CN106543648A - Modified epoxy resin-based super-weather-resistant composite material for bus duct - Google Patents

Modified epoxy resin-based super-weather-resistant composite material for bus duct Download PDF

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Publication number
CN106543648A
CN106543648A CN201611112880.7A CN201611112880A CN106543648A CN 106543648 A CN106543648 A CN 106543648A CN 201611112880 A CN201611112880 A CN 201611112880A CN 106543648 A CN106543648 A CN 106543648A
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China
Prior art keywords
parts
weather
bus duct
epoxy resin
agent
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CN201611112880.7A
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CN106543648B (en
Inventor
陈斌
张堂
张盖同
陈苏琴
王登
汤继俊
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Jiangsu Tianyan Electric Technology Co ltd
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Jiangsu University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to a modified epoxy resin-based super-weather-resistant composite material for a bus duct, which comprises the following components in parts by weight: 100 parts of epoxy resin, 8-10 parts of hexamethylene diisocyanate polyisocyanate, 8-10 parts of dibutyltin dilaurate, 32-40 parts of polytetramethylene ether glycol, 50-100 parts of curing agent, 150-200 parts of aluminum hydroxide powder, 50-250 parts of alumina, 1-25 parts of short glass fiber shreds, 1-5 parts of coupling agent and 10-20 parts of diluent; the invention has the characteristics of high strength, high toughness, weather resistance, chemical resistance and excellent waterproof and anticorrosive performance, and the service life is greatly prolonged.

