresses the gold in bending or flexing
The rupture or peeling of category coating；And/or benzotriazole (BTA) corrosion-resistant coating being arranged at least described coat of metal.
In the material volume of the selective plating of second aspect present invention：The coat of metal includes copper and/or nickel；It is described exhausted
Edge ink includes silicone ink；The catalyst coat includes butadiene nitrile polymer and palladium；And described matrix bag
Taffeta fabric containing polyester.
Third aspect present invention additionally provides a kind of material volume of selective plating, and it includes：Matrix；In described matrix
Electric conductivity ink；The electric conductivity ink coat of metal waterborne.
In the material volume of the selective plating of third aspect present invention, the coat of metal electroless deposition is in the electric conductivity
It is no to there is no plating at the electric conductivity ink on the matrix on ink.
The material volume of the selective plating of third aspect present invention also includes one or more following layers：It is arranged at least institute
State the electro deposition on the coat of metal；And/or the antioxidant coating that is arranged at least described coat of metal and/or wear-resisting painting
Layer；And/or the water-based polyurethane coating being arranged at least described coat of metal, the water-based polyurethane coating suppression is in bending
Either during flexing the coat of metal rupture or peeling；And/or the benzotriazole being arranged at least described coat of metal
(BTA) corrosion-resistant coating.
In the material volume of the selective plating of third aspect present invention：The electric conductivity ink is poly- comprising butadiene acrylonitrile
Compound and silver and/or palladium filler；And/or the coat of metal is comprising copper and/or nickel；And/or described matrix includes polyester tower husband
Silk fabric fabric.
Fourth aspect present invention additionally provides a kind of method of selective plating material volume, and methods described includes：In matrix
Upper applying insulation inks；Apply catalyst coat on the matrix so that the catalyst coat can be present in described matrix
On do not exist at the insulation inks；With the deposited metal coating on the catalyst coat.
The method of the selective plating material volume of fourth aspect present invention also includes：Apply the insulation on the matrix
The material volume debatching is made before ink and applies to rewind the material after the insulation inks on the matrix；
And/or apply to make the material volume debatching before the catalyst coat on the matrix and apply on the matrix described
The material is rewound after catalyst coat；And/or make before on the catalyst coat depositing the coat of metal
The material volume debatching and deposit on the catalyst coat after the coat of metal and rewind the material.
In the method for the selective plating material volume of fourth aspect present invention, the gold is deposited on the catalyst coat
Category coating is included on the catalyst coat coat of metal described in electroless deposition, without being plated in the insulation inks,
So as to the insulation inks are without the coat of metal.
In the method method of the selective plating material volume of fourth aspect present invention：Apply the insulation inks and be included in boundary
Determine to print the insulation inks in the pattern in the described matrix of one or more insulated parts in described matrix；Described matrix
Including one or more coating sections, in pattern of one or more of coating sections by the insulation inks without printing
Region define or with the area coincidence；And one or more of coating sections include the catalyst coat.
In the method for the selective plating material volume of fourth aspect present invention, apply the insulation inks and be included in the base
Intaglio printing or insulation inks described in ink jet printing in pattern on body.
The method of the selective plating material volume of fourth aspect present invention also include with one or more with lower floor coat to
Few coat of metal：The electro deposition of metal；And/or antioxidant coating；And/or wear-resistant coating；And/or water-based polyurethane
Coating；And/or benzotriazole (BTA) corrosion-resistant coating.
The method of the selective plating material volume of fourth aspect present invention be additionally included at least described coat of metal of coating it
Before make the material volume debatching and rewind the material after at least described coat of metal is coated.
In the method for the selective plating material volume of fourth aspect present invention：The coat of metal includes copper and/or nickel；Institute
Insulation inks are stated comprising silicone ink；The catalyst coat includes butadiene-acrylonitrile and palladium；And described matrix is comprising poly-
Ester taffeta fabric.
The method of the selective plating material volume of fourth aspect present invention is in the feelings not being plated in the insulation inks
Carry out under condition.
Fifth aspect present invention additionally provides a kind of method of selective plating material volume, and methods described includes：In matrix
Upper applying electric conductivity ink；With in electric conductivity ink electroless deposition of metals coating waterborne.
The method of the selective plating material volume of fifth aspect present invention also includes：Apply the conduction on the matrix
The material volume debatching is made before property ink and apply to rewind the material after the electric conductivity ink on the matrix
Material；And/or the material volume debatching was made before electric conductivity ink electroless deposition of metals coating waterborne and in the electric conductivity
The material is rewound on ink after electroless deposition of metals coating.
In the method for the selective plating material volume of fifth aspect present invention：The electric conductivity ink includes butadiene
Nitrile polymer and silver and/or palladium filler；The coat of metal includes nickel and/or copper；And described matrix includes polyester taffeta
Fabric.
There is no described leading on the matrix no in the method for the selective plating material volume of fifth aspect present invention
Electrically carry out in the case of plating at ink.
The method of the selective plating material volume of fifth aspect present invention also include with one or more with lower floor coat to
Few coat of metal：The electro deposition of metal；And/or antioxidant coating；And/or wear-resistant coating；With/
Or water-based polyurethane coating；And/or benzotriazole (BTA) corrosion-resistant coating.
Description of the drawings
Accompanying drawing described herein is merely to illustrate the embodiment of selection, rather than all possible enforcement, is not intended to limit
The scope of the present disclosure processed.
Fig. 1 is the top view of the material of the selective plating according to illustrative embodiments；
Fig. 2 is the side view of the material of the selective plating according to illustrative embodiments；
Fig. 3 is the flow chart of the method for the selective plating material according to illustrative embodiments, is printed wherein on the material
It is brushed with the pattern of insulation inks and has carried out plating；
Fig. 4 is a part for the fabric sample for being printed with insulation inks pattern and then plating according to illustrative embodiments
Top view；
Fig. 5 depicts the material volume of the selective plating according to illustrative embodiments, wherein, make material debatching and print
The pattern of insulation inks, rewinds, and then debatching and plating, rewind again；
Fig. 6 depicts the material volume of another kind of selective plating according to illustrative embodiments, wherein, material is being printed
When the pattern and then plating of brush insulation inks, material is made through a series of debatchings and rewind step；
Fig. 7 depicts the sample of the material of the selective plating according to illustrative embodiments；
Fig. 8 depicts example pattern, wherein, insulation inks can be printed on matrix, so as to insulation inks define matrix
On meeting on the region and matrix that will not be plated no any insulation of selective plating is carried out according to illustrative embodiments
The region of ink；
Fig. 9 depicts the material volume of the selective plating according to illustrative embodiments, wherein, with material printing and
Through a series of debatchings and re-winding step during plating, material is printed with insulation inks pattern and then plating；
Figure 10 is the flow chart of the method for the selective plating material of illustrative embodiments, is wherein printed with the material
The pattern of electric conductivity ink has simultaneously carried out plating；
Figure 11 illustrates the material volume according to illustrative embodiments debatching, is wherein printed with electric conductivity ink on the material
Water；
Figure 12 illustrates the Figure 11 for carrying out plating process to provide the electric conductivity ink coat of metal waterborne and is printed with conduction
The material of property ink；
Figure 13 shows the selective plating material of the Figure 12 for being wound；With
Figure 14 is the side view of a part for the selective plating material shown in Figure 13.
