A kind of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver and its production method
Technical field
The present invention relates to a kind of friction improver for lubricating oil, and in particular to a kind of cycloalkanes-yttrium tungsten silicon titanium calcium friction
Modifier and its production method.
Background technology
During machine operation, fretting wear is the natural phenomena of generally existing, the friction loss world about 1/3rd
=energy, abrasion is to cause material and one of damage of facilities and three kinds of most important forms of failure.Modern times friction research table
Bright, the 1/3-1/2 of energy is to be wasted in a variety of manners in frictional dissipation in the world, and economic loss is very big, by taking automobile as an example, hair
The power that motivation is sent only has 1/3 to reach ground, and remaining power is consumed in self friction.Mitigate self friction consumption, hair
Motivation is just greatly improved using power, so as to reach the effect of energy-conservation.Have in addition to frictional dissipation, during various mechanical abrasions
Occur.Show according to relevant information, energy loss caused by mechanical wear is 5-25 times of friction loss.Add at machine operation position
Plus-minus rub, antiwear additive come mitigate mechanical wear loss, the prolonged mechanical life-span, increase effective operation time all be energy-conservation important ring
One of section.
The abrasion that mechanical part is too fast is prevented, then needs to establish oil film between two slidingsurfaces, there is adequate thickness
Oil film separates the relative mechanical part surface slided, and the purpose of abrasion is reduced with regard to that can reach.Lubrication is then to reduce friction, reduce
Or the most effective technology of abrasion is avoided, lubricating oil is used in all kinds mechanically to reduce friction, protection machinery and workpiece
Fluid lubricant, mainly play lubrication, cooling, antirust, cleaning, sealing and buffering etc..Lubricating oil contains base oil and added
Add agent, friction improver is a kind of additive of lubricating oil, is used for moving component when adding friction improver in conventional foundation oil
Between when, from the point of view of physical property friction improver can significantly reduce contact surface coefficient of friction.Friction improver generally contains
Polarized group, mainly adsorbed by polar group in metal surface, form the diaphragm of similar cushion pad by friction surface
Separate the effect for reaching and reducing abrasion;Adsorbed film can be divided into physical absorption and chemisorbed again, and physical absorption is main
It is to lean on intermolecular active force, and chemisorbed then adsorbs friction improver in metal surface also by the way that chemical reaction occurs,
So that adsorption effect is more preferable.Common friction improver mainly has carboxylic acid and its derivative, acid amides, acid imide, amine and its derivative
Thing, phosphorus and phosphoric acid derivatives and organic polymer and organo-metallic compound.Friction improver master in current practice
There are two types, when organic friction modifiers, second, metal class especially organic metal molybdenum class friction improver.It is organic to rub
Wiping modifier is generally divided into the chemical reaction film with saturated fatty acid, phosphoric acid and D2EHDTPA and sulfur-bearing aliphatic acid etc. for representative
Class, and the physical absorption film class with long-chain carboxylic acid, amino-compound, acid imide etc. for representative, and with unsaturated complex ester, different
Butenoate etc. polymerize species for the formation of representative.Organic metal molybdenum class friction improver can be largely classified into not phosphorous, sulphur class
Organic metal molybdenum and phosphorous, sulphur class organic metal molybdenum;Conventional not phosphorous, sulphur organic-molybdenum is mainly complicated aluminium amines,
Phosphorous, sulphur class organic metal molybdenum is mainly molybdenum dialkyl-dithiophosphate and molybdenum dialkyldithiocarbamacompositions etc..
The fuel economy of engine lubricating oil is lifted by adding friction improver, helping, which reduces abrasion, saves energy
Source, it is an important directions of future development;However, containing S, although the friction improver of the element such as P has excellent friction
Performance is learned, can but be brought than more serious etching problem;The friction of organic metal molybdenum class improves
Although agent improves the antifriction performance of oil product, but organic molybdenum additive of the prior art is in extremely harsh work
Under the conditions of work, as performance under the conditions of high temperature and top load is bad, maximum nonseizure load(PB)Do not make us with antiseizing full yet
Meaning.
