CN106555338A - A kind of environment-friendly highly efficient degreaser and its preparation method and application - Google Patents
A kind of environment-friendly highly efficient degreaser and its preparation method and application Download PDFInfo
- Publication number
- CN106555338A CN106555338A CN201610997110.9A CN201610997110A CN106555338A CN 106555338 A CN106555338 A CN 106555338A CN 201610997110 A CN201610997110 A CN 201610997110A CN 106555338 A CN106555338 A CN 106555338A
- Authority
- CN
- China
- Prior art keywords
- environment
- highly efficient
- friendly highly
- degreaser
- efficient degreaser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Invention provides a kind of environment-friendly highly efficient degreaser and its preparation method and application.The environment-friendly highly efficient degreaser is included by mass fraction：AEO 5% 20%；Between pentadecyl phenol polyethenoxy ether 5% 20%；Alkylsulfonate 5% 10%；Fatty alcohol polyoxyethylene ether sulfate 5% 10%；Polyster fibre swelling agent 5% 10%；The water of surplus.
Description
Technical field
The present invention relates to the oil removing process such as textile fabric, fiber field, more particularly to a kind of environment-friendly highly efficient degreaser and
Its preparation method and application.
Background technology
In fabric raw yarn, containing finishes such as dimethicone, amino modified or polyether modified silicon oils, during fabric knitting,
In order to improve fibre cohesion, protection fiber strength, reduce end breakage rate, it will usually add special textile finish oil or mineral oil etc.
Finish is smoothly weaving.Fabric must go to degreaser before dyeing, and oil mark otherwise occurs, cause substandard products, therefore to weaving
Fabric to carry out oil removing be necessary.
Effect：There is height emulsification, dispersibility to paraffin, oily wax, can be used as fiber, synthetic fibers, wool and its mix
The concise detergent of yarn fabric is closed, has good washing removal effect to sticking to the wax on fabric, finish, dirt.It is basic to join
Number consumption：5 g/L –10 g/L.Existing degreaser, in oil removing process, it usually needs higher except oil temperature, 130 DEG C or
More than, therefore, at this temperature, fiber or fabric easily cause a certain amount of hydrolysis, especially for cotton fiber for,
In oil removal process, easily fiber or fabric are caused to damage, so as to affect the quality of fiber or fabric, in later stage dyeing
In, affect Color.
Therefore, a degreaser for being capable of efficient degreasing at a lower temperature is needed at present, to solve to remove in prior art
The defect of finish, while meeting environmental requirement.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly highly efficient degreaser, is applied to the oil removing process of fabric or fiber
In, in the oil removing process particularly before dyeing；Oil removing is carried out compared with prior art lower temperature, reach and compare prior art
Degreaser more deoiling effect；And reagent contamination used is less, to reach the requirement of relative environmental protection.
To achieve these goals, present invention firstly provides a kind of environment-friendly highly efficient degreaser, the environment-friendly highly efficient is removed
Finish is included by mass fraction：
AEO 5%-20%；
Between pentadecyl phenol polyethenoxy ether 5%-20%；
Alkylsulfonate 5%-10%；
Fatty alcohol polyoxyethylene ether sulfate 5%-10%；
Polyster fibre swelling agent 5%-10%；
Water surplus.
In an embodiment of the present invention, the AEO include Brij 35,18
At least one in alkyl alcohol ethoxylates.
In an embodiment of the present invention, it is characterised in that the general structure of pentadecyl phenol polyethenoxy ether between described
For：
Wherein, the direct-connected alkyl of 15 carbon of R=, can be saturated alkyl, alternatively unsaturated alkyl；n=7-15.
In an embodiment of the present invention, the alkylsulfonate includes secondary alkyl sulfonate, dodecyl benzene sulfonate, alkene
At least one in sulfonated hydrocarbon.
In an embodiment of the present invention, the fatty alcohol polyoxyethylene ether sulfate is direct-connected AEO sulphur
Hydrochlorate or isomery fatty alcohol polyoxyethylene ether sulfate.
In an embodiment of the present invention, the polyster fibre swelling agent includes dibutyl succinate, Ergol, bigcatkin willow
At least one in acid benzyl ester.