Specific embodiment
Illustrative embodiments are described more fully with now with reference to accompanying drawing.
The inventor have observed that, it is likely to occur during electroless deposition of metals coating on fabric and other materials tired
It is difficult.For example, during metal fever is embossing in the selected part of material, without selection for the coat of metal on material
Part is likely to be changed into being plated.It is likely difficult to control the interaction of active catalytic surface and copper so as to by Electroless copper deposition
Undesired effect is not produced on active surface (such as unnecessary plating).
Therefore, disclosed herein is the material (for example, fabric warrping of selective plating etc.) of selective plating and being configured for
In the illustrative embodiments of the material (for example, fabric warrping etc.) for carrying out selective metal plating.Also disclose configuration material (example
Such as, fabric warrping etc.) with the illustrative methods and selective plating of selective metal plating with the material of the offers such as such as roll form
The illustrative methods of (for example, fabric warrping etc.).
In the exemplary embodiment, each mistake when material volume (for example, textile material volume etc.) carries out selective plating
Cheng Zhong, material volume may be through a series of debatchings and re-winding step.For example, material volume debatching can be made, then can be by
Insulation inks (for example, silicone ink etc.) are printed or are otherwise applied on the material of debatching.There is thereon insulation
Then the material of ink can rewind and be transferred to diverse location after insulation inks are dried, such as catalyst coated.
The material volume with insulation inks and then debatching and catalyst coat can be applied on the material of debatching again thereon.Its
The upper material with catalyst coat and then can the debatching and to be transferred to another different again after catalyst coat is dried
Position, such as metal deposition platform.Material volume with catalyst coat and then can debatching and metal lining again thereon.Metal
Then the material of plating can again rewind and be transferred to other positions for further process, such as corrosion inhibitor coating (example
Such as, benzotriazole (BTA) etc.), antioxidant coating (for example, polyurethane etc.) and/or wear-resisting coating (for example, carbamate
Deng) etc..Therefore, in this example material volume can be multiple with debatching and re-winding.Advantageously, with traditional batch technique phase
Than, this illustrative embodiments can realize with higher production capacity produced (for example, linear velocity is for about 3 ms/min etc.) and/
Or can realize bigger pattern (for example, fabric width can improve to 1.5 meter Kuan etc.).
In the various exemplary embodiments, it is configured to the material volume (for example, textile material volume etc.) of selective plating
Including the matrix (for example, fabric substrate etc.) with one or more insulated parts and one or more coating sections.Described one
Individual or multiple insulated parts are applied to insulation inks (for example, the silicone on matrix on matrix by printing or other modes
Ink etc.) defined.One or more of coating sections are not had any exhausted by matrix without insulation inks or thereon
The region of edge ink or part define or, and shown region or partially overlap.In other words, one or more of plating portions
Point defined by there are no insulation inks on matrix.Again in other words, one or more of coating sections are defined in along base
The position that there are no insulation inks of body.
Insulation inks can be applied to matrix by predetermined pattern printing or other modes.For example, insulation inks can be wrapped
Pbz polymer organic polymer modified dimethyl polysiloxane solution (or fluorine richness polydimethylsiloxane solution), its according to
Desired pattern is coated on matrix.Further for example, insulation inks can be by intaglio printing (by the image carving of pattern to rotation
On the image-carrier of the drum forms of printer) it is applied on matrix.As an alternative, insulation inks can be applied via other techniques
It is added on matrix, such as ink jet printing, spraying, printing head, brushing, screen painting, bat printing, silk screen printing, roller coat, other printings
Method etc..
Insulation inks can then be dried on matrix.For example, insulation inks can be made in base in material volume debatching
It is dried on body, and keeps in temperature is for about 100 DEG C of baking oven about 10 minutes, guarantees that ink is cured.It is exemplary at other
In embodiment, this drying steps can be removed and/or insulation inks can be made to be dried in room temperature or other suitable temperature.
Then catalyst coat can be applied (for example, via dipping and imprint process etc.) there is no insulation to matrix
One or more coating sections of ink.For example, whole matrix can be immersed catalyst ink (for example, the fourth two containing palladium
Alkene acrylonitrile polymer etc.).Catalyst ink can be comprising the palladium and amine being distributed in butadiene acrylonitrile polymer solution
Complex.Whole fabric (volume) matrix can be immersed in catalyst ink, then be imprinted to remove unnecessary coating, then be done
It is dry.Dip time can be only several seconds, for example, about 3～12 seconds etc..For example, catalyst coat can include United States Patent (USP) 5,
Catalyst disclosed in 082,734, is expressly incorporated herein entire contents by quoting.
Catalyst coat can be retained on (for example, attachment or adhesion etc.) matrix and be not provided with insulation inks, for example,
One or more coating sections.But, due to the presence of insulation inks, catalyst coat will not retain or be present in one
Or multiple insulated parts, because catalyst coat will not adhere to or adhere to insulation inks.Therefore, after moulding process,
Catalyst coat can be removed from insulation inks, will not be remained in insulation inks.But catalyst coat can remain in described
On one or more coating sections, so as to provide catalytic surface, for example, for electroless deposition of metals coating.
Catalyst coat can be in e.g., from about 180 DEG C dryings about 15 minutes etc..Then, thereon with insulation inks and catalysis
The matrix of agent coating can carry out electroless process.During electroless, the coat of metal can be with electroless deposition in matrix
Have due to the presence of catalyst coat on one or more coating sections of catalytic surface.But matrix is printed with absolutely
One or more insulated parts of edge ink will not have the coat of metal, will be without the coat of metal.In some exemplary enforcements
It is at least partly that, due to the insulation inks on insulated part, the plating carried out to the coating section is substantially in mode
Plating will not be produced on insulated part.Therefore, insulation inks be configurable to one during electroless or
Multiple insulated part isolations avoid being plated.For example, electroless nickel can be deposited about 1～3 minute and/or without electricity at about 30～70 DEG C
Copper can be deposited about 10～30 minutes at about 40～60 DEG C.Further for example, electroless technique can include United States Patent (USP)
4910072nd, United States Patent (USP) 5075037, United States Patent (USP) 5227223, United States Patent (USP) 5328750, the United States Patent (USP) 5403649, U.S.
Patent 5411795 and United States Patent (USP) 5437916 it is any one or more disclosed in electroless technique, by quoting it
Full content be expressly incorporated herein.
In an alternative embodiment, electric conductivity ink is (for example, comprising the butadiene acrylonitrile with silver and/or palladium filler
The printable ink of polymer etc.) can print or other modes be applied to matrix (for example, polyester taffeta fabric, other
Fabric substrate etc.).Then, the matrix thereon with electric conductivity ink carries out above-mentioned electroless.During electroless,
Only electroless deposition is waterborne in electric conductivity ink for the coat of metal.There is no metal on the fabric of the part not comprising electric conductivity ink
Coating.Can on the coat of metal deposited metal (for example, nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.) electro deposition.
For example, can on the coat of metal electrolytic coating nickel dam, so as to nickel dam provide corrosion resistance.And implement in these replacements
In mode, it is not necessary to insulation inks printing process.In addition, material volume can be through one during each above-mentioned printing and plating
Serial debatching and re-winding step (for example, Figure 10 to 12 etc.).