Description

A kind of bus duct extra-weather-proof composite of modified epoxy base
Technical field
The present invention relates to a kind of bus duct extra-weather-proof composite of modified epoxy base, belongs to high polymer material technology Field.
Background technology
With modernization project facility and emerging in large numbers for equipping, the especially fast increasing of power consumption of all trades and professions, numerous high levels Building and large-sized workshop workshop appearance, as transmission pressure traditional cable in high current induction system can not meet will Ask, bus duct indoors instead of electric wire in the power transmission trunk project project of low pressure more and more, but mesh The resin base bus duct of the poured with epoxy resin production on front market is relatively crisp, out of doors the ring such as ultraviolet irradiation, high temperature In border, the reason for the light degradation and thermal degradation of epoxy resin, it is easy to cracking problem.
The content of the invention
The purpose of the present invention is the defect for prior art, there is provided a kind of bus duct is extra-weather-proof with modified epoxy base Composite, with high intensity, high tenacity, the especially outstanding spy of weather resisteant, chemical resistance, waterproof anti-corrosion performance Point, service life are greatly prolonged.
The present invention is achieved by the following technical solutions:
A kind of bus duct extra-weather-proof composite of modified epoxy base, its constituent is as follows according to the mass fraction:
100 parts of epoxy resin
8 ~ 10 parts of two isocyanate group polyisocyanate of hexa-methylene
8 ~ 10 parts of dibutyl tin laurate
32 ~ 40 parts of polytetramethylene ether diol
50 ~ 100 parts of firming agent
150 ~ 200 parts of aluminium-hydroxide powder
50 ~ 250 parts of aluminium oxide
1 ~ 25 part of short glass fiber shredding
1 ~ 5 part of coupling agent
10 ~ 20 parts of diluent.
A kind of above-mentioned bus duct extra-weather-proof composite of modified epoxy base, wherein, the epoxy resin is epoxy One kind in resin E44, epoxy resin E51, epoxy resin E54.
A kind of above-mentioned bus duct extra-weather-proof composite of modified epoxy base, wherein, the polytetramethylene ether two The weight average molecular weight of alcohol is 1000,1500 or 2000, it is preferable that the weight average molecular weight of polymethylene ether glycol is 1000.
A kind of above-mentioned bus duct extra-weather-proof composite of modified epoxy base, wherein, the firming agent is solid for amine Agent, the amine curing agent are that modified by cardanol series firming agent, Modified by Aromatic Amines series firming agent or polyamide series are solid Agent, it is preferable that amine curing agent is polyamide series firming agent.
A kind of above-mentioned bus duct extra-weather-proof composite of modified epoxy base, wherein, the coupling agent is coupling agent The two kinds of mixing of one kind in KH550 and coupling agent KH560.
A kind of above-mentioned bus duct extra-weather-proof composite of modified epoxy base, wherein, the diluent be toluene, two One or more mixing in toluene, acetone, butanone, ethyl acetate.
Beneficial effects of the present invention are:
The present invention adopts HDI types isocyanate derivates-hexamethylene diisocyanate base polyisocyanate and polytetramethylene Ether glycol for modifying agent, modified epoxy, hexamethylene diisocyanate base polyisocyanate viscosity are very low, reduce production During operation difficulty, short glass fiber shredding improve tensile strength, the bus duct composite obtained after resin solidification, Toughness is very good, and weather resisteant, chemical resistance, waterproof anti-corrosion performance are especially outstanding, and service life is greatly prolonged.
Specific embodiment
The specific embodiment of the present invention is described further with reference to embodiment.
Epoxy resin E44, epoxy resin E51, epoxy resin E54 are purchased from Wuxi mayor's mummification work company limited;Six is sub- Two isocyanate group polyisocyanate of methyl(CAS: 28182-81-2)Structural formula is:
, Desmodur N 3300, Asahi Chemical Industry are created purchased from Cohan The China of TPA-90 SB or ten thousand Wannate HT-100;Dibutyl tin laurate is purchased from Jining Hua Kai resin company limited;It is poly- Tetramethylene ether glycol(CAS:25190-06-1)Structural formula is as follows:
Purchased from Shanghai Jin Jin pleasure chemistry You Xian companies, coupling agent KH550 and idol Connection agent KH560 is purchased from Zhengzhou Kang Fei Chemical Co., Ltd.s, coupling agent KH550 and coupling agent KH560 in mass ratio 1:1 mixing; Short glass fiber shredding is purchased from Yancheng City Hialid dimension fibre company limited;Polyamide series firming agent 650/651/593 Purchased from Huntsman Polyurethanes company limited.
Embodiment 1:
Take 9 parts of hexa-methylenes, two isocyanate group polyisocyanate according to the mass fraction, after the mixing of 38 parts of polytetramethylene ether diols Add 9 parts of dibutyl tin laurates, be sufficiently stirred for, stand 0.5h, then with 100 parts of epoxy resin E44,85 parts of polyamide cures 650,155 parts of aluminium-hydroxide powders of agent, 180 parts of aluminium oxidies, 21 parts of short glass fiber shreddings, 3 parts of coupling agent KH550,15 parts of first Benzene mixes, and is sufficiently stirred for rear evacuation, is filled into and puts well in conducting copper mould, solidify at room temperature, and the demoulding obtains bus duct.
Embodiment 2:
Take 8 parts of hexa-methylenes, two isocyanate group polyisocyanate according to the mass fraction, after the mixing of 34 parts of polytetramethylene ether diols Add 8 parts of dibutyl tin laurates, be sufficiently stirred for, stand 1h, then with 100 parts of epoxy resin E51,72 parts of polyamide curing agents 651st, 168 parts of aluminium-hydroxide powders, 135 parts of aluminium oxidies, 19 parts of short glass fiber shreddings, 4 parts of coupling agent KH560,3 parts of acetone, 12 parts of ethyl acetate mixing, are sufficiently stirred for rear evacuation, are filled into and put well in conducting copper mould, solidify at room temperature, the demoulding Obtain bus duct.
Embodiment 3:
Take 10 parts of hexa-methylenes, two isocyanate group polyisocyanate according to the mass fraction, after the mixing of 36 parts of polytetramethylene ether diols 10 parts of dibutyl tin laurates are added, is sufficiently stirred for, stand 0.6h, then it is solid with 100 parts of epoxy resin E54,55 parts of polyamide 593,175 parts of aluminium-hydroxide powders of agent, 210 parts of aluminium oxidies, 17 parts of short glass fiber shreddings, 2 parts of coupling agent KH550,2 parts of idols Connection agent KH560,5 parts of dimethylbenzene, 2 parts of butanone, 8 parts of ethyl acetate mixing, are sufficiently stirred for rear evacuation, are filled into and put conductive copper well In row's mould, solidify at room temperature, the demoulding obtains bus duct.
Embodiment 4:
Take 9 parts of hexa-methylenes, two isocyanate group polyisocyanate according to the mass fraction, after the mixing of 33 parts of polytetramethylene ether diols 10 parts of dibutyl tin laurates are added, is sufficiently stirred for, stand 0.5h, then it is solid with 100 parts of epoxy resin E54,60 parts of polyamide 650,152 parts of aluminium-hydroxide powders of agent, 78 parts of aluminium oxidies, 5 parts of short glass fiber shreddings, 4 parts of coupling agent KH560,13 part two Toluene:The mixing of 125 parts of combined stuffings, the combined stuffing by epoxy powder, titanium dioxide, quartz sand, Kaolin, zirconium dioxide, Beryllium oxide, kieselguhr in mass ratio 3:10:15:6:8:4:3 compositions, are sufficiently stirred for rear evacuation, are filled into and put conducting copper well In mould, solidify at room temperature, the demoulding obtains bus duct.
Bus duct fire resistance obtained in real-time example 1-4 is required up to UL94 V-0 levels, degree of protection reaches IP68, with excellent Good insulating properties, can bear 20 joules of mechanical shock, -40 DEG C of environment of low temperature, outdoor ultraviolet irradiation, long-term in hot environment Using not ftractureing, A level fire resistances, can work in 900 ~ 1100 DEG C of flame more than 95min, long-term tolerance acid, alkali, salt fog and The erosion of sea water.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, the change or replacement that can be readily occurred in, Should all cover within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection domain of claims It is defined.