The present invention also provides the preparation method of above-mentioned environment-friendly highly efficient degreaser.Methods described includes：By environment-friendly highly efficient
The mass fraction of degreaser obtains following components：AEO 5%-20%；Between pentadecyl phenol polyethenoxy ether 5%-
20%；Alkylsulfonate 5%-10%；Fatty alcohol polyoxyethylene ether sulfate 5%-10%；Polyster fibre swelling agent 5%-10%；To obtain
Each component put in reactor, by mass fraction add surplus water, be warming up to 45 DEG C -55 DEG C, stir, i.e.,
Obtain environment-friendly highly efficient degreaser.
In an embodiment of the present invention, pentadecyl phenol polyethenoxy ether between described in obtaining：Rectifying decarboxylation cashew nut shell crude oil
Obtain a pentadecyl phenol semi-finished product, heating in vacuum to 100 DEG C, distillation dehydration, pentadecyl phenol finished product between extraction；15 by between
Alkyl phenol finished product with enter oxirane according to mol ratio 1:7-1:15 mixing, are allowed to fully reaction, and reaction condition is：Reaction temperature
130℃-150℃；Normal temperature is cooled to, pentadecyl phenol polyethenoxy ether between extraction.
The present invention also provides application of the above-mentioned environment-friendly highly efficient degreaser in fabric or fiber oil removing process.
In an embodiment of the present invention, the oil removing time of described environment-friendly highly efficient degreaser is in 8 min -15min；Remove
Oil temperature is at 95 DEG C -100 DEG C.
It is understood that if no special instructions, reagent of the present invention has known preparation method or commercial goods.
In the environment-friendly highly efficient degreaser of the present invention, AEO can be used to washing, in degreaser,
But water-soluble poorer in the case where temperature is higher, dirt-removing power is poorer；Between the degree of polymerization in pentadecyl phenol polyethenoxy ether
Higher, hydrophily is comparatively better, and lipophile is poorer, accordingly, as the composition in degreaser, in order to take into account parent in the present invention
Aqueous and lipophile, the polymerization degree n in pentadecyl phenol polyethenoxy ether is between 7-15 therebetween；Alkylsulfonate alkalescence,
It is relatively stable in neutral and weakly acidic solution, and resistance to hard water, and there is preferable dirt-removing power, AEO sulphur
Hydrochlorate, it is soluble in water, with excellent decontamination, emulsification, foam performance and hard water resistance performance；Polyster fibre swelling agent makes fiber point
Son occurs degraded, fiber intermolecular forces decrease contributes to decontamination；And the various composition in the present invention is mostly degradable, have
The feature of environmental protection.And it is of the prior art except oil temperature is higher, typically at 130 DEG C, higher temperature can cause to damage to fiber, because
This, reduces except oil temperature, and while take into account the characteristic of each composition, therefore the degreaser in the present invention using temperature at 98 DEG C is
Most preferably.
In the degreaser application of the present invention, AEO and a pentadecyl phenol polyethenoxy ether for it is non-from
Sub- surfactant, itself has stronger emulsifying ability, dispersion force and washing force, and the removal to greasy dirt has significant effect.Alkane
The anion surfactants such as base sulfonate, fatty alcohol polyoxyethylene ether sulfate have good washing ability, can be effectively clear
Except the dustiness sticked on fabric, and can use cooperatively with nonionic surfactant, good cooperative effect can be played.Terylene
Low-fiber vitrification point, can drop in the addition of swelling of fiber agent, make fiber can change at a lower temperature amorphous region and
Expansion is loose, is conducive to surfactant to enter into fibrous inside, can fast and effeciently remove the greasy dirt on fabric.Therefore, originally
The environment-friendly highly efficient quick deoiling agent that invention is related to can reach common process compared with low processing temperature and in shorter process time
Deoiling effect, meets energy-conserving and environment-protective requirement.
Specific embodiment
Hereinafter, with reference to specific embodiment, the technology of the present invention is described in detail.It is appreciated that the various following have
Body embodiment is only used for helping skilled in the art to understand the present invention, rather than limitation of the present invention.
A kind of environment-friendly highly efficient degreaser, is included by mass fraction, AEO 5%-20%；Between pentadecyl
Phenol polyethenoxy ether 5%-20%；Alkylsulfonate 5%-10%；Fatty alcohol polyoxyethylene ether sulfate 5%-10%；Polyster fibre is expanded
Agent 5%-10%；Water surplus.