Fig. 1 is configured to the illustrative embodiments of the material 20 of selective plating in terms of depicting according to the disclosure.
Material 20 includes matrix 24 (such as fabric substrate etc.), thereon with the pattern defined by insulation inks 44 and catalyst coat 40
28.Insulation inks 44 define along matrix 24 insulated part 36 for being provided with insulation inks 44.Catalyst coat 40 define along
One or more coating sections 32 of matrix 24.
Specifically, for example, insulated part 36 prints (for example, via intaglio printing, ink jet printing etc.) insulation inks
44 (for example, silicone inks etc.), thereon will not attached catalyst coating 40.Coating section 32 is that matrix 24 does not provide insulation
Those parts of ink 44.Therefore, matrix 24 is immersed into catalyst ink 40, (for example, the butadiene acrylonitrile containing palladium gathers
Compound etc.) when, catalyst coat 40 (for example, about 0.1 ounce per square yard etc.) adheres to and remains on coating section 32.Matrix
Catalyst coat 40 on 24 provides or defines the catalytic surface for electroless deposition of metals.It should be noted that in order to simple clear
Chu's ground explanation, the key element shown in figure is not drawn necessarily to scale.And for easy and clear, the size possibility of some key elements
Excessive relative to other key elements, nexus element is possibly shown as more clearer and more definite than the situation in some actual embodiments in figure
Ground is from drawing each other.
Fig. 2 shows the material 20 from Fig. 1 after selective plating is carried out according to an illustrative embodiments.
As illustrated, the coat of metal 64 provides (for example, electroless deposition) on the catalyst coat 40 of coating section 32.Can be in metal
The electro deposition of deposited metal (for example, nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.) on coating 64.For example, can be in metal-plated
Electrolytic coating nickel dam on layer 64, so as to provide corrosion resistance with nickel dam.Substantially, in the insulation inks 44 of insulated part 36 not
There is the coat of metal.In this example embodiment, coating section 32 has electric conductivity, and insulated part 36 does not have conduction
Property.
A kind of flow chart of exemplary method of selective plating material volume (such as fabric warrping) is in figure 3 generally such as accompanying drawing mark
Shown in note 100.In this illustrative methods, when material volume carries out selective plating, may be through one in each process in which materials
The debatching of row and re-winding step.For example, process 104 is potentially included makes material volume debatching.In process 108, by dielectric ink
Printing stock (for example, via intaglio plate or screen painting etc.) or other modes are applied to along in the pattern of matrix.Insulation inks
Define the insulated part on matrix.Define coating section in the position without insulation inks along matrix.It is dried in insulation inks
After 109, then material can be rewound in process 110, and in the debatching again of process 111.In process 112, in insulation
After ink dried, catalyst coat coating (for example, via dipping and imprint process etc.) or other modes are applied to into plating
Part.In process 116, catalyst coat can for example in about 180 DEG C of dryings about 15 minutes etc..It is dried in catalyst coat
Afterwards, then material can be rewound and in the debatching again of process 118 in process 117.Process 119 includes metal is heavy without electricity
Product is on the catalyst coat of coating section.For example, matrix can be exposed to coating solution.As catalysis is carried out, the coat of metal
It is gathered on the catalyst coat on coating section.Only as an example, can be by the fabric warrping immersion about 40～60 after catalysis
Carrying out copper facing without electrolytic copper solution and depositing about 10～30 minutes for DEG C (for example, about 48 DEG C etc.), is then immersed in about 40～60 DEG C of ammonia
Base sulfonic acid nickel solution carries out nickel deposition about 5～15 minutes.Optional process 120 include by such as nickel, stannum, gold, silver, cobalt, aluminum,
The electrolytic coatings such as zinc, copper are in process 119 on the metal of electroless deposition.For example, nickel dam electrolytic coating can be arrived in process 120
In process 119 on the copper coating of electroless deposition, thus nickel dam provides corrosion resistance.
Material can rewind and in the debatching again of process 122 in process 121.In process 126, can be by antioxidation
Agent coating applies (for example, by dipping, spraying, brush etc.) and/or can be by wear-resistant coating (for example, urethane coating
Deng) it is applied to the non-coating section of the coat of metal and matrix.For example, antioxidant coating can include scraper for coating thickening gather
Urethane solution.Or, for example, water-borne polyurethane coatings can will be immersed so as to apply coating (example including the matrix of metal lining
Such as, about 0.1 ounce per square yard etc.).Water-based polyurethane coating can improve flexural property and assist in keeping the coat of metal and avoid
Rupture when bending or flexing or peel off.It is dried after 127 in coating, then material can be rewound in process 129.
The reference 300 of flow chart answer such as Figure 10 of another case method of selective plating material volume such as fabric warrping
It is shown.In the exemplary method, when material volume carries out selective plating, may be through a series of debatching in each process in which materials
With re-winding step.For example, process 304 is potentially included makes material volume debatching.In process 308, by electric conductivity ink (for example
Printable ink etc. comprising butadiene nitrile polymer and silver and/or palladium filler) printing or other modes are applied to edge
In the pattern of matrix.After electric conductivity ink dried 309, then material can be rewound in process 310, and in process
311 debatchings again.Process 319 is included in electric conductivity ink electroless deposition of metals waterborne.For example, can be exposed to plating molten for matrix
Liquid so that the coat of metal to be gathered in electric conductivity ink waterborne.Only as an example, can be by the fabric warrping immersion about 40 after catalysis
～60 DEG C (for example, about 48 DEG C etc.) without electrolytic copper solution carry out copper facing deposit about 10～30 minutes, be then immersed in about 40～60 DEG C
Nickel sulfamic acid solution carry out nickel deposition about 5～15 minutes.Optional process 320 include by such as nickel, stannum, gold, silver,
The electrolytic coatings such as cobalt, aluminum, zinc, copper are in process 319 on the metal of electroless deposition.For example, nickel dam can be electrolysed in process 320
It is plated in process 319 on the copper coating of electroless deposition, thus nickel dam provides corrosion resistance.
Material can rewind and in the debatching again of process 322 in process 321.In process 326, can be by antioxidation
Agent coating applies (for example, by dipping, spraying, brush etc.) and/or can be by wear-resistant coating (for example, urethane coating
Deng) it is applied to the non-coating section of the coat of metal and matrix.For example, antioxidant coating can include scraper for coating thickening gather
Urethane solution.Or, for example, water-borne polyurethane coatings can will be immersed so as to apply coating (example including the matrix of metal lining
Such as, about 0.1 ounce per square yard etc.).Water-based polyurethane coating can improve flexural property and assist in keeping the coat of metal and avoid
Rupture when bending or flexing or peel off.Water-based polyurethane coating can also keep improve wearability and help prevent or suppress to knit
Thing avoids abrasion in cross cutting.It is dried after 327 in coating, then material can be rewound in process 329.
