CN106535597A - NiCo polyaniline absorbing material - Google Patents

NiCo polyaniline absorbing material Download PDF

Info

Publication number
CN106535597A
CN106535597A CN201610989423.XA CN201610989423A CN106535597A CN 106535597 A CN106535597 A CN 106535597A CN 201610989423 A CN201610989423 A CN 201610989423A CN 106535597 A CN106535597 A CN 106535597A
Authority
CN
China
Prior art keywords
polyaniline
layer
nico
impedance matching
absorbing material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610989423.XA
Other languages
Chinese (zh)
Inventor
张达明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Mingsheng Strong Blower Co Ltd
Original Assignee
Wuxi Mingsheng Strong Blower Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Mingsheng Strong Blower Co Ltd filed Critical Wuxi Mingsheng Strong Blower Co Ltd
Priority to CN201610989423.XA priority Critical patent/CN106535597A/en
Publication of CN106535597A publication Critical patent/CN106535597A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • H05K9/0073Shielding materials
    • H05K9/0081Electromagnetic shielding materials, e.g. EMI, RFI shielding
    • H05K9/0088Electromagnetic shielding materials, e.g. EMI, RFI shielding comprising a plurality of shielding layers; combining different shielding material structure

Abstract

A NiCo polyaniline absorbing material disclosed by the present invention is composed of an impedance matching layer, a depletion layer and a reflection layer from top to bottom, the impedance matching layer is formed by dispersing 2-8 wt% of Ni0.8Co0.2 powder in the polyaniline, the depletion layer is formed by dispersing the hydroxy iron powder in the chloroprene rubber, and the reflection layer is formed by dispersing the graphite in the chloroprene rubber. According to the present invention, by selecting the specific composition from the NiCo alloy powder to match the polyaniline, an unexpected technical effect is generated.

Description

A kind of NiCo polyaniline wave absorbing materials
Technical field
A kind of the present invention relates to new material technology field, more particularly to NiCo polyaniline wave absorbing materials.
Background technology
With the development of modern science and technology, impact of the electromagenetic wave radiation to environment increasingly increases.Airport, machine flight because Electromagnetic Interference cannot be taken off and overdue;The normal work of various electronic instrument for diagnosing and curing diseases devices can often be disturbed in hospital, mobile phone.Cause This, administers electromagnetic pollution, finds a kind of material absorbing material that can be kept out and weaken electromagenetic wave radiation, it has also become material supply section The big problem learned.
Absorbing material refer to can absorb, decaying projects the electromagnetic wave energy of material surface, and by electromagnetic energy by material The dielectric loss in portion is converted into into the class functional material that the energy dissipation of the other forms such as heat energy is fallen.Absorbing material is by absorbing Agent, adhesive and various auxiliary agents composition, the electromagnetic performance of wherein absorbent determines the quality of microwave absorbing coating performance, in cell material Misusing for key is played in material.
Research confirms that ferrite wave-absorbing material performance is optimal, and it has, and absorption frequency range is high, absorbance is high, matching thickness is thin The features such as.This materials application is can absorb in electronic equipment the electromagnetic radiation of leakage, the mesh for eliminating electromagnetic interference can be reached 's.According to the rule that electromagnetic wave is propagated from the high magnetic conductance direction of low magnetic steering in media as well, using high magnetic conductivity ferrite guiding electricity Magnetic wave, by resonance, the emittance of a large amount of electromagnetic wave absorptions, then by coupling the energy conversion of electromagnetic wave into heat energy.
With the development of modern crafts, the requirement more and more higher to absorbing material, it is desirable to while wave-absorbing effect is preferable, Possess preferable physical and mechanical propertiess, preferable heat-resisting quantity and working service simple etc..
The content of the invention
It is an object of the invention to propose a kind of NiCo polyaniline wave absorbing materials, the absorbing property of material is enabled to significantly Lifted.
It is that, up to this purpose, the present invention is employed the following technical solutions:
A kind of NiCo polyaniline wave absorbing materials, which is made up of impedance matching layer, depletion layer and reflecting layer from top to bottom, impedance Ni of the matching layer by 2-8wt%0.8Co0.2Powder body is formed in being distributed to polyaniline, and depletion layer is distributed to neoprene rubber for hydroxy iron powder Formed in glue, reflecting layer is formed in neoprene by graphite dispersion.
The present invention is combined by specific recipe ingredient, devise impedance matching layer/depletion layer/reflecting layer composition three layers Thin film, its positive wave-absorbing effect are significantly better than reverse side, the front membrane structure design it is correct.Suction of the present invention Wave material,, when thickness is 0.2mm, its absorption maximum exceedes -18.9dB, excellent performance for which.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of NiCo absorbing materials, which is made up of impedance matching layer, depletion layer and reflecting layer from top to bottom, impedance matching layer By the Ni of 2wt%0.8Co0.2Powder body is formed in being distributed to polyaniline, and depletion layer is distributed in neoprene for hydroxy iron powder and is formed, Reflecting layer is formed in neoprene by graphite dispersion.
Embodiment 2
A kind of NiCo absorbing materials, which is made up of impedance matching layer, depletion layer and reflecting layer from top to bottom, impedance matching layer By the Ni of 8wt%0.8Co0.2Powder body is formed in being distributed to polyaniline, and depletion layer is distributed in neoprene for hydroxy iron powder and is formed, Reflecting layer is formed in neoprene by graphite dispersion.
Comparative example 1
NiCo alloy powders are Ni0.6Co0.4, remaining is same as Example 1.
Comparative example 2
NiCo alloy powders are Ni0.9Co0.1, remaining is same as Example 2.
Embodiment 3
The base material of impedance matching layer is butadiene rubber, and remaining is same as Example 1.
Absorbing material described in embodiment 1 and 2, absorption maximum exceed -18.9dB, and the absorption maximum of comparative example 1-3, Below below -10dB and -17dB.The comparative illustration of embodiment 1-2 and comparative example 1-3, it is of the invention from CoNi alloy powders, Specific composition, the cooperation with polyaniline is selected to generate unforeseeable technique effect.