Wherein, the AEO includes Brij 35, stearyl alcohol polyoxyethylene
At least one in ether.
The general structure of described pentadecyl phenol polyethenoxy ether is：
Wherein, the direct-connected alkyl of 15 carbon of R=, can be saturated alkyl, alternatively unsaturated alkyl；n=7-15.
The alkylsulfonate includes in secondary alkyl sulfonate, dodecyl benzene sulfonate, alkene sulfonate at least one
Kind.
The fatty alcohol polyoxyethylene ether sulfate is direct-connected fatty alcohol polyoxyethylene ether sulfate or isomery poly alkyl alcohol
Oxygen ethene ether sulfate.
The polyster fibre swelling agent includes dibutyl succinate, Ergol, at least one in benzyl salicylate.
In above-mentioned environment-friendly highly efficient degreaser, the consumption of polyster fibre swelling agent 5%-10% can not be very few, very few to knit
The vitrification point of thing or fiber is too high, affects oil removal efficiency；But can not be excessive, cross and at most can fabric or fiber be caused to damage
It is bad, affect the quality of product.
In above-mentioned environment-friendly highly efficient degreaser, likewise, nonionic surfactant, anion surfactant
Consumption should reach adaptable ratio, and just both can so effectively used cooperatively, to reduce the environment-friendly highly efficient of the present invention
Degreaser application temperature and shortening oil removing time.
It is in order to absolutely prove above-mentioned environment-friendly highly efficient degreaser, with reference to specific preparation method and embodiment, right
Above-mentioned environment-friendly highly efficient degreaser is illustrated.
Embodiment 1：
A kind of environment-friendly highly efficient degreaser, by mass fraction, its composition is as follows：Brij 35 15%；Between 15
APES 10%；SAS 5%；Isomerous tridecanol polyoxyethylene ether sodium sulphate：5% dibutyl succinate
5%；The water of surplus.
Preparation method is as follows：Brij 35, a pentadecyl phenol of above-mentioned mass fraction are obtained respectively
APEO, SAS, SAS, isomerous tridecanol polyoxyethylene ether sodium sulphate, dibutyl succinate,
Then put in reactor, add the water of surplus, be warming up to 45 DEG C -55 DEG C, stir, obtain final product environment-friendly highly efficient and remove
Finish.
In this step, the obtaining step of a pentadecyl phenol polyethenoxy ether is：Rectifying decarboxylation cashew nut shell crude oil is obtained
Between pentadecyl phenol semi-finished product, heating in vacuum to 100 DEG C, distillation dehydration, pentadecyl phenol finished product between extraction；The pentadecyl by between
Phenol finished product with enter oxirane according to mol ratio 1:7-1:15 mixing, are allowed to fully reaction, and reaction condition is：Reaction temperature 130
℃-150℃；Normal temperature is cooled to, pentadecyl phenol polyethenoxy ether between extraction.
Embodiment 2：
A kind of environment-friendly highly efficient quick deoiling agent, by mass fraction, its composition is as follows：Stearyl alcohol APEO： 10%；
Between pentadecyl phenol polyethenoxy ether 15%；Neopelex 5%；Isomerous tridecanol polyoxyethylene ether sodium sulphate 5%；Benzene
Benzyl formate 5%；The water of surplus.
Preparation method：Difference is the difference of fractions, and its step is same as Example 1.
Case study on implementation 3：
A kind of environment-friendly highly efficient quick deoiling agent, by mass fraction, its composition is as follows：Brij 35 10%；Between
Pentadecyl phenol polyethenoxy ether 10%；SAS 5%；Brij 35 sulfate 5%；Ten alcohol of isomery
Polyethenoxy ether sodium sulfate 5%；Benzyl salicylate 5%；The water of surplus.
Preparation method：Difference is the difference of fractions, and its step is same as Example 1.
Case study on implementation 4：
A kind of environment-friendly highly efficient quick deoiling agent, by mass fraction, its composition is as follows：Stearyl alcohol APEO 10%；Between
Pentadecyl phenol polyethenoxy ether 10%；SAS 5%；Brij 35 sulfate 5%；Succinic acid two
Butyl ester：10%；The water of surplus.