Figure 11 shows (for example, the fabric base of matrix 424 of the candy strip 428 with electric conductivity ink 44 being de-rolled
Body etc.).Figure 12 illustrate carry out plating process with provide the coat of metal 464 on electric conductivity ink 444 with candy strip
428 matrix 424.Figure 13 shows the selective plating material 420 of the Figure 12 for being wound.Figure 14 is selective plating material
The side view of 420 part.In this example, the coat of metal 464 is only along the electroless deposition of electric conductivity ink 444, and does not plate
Overlay in matrix 424 and do not exist at electric conductivity ink 444.The coat of metal 464 has electric conductivity, and along matrix outermost edge
Region between part 436 that matrix 424 is not plated and the striped of the coat of metal 464 does not have electric conductivity.Can be in metal
The electro deposition of deposited metal (such as nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.) on coating 464.For example, can be in metal-plated
Electrolytic coating nickel dam on layer 464, so as to provide corrosion resistance with nickel dam.
On a large scale material and matrix can carry out selective plating, including woven fabric volume in mode as disclosed herein
(for example, fabric warrping with plain weave etc.), adhesive-bonded fabric, fabric, side for woven fabric opposite side for adhesive-bonded fabric volume,
Other materials etc..For example, matrix may include Polyester Fabric or adhesive-bonded fabric, polyester taffeta, polyester taffeta laminates,
Nylon or Nylon ripstop (NRS) fabric or laminates, other anticracking fabrics or laminates, yarn fabric etc..
Embodiment
Only as an example, not limit, will now provide the exemplary side of the fabric of manufacture, production or formation selective plating
The explanation of method.
Embodiment 1
In this embodiment 1, sample includes being knitted made by polyester taffeta (for example, about 100 meters long, about 1 meter Kuan etc.)
Thing matrix, to it selective plating is carried out as follows.Insulation inks are printed on fabric by candy strip, its part such as Fig. 4 institutes
Show.Insulation inks are silicone ink.After insulation inks are dried, by catalyst coat (for example, the butadiene containing palladium
Nitrile polymer etc.) it is applied on the part without insulation inks in printing of fabric substrate.By catalyst coat e.g., from about 180
DEG C drying about 15 minutes etc..
Plating process is carried out to sample, wherein using copper solution come by copper coating electroless deposition to catalyst coat.Nothing
Electrolytic copper solution content can include about 1～4 g/l of (g/L) copper ion, about 2～8g/L sodium hydroxide, about 15～40g/L
EDTA (ethylenediaminetetraacetic acid) and about 2～8g/L formaldehyde.After electroless process, enough electrolysis nickel coatings are subsequently added into
So that the corrosion resistance of copper and reinforced fabric is completely covered, then apply water-based polyurethane coating (for example, about 0.1 ounce per square yard
Deng).
Visual inspection sample.First 80 meters of sample seem to have obtained satisfied plating.Sample (Fig. 5) shows well
Plating, not along whole length (for example, about 100 meters long etc.) the unnecessary plating of sample.Along the plating portion of material volume
Points 204 and insulated part 208 it is as shown in Figure 5.
Embodiment 2
In this embodiment 2, according to program same as Example 1 sample is prepared.By fabric carbamate process,
For example, water-based polyurethane coating (for example, about 0.1 ounce per square yard etc.).After the completion of plating process, sample is visually inspected.Sample
Product show good plating, good outward appearance, without unnecessary plating.Sample is as shown in Figure 6.Test metal deposition track and gold
The surface resistivity of the insulating regions (as shown in Figure 4) between category plating track.Test result is as shown in table 1 below.Fig. 4 shows plating
Cover the position of part or track 270,274 and 278, the non-coating section 280, Yi Jijin between metal deposition track 270 and 274
Non- coating section 284 between category coating section 274 and 278 is listed in the table below in 1.
Table 1
Surface resistivity (s-r ohm/sq)
Thickness (mm)
Track 270 0.045
Track 274 0.046
Track 278 0.045
Non- coating section 280 0.041
Non- coating section 284 0040
Width (mm)
Track 270 86.2
Track 274 9.7
Track 278 95.1
Non- coating section 280 9.7
Non- coating section 284 22.6
Embodiment 3
In this embodiment 3, according to program same as Example 1 sample is prepared.Sample is 1 centimetre and 2 comprising width
Centimetre copper plating zones (track).Fabric has plain weave, and provides the volume that width is 145 centimetres.Sample is 12 inches long.Such as
Shown in Fig. 7, carry out point-to-point track resistance across the length of track using the microhmmeters of Keithley 580 and 4 line alligator clamp and survey
Amount.Measure 24 DEG C temperature and 63% relative humidity carry out.Measurement resistance is as shown in table 2 below.
Table 2
Fabric point-to-point track resistance --- 12 inchages of selective plating
145cm width plain weave is rolled up
Embodiment 4
In this embodiment 4, sample 244 (Fig. 9) includes by made by polyester taffeta matrix (for example, in fig .9 from upper
To lower about 1 meter Kuan etc.), selective plating is carried out as follows to it.
Insulation inks are pressed into pattern printing on fabric, its part is as shown in Figure 8.The pattern includes 6 20 millimeters of pros
Shape and a 20 mm wide rectangles.Pattern is repeated print into (for example, via intaglio printing, ink jet printing etc.) on sample.Just
The square spacing and between rectangle is 2 millimeters.Interval region receives insulation inks.Square is represented without insulation inks with rectangle
Or thereon not with any insulation inks region.
Square and rectangle will receive catalyst coat, because it adhesion or will not be attached to insulation inks.In insulation
After ink dried, catalyst coat (for example, butadiene nitrile polymer containing palladium etc.) is applied to into no print of matrix
Paint the part of insulation inks.By catalyst coat in e.g., from about 180 DEG C dryings about 15 minutes etc..Insulation inks are silicone ink
Water.
Catalytic process is carried out to sample, wherein using copper solution come by copper coating electroless deposition to catalyst coat.Sample
Product are with very slow speed (2.5 feet/min) plating, but sheet resistance is maintained at from the beginning to the end 0.05～0.07 Ω/flat
Side.In this embodiment, without electrolytic copper solution content comprising about 1～4 g/l of (g/L) copper ion, about 2～8g/L sodium hydroxide,
About 15～40g/L EDTA (ethylenediaminetetraacetic acid) and about 2～8g/L formaldehyde.After the completion of plating process, apply (for example, via
Dipping process etc.) corrosion-resistant coating (for example, benzotriazole (BTA) etc.).Visual inspection sample (for example, about 100 meters long etc.).Survey
The surface resistivity of the metal coating section on examination plating sample, and measure thickness.Also measurement interval region (as shown in Figure 8)
Size " o ", " p " and " w " (or opening, spacing and width).Test result is shown in table 3 below, and it is included in about 6 English across volume
5 different measurings carried out on the diverse location of very little remote width.In non-plating striped 208 between plating zones 204 not
See measurable electric conductivity.
Table 3
Surface resistivity (s-r ohm/sq)：
Thickness (mm)：
Spacing (mm)：
Embodiment 5
In this embodiment 5, sample includes being knitted made by polyester taffeta (for example, about 100 meters long, about 1 meter Kuan etc.)
Thing matrix, to it selective plating is carried out as follows.Electric conductivity ink (is for example filled out comprising butadiene nitrile polymer and silver
Printable ink of material etc.) it is printed on fabric by candy strip.Then, the fabric to having electric conductivity ink thereon carries out nothing
Electrolytic copper plating and electrolytic nickel plating process.