Claims (1)

1. a kind of NiCo polyaniline wave absorbing materials, which is made up of impedance matching layer, depletion layer and reflecting layer from top to bottom, impedance With layer by 2-8wt% Ni0.8Co0.2Powder body is formed in being distributed to polyaniline, and depletion layer is distributed to neoprene for hydroxy iron powder Middle formation, reflecting layer is formed in neoprene by graphite dispersion.
CN201610989423.XA 2016-11-10 2016-11-10 NiCo polyaniline absorbing material Pending CN106535597A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610989423.XA CN106535597A (en) 2016-11-10 2016-11-10 NiCo polyaniline absorbing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610989423.XA CN106535597A (en) 2016-11-10 2016-11-10 NiCo polyaniline absorbing material

Publications (1)

Publication Number Publication Date
CN106535597A true CN106535597A (en) 2017-03-22

Family

ID=58350699

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610989423.XA Pending CN106535597A (en) 2016-11-10 2016-11-10 NiCo polyaniline absorbing material

Country Status (1)

Country Link
CN (1) CN106535597A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003289196A (en) * 2002-03-28 2003-10-10 Komatsu Seiren Co Ltd Resistive film for radio wave absorbent and its manufacturing method
CN102044319A (en) * 2009-10-23 2011-05-04 中国科学院物理研究所 Composite wave absorbing material and preparation method thereof
CN102179965A (en) * 2010-12-28 2011-09-14 中国航空工业集团公司北京航空材料研究院 Three-layer composite wave-absorbing film and preparation method thereof
CN102917577A (en) * 2012-10-16 2013-02-06 西南科技大学 Composite electromagnetic shielding material and method for manufacturing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003289196A (en) * 2002-03-28 2003-10-10 Komatsu Seiren Co Ltd Resistive film for radio wave absorbent and its manufacturing method
CN102044319A (en) * 2009-10-23 2011-05-04 中国科学院物理研究所 Composite wave absorbing material and preparation method thereof
CN102179965A (en) * 2010-12-28 2011-09-14 中国航空工业集团公司北京航空材料研究院 Three-layer composite wave-absorbing film and preparation method thereof
CN102917577A (en) * 2012-10-16 2013-02-06 西南科技大学 Composite electromagnetic shielding material and method for manufacturing same

Similar Documents

Publication Publication Date Title
CN107852846A (en) Magnetic shielding unit
CN104972708B (en) One kind inhales the difunctional composite of wave dispersion heat and its manufacture method
CN106356638A (en) Absorption-rate-adjustable bandwidth electromagnetic wave absorber based on graphene film
Zachariah et al. Hybrid materials for electromagnetic shielding: A review
CN207885101U (en) A kind of electromagnetic shielding film
JP5218396B2 (en) Electromagnetic interference suppression sheet, high-frequency signal flat cable, flexible printed circuit board, and electromagnetic interference suppression sheet manufacturing method
TWI482585B (en) Shielding composite diaphragm
CN107415336A (en) A kind of multilayer high temperature resistant absorbent structure based on honeycomb
TW201112939A (en) Electromagnetic wave absorption component and electromagnetic wave absorption device
Zhou et al. Gradient carbonyl-iron/carbon-fiber reinforced composite metamaterial for ultra-broadband electromagnetic wave absorption by multi-scale integrated design
US20070052575A1 (en) Near-field electromagnetic wave absorber
Yang et al. Microwave absorption of sandwich structure based on nanocrystalline SrFe12O19, Ni0. 5Zn0. 5Fe2O4 and α-Fe hollow microfibers
CN106535597A (en) NiCo polyaniline absorbing material
KR20140102033A (en) Magnetic sheet and apparatus for receiving a wireless power using the same
CN106739301A (en) A kind of NiCo polypyrroles absorbing material
CN106739302A (en) A kind of NiCo absorbing materials
CN106535595A (en) FeNiCo wave-absorbing material
CN106739305A (en) A kind of FeNi absorbing materials
CN116646722A (en) Composite electromagnetic shielding radome and manufacturing method thereof
CN106696404A (en) FeNi absorbing material of improved substrate
CN106739303A (en) A kind of FeNi absorbing materials for improving substrate
JP2000244167A (en) Electromagnetic-wave-disturbance preventive material
CN203105046U (en) Structure for inhibition of electromagnetic wave interference, and flexible printed circuit comprising the same
CN202406151U (en) Mobile phone capable of reducing radiation stray
CN201425843Y (en) Novel broadband multilayer absorber

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170322