Preparation method：Difference is the difference of fractions, and its step is same as Example 1.
Application Example：
Application note：Knit for pure chemical fiber fabric or the blend fabric containing chemical ＆ blended fabric, particularly terylene, polyester cotton blending during use
Thing.Environment-friendly highly efficient quick deoiling agent consumption is 0.3-1%owf（Relative to the gross mass of pending fabric）.Described ring
The oil removing time of protecting high-efficiency degreaser is in 8 min -15min；Except oil temperature is at 95 DEG C -100 DEG C.Common process temperature 130
℃；1/3-1/2 of the process time with the common process time.
Application effect：
Referring to table 1, table 1 gives the product obtained by embodiment 1, embodiment 2, embodiment 3, embodiment 4, is applied to the short stream of low temperature
Journey（98 DEG C of processing 10min）With conventional degreaser technique（130 DEG C of processing 10min）Comparing result.The technique applied by table 1 is
Impregnation technology, the fabric applied wash knitted fabric for pure.
Table 1：The Comparison study result of the degreaser in embodiment of the present invention 1- embodiment 4 and existing conventional degreaser.
| Index | 1 product of embodiment | 2 product of embodiment | 3 product of embodiment | 4 product of embodiment | Certain conventional degreaser sample A | Certain conventional degreaser sample B |
| Technological temperature | 98℃ | 98℃ | 98℃ | 98℃ | 130℃ | 130℃ |
| Process time | 10min | 10min | 10min | 10min | 10min | 10min |
| Degreaser consumption | 0.50% | 0.50% | 0.50% | 0.50% | 0.50% | 0.50% |
| Oil removal rate | 80.20% | 80.10% | 79.30% | 79.70% | 58.90% | 58.80% |
Referring to table 2, table 2 gives the product obtained by embodiment 1, embodiment 2, embodiment 3, embodiment 4, is applied to low temperature
Short route（98 DEG C of processing 10min）With conventional degreaser technique（130 DEG C of processing 30min）Comparing result.
The technique applied by table 2 is impregnation technology, and the fabric applied washs knitted fabric for pure.
| Index | 1 product of embodiment | 2 product of embodiment | 3 product of embodiment | 4 product of embodiment | Certain conventional degreaser sample A | Certain conventional degreaser sample B |
| Technological temperature | 98℃ | 98℃ | 98℃ | 98℃ | 130℃ | 130℃ |
| Process time | 10min | 10min | 10min | 10min | 30min | 30min |
| Degreaser consumption | 0.50% | 0.50% | 0.50% | 0.50% | 0.50% | 0.50% |
| Oil removal rate | 80.20% | 80.10% | 79.30% | 79.70% | 78.20% | 78.80% |
Relevant explanation in table given below 1,2：Oil removal rate test instrument in table 1,2 is quickly taken out for fiber grease
Go out device.
In table 1,2, oil removal rate method of testing is：
S1 accurately weighs dacron m0g；
Fabric in S1 is pressed PROCESS FOR TREATMENT in table 1, bath raio 1 by S2：15,1 DEG C/min of programming rate, weigh after washing drying m1g；
Dacron after S3 will be processed in S2 is immersed in tetrafluoroethene, and weigh after air-drying m2g。
In table 1,2, oil removal rate computational methods are formula：
Oil removal rate（%）=[（m0- m1）/（m0- m2）]*100%
As it can be seen from table 1 the present invention be suitable for for pure chemical fiber fabric or the blend fabric containing chemical ＆ blended fabric, particularly terylene,
The oil removing of polyester cotton.With common process in contrast, at a temperature of relatively low oil removing, in same time, this
The efficiency of bright degreaser is higher.
From table 2 it can be seen that with common process in contrast, it is to reach same or like deoiling effect, then existing
Some degreasers at least want the time of 30min, thus, it will be seen that the degreaser of the present invention its oil removing speed.
Find out from table 1 or table 2, nonionic surfactant, the consumption of anion surfactant should reach adaptable
Ratio, although the nonionic surfactant consumption of embodiment 1,2 is high compared with embodiment 3,4, but using effect significantly carries
It is high.
In sum, degreaser of the invention, had both reduced processing temperature, and had shortened process time again, and can expire
Sufficient plant produced requires, has saved the energy, more conformed to the environmental requirement of energy-saving and emission-reduction.