More specifically, during the plating for carrying out to sample using copper solution by copper coating electroless deposition in electric conductivity
On ink.1～4 g/l of (g/L) copper ion, about 2～8g/L sodium hydroxide are can include about without electrolytic copper solution content, about 15～
40g/L EDTA (ethylenediaminetetraacetic acid) and about 2～8g/L formaldehyde.After electroless process, enough electrolysis are subsequently added into
Nickel coating so that the corrosion resistance of copper and reinforced fabric is completely covered, then apply water-based polyurethane coating (for example, about 0.1 ounce/
Square yard etc.).
Visual inspection sample (e.g., from about 100 meters long etc.).Sample shows good plating, not along the whole of sample
The unnecessary plating of individual length (for example, about 100 meters long etc.).The sheet resistance of the metal coating section of test sample.Test result is such as
Shown in table 4 below, it is included in 5 different measurings carried out on the diverse location of the width of about 6 inchs across volume.Along
Measurable electric conductivity is not had not seen in region between the non-coating section and metal deposition striped of matrix outermost edge.
Table 4
Sheet resistance (s-r ohm/sq):
Sample has also carried out following wearability or adhesion test, and it generally estimates how many metal is removed after friction.
Sample is tested in the case of without urethane coating.In the test, sample achieves 4 grades, 3 grades and 4 grades.Subsequently to sample
Product are tested after carbamate is coated with.It is coated with the sample of carbamate and achieves 5 in 3 different this world
Divide or level.Advantageously, urethane coating contributes to improve wearability.In addition, urethane coating additionally aid it is pre-
Anti- or suppression fabric avoids abrasion in cross cutting.
The abrasion resistance test method of sample is disclosed in United States Patent (USP) 5411795 in embodiment 5.Wearability characteristic manner is such as
Under：With reciprocating friction before and after on fabric face of the acrylic acid finger piece in slotted bracket, the fabric weight caused by friction is measured
Amount loss.Acrylic acid finger piece is arranged on the end of load-bearing reciprocal arm.The test utilizes improved crockmeter, wherein
The acrylic acid finger piece of offer has the bottom of 9.5mm (3/8 inch) diameter peace, loads as 3.1 kilograms, complete on sample
Into 50 reciprocating frictions (that is, 25 circulations), sample is coated with 2 layers of adhesive tape.After friction, adhesive tape is removed from fabric, with true
Surely the amount of metal taken out of by adhesive tape, and the standard shown in the figure with United States Patent (USP) 5411795 is compared.Generally, " 5 points "
It is suitable for metal and therefore pole is only taken out of by adhesive tape after using the friction of improved crockmeter with collective's good bonding
The sample of a small amount of metal；" 4 points " be suitable for more metals be carried over therefore acrylic acid finger piece track profile it is almost invisible
Situation；" 3 points " are suitable for the clear profile of the track for having taken enough metals therefore finger piece out of and are evident that situation；
" 2 points " are suitable for the situation that friction paths are filled up completely by metal；" 1 point " is suitable for that track is filled and metal is attached to finger
The situation in the region of shape thing path outside belt.
In the exemplary embodiment, material volume generally includes not exist in the insulation inks and matrix on matrix, matrix
Catalyst coat at insulation inks.Matrix can include one or more insulated parts and one or more coating sections.Absolutely
Edge ink may be in the pattern for define on matrix one or more of insulated parts.One or more of coating sections
Can be defined by the region in the pattern without printing insulation inks or be overlapped with it.One or more of plating portions
Dividing can include catalyst coat, and it is configured to provide one or more catalytic surfaces for electroless deposition of metals to matrix.
Material volume can also include the coat of metal (such as copper etc.) of the electroless deposition on catalyst coat without being redundantly plated on
In insulation inks, thus insulation inks are without the coat of metal.Can at least described coat of metal deposit electrolyte coating (example
Such as, nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.).Antioxidant coating and/or wear-resistant coating can be arranged at least described metal
On coating.Water-based polyurethane coating can be arranged at least described coat of metal, and it suppresses the coat of metal in bending or bends
Rupture when bent or peel off.Benzotriazole (BTA) corrosion-resistant coating can be arranged at least described coat of metal.Insulation inks
Silicone ink can be included.Catalyst coat can be comprising butadiene nitrile polymer and palladium.Matrix can include polyester
Taffeta fabric.
In another illustrative embodiments, the material volume of selective plating generally includes the insulation on matrix, matrix
There is no the coat of metal on the catalyst coat and catalyst coat at the insulation inks in ink, described matrix.Metal
Coating can be with electroless deposition on catalyst coat and not redundantly plating insulation inks, and thus insulation inks are without metal-plated
Layer.Matrix can include one or more insulated parts and one or more coating sections.Insulation inks may be on matrix
In defining the pattern of one or more of insulated parts.One or more of coating sections can be by without printing insulation
Define or overlap with it in region in the pattern of ink.One or more of coating sections can be applied including catalyst
Layer.Can at least described coat of metal deposit electrolyte coating (for example, nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.).Antioxygen
Agent coating and/or wear-resistant coating can be arranged at least described coat of metal.Water-based polyurethane coating can be arranged on to
On few coat of metal, it suppresses the coat of metal to rupture or peel off in bending either flexing.The anti-corruption of benzotriazole (BTA)
Erosion resisting coating can be arranged at least described coat of metal.The coat of metal can be comprising copper and/or nickel.Insulation inks can be included
Silicone ink.Catalyst coat can be comprising butadiene nitrile polymer and palladium.Matrix can be knitted comprising polyester taffeta
Thing.
In another illustrative embodiments, the material volume of selective plating generally includes the conduction on matrix, matrix
The property ink and electric conductivity ink coat of metal waterborne.The coat of metal can be waterborne in electric conductivity ink with electroless deposition and not redundantly be plated
Cover and do not exist in described matrix at the electric conductivity ink.Can deposit electrolyte coating be (for example, at least described coat of metal
Nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.).Antioxidant coating and/or wear-resistant coating can be arranged at least described metal-plated
On layer.Water-based polyurethane coating can be arranged at least described coat of metal, and it suppresses the coat of metal in bending or flexing
When rupture or peel off.Benzotriazole (BTA) corrosion-resistant coating can be arranged at least described coat of metal.The coat of metal can
With comprising copper and/or nickel.Matrix can include polyester taffeta fabric.Electric conductivity ink can be polymerized comprising butadiene acrylonitrile
Thing and silver and/or palladium filler.
A kind of illustrative methods of selective plating material volume generally include that insulation inks are applied on matrix, will be catalyzed
Agent coating is applied on matrix so that catalyst coat can be present in described matrix does not exist at the insulation inks, and in institute
State deposited metal coating on catalyst coat.The method can be additionally included in described matrix and apply to be made before the insulation inks
The material volume debatching and apply to rewind the material after the insulation inks on the matrix；And/or described
Apply to make the material volume debatching before the catalyst coat and apply on the matrix the catalyst coat on matrix
The material is rewound afterwards；And/or made the material volume debatching before deposited metal coating on the catalyst coat
The material is rewound with after deposited metal coating on the catalyst coat.The method can be included the coat of metal
Electroless deposition on catalyst coat and not redundantly plating insulation inks, thus insulation inks include the coat of metal.The method
Can also include insulation inks are printed on matrix in the pattern of one or more insulated parts defined on matrix.Matrix can
So that including one or more coating sections, it is defined or heavy with it by the region in the pattern without printing insulation inks
Close.One or more of coating sections can include catalyst coat.In this embodiment, applying insulation inks can include
By in the pattern of insulation inks intaglio printing or ink jet printing on matrix.(for example, the method can also be included with metal
Nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.) electro deposition, antioxidant coating, wear-resistant coating, water-based polyurethane coating and/
Or at least described coat of metal of one or more coating in benzotriazole (BTA) corrosion-resistant coating.The method can be included in
The material volume debatching is made before the coating at least coat of metal and the material is rewound after the coating at least coat of metal.
