CN106519322A

CN106519322A - Non-slip rubber material

Info

Publication number: CN106519322A
Application number: CN201610988850.6A
Authority: CN
Inventors: 肖慧; 李增录; 周素静
Original assignee: Jihua 3515 Leather and Leather Shoe Co Ltd
Current assignee: Jihua 3515 Leather and Leather Shoe Co Ltd
Priority date: 2016-11-10
Filing date: 2016-11-10
Publication date: 2017-03-22

Abstract

The invention discloses a non-slip rubber material. The non-slip rubber material is composed of two parts of raw materials; the first part is composed of natural rubber, butadiene rubber, butadiene styrene rubber, zinc oxide, octadecanoic acid, age resisters, reinforcing agents, polyethylene glycol, coumarone resin, softening agents and glass fibers; and the second part is composed of vulcanizing agents and vulcanization accelerators, wherein the vulcanizing agents account for 0.9-1.1% of the total weight of the first part, and the vulcanization accelerators account for 0.59-1.01% of the total weight of the first part. According to the formula, the natural rubber is adopted as the main body material, the adverse factor that a rubber sole becomes hard in winter is overcome according to the particularity of a molecular structure of the natural rubber, the special composite, namely the glass fibers are added into the rubber material, the glass fibers are organically integrated with the rubber material through the resin and act like small nails after buried into the rubber sole, and therefore the rubber sole can feel like fine abrasive paper and the effect of preventing slip on ice surfaces can be realized.

Description

A kind of on-slip sizing material

Technical field

The invention belongs to field of rubber technology, and in particular to a kind of on-slip sizing material.

Background technology

Generally winter temperature is relatively low, and current footwear glue bottom is easily hardened, particularly the particularity of winter ice face, Footwear glue bottom is reduced with the coefficient of friction of ice face, and the non-skid property at footwear glue bottom is decreased obviously, and causes the easy Fall injuries of human body.

The content of the invention

The purpose of the present invention is that as solving the deficiencies in the prior art and provides a kind of on-slip sizing material suitable for ice face.

The purpose of the present invention is realized in the following manner：

A kind of on-slip sizing material, is made up of two parts raw material, and Part I is made up of the raw material of following weight portion：Natural rubber 30.72-31.79 parts, butadiene rubber 9.00-10.07 parts, butadiene-styrene rubber 9.54-10.60 parts, Zinc Oxide 2.17-2.65 part, ten Eight alkanoic acid 1.59-2.64 parts, age resistor 1.17-1.44 parts, reinforcing agent 25.07-27.61 parts, Polyethylene Glycol 1.42-1.53 parts, Coumarone indene resin 1.59-2.68 parts, softening agent 9.53-10.10 parts, glass fibre 1.06-1.59 parts；Part II raw material is by sulfur Agent and vulcanization accelerator composition, 0.9-1.1% of the vulcanizing agent for Part I raw material gross weight, vulcanization accelerator is Part I The 0.59-1.01% of raw material gross weight.

N- isopropyl-N '-diphenyl-para-phenylene diamine and 0.63-0.79 weight of the age resistor by 0.54-0.65 weight portions 2,2,4- trimethyl -1,2- dihyaroquinolines the composition of part.

The reinforcing agent is white carbon.

The softening agent is machine oil.

The vulcanizing agent is sulfur.

The vulcanization accelerator is made up of altax, accelerant CZ and diphenylguanidine；Altax is Part I raw material The 0.09-0.11% of gross weight, accelerant CZ for Part I raw material gross weight 0.3-0.5%, diphenylguanidine are Part I raw material The 0.2-0.4% of gross weight.

The preparation method of insulation acid and alkali-resistance sizing material as above, comprises the following steps：

（1）After natural rubber is plasticated, add butadiene rubber, butadiene-styrene rubber and refine；

（2）In step（1）In add in the sizing material plasticated and anticipate impregnated glass fiber, mix homogeneously；

（3）By step（2）In the plastic cement input banbury for obtaining, successively by Zinc Oxide, octadecanoid acid, age resistor, coumarone Resin, reinforcing agent, Polyethylene Glycol, softening agent input banbury mix homogeneously；

（4）In the logical radiating of flat machine pull-up after dumping, vulcanizing agent and accelerator is added, mixing is uniform.

This formula using the particularity of its molecular structure, overcomes glue bottom in the winter time using natural rubber as material of main part The unfavorable factor that glue bottom is hardened under environment, adds special composite material-glass fibre, in addition in sizing material using resin by glass Fiber is organically blended in sizing material with sizing material, and glass fibre is embedded in rear such as nail small one by one in glue bottom, makes rubber glue The effect in ice face on-slip is played just like the sensation as fine sandpaper in bottom.

Jing third party's test chamber is tested, and made by this sizing material, there is being foaming agent at glue bottom（SLS）It is above the ceramic tile of solution, front The anti-skidding coefficient of friction 0.45 of the palm, the anti-skidding coefficient of friction 0.37 of heel reach EU criteria requirement.