The present invention is been described by by above-mentioned related embodiment, but above-described embodiment only implements the example of the present invention.
It must be noted that, it has been disclosed that embodiment be not limiting as the scope of the present invention.On the contrary, being contained in the spirit of claims
And scope modification and impartial setting be included in the scope of the present invention.
Claims (10)
1. a kind of environment-friendly highly efficient degreaser, it is characterised in that the environment-friendly highly efficient degreaser is included by mass fraction：
AEO 5%-20%；
Between pentadecyl phenol polyethenoxy ether 5%-20%；
Alkylsulfonate 5%-10%；
Fatty alcohol polyoxyethylene ether sulfate 5%-10%；
Polyster fibre swelling agent 5%-10%；
Water surplus.
2. environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that the AEO includes ten
At least one in dialkyl group alcohol APEO, stearyl alcohol APEO.
3. environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that it is characterized in that pentadecyl between described
The general structure of phenol polyethenoxy ether is：
Wherein, the direct-connected alkyl of 15 carbon of R=, can be saturated alkyl, alternatively unsaturated alkyl；n=7-15.
4. environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that the alkylsulfonate includes secondary alkyl sulphur
At least one in hydrochlorate, dodecyl benzene sulfonate, alkene sulfonate.
5. environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that the fatty alcohol polyoxyethylene ether sulfate
For direct-connected fatty alcohol polyoxyethylene ether sulfate or isomery fatty alcohol polyoxyethylene ether sulfate.
6. environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that the polyster fibre swelling agent includes fourth two
Dibutyl phthalate, Ergol, at least one in benzyl salicylate.
7. a kind of preparation method of environment-friendly highly efficient degreaser as claimed in claim 1, it is characterised in that methods described bag
Include：Following components is obtained by the mass fraction of environment-friendly highly efficient degreaser：AEO 5%-20%；Between pentadecyl
Phenol polyethenoxy ether 5%-20%；Alkylsulfonate 5%-10%；Fatty alcohol polyoxyethylene ether sulfate 5%-10%；Polyster fibre is expanded
Agent 5%-10%；The each component of acquisition is put in reactor, the water of surplus is added by mass fraction, is warming up to 45 DEG C -55 DEG C,
Stir, obtain final product environment-friendly highly efficient degreaser.
8. the preparation method of environment-friendly highly efficient degreaser as claimed in claim 8, it is characterised in that obtain it is described between pentadecane
Base phenol polyethenoxy ether：Rectifying decarboxylation cashew nut shell crude oil obtains a pentadecyl phenol semi-finished product, and heating in vacuum is distilled to 100 DEG C
Dehydration, pentadecyl phenol finished product between extraction；Will between pentadecyl phenol finished product with enter oxirane according to mol ratio 1:7-1:15 mix
Close, be allowed to fully reaction, reaction condition is：130 DEG C -150 DEG C of reaction temperature；Normal temperature is cooled to, pentadecyl phenol gathers between extraction
Oxygen vinethene.
9. application of a kind of environment-friendly highly efficient degreaser as claimed in claim 1 in fabric or fiber oil removing process.