The content of the invention
It is an object of the invention to provide a kind of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver and its production method, the cycloalkanes-yttrium
The production process safety and environmental protection of tungsten silicon titanium calcium friction improver, environmentally safe, the cycloalkanes for producing to obtain-yttrium tungsten silicon titanium calcium rubs
Wiping modifier has very strong antiwear and antifriction, carrying and antioxygenic property, and non-corrosiveness, is added in lubricating oil, can make
Lubricating oil has very strong wear-resistant effect, can make the operating of mechanical part safety and stability under various harsh conditions, and not
Etching problem can be brought to plant equipment.
To achieve the above object, the present invention adopts the following technical scheme that:
A kind of production method of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, production method step are as follows:
(1)According to yttrium powder:Tungsten powder is 1:1 weight ratio is put into reactor after being well mixed yttrium powder and tungsten powder, then
Yttrium powder is added in a kettle and tungsten powder gross weight 45-55% cycloalkanes is mixed evenly;
(2)The zinc dialkyl dithiophosphate of reaction mass gross weight 4-10% in reactor is added, then heats to 100-
200 DEG C, add the silica flour of yttrium powder and tungsten powder gross weight 15-20%, the titanium valve of addition yttrium powder and tungsten powder gross weight 15-20% and add
Enter yttrium powder and tungsten powder gross weight 10-15% calcium hydroxide, be mixed evenly, react 20-140 hours;
(3)Question response thing color is cooled to room temperature after being changed into rufous, stands more than 20 hours, filtering, and filtrate is transparent
Rufous finished product, filter residue recycle.
The production method of above-mentioned cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, described yttrium powder and tungsten powder crush before using
Into 270-400 mesh powders, described silica flour and titanium valve are using being preceding ground into 120-200 mesh powders.
The production method of above-mentioned cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, described cycloalkanes is for naphthenic oil or containing 5-11
The cycloalkane of individual carbon atom, including pentamethylene, hexamethylene, cyclooctane, ring hendecane etc..Described naphthenic oil be using cycloalkane as
The petroleum distillate of main component, relative density 0.89~0.95,160 DEG C of flash-point >, acid number < 0.1mgKOH/g, aniline point 66
~82 DEG C, pour point -40~-12 DEG C, naphthenic oil has saturated cyclic carbon-chain structure, has a low pour point, high density, high viscosity,
The features such as having no toxic side effect.
Product obtained by the production method of above-mentioned cycloalkanes-yttrium tungsten silicon titanium calcium friction improver.
Cycloalkanes produced by the invention-yttrium tungsten silicon titanium calcium friction improver is with yttrium powder, tungsten powder, cycloalkanes, dialkyl dithio
Trbasic zinc phosphate, silica flour, titanium valve and calcium hydroxide are that raw material produces what is obtained, and the cycloalkanes-yttrium tungsten silicon titanium calcium friction improver has
Very strong antiwear and antifriction effect, can substantially reduce metal friction trace.The present invention cycloalkanes-yttrium tungsten calcium friction improver relative to
What inventor developed before is entitled:" organic W-Mo friction improver and its manufacture method ", Patent No.
98102323.1 patent of invention, cost is lower, and the present invention does not have to expensive rape oil, using the relatively low cycloalkanes of price, pole
The big cost for reducing production;It is and entitled relative to what is developed before:" organic W-Mo friction improver and its system
Make method " invention, the obtained cycloalkanes-yttrium tungsten silicon titanium calcium friction improver of present invention production, antiwear and antifriction, carrying and anti-oxidant
Performance is more preferable, and wear-resistant effect is stronger, the coefficient of friction for reducing lubricating oil that can be by a larger margin, maximum nonseizure load PB
(N) it is also higher;And the product is applied to waterborne carrying engine or coating, made the country prosperous for Development of Marine helpful.
Beneficial effects of the present invention are:
1st, cycloalkanes-yttrium tungsten silicon titanium calcium friction improver non-corrosiveness that present invention production obtains, needs to lubricate suitable for all
Plant equipment, it is and odorless, pollution-free;Production process only has minimal amount of residue, residue be the complete yttrium powder of unreacted and
The noble metals such as tungsten powder, recoverable, no waste water produces, therefore environmental nonpollution.The cycloalkanes-yttrium tungsten silicon titanium calcium friction improver tool
There is very strong antiwear and antifriction effect, the cycloalkanes-yttrium tungsten silicon titanium calcium friction improver is added in lubricating oil, can obviously reduce profit
The coefficient of friction of lubricating oil, the economy of engine fuel (gasoline or diesel oil) is improved, extend the life-span of engine, raising is started
Acc power, reduce the discharge capacity of waste gas;
2nd, the cycloalkanes for producing this law open-birth-yttrium tungsten silicon titanium calcium friction improver uses cycloalkanes to be produced as organic substrate
The product arrived is low-phosphorous low sulfur product, meets national environmental protection policy.The product, which is added in lubricating oil to produce, obtains high-quality
Lubricating oil, make lubricating oil that there is very strong wear-resistant effect, be advantageous to improve China's senior lubricant automobile-used domestic and international market
Competitiveness;And the dosage of the friction improver of the increase present invention, the wear-resistant effect of lubricating oil can be made to obtain further
Improve;The product applies also for waterborne carrying engine or coating, is made the country prosperous for Development of Marine helpful.