Claims (6)

1. a kind of bus duct extra-weather-proof composite of modified epoxy base, it is characterized by, mass fraction is pressed in its constituent It is calculated as follows:
100 parts of epoxy resin
8 ~ 10 parts of two isocyanate group polyisocyanate of hexa-methylene
8 ~ 10 parts of dibutyl tin laurate
32 ~ 40 parts of polytetramethylene ether diol
50 ~ 100 parts of firming agent
150 ~ 200 parts of aluminium-hydroxide powder
50 ~ 250 parts of aluminium oxide
1 ~ 25 part of short glass fiber shredding
1 ~ 5 part of coupling agent
10 ~ 20 parts of diluent.
2. a kind of bus duct extra-weather-proof composite of modified epoxy base as claimed in claim 1, it is characterized by, it is described Epoxy resin is epoxy resin E44, epoxy resin E51, the one kind in epoxy resin E54.
3. a kind of bus duct extra-weather-proof composite of modified epoxy base as claimed in claim 1, it is characterized by, it is described The weight average molecular weight of polytetramethylene ether diol is 1000,1500 or 2000, it is preferable that the Weight-average molecular of polymethylene ether glycol Measure as 1000.
4. a kind of bus duct extra-weather-proof composite of modified epoxy base as claimed in claim 1, it is characterized by, it is described Firming agent is amine curing agent, and the amine curing agent is modified by cardanol series firming agent, Modified by Aromatic Amines series firming agent Or polyamide series firming agent, it is preferable that amine curing agent is polyamide series firming agent.
5. a kind of bus duct extra-weather-proof composite of modified epoxy base as claimed in claim 1, it is characterized by, it is described Coupling agent is the two kinds of mixing of one kind in coupling agent KH550 and coupling agent KH560.
6. a kind of bus duct extra-weather-proof composite of modified epoxy base as claimed in claim 1, it is characterized by, it is described Diluent is toluene, dimethylbenzene, acetone, butanone, one or more mixing in ethyl acetate.
CN201611112880.7A 2016-12-07 2016-12-07 Modified epoxy resin-based super-weather-resistant composite material for bus duct Active CN106543648B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107033318A (en) * 2017-04-25 2017-08-11 山东泰开电缆有限公司 Prefabricated bus, preparing raw material and the method for transformer platform based on integration and application
CN107629414A (en) * 2017-10-17 2018-01-26 高昕文 A kind of preparation method of bus duct high-strength anti-flaming resin
CN108988256A (en) * 2018-06-05 2018-12-11 江苏大印电子科技有限公司 A kind of bus duct and preparation method thereof being easily installed
CN111117161A (en) * 2019-12-29 2020-05-08 江苏江城电气有限公司 Super weather-resistant bus for ships and ocean platforms
CN111484729A (en) * 2020-06-16 2020-08-04 江苏科技大学 Castable for three-network copolymerization bus duct
CN111541127A (en) * 2020-04-27 2020-08-14 江苏华强电力设备有限公司 All-insulation pouring initial-end bus and preparation method thereof
CN116656209A (en) * 2023-06-01 2023-08-29 无锡兴华衡辉科技有限公司 Sample disc protective coating for ion beam sputtering coating machine and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102482399A (en) * 2009-07-20 2012-05-30 赢创德固赛有限公司 Catalysis of epoxy resin formulations having sparingly soluble catalysts
CN102516916A (en) * 2011-12-12 2012-06-27 东莞市派乐玛新材料技术开发有限公司 Liquid crystal sealant composition
CN103113604A (en) * 2013-01-28 2013-05-22 北京化工大学常州先进材料研究院 Method for improving interlaminar shear strength of medium/low-temperature cured prepreg by using polyurethane prepolymer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102482399A (en) * 2009-07-20 2012-05-30 赢创德固赛有限公司 Catalysis of epoxy resin formulations having sparingly soluble catalysts
CN102516916A (en) * 2011-12-12 2012-06-27 东莞市派乐玛新材料技术开发有限公司 Liquid crystal sealant composition
CN103113604A (en) * 2013-01-28 2013-05-22 北京化工大学常州先进材料研究院 Method for improving interlaminar shear strength of medium/low-temperature cured prepreg by using polyurethane prepolymer

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107033318A (en) * 2017-04-25 2017-08-11 山东泰开电缆有限公司 Prefabricated bus, preparing raw material and the method for transformer platform based on integration and application
CN107629414A (en) * 2017-10-17 2018-01-26 高昕文 A kind of preparation method of bus duct high-strength anti-flaming resin
CN107629414B (en) * 2017-10-17 2019-08-23 江苏帅天电气有限公司 A kind of preparation method of bus duct high-strength anti-flaming resin
CN108988256A (en) * 2018-06-05 2018-12-11 江苏大印电子科技有限公司 A kind of bus duct and preparation method thereof being easily installed
CN111117161A (en) * 2019-12-29 2020-05-08 江苏江城电气有限公司 Super weather-resistant bus for ships and ocean platforms
CN111541127A (en) * 2020-04-27 2020-08-14 江苏华强电力设备有限公司 All-insulation pouring initial-end bus and preparation method thereof
CN111484729A (en) * 2020-06-16 2020-08-04 江苏科技大学 Castable for three-network copolymerization bus duct
CN116656209A (en) * 2023-06-01 2023-08-29 无锡兴华衡辉科技有限公司 Sample disc protective coating for ion beam sputtering coating machine and preparation method thereof

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Address after: Daquan Road, science and Technology Park, Xinba Town, Yangzhong City, Zhenjiang City, Jiangsu Province

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Patentee before: JIANGSU University OF SCIENCE AND TECHNOLOGY

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Address after: Daquan Road, science and Technology Park, Xinba Town, Yangzhong City, Zhenjiang City, Jiangsu Province

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Address before: Daquan Road, science and Technology Park, Xinba Town, Yangzhong City, Zhenjiang City, Jiangsu Province

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