10. the application of environment-friendly highly efficient degreaser as claimed in claim 9, it is characterised in that described environment-friendly highly efficient is removed
The oil removing time of finish is in 8 min -15min；Except oil temperature is at 95 DEG C -100 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610997110.9A CN106555338A (en) | 2016-11-14 | 2016-11-14 | A kind of environment-friendly highly efficient degreaser and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610997110.9A CN106555338A (en) | 2016-11-14 | 2016-11-14 | A kind of environment-friendly highly efficient degreaser and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106555338A true CN106555338A (en) | 2017-04-05 |
Family
ID=58443601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610997110.9A Pending CN106555338A (en) | 2016-11-14 | 2016-11-14 | A kind of environment-friendly highly efficient degreaser and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106555338A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108560266A (en) * | 2018-05-24 | 2018-09-21 | 苏州维明化学工业有限公司 | A kind of environmental protection oil removing refining agent and preparation method thereof |
| CN114561806A (en) * | 2022-04-01 | 2022-05-31 | 宜城成雄织造有限公司 | Environment-friendly phosphorus-free oil and wax removing scouring agent as well as preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1919993A (en) * | 2005-08-23 | 2007-02-28 | 穆世民 | High effective environmental protection multifunctional deoiling decontaminant |
| CN101629130A (en) * | 2009-08-14 | 2010-01-20 | 福建省晋江新德美化工有限公司 | Fabric one-bath deoiling agent |
| CN101690877A (en) * | 2009-08-10 | 2010-04-07 | 北京东方晴空科技有限公司 | Pentadecyl phenol polyethenoxy ether strong biodegradable surfactant |
| CN103952905A (en) * | 2014-05-13 | 2014-07-30 | 浙江丝科院轻纺材料有限公司 | One-bath multifunctional treating agent and preparation method thereof |
-
2016
- 2016-11-14 CN CN201610997110.9A patent/CN106555338A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1919993A (en) * | 2005-08-23 | 2007-02-28 | 穆世民 | High effective environmental protection multifunctional deoiling decontaminant |
| CN101690877A (en) * | 2009-08-10 | 2010-04-07 | 北京东方晴空科技有限公司 | Pentadecyl phenol polyethenoxy ether strong biodegradable surfactant |
| CN101629130A (en) * | 2009-08-14 | 2010-01-20 | 福建省晋江新德美化工有限公司 | Fabric one-bath deoiling agent |
| CN103952905A (en) * | 2014-05-13 | 2014-07-30 | 浙江丝科院轻纺材料有限公司 | One-bath multifunctional treating agent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108560266A (en) * | 2018-05-24 | 2018-09-21 | 苏州维明化学工业有限公司 | A kind of environmental protection oil removing refining agent and preparation method thereof |
| CN114561806A (en) * | 2022-04-01 | 2022-05-31 | 宜城成雄织造有限公司 | Environment-friendly phosphorus-free oil and wax removing scouring agent as well as preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101575804B (en) | Alkali-resistant penetrant for short-process pretreatment of pure-cotton woven fabric | |
| CN111996803B (en) | Novel environment-friendly low-foam low-temperature degreasing agent and preparation method thereof | |
| CN105358760A (en) | Urethane based polymeric extenders for compositions to modify the surface properties of substrates | |
| CN105002022A (en) | Low-temperature deoiling scouring agent and preparation method thereof | |
| CN105803766B (en) | A kind of ultra-fine yarn spinning oil agent and preparation method | |
| CN107724128A (en) | Environment protection type dye is the same as bath dispersant | |
| CN107630370A (en) | Collect multi-functional dyeing with bath degreaser | |
| CN103194324A (en) | Chemical fiber degreaser and preparation method thereof | |
| CN106087407A (en) | A kind of textile highly effective oil remover | |
| CN106555338A (en) | A kind of environment-friendly highly efficient degreaser and its preparation method and application | |
| JP2015522721A (en) | Dyeing aid for polyester fiber, polyester fiber dyeing method using the same, and dyed product manufacturing method | |
| CN105155249A (en) | Low-temperature scouring agent as well as preparation and application thereof | |
| CN111910451A (en) | Wide-temperature range deoiling refining agent and preparation method thereof | |
| CN107541949A (en) | A kind of environment-friendly low-temperature scouring agent | |
| CN115198520A (en) | Bio-based softening agent and preparation method and application thereof | |
| CN116043538A (en) | Softening agent in biological base bath and preparation method and application thereof | |
| CN108004696A (en) | A kind of pigment auxiliary agent of no sewage nanometer printing and dyeing and its preparation method and application | |
| CN114134734A (en) | Preparation method of soaping agent for one-step pad dyeing of polyester-cotton blended woven fabric | |
| CN102965917A (en) | Softening finishing agent for textiles and preparation method of agent | |
| CN102127869A (en) | High-temperature leveling agent and production process thereof | |
| CN105463849B (en) | A kind of non-phosphate scouring agent and preparation method for RIPSTOP | |
| CN109267393B (en) | A kind of preparation method of the oil removing level dyeing compound emulsifying agent for dacron | |
| CN102080330A (en) | Superfine finishing method of textile fabrics and ready-made clothes | |
| CN102995468A (en) | Polyester fabric dyeing degreaser and preparation method thereof | |
| CN110592925A (en) | Chemical fiber desizing agent and preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170405 |