Specific embodiment

Embodiment 1：

Preferably, N- isopropyl-N '-diphenyl-para-phenylene diamine and 0.63- of the age resistor by 0.54-0.65 weight portions 2,2,4- trimethyl -1,2- dihyaroquinolines the composition of 0.79 weight portion；The reinforcing agent is white carbon；The softening agent is machine Oil；The vulcanizing agent is sulfur；The vulcanization accelerator is made up of altax, accelerant CZ and diphenylguanidine；Altax is The 0.09-0.11% of Part I raw material gross weight, accelerant CZ for Part I raw material gross weight 0.3-0.5%, diphenylguanidine is The 0.2-0.4% of Part I raw material gross weight.

（2）In step（1）In add in the sizing material plasticated and anticipate impregnated glass fiber, make preimpregnation adhesive Glass fibre can be combined together with rubber well, close uniform；

（3）By step（2）In the plastic cement input banbury for obtaining, successively by Zinc Oxide, octadecanoid acid, age resistor, coumarone Resin, reinforcing agent, Polyethylene Glycol, softening agent input banbury mix homogeneously；Avoid the conglomerations such as softening agent；

（4）In the logical radiating of flat machine pull-up after dumping, vulcanizing agent and accelerator is added, beat triangle bag and perpendicular bag is each 3 times, and knead equal It is even.

Embodiment 2

A kind of on-slip sizing material, is made up of two parts raw material, and Part I is made up of following raw material：Natural rubber 31.1Kg, suitable fourth 9.5 Kg of rubber, 10.3 Kg of butadiene-styrene rubber, 2.2 Kg of Zinc Oxide, 1.59 Kg of octadecanoid acid, 0.6 Kg of antioxidant 4010NA and 0.68 Kg of anti-aging agent RD, 26.6 Kg of reinforcing agent white carbon, 1.5 Kg of Polyethylene Glycol, 2.4 Kg of coumarone indene resin, softening agent 10.05 Kg of machine oil, 1.4 Kg of glass fibre, Part II raw material are made up of vulcanizing agent and vulcanization accelerator, and vulcanizing agent is sulfur Sulphur, accounts for the 0.9% of Part I raw material gross weight, i.e. 0.88Kg；Vulcanization accelerator is by altax, accelerant CZ and diphenylguanidine group Into；Altax for Part I raw material gross weight 0.09%, i.e. 0.09Kg, accelerant CZ are Part I raw material gross weight 0.3%, i.e. 0.29Kg, accelerator for Part I raw material gross weight 0.4%, i.e. 0.39Kg；Preparation method is with embodiment 1.

The on-slip sizing compound formula that embodiment of the present invention 3-20 is provided is shown in Table 1-3, and other are with embodiment 1.

Above-described is only the preferred embodiment of the present invention, it is noted that for a person skilled in the art, not Under the premise of departing from general idea of the present invention, some changes and improvements can also be made, these should also be considered as the protection of the present invention Scope.

Claims

1. a kind of on-slip sizing material, it is characterised in that be made up of two parts raw material, Part I is made up of the raw material of following weight portion： Natural rubber 30.72-31.79 parts, butadiene rubber 9.00-10.07 parts, butadiene-styrene rubber 9.54-10.60 parts, Zinc Oxide 2.17- 2.65 parts, octadecanoid acid 1.59-2.64 parts, age resistor 1.17-1.44 parts, reinforcing agent 25.07-27.61 parts, Polyethylene Glycol 1.42-1.53 parts, coumarone indene resin 1.59-2.68 parts, softening agent 9.53-10.10 parts, glass fibre 1.06-1.59 parts；Second Part material is made up of vulcanizing agent and vulcanization accelerator, and 0.9-1.1% of the vulcanizing agent for Part I raw material gross weight, sulfuration promote 0.59-1.01% of the agent for Part I raw material gross weight.

2. on-slip sizing material as claimed in claim 1, it is characterised in that N- isopropyl of the age resistor by 0.54-0.65 weight portions 2,2,4- trimethyl -1,2- dihyaroquinolines the composition of base-N '-diphenyl-para-phenylene diamine and 0.63-0.79 weight portions.

3. on-slip sizing material as claimed in claim 1, it is characterised in that the reinforcing agent is white carbon.

4. on-slip sizing material as claimed in claim 1, it is characterised in that the softening agent is machine oil.

5. on-slip sizing material as claimed in claim 1, it is characterised in that the vulcanizing agent is sulfur.

6. on-slip sizing material as claimed in claim 1, it is characterised in that the vulcanization accelerator by altax, accelerant CZ and Diphenylguanidine is constituted；0.09-0.11% of the altax for Part I raw material gross weight, accelerant CZ are Part I raw material gross weight 0.3-0.5%, diphenylguanidine for Part I raw material gross weight 0.2-0.4%.

7. as described in any one of claim 1-6 insulation acid and alkali-resistance sizing material preparation method, it is characterised in that including following step Suddenly：