The coat of metal can be comprising copper and/or nickel.Insulation inks can include silicone ink.Catalyst coat can include butadiene
Acrylonitrile polymer and palladium.Matrix can include polyester taffeta fabric.This exemplary method can be in not redundantly plating insulation
Carry out in the case of ink.
Another kind of exemplary method of selective plating material volume generally include by electric conductivity ink be applied on matrix and
Electric conductivity ink electroless deposition of metals coating waterborne.The method can be additionally included in described matrix and apply the electric conductivity ink
The material volume debatching is made before water and applies to rewind the material after the electric conductivity ink on the matrix；
And/or the material volume debatching was made before electric conductivity ink electroless deposition of metals coating waterborne and in the electric conductivity ink
The material is rewound after upper electroless deposition of metals coating.Electric conductivity ink can comprising butadiene nitrile polymer with
Silver and/or palladium filler.The coat of metal can be comprising nickel and/or copper.Matrix can include polyester taffeta fabric.This exemplary method
Can be not redundantly plated in described matrix do not exist at the electric conductivity ink in the case of carry out.The method can be also
Including electro deposition, antioxidant coating, wear-resistant coating, water with metal (for example, nickel, stannum, gold, silver, cobalt, aluminum, zinc, copper etc.)
At least described coat of metal of one or more coating in based polyurethanes coating and/or benzotriazole (BTA) corrosion-resistant coating.
Some the existing sides of illustrative embodiments disclosed herein relative to selective plating fabric and/or other materials
Method can provide following advantages of one or more (but being not necessarily all or whole).For example, it is disclosed herein exemplary
Embodiment shows good electric property and also with highly flexible.Some illustrative embodiments include improving flexing
Performance and assist in keeping the coat of metal avoid in bending either flexing rupture or peel off carbamate process (for example,
Water-based polyurethane coating etc.).Because catalyst coat and resultant electroless occur over just desired pre- on matrix
Determine region, material cost can be reduced.Only figuratum selection area is plated so as to easily control the nothing during plating
Electrolytic copper activity.Low-resistivity can be more easily realized, the unnecessary plating in unselected matrix region can be avoided.Various
In embodiment, other step is not needed after plating (such as mask).
Example embodiment is provided so that the disclosure discloses fully and completely scope to those skilled in the art.Elaborate big
The detail of amount, such as concrete composition, the example of apparatus and method, so as to provide fully understanding for embodiment of the present disclosure.
It will be understood by the skilled person that detail is not required to adopt, example embodiment can be implemented in many different forms, should not
It is interpreted as limiting the scope of the present disclosure.In some example embodiments, known technique, known device are not documented
Structure and known technology.Furthermore it is possible to the advantage realized using one or more illustrative embodiments of the disclosure and change
It is kind to be for illustration purposes only and provide, the scope of the present disclosure is not intended to limit, because illustrative embodiments disclosed herein may
There is provided or all above-mentioned advantages and improvement are not provided, but still fall into the scope of the present disclosure.
Concrete size disclosed herein, concrete material and/or concrete shape are substantially examples, are not intended to limit the disclosure
Scope.This paper is not to can be used for disclosed herein one for the disclosure of the concrete scope of the value of the occurrence of given parameters
The limit of the other values of individual or multiple examples and the scope of value.And, it is contemplated to any two of special parameter as herein described
Occurrence can define the scope of the value for going for given parameters end points (that is, for given parameters first value and
Any value that the disclosure of second value can be construed to disclose between first value and second value can be used for given ginseng
Number).For example, if having value A and also exemplified with value Z exemplified with parameter X herein, contemplating parameter X can have
The scope of the value of about A～about Z.Similarly, it is contemplated that disclosure (no matter these models of the scope for the plural value of parameter
Enclose whether nested, overlap or different) including all possible scope of the value that the end points of scope of disclosure may be used to advocate
Combination.For example, if having 1～10 or 2～9 or 3～8 value exemplified with parameter X herein, it also contemplates parameter X can
To have including the other values scope including 1～9,1～8,1～3,1～2,2～10,2～8,2～3,3～10 and 3～9.
Terms used herein is not intended to be limited merely for the purpose of description specific example embodiment.Herein
The possible intention of singulative " a ", " an " and " the " for using also includes plural form, unless the context clearly indicates otherwise.Art
Language "comprising", " including ", " containing " and " having " are inclusives, therefore specify the feature, integer, step, operation, unit
Element and/or composition presence, but be not excluded for one or more other features, integer, step, operation, element, composition and/or its
The presence of group.Method steps described herein, process and operation should not be construed as must need its by discuss or illustrate
Particular order is carried out, unless be made exclusively for carrying out sequentially pointing out.It should also be understood that the step of other or alternative can be adopted.
When element either layer be referred to as another element or layer " on " with its " with reference to ", " connection " or " engagement " when, it can
Can directly on another element either layer, it is in connection, connection or engage, either there may be neutral element or layer.Phase
Than under, when element is referred to as directly " on another element or layer " and its " directly in conjunction with ", " being directly connected to " or " directly
During engagement ", may exist without neutral element or layer.Other vocabulary for describing the relation between element should be with similar side
Formula explain (for example, " and ... between " to " between directly existing ... ", " adjacent " to " direct neighbor " etc.).Art used herein
Language "and/or" includes any and all combination of the project that one or more correlations are listed.
Although may be described using term first, second, third, etc. herein various elements, composition, region, layer and/or
Part, but these elements, composition, region, layer and/or part should not be limited by these terms.These terms may be used only
In by an element, composition, region, layer or part with another region, layer or part distinguish.As " first ", " second " and
The terms such as other numerical terms not imply when in use order or sequence, unless context is clearly dictated otherwise.Therefore, not
Depart from example embodiment teaching in the case of, the first element, composition, region, layer or part can be named as second element,
Composition, region, layer or part.
The term of space correlation, such as " inside ", " outside ", " lower section ", " under ", D score, " on " and " on ", at this
Perhaps to convenient illustrate to describe an element as depicted or feature with other elements or the relation of feature in text.Space
The difference of the device that related term may be intended that in the use or work covered in addition to the orientation shown in figure takes
To.For example, if in figure device upset, be described in other elements either feature " under " or the element of " lower section " will take
To for other elements or feature " on ".Therefore, exemplary term " under " can cover above and below orientation.Device
Can otherwise be orientated (be rotated by 90 ° or other orientations) and space correlation used herein description is solved accordingly
Release.