3rd, cycloalkanes-a kind of additive of the yttrium tungsten silicon titanium calcium friction improver as lubricating oil of the invention, and other types
Additive compatibility it is good, can be used cooperatively with any kind of additive such as antioxidant and preservative etc., it is of the invention
Cycloalkanes-yttrium tungsten silicon titanium calcium friction improver is added in lubricating oil, can improve the profit of the parts under the conditions of high temperature and height load with lotus
Slip energy, improve maximum nonseizure load(PB)And antiseizing.The maximum nothing of cycloalkanes-yttrium tungsten calcium friction improver of the present invention
Seizing load PB, (N) >=830.
4th, cycloalkanes-yttrium tungsten silicon titanium calcium friction improver preparation technology for preparing of the present invention is simple, cost is low, and cost is much low
In the cost of in the market friction improver;And the present invention be prepared friction improver have very strong antiwear and antifriction,
Carrying and antioxygenic property, have very big market prospects.
Embodiment
Embodiment 1
A kind of production method of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, production method step are as follows:
(1)According to yttrium powder:Tungsten powder is 1:1 weight ratio is put into reactor after being well mixed yttrium powder and tungsten powder, yttrium powder
With tungsten powder using 270 mesh powders are preceding ground into, yttrium powder is then added in a kettle and the pentamethylene of tungsten powder gross weight 45% mixes
Conjunction stirs;
(2)The zinc dialkyl dithiophosphate of reaction mass gross weight 4% in reactor is added, then heats to 100 DEG C,
The silica flour for adding yttrium powder and tungsten powder gross weight 15%, the titanium valve and addition yttrium powder and tungsten powder that add yttrium powder and tungsten powder gross weight 15%
The calcium hydroxide of gross weight 10%, is mixed evenly, and reacts 140 hours, and described silica flour and titanium valve are using being preceding ground into 120
Mesh powder;
(3)Question response thing color is cooled to room temperature after being changed into rufous, stands 20 hours, filtering, and filtrate is transparent reddish brown
Color finished product, filter residue recycle.
Embodiment 2
A kind of production method of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, production method step are as follows:
(1)According to yttrium powder:Tungsten powder is 1:1 weight ratio is put into reactor after being well mixed yttrium powder and tungsten powder, yttrium powder
It is to be ground into 325 mesh powders with tungsten powder, the cyclooctane mixing for then adding yttrium powder and tungsten powder gross weight 49% in a kettle is stirred
Mix uniformly;
(2)The zinc dialkyl dithiophosphate of reaction mass gross weight 8% in reactor is added, then heats to 160 DEG C,
The silica flour for adding yttrium powder and tungsten powder gross weight 17%, the titanium valve and addition yttrium powder and tungsten powder that add yttrium powder and tungsten powder gross weight 18%
The calcium hydroxide of gross weight 12%, is mixed evenly, and reacts 95 hours, described silica flour and titanium valve are the powder for being ground into 150 mesh
End;
(3)Question response thing color is cooled to room temperature after being changed into rufous, stands 30 hours, and filtering, filtrate is transparent red
Brownstock, filter residue recycle.
Embodiment 3
A kind of production method of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, production method step are as follows:
(1)According to yttrium powder:Tungsten powder is 1:1 weight ratio is put into reactor after being well mixed yttrium powder and tungsten powder, yttrium powder
It is to be ground into 400 mesh powders with tungsten powder, then adds the ring hendecane mixing of yttrium powder and tungsten powder gross weight 55% in a kettle
Stir;
(2)The zinc dialkyl dithiophosphate of reaction mass gross weight 10% in reactor is added, then heats to 200 DEG C,
The silica flour for adding yttrium powder and tungsten powder gross weight 20%, the titanium valve and addition yttrium powder and tungsten powder that add yttrium powder and tungsten powder gross weight 20%
The calcium hydroxide of gross weight 15%, is mixed evenly, and reacts 20 hours, described silica flour and titanium valve are the powder for being ground into 200 mesh
End;
(3)Question response thing color is cooled to room temperature after being changed into rufous, stands more than 20 hours, filtering, and filtrate is transparent
Rufous finished product, filter residue recycle.
Embodiment 4
A kind of production method of cycloalkanes-yttrium tungsten silicon titanium calcium friction improver, production method step are as follows:
(1)According to yttrium powder:Tungsten powder is 1:1 weight ratio is put into reactor after being well mixed yttrium powder and tungsten powder, yttrium powder
It is to be ground into 325 mesh powders with tungsten powder, the naphthenic oil mixing for then adding yttrium powder and tungsten powder gross weight 48% in a kettle is stirred
Mix uniformly;
(2)The zinc dialkyl dithiophosphate of reaction mass gross weight 6% in reactor is added, then heats to 150 DEG C,
The silica flour for adding yttrium powder and tungsten powder gross weight 18%, the titanium valve and addition yttrium powder and tungsten powder that add yttrium powder and tungsten powder gross weight 17%
The calcium hydroxide of gross weight 13%, is mixed evenly, and reacts 100 hours;Described silica flour and titanium valve is to be ground into 200 purposes
Powder;
(3)Question response thing color is cooled to room temperature after being changed into rufous, stands more than 20 hours, filtering, and filtrate is transparent
Rufous finished product, filter residue recycle.
Application effect:
(One)The friction reducing effect experiment of friction improver of the present invention
Obtained friction improver in the embodiment of the present invention 1 is added in base oil lubricating oil sample is made, subtracted
Rub application test (four ball method), tests the coefficient of friction of different time, as a result as shown in table 1 below:
From the experimental data of upper table 1, when in base oil, when the addition of friction improver of the present invention is 0%, friction
Coefficient is increased over time and gradually increased;When friction improver of the present invention addition be 0.25% when, coefficient of friction with
The increase of time and gradually reduce, and 0.031 fall below 0.009 by coefficient of friction at 12 minutes, reduce
Quickly, illustrate that friction improver produced by the present invention has good antifriction function;When the addition of friction improver of the present invention
For 0.50% when, coefficient of friction gradually decreases with the increase of time, and to coefficient of friction at 12 minutes by
0.028 falls below 0.004, and the amplitude of reduction is very big, illustrates the dosage for increasing friction improver of the present invention, can further improve
The antifriction function of lubricating oil.
(Two)The application test of the reduction abrasive effect of friction improver of the present invention.
Obtained friction improver in the embodiment of the present invention 1 is added in base oil lubricating oil sample is made, Ran Houjin
The ball wear of row four is tested, and respectively under the conditions of 20kg and 40kg, tests grinding defect diameter, as a result as shown in table 2 below:
It was found from from upper table 2, when in base oil, when the addition of friction improver of the present invention is 0%, 20kg and 40kg's
Grinding defect diameter is respectively 0.73mm and 1.93mm;When the addition of friction improver of the present invention is 1.0%, 20kg and 40kg's
Grinding defect diameter is respectively 0.22mm and 0.45mm;Illustrate after adding the friction improver of the present invention, can have lubricating oil very strong
Wear-resistant effect, abrasion can be significantly reduced, so as to protect plant equipment;When the addition of friction improver of the present invention is 2.0%
When, 20kg and 40kg grinding defect diameter are respectively 0.18mm and 0.30mm;Illustrate the dosage of the friction improver of the increase present invention,
The wear-resistant effect of lubricating oil can be made to be further improved.
(Three)The cost comparable situation of friction improver of the present invention and conventional anti-friction agent
By obtained friction improver in the embodiment of the present invention 1 compared with the cost for the anti-friction agent that in the market is commonly used,
As a result it is as shown in table 3 below:
The cost for the friction improver being prepared from upper table 3, the present invention is well below in the market friction improver
Cost, greatly reduce the cost of friction improver;And the friction improver that the present invention is prepared has very strong resist
Wear away and rub, carry and antioxygenic property.