For the purpose of illustration and description there is provided the preceding description of embodiment.It is not intended to limit or limit publicity
Content.The purposes or the feature of specific embodiment that individual element of volume, intention are either stated generally, be not limited to specific embodiment,
But, it is also embodiment party that is interchangeable and can be used for selection even if being not specifically illustrated or describing in where applicable
Formula.Same mode can also change in a number of ways.Such change is not regarded as a departure from the disclosure, all such modifications
All should include within the scope of the present disclosure.
Claims (28)
1. a kind of material volume, it is included：
Matrix；
Insulation inks in described matrix；With
There is no the catalyst coat at the insulation inks in described matrix.
2. material volume as claimed in claim 1, wherein：
Described matrix includes one or more insulated parts and one or more coating sections；
The insulation inks are in the pattern for defining one or more of insulated parts in described matrix；
One or more of coating sections by without printing insulation inks pattern in region define or with this
Area coincidence；And
One or more of coating sections include the catalyst coat, and the catalyst coat is configured to be carried to described matrix
For for one or more catalytic surfaces of metal electroless.
3. material volume as claimed in claim 1, it is additionally included on the catalyst coat electroless deposition without being plated on
The coat of metal in the insulation inks, so as to the insulation inks are without the coat of metal.
4. material volume as claimed in claim 3, it also includes one or more following layers：
The electro deposition being arranged at least described coat of metal；And/or
The antioxidant coating being arranged at least described coat of metal and/or wear-resistant coating；And/or
The water-based polyurethane coating being arranged at least described coat of metal, the water-based polyurethane coating suppress in bending or
The rupture or peeling of coat of metal during flexing；And/or
Benzotriazole (BTA) corrosion-resistant coating being arranged at least described coat of metal.
5. the material volume as described in claim 1,2,3 or 4, wherein：
The insulation inks include silicone ink；
The catalyst coat includes butadiene nitrile polymer and palladium；And
Described matrix includes polyester taffeta fabric.
6. a kind of material volume of selective plating, it includes：
Matrix；
Insulation inks in described matrix；
There is no the catalyst coat at the insulation inks in described matrix；With
The coat of metal on the catalyst coat.
7. the material volume of selective plating as claimed in claim 6, wherein, the coat of metal electroless deposition is in the catalysis
Without being plated in the insulation inks in agent coating, so as to the insulation inks are without the coat of metal.
8. the material volume of selective plating as claimed in claim 6, wherein：
Described matrix includes one or more insulated parts and one or more coating sections；
The insulation inks are in the pattern for defining one or more of insulated parts in described matrix；
One or more of coating sections by without printing insulation inks pattern in region define or with this
Area coincidence；And
One or more of coating sections include the catalyst coat.
9. the material volume of selective plating as claimed in claim 6, it also includes：
The electro deposition being arranged at least described coat of metal；And/or
The antioxidant coating being arranged at least described coat of metal and/or wear-resistant coating；And/or
The water-based polyurethane coating being arranged at least described coat of metal, the water-based polyurethane coating suppress in bending or
The rupture or peeling of coat of metal during flexing；And/or
Benzotriazole (BTA) corrosion-resistant coating being arranged at least described coat of metal.
10. the material volume of the selective plating as described in claim 6,7,8 or 9, wherein：
The coat of metal includes copper and/or nickel；
The insulation inks include silicone ink；
The catalyst coat includes butadiene nitrile polymer and palladium；And
Described matrix includes polyester taffeta fabric.
A kind of 11. material volumes of selective plating, it includes：
Matrix；
Electric conductivity ink in described matrix；
The electric conductivity ink coat of metal waterborne.
The material volume of 12. selective platings as claimed in claim 11, wherein, the coat of metal electroless deposition is led described
It is no to there is no plating at the electric conductivity ink on the matrix electrically on ink.
The material volume of 13. selective platings as claimed in claim 11, it also includes one or more following layers：
The electro deposition being arranged at least described coat of metal；And/or
The antioxidant coating being arranged at least described coat of metal and/or wear-resistant coating；And/or
The water-based polyurethane coating being arranged at least described coat of metal, the water-based polyurethane coating suppress in bending or
The rupture or peeling of coat of metal during flexing；And/or
Benzotriazole (BTA) corrosion-resistant coating being arranged at least described coat of metal.
The material volume of 14. selective platings as described in claim 11,12 or 13, wherein：
The electric conductivity ink includes butadiene nitrile polymer and silver and/or palladium filler；And/or
The coat of metal includes copper and/or nickel；And/or
Described matrix includes polyester taffeta fabric.
A kind of 15. methods of selective plating material volume, methods described includes：
Apply insulation inks on matrix；
Apply catalyst coat on the matrix so that the catalyst coat can be present in described matrix do not exist it is described
At insulation inks；With
The deposited metal coating on the catalyst coat.
16. methods as claimed in claim 15, it also includes：
Apply on the matrix to make the material volume debatching before the insulation inks and apply described exhausted on the matrix
The material is rewound after edge ink；And/or
Apply on the matrix to make the material volume debatching before the catalyst coat and apply on the matrix described
The material is rewound after catalyst coat；And/or
The material volume debatching is made before depositing the coat of metal on the catalyst coat and in the catalyst coat
Upper deposition rewind the material after the coat of metal.
17. methods as described in claim 15 or 16, wherein, the coat of metal is deposited on the catalyst coat to be included
The coat of metal described in electroless deposition on the catalyst coat, without being plated in the insulation inks, so as to described exhausted
Edge ink is without the coat of metal.
18. methods as described in claim 15 or 16, wherein：
Apply the figure that the insulation inks are included in the described matrix of one or more insulated parts defined in described matrix
The insulation inks are printed in case；
Described matrix includes one or more coating sections, and one or more of coating sections are by the dielectric ink without printing
Region in the pattern of water define or with the area coincidence；And
One or more of coating sections include the catalyst coat.
19. methods as described in claim 15 or 16, wherein, apply the insulation inks including pattern on the matrix
Insulation inks described in middle intaglio printing or ink jet printing.
20. methods as described in claim 15 or 16, it also includes coating at least described metal with lower floor with one or more
Coating：
The electro deposition of metal；And/or
Antioxidant coating；And/or
Wear-resistant coating；And/or
Water-based polyurethane coating；And/or
Benzotriazole (BTA) corrosion-resistant coating.
21. methods as claimed in claim 20, it is additionally included in before at least described coat of metal of coating and makes the material volume
Debatching and rewind the material after at least described coat of metal is coated.
22. methods as described in claim 15 or 16, wherein：
The coat of metal includes copper and/or nickel；
The insulation inks include silicone ink；
The catalyst coat includes butadiene nitrile polymer and palladium；And
Described matrix includes polyester taffeta fabric.
23. methods as described in claim 15 or 16, it is carried out in the case where not being plated in the insulation inks.
A kind of 24. methods of selective plating material volume, methods described includes：
Apply electric conductivity ink on matrix；With
In electric conductivity ink electroless deposition of metals coating waterborne.
25. methods as claimed in claim 24, it also includes：
Apply on the matrix to make the material volume debatching before the electric conductivity ink and apply on the matrix described
The material is rewound after electric conductivity ink；And/or
The material volume debatching was made before electric conductivity ink electroless deposition of metals coating waterborne and in the electric conductivity ink
The material is rewound after upper electroless deposition of metals coating.
26. methods as described in claim 24 or 25, wherein：
The electric conductivity ink includes butadiene nitrile polymer and silver and/or palladium filler；
The coat of metal includes nickel and/or copper；And
Described matrix includes polyester taffeta fabric.
27. methods as described in claim 24 or 25, it does not exist on the matrix at the electric conductivity ink no
Carry out in the case of plating.
28. methods as described in claim 24 or 25, it also includes coating at least described metal with lower floor with one or more
Coating：
The electro deposition of metal；And/or
Antioxidant coating；And/or
Wear-resistant coating；And/or
Water-based polyurethane coating；And/or
Benzotriazole (BTA) corrosion-resistant coating.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510646050.1A CN106567073B (en) | 2015-10-08 | 2015-10-08 | The material volume and correlation technique of selective plating |
| EP16854064.9A EP3360400A4 (en) | 2015-10-08 | 2016-09-20 | Selectively plated rolls of materials and related methods |
| PCT/US2016/052642 WO2017062173A1 (en) | 2015-10-08 | 2016-09-20 | Selectively plated rolls of materials and related methods |
| DE202016008798.4U DE202016008798U1 (en) | 2015-10-08 | 2016-09-20 | Selective plated material rolls |
| US15/947,080 US10492348B2 (en) | 2015-10-08 | 2018-04-06 | Selectively plated rolls of materials and related methods |
| US16/425,463 US20190281735A1 (en) | 2015-10-08 | 2019-05-29 | Selectively Plated Rolls Of Materials And Related Methods |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510646050.1A CN106567073B (en) | 2015-10-08 | 2015-10-08 | The material volume and correlation technique of selective plating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106567073A true CN106567073A (en) | 2017-04-19 |
| CN106567073B CN106567073B (en) | 2019-06-18 |
Family
ID=58506481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510646050.1A Active CN106567073B (en) | 2015-10-08 | 2015-10-08 | The material volume and correlation technique of selective plating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106567073B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112996864A (en) * | 2018-11-27 | 2021-06-18 | 麦克德米德乐思公司 | Selective plating of three-dimensional surfaces to create decorative and functional effects |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152628A (en) * | 1989-12-21 | 1997-06-25 | 阿米斯布里集团公司 | Catalytic water-soluble polymeric films for metal coatings |
| CN101569247A (en) * | 2006-12-20 | 2009-10-28 | 3M创新有限公司 | Methods of patterning a deposit metal on a substrate |
| CN102245827A (en) * | 2008-11-13 | 2011-11-16 | 赛法股份公司 | Fabric, device having fabric and production method for fabric |
| US20120291275A1 (en) * | 2011-05-19 | 2012-11-22 | Korea Institute Of Machinery & Materials | Method of forming metal interconnection line on flexible substrate |
| CN102817232A (en) * | 2012-08-14 | 2012-12-12 | 深圳市飞荣达科技股份有限公司 | Preparation method for electricity conductive cloth, and electricity conductive cloth |
| CN104412451A (en) * | 2012-05-11 | 2015-03-11 | 尤尼皮克塞尔显示器有限公司 | Ink composition for manufacture of high resolution conducting patterns |
-
2015
- 2015-10-08 CN CN201510646050.1A patent/CN106567073B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152628A (en) * | 1989-12-21 | 1997-06-25 | 阿米斯布里集团公司 | Catalytic water-soluble polymeric films for metal coatings |
| CN101569247A (en) * | 2006-12-20 | 2009-10-28 | 3M创新有限公司 | Methods of patterning a deposit metal on a substrate |
| CN102245827A (en) * | 2008-11-13 | 2011-11-16 | 赛法股份公司 | Fabric, device having fabric and production method for fabric |
| US20120291275A1 (en) * | 2011-05-19 | 2012-11-22 | Korea Institute Of Machinery & Materials | Method of forming metal interconnection line on flexible substrate |
| CN104412451A (en) * | 2012-05-11 | 2015-03-11 | 尤尼皮克塞尔显示器有限公司 | Ink composition for manufacture of high resolution conducting patterns |
| CN102817232A (en) * | 2012-08-14 | 2012-12-12 | 深圳市飞荣达科技股份有限公司 | Preparation method for electricity conductive cloth, and electricity conductive cloth |
Non-Patent Citations (1)
| Title |
|---|
| 吴世敏等: "《简明精细化工大辞典》", 30 June 1999, 沈阳：辽宁科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112996864A (en) * | 2018-11-27 | 2021-06-18 | 麦克德米德乐思公司 | Selective plating of three-dimensional surfaces to create decorative and functional effects |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106567073B (en) | 2019-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9873276B2 (en) | Microcontact printing stamps with functional features | |
| CN105189828B (en) | Nickel chromium triangle nanometer laminate coat with high rigidity | |
| CN105839157B (en) | For etch-proof electroplating nano laminated coating and covering | |
| CN106413268B (en) | The manufacturing method of Copper foil with carrier, laminate, the manufacturing method of printing distributing board and electronic equipment | |
| CN106413267B (en) | The manufacturing method of Copper foil with carrier, laminate, the manufacturing method of printing distributing board and electronic equipment | |
| CN102803562B (en) | The method of Wet-type etching self-assembled monolayer patterned substrate and metal pattern goods | |
| ATE552597T1 (en) | RESISTANCE AND METHOD FOR PRODUCING IT | |
| CN102245827A (en) | Fabric, device having fabric and production method for fabric | |
| KR101736537B1 (en) | Copper foil for high frequency circuit, copper clad laminate for high frequency circuit, printed wiring board for high frequency circuit, copper foil attached with carrier for high frequency circuit, electronic device, and method for manufacturing printed wiring board | |
| CN106567073B (en) | The material volume and correlation technique of selective plating | |
| TW200813288A (en) | Color-coated, fouling-resistant conductive clothes and manufacturing method thereof | |
| CN101160212B (en) | Surface-treated doctor blade | |
| JPWO2017170510A1 (en) | Plating processing method, plating processing apparatus, and sensor apparatus | |
| Chiu et al. | A supercritical CO2 promoted electroless Ni-P plating on silk and their fundamental characteristics investigations | |
| CN205077147U (en) | Material book of selectivity plating | |
| Chen et al. | Activity on electrochemical surface area: silver nanoplates as new catalysts for electroless copper deposition | |
| JP6134569B2 (en) | Copper foil with carrier, method for producing copper foil with carrier, method for producing copper-clad laminate, and method for producing printed wiring board | |
| BRPI0512138B1 (en) | Device and method for electrolytically treating boring workpieces | |
| CN101720423A (en) | Be used on the surface of device, preparing the method for conductive strain sensor | |
| US20180235115A1 (en) | Selectively Plated Rolls Of Materials And Related Methods | |
| TW200841800A (en) | Composite material for eletric and electronic parts, electric and electronic parts, and method of producing the composite material for electric and electronic parts | |
| JP6514942B2 (en) | Conductive cloth | |
| CN102653159B (en) | Method for manufacturing printing screen with protective layer | |
| JP5558437B2 (en) | Copper foil for printed wiring board and laminated board using the same | |
| CN105531780B (en) | The electrocontact structure being made of travelling contact portion and fixed contact portion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |