CN106498432B - A kind of Hydrogen Energy air mixture production equipment and method - Google Patents
A kind of Hydrogen Energy air mixture production equipment and method Download PDFInfo
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- CN106498432B CN106498432B CN201710010309.2A CN201710010309A CN106498432B CN 106498432 B CN106498432 B CN 106498432B CN 201710010309 A CN201710010309 A CN 201710010309A CN 106498432 B CN106498432 B CN 106498432B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/14—Injection, e.g. in a reactor or a fuel stream during fuel production
- C10L2290/141—Injection, e.g. in a reactor or a fuel stream during fuel production of additive or catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- General Chemical & Material Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses a kind of Hydrogen Energy air mixture production equipment and methods, its structure includes electrolytic cell, level-one gas-liquid separation device, catalyst catalytic mixing device, two level gas-liquid separation device and gas surge tank, the water inlet of level-one gas-liquid separation device is connected to by pipeline with water level regulation water tank, the air inlet of level-one gas-liquid separation device is connected to by pipeline with heat exchanger, and the air inlet of heat exchanger is connected to by pipeline with electrolytic cell；The outlet of the level-one gas-liquid separation device is connected to by pipeline with catalyst catalytic mixing device, the top exit of catalyst catalytic mixing device is connected to by pipeline with two level gas-liquid separation device, the top gas outlet of two level gas-liquid separation device is connected to by pipeline with gas buffer tank, and the gas outlet of gas buffer tank is connected to industrial combustion gas boiler by gas pipeline.Present invention reduces the consumption of electric energy, improves the heat biography in entire gas-making process and change efficiency, the Hydrogen Energy mixed gas of generation, which is produced, to be used, and the danger of gas memory leak is avoided.
Description
Technical field
The present invention relates to new energy field of combustion technology, specifically a kind of Hydrogen Energy air mixture production equipment and side
Method.
Background technology
With the development of national economy, national year fuel consumption is more than 4.5 hundred million tons.Huge fuel consumption is not only to increasingly
Exhausted petroleum-based energy is exerted heavy pressures on, while great amount of fuel oil is burnt improper given off floating charcoal, hydrocarbon（HC）、
Carbon monoxide (CO), nitrogen oxides (NOX), sulfur dioxide（SO2）Deng as big and medium-sized cities major pollutants source.In recent years,
Due to fossil-fuel-fired generated haze, pollution air greatly destroys the ecological environment of the earth, seriously affects people's
Raw body health.Because there is energy saving and environmentally friendly both sides an urgent demand, various improvement are all being studied by major country in the world
The technology of fuel combustion quality, most study is carried out by large scale equipment by the way that various chemical raw materials are added in fuel
Fuel（Add hydrogen etc.）It reforms, achievees the purpose that promote fuel quality, improve efficiency of combustion, reduce exhaust emissions.Hydrogen Energy is new generation
The most environmentally friendly regenerative resource of discipline, but there is also many nothings for the preparation due to Hydrogen Energy, storage, transport and security application etc.
Method solves the problems, such as, it is difficult to be widely applied in civilian industry, while the oxyhydrogen generator of the prior art includes electrolytic cell, setting
Electrolytic cell upper end gas outlet and the positive and negative electrode in electrolyte bath is set, but due to the calorific value of positive and negative conductive electrode
Greatly, the gas temperature when generating hydrogen and oxygen is high, and atom is more active, and stability is poor, and bubble is easy heap on electrode pad
It accumulates and electric current is prevented to pass through, at this point, hydrogen atom is easy to recombine with oxygen atom, form hydrone, cause electrolysis hydrogen and oxygen
The efficiency of gas reduces, and energy consumption is relatively high.
Invention content
The technical assignment of the present invention is to provide a kind of Hydrogen Energy air mixture production equipment and method reducing power consumption.
The present invention technical assignment realize in the following manner, the Hydrogen Energy air mixture production equipment include electrolytic cell,
Heat exchanger, level-one gas-liquid separation device, catalyst catalytic mixing device, two level gas-liquid separation device and gas surge tank, it is described
The water inlet of level-one gas-liquid separation device be connected to water level regulation water tank by pipeline, the air inlet of level-one gas-liquid separation device
It is connected to heat exchanger by pipeline, the air inlet of heat exchanger is exported by the hydrogen and oxygen gas mixture of pipeline and electrolytic cell to be connected
It is logical；The outlet of the level-one gas-liquid separation device is connected to by pipeline with catalyst catalytic mixing device, catalyst catalytic mixing dress
The top exit set is connected to by pipeline with two level gas-liquid separation device, and the top gas outlet of two level gas-liquid separation device passes through pipe
Road is connected to gas buffer tank, and the gas outlet of gas buffer tank is connected to industrial combustion gas boiler by gas pipeline；
The water inlet of the heat exchanger is connected to by pipeline with cooling water tank, and the cooling water inlet of cooling water tank passes through
Pipeline is connected to the cooling water outlet of heat exchanger.
The air inlet of the level-one gas-liquid separation device is connected to by pipeline at least one heat exchanger；There are two
Or when more than two heat exchangers, the cooling water outlet and cooling water inlet between two or more heat exchangers are logical
Piping is connected to, and the air inlet of each heat exchanger is connected to by pipeline with an electrolytic cell.
Water level regulation controller and water level regulation pump are installed on the water inlet line of the water level regulation water tank；
Electrolyte circulating pump is installed on the pipeline that the heat exchanger is connected to electrolytic cell；
Cooling water circulating pump is installed on the pipeline that the heat exchanger is connected to cooling water tank；
The bottom liquid outlet of the two level gas-liquid separation device is connected to by reflux line with catalyst catalytic mixing device,
Connection valve is installed on the reflux line；The bottom of the catalyst catalytic mixing device is equipped with catalyst adding mouth；
Spark arrester is installed on the gas pipeline of the gas buffer tank connection.
The electrolytic cell includes negative electrode end plate, positive electrode end plate, electrolytic zinc-coated steel sheet and insulative pin, and the negative electricity is extreme
Plate is connect with negative electrode, and positive electrode end plate is connect with positive electrode；It is connected between the negative electrode end plate and positive electrode end plate
The more insulative pins being mutually parallel uniformly are configured with multiple electrolytic zinc-coated steel sheets in insulative pin；It is configured on the positive electrode end plate
There is electrolyte inlet, electrolyte outlet is configured on negative electrode end plate.
The both ends of the insulative pin are linked together with negative electrode end plate, positive electrode end plate respectively by nut.
The electrolytic zinc-coated steel sheet is circle, is uniformly provided with insulative pin corresponding with insulative pin quantity hole on electrolytic zinc-coated steel sheet, absolutely
Edge bolt runs through insulative pin hole, opens that there are one electrolyte flow holes on the circumference where two neighboring insulative pin hole；It is adjacent
Felt pad is configured between two electrolytic zinc-coated steel sheets.
The catalyst catalytic mixing device includes shell, and the top of shell is configured with gas outlet, and the bottom of shell configures
There is at least one catalyst adding mouth, taper aeration board, the exposure are configured in the lower part of the housing inner cavity above catalyst adding mouth
Multiple solarization air caps are uniformly provided on gas plate.
Steps are as follows for Hydrogen Energy air mixture production method：
It injects the electrolyte into electrolytic cell and is electrolysed, electrolysate enters heat exchanger, is cooled to through over-heat-exchanger
15-40 DEG C, aqueous vapor separation is carried out subsequently into level-one gas-liquid separation device, the mixed gas after aqueous vapor detaches passes through connection
Pipeline enters the catalyst catalytic mixing device for being previously added liquid catalyst, while being passed through gas to catalyst catalytic mixing device and touching
Matchmaker, after catalyst catalytic mixing, mixed gas enters two level gas-liquid separation device by pipeline and carries out gas-liquid separation, gas-liquid separation
Mixed gas afterwards is transported to industrial combustion gas boiler combustion by spark arrester and gas pipeline；
The electrolyte is the KOH solution of mass percent concentration 25%, and the electrolysate is gas-liquid mixture,
That is the mixture of hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte.
The liquid catalyst is the ethanol solution of 92# gasoline, 95# gasoline or 95% or more mass percent concentration；Institute
The gas catalyst stated is coal gas or natural gas.
It is configured with multiple electrolytic zinc-coated steel sheets in the electrolytic cell, is configured with felt pad between adjacent electrolytic zinc-coated steel sheet, on electrolytic zinc-coated steel sheet
Bubble and electrolyte mix, electrolytic cell is quickly taken out of by electrolyte circulating pump, by after heat exchanger enter one
Grade gas-liquid separation device separation, the time that bubble adsorbs on electrolytic zinc-coated steel sheet shorten, will not be accumulated between bubble；Electrolyte exists
It is quickly flowed by electrolyte circulating pump between electrolytic cell, heat exchanger and level-one gas-liquid separation device, accelerates the electrolysis of water, together
When quick separating go out the mixed gas containing hydroxyl ion；
The two level gas-liquid separation device carries out the liquid left after gas-liquid separation, is urged by being connected to valve inflow catalyst
Change mixing arrangement to recycle.
Compared to the prior art a kind of Hydrogen Energy air mixture production equipment and method of the present invention, greatly reduces electric energy
Consumption, the heat biography improved in entire gas-making process change efficiency, and the mixed gas produced is after knockout drum detaches
Into catalyst catalytic mixing, after the gas after catalytic mixing out enters two level gas-liquid separation, become comparatively safe incendivity
Gas, can be directly as the main fuel of the burning of Industrial Boiler.And the Hydrogen Energy mixed gas generated need not store,
I.e. production is used, and avoids the danger that gas memory leak is brought, whole system operates in low temperature（15-40℃）, low pressure（0.03--
0.09Mpa) under state, safety easy to control, easy to operate；With the flame envelope temperature for the mixed gas burning that the device and method generate
Degree is up to 1200 DEG C or more（Only 800 DEG C -900 DEG C of high-quality natural gas）, and 1 the consumed electric energy of side's mixed gas is often made only
2.3 degree of electricity, greatly reduce energy consumption.
Description of the drawings
Attached drawing 1 is the structural schematic diagram of Hydrogen Energy air mixture production equipment.
Attached drawing 2 is the structural schematic diagram of electrolytic cell.
Attached drawing 3 is the structural schematic diagram of electrolytic zinc-coated steel sheet.
Attached drawing 4 is the structural schematic diagram of catalyst catalytic mixing device.
In figure：101, electrolytic cell, 102, cooling water circulating pump, 103, heat exchanger, 104, cooling water inlet, 105, cooling
Water tank, 106, water level regulation controller, 107, water level regulation pump, 108, water level regulation water tank, 109, level-one gas-liquid separation device,
110, catalyst catalytic mixing device, 111, two level gas-liquid separation device, 112, gas buffer tank, 113, spark arrester, 114, connection
Valve, 115, positive electrode, 116, negative electrode, 117, hydrogen and oxygen gas mixture outlet, 118, catalyst adding mouth, 119, cooling water goes out
Mouthful, 120, electrolyte circulating pump, 201, negative electrode end plate, 202, positive electrode end plate, 203, electrolytic zinc-coated steel sheet, 204, felt pad, 205,
Electrolyte inlet, 206, electrolyte outlet, 207, insulative pin, 208, nut, 301, electrolyte flow hole, 302, insulative pin
Hole, 401, aeration board, 402, solarization air cap, 403, gas outlet, 404, shell.
Specific implementation mode
Embodiment 1：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment include electrolytic cell 101, heat exchanger 103, level-one gas-liquid separation device 109,
Catalyst catalytic mixing device 110, two level gas-liquid separation device 111 and gas surge tank 112, the level-one gas-liquid separation device
109 water inlet is connected to by pipeline with water level regulation water tank 108, and water is equipped on the water inlet line of water level regulation water tank 108
Position adjusting control device 106 and water level regulation pump 107；The air inlet of level-one gas-liquid separation device 109 is handed over by pipeline and a heat
Parallel operation 103 is connected to, and the air inlet of heat exchanger 103 is connected by the hydrogen and oxygen gas mixture of pipeline and an electrolytic cell 101 outlet 117
It is logical, electrolyte circulating pump 120 is installed on the pipeline that heat exchanger 103 is connected to electrolytic cell 101；The water inlet of heat exchanger 103
Mouth is connected to by pipeline with cooling water tank 105, and cooling water is equipped on the pipeline that heat exchanger 103 is connected to cooling water tank 105
Circulating pump 102；The cooling water inlet 104 of cooling water tank 105 is connected to by pipeline with the cooling water outlet 119 of heat exchanger 103；
The outlet of the level-one gas-liquid separation device 109 is connected to by pipeline with catalyst catalytic mixing device 110, catalyst catalytic mixing
Device 110 includes shell 404, and the top of shell 404 is configured with gas outlet 403, and the bottom installation of shell 404 adds there are one catalyst
Add mouth 118；It is configured with taper aeration board 401, the aeration board in 404 lower lumen of shell of 118 top of catalyst adding mouth
Multiple solarization air caps 402 are uniformly provided on 401.The top exit of catalyst catalytic mixing device 110 passes through pipeline and two level gas-liquid point
It is connected to from device 111, the bottom liquid outlet of two level gas-liquid separation device 111 passes through reflux line and catalyst catalytic mixing device
110 are connected to, and connection valve 114 is equipped on the reflux line；The top gas outlet of two level gas-liquid separation device 111 passes through
Pipeline is connected to gas buffer tank 112, and the gas outlet of gas buffer tank 112 is connected to industrial combustion gas boiler by gas pipeline；Gas
Spark arrester 113 is installed on the gas pipeline that body surge tank 112 is connected to.
The electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, the negative electrode end plate 201 is connect with negative electrode 116, and positive electrode end plate 202 is connect with positive electrode 115；Described is negative
It is connected with the more insulative pins being mutually parallel 207 between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
It is even to be configured with multiple electrolytic zinc-coated steel sheets 203, it is configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；The positive electrode end plate
It is configured with electrolyte inlet 205 on 202, electrolyte outlet 206 is configured on negative electrode end plate 201；The insulative pin 207
Both ends linked together respectively with negative electrode end plate 201, positive electrode end plate 202 by nut 208；The electrolytic zinc-coated steel sheet 203
For circle, it is uniformly provided with insulative pin corresponding with 207 quantity of insulative pin hole 302 on electrolytic zinc-coated steel sheet 203, insulative pin 207 is passed through
It wears insulative pin hole 302, opens that there are one electrolyte flow holes 301 on the circumference where two neighboring insulative pin hole 302.
Steps are as follows for Hydrogen Energy air mixture production method：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate
Into heat exchanger 103,15 DEG C are cooled to through over-heat-exchanger 103, aqueous vapor is carried out subsequently into level-one gas-liquid separation device 109
Separation, the mixed gas after aqueous vapor detaches enter the catalyst catalytic mixing dress for being previously added 92# gasoline by connecting pipe
110 are set, while coal gas is passed through to catalyst catalytic mixing device 110（It is passed through the H30 hydroxonium ion that the amount of coal gas is come out by electrolysis production
The amount of son and hydroxyl ion determines that the normal condition consumption of gas is percent by volume 3-5%）, after catalyst catalytic mixing,
In conjunction with generation C6H18O2And CH3-OH-CH2-CH2Admixture of gas, mixed gas enter two level gas-liquid separation device by pipeline
111 carry out gas-liquid separation, and the mixed gas after gas-liquid separation is transported to industrial combustion gas boiler by spark arrester 113 and gas pipeline
Burning；
The electrolysate is gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Mixture.
It is configured with multiple electrolytic zinc-coated steel sheets 203 in the electrolytic cell 101, felt pad is configured between adjacent electrolytic zinc-coated steel sheet 203
204, bubble and electrolyte on electrolytic zinc-coated steel sheet 203 mix, and electrolytic cell 101 is quickly taken out of by electrolyte circulating pump 120,
It being detached by entering level-one gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
It will not be accumulated between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and level-one gas-liquid separation device 109
It crosses electrolyte circulating pump 120 quickly to flow, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The two level gas-liquid separation device 111 carries out the liquid left after gas-liquid separation, is flowed by being connected to valve 114
Catalyst catalytic mixing device 110 recycles.
Embodiment 2：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment include electrolytic cell 101, heat exchanger 103, level-one gas-liquid separation device 109,
Catalyst catalytic mixing device 110, two level gas-liquid separation device 111 and gas surge tank 112, the level-one gas-liquid separation device
109 water inlet is connected to by pipeline with water level regulation water tank 108, and water is equipped on the water inlet line of water level regulation water tank 108
Position adjusting control device 106 and water level regulation pump 107；The air inlet of level-one gas-liquid separation device 109 is handed over by pipeline and two heat
Parallel operation 103 is connected to, and the cooling water outlet between two heat exchangers 103 is connected to cooling water inlet by pipeline, and each heat is handed over
The air inlet of parallel operation 103 be connected to by pipeline with the hydrogen and oxygen gas mixture of electrolytic cell 101 outlet 117, heat exchanger 103 and
Electrolyte circulating pump 120 is installed on the pipeline that electrolytic cell 101 is connected to；The water inlet of heat exchanger 103 passes through pipeline and cooling
Water tank 105 is connected to, and cooling water circulating pump 102 is equipped on the pipeline that heat exchanger 103 is connected to cooling water tank 105；Cooling water
The cooling water inlet 104 of case 105 is connected to by pipeline with the cooling water outlet 119 of heat exchanger 103；The level-one gas-liquid point
Outlet from device 109 is connected to by pipeline with catalyst catalytic mixing device 110, and catalyst catalytic mixing device 110 includes shell
404, the top of shell 404 is configured with gas outlet 403, and there are two catalyst adding mouths 118 for the bottom installation of shell 404；Catalyst adds
Add and be configured with taper aeration board 401 in 404 lower lumen of shell of 118 top of mouth, is uniformly provided on the aeration board 401 more
A solarization air cap 402.The top exit of catalyst catalytic mixing device 110 is connected to by pipeline with two level gas-liquid separation device 111, and two
The bottom liquid outlet of grade gas-liquid separation device 111 is connected to by reflux line with catalyst catalytic mixing device 110, the reflux
Connection valve 114 is installed on pipeline；The top gas outlet of two level gas-liquid separation device 111 passes through pipeline and gas buffer tank
The gas outlet of 112 connections, gas buffer tank 112 is connected to industrial combustion gas boiler by gas pipeline；What gas buffer tank 112 was connected to
Spark arrester 113 is installed on gas pipeline.
The electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, the negative electrode end plate 201 is connect with negative electrode 116, and positive electrode end plate 202 is connect with positive electrode 115；Described is negative
It is connected with the more insulative pins being mutually parallel 207 between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
It is even to be configured with multiple electrolytic zinc-coated steel sheets 203, it is configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；The positive electrode end plate
It is configured with electrolyte inlet 205 on 202, electrolyte outlet 206 is configured on negative electrode end plate 201；The insulative pin 207
Both ends linked together respectively with negative electrode end plate 201, positive electrode end plate 202 by nut 208；The electrolytic zinc-coated steel sheet 203
For circle, it is uniformly provided with insulative pin corresponding with 207 quantity of insulative pin hole 302 on electrolytic zinc-coated steel sheet 203, insulative pin 207 is passed through
It wears insulative pin hole 302, opens that there are one electrolyte flow holes 301 on the circumference where two neighboring insulative pin hole 302.
Steps are as follows for Hydrogen Energy air mixture production method：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate
Into heat exchanger 103,28 DEG C are cooled to through over-heat-exchanger 103, aqueous vapor is carried out subsequently into level-one gas-liquid separation device 109
Separation, the mixed gas after aqueous vapor detaches enter the catalyst catalytic mixing dress for being previously added 95# gasoline by connecting pipe
110 are set, while coal gas is passed through to catalyst catalytic mixing device 110（It is passed through the H30 hydroxonium ion that the amount of coal gas is come out by electrolysis production
The amount of son and hydroxyl ion determines that the normal condition consumption of gas is percent by volume 3-5%）, after catalyst catalytic mixing,
Mixed gas enters two level gas-liquid separation device 111 by pipeline and carries out gas-liquid separation, and the mixed gas after gas-liquid separation passes through
Spark arrester 113 and gas pipeline are transported to industrial combustion gas boiler combustion；
The electrolysate is gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Mixture.
It is configured with multiple electrolytic zinc-coated steel sheets 203 in the electrolytic cell 101, felt pad is configured between adjacent electrolytic zinc-coated steel sheet 203
204, bubble and electrolyte on electrolytic zinc-coated steel sheet 203 mix, and electrolytic cell 101 is quickly taken out of by electrolyte circulating pump 120,
It being detached by entering level-one gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
It will not be accumulated between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and level-one gas-liquid separation device 109
It crosses electrolyte circulating pump 120 quickly to flow, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The two level gas-liquid separation device 111 carries out the liquid left after gas-liquid separation, is flowed by being connected to valve 114
Catalyst catalytic mixing device 110 recycles.
Embodiment 3：
Hydrogen Energy air mixture production equipment is assembled：
The Hydrogen Energy air mixture production equipment include electrolytic cell 101, heat exchanger 103, level-one gas-liquid separation device 109,
Catalyst catalytic mixing device 110, two level gas-liquid separation device 111 and gas surge tank 112, the level-one gas-liquid separation device
109 water inlet is connected to by pipeline with water level regulation water tank 108, and water is equipped on the water inlet line of water level regulation water tank 108
Position adjusting control device 106 and water level regulation pump 107；The air inlet of level-one gas-liquid separation device 109 is handed over by pipeline and three heat
Parallel operation 103 is connected to, and the cooling water outlet between three heat exchangers 103 is connected to cooling water inlet by pipeline, and each heat is handed over
The air inlet of parallel operation 103 be connected to by pipeline with the hydrogen and oxygen gas mixture of electrolytic cell 101 outlet 117, heat exchanger 103 and
Electrolyte circulating pump 120 is installed on the pipeline that electrolytic cell 101 is connected to；The water inlet of heat exchanger 103 passes through pipeline and cooling
Water tank 105 is connected to, and cooling water circulating pump 102 is equipped on the pipeline that heat exchanger 103 is connected to cooling water tank 105；Cooling water
The cooling water inlet 104 of case 105 is connected to by pipeline with the cooling water outlet 119 of heat exchanger 103；The level-one gas-liquid point
Outlet from device 109 is connected to by pipeline with catalyst catalytic mixing device 110, and catalyst catalytic mixing device 110 includes shell
404, the top of shell 404 is configured with gas outlet 403, and there are three catalyst adding mouths 118 for the bottom installation of shell 404；Catalyst adds
Add and be configured with taper aeration board 401 in 404 lower lumen of shell of 118 top of mouth, is uniformly provided on the aeration board 401 more
A solarization air cap 402.The top exit of catalyst catalytic mixing device 110 is connected to by pipeline with two level gas-liquid separation device 111, and two
The bottom liquid outlet of grade gas-liquid separation device 111 is connected to by reflux line with catalyst catalytic mixing device 110, the reflux
Connection valve 114 is installed on pipeline；The top gas outlet of two level gas-liquid separation device 111 passes through pipeline and gas buffer tank
The gas outlet of 112 connections, gas buffer tank 112 is connected to industrial combustion gas boiler by gas pipeline；What gas buffer tank 112 was connected to
Spark arrester 113 is installed on gas pipeline.
The electrolytic cell 101 includes negative electrode end plate 201, positive electrode end plate 202, electrolytic zinc-coated steel sheet 203 and insulative pin
207, the negative electrode end plate 201 is connect with negative electrode 116, and positive electrode end plate 202 is connect with positive electrode 115；Described is negative
It is connected with the more insulative pins being mutually parallel 207 between electrode end plate 201 and positive electrode end plate 202, in insulative pin 207
It is even to be configured with multiple electrolytic zinc-coated steel sheets 203, it is configured with felt pad 204 between two neighboring electrolytic zinc-coated steel sheet 203；The positive electrode end plate
It is configured with electrolyte inlet 205 on 202, electrolyte outlet 206 is configured on negative electrode end plate 201；The insulative pin 207
Both ends linked together respectively with negative electrode end plate 201, positive electrode end plate 202 by nut 208；The electrolytic zinc-coated steel sheet 203
For circle, it is uniformly provided with insulative pin corresponding with 207 quantity of insulative pin hole 302 on electrolytic zinc-coated steel sheet 203, insulative pin 207 is passed through
It wears insulative pin hole 302, opens that there are one electrolyte flow holes 301 on the circumference where two neighboring insulative pin hole 302.
Steps are as follows for Hydrogen Energy air mixture production method：
By electrolyte（The KOH solution of mass percent concentration 25%）It is electrolysed in injection electrolytic cell 101, electrolysate
Into heat exchanger 103,40 DEG C are cooled to through over-heat-exchanger 103, aqueous vapor is carried out subsequently into level-one gas-liquid separation device 109
Separation, the mixed gas after aqueous vapor detaches enter the ethyl alcohol for being previously added mass percent concentration 97% by connecting pipe
The catalyst catalytic mixing device 110 of solution, while being passed through natural gas to catalyst catalytic mixing device 110（It is passed through the amount of natural gas
The amount of the hydrogen ion and hydroxyl ion that are come out by electrolysis production determines that the normal condition consumption of gas is percent by volume
3-5%）, after catalyst catalytic mixing, mixed gas enters two level gas-liquid separation device 111 by pipeline and carries out gas-liquid separation, gas
Mixed gas after liquid separation is transported to industrial combustion gas boiler combustion by spark arrester 113 and gas pipeline；
The electrolysate is gas-liquid mixture, i.e. hydrogen, oxygen, hydrogen ion, hydroxyl ion and electrolyte
Mixture.
It is configured with multiple electrolytic zinc-coated steel sheets 203 in the electrolytic cell 101, felt pad is configured between adjacent electrolytic zinc-coated steel sheet 203
204, bubble and electrolyte on electrolytic zinc-coated steel sheet 203 mix, and electrolytic cell 101 is quickly taken out of by electrolyte circulating pump 120,
It being detached by entering level-one gas-liquid separation device 109 after heat exchanger 103, the time that bubble adsorbs on electrolytic zinc-coated steel sheet 203 shortens,
It will not be accumulated between bubble；Electrolyte leads between electrolytic cell 101, heat exchanger 103 and level-one gas-liquid separation device 109
It crosses electrolyte circulating pump 120 quickly to flow, accelerates the electrolysis of water, while quick separating goes out the mixed gas containing hydroxyl ion；
The two level gas-liquid separation device 111 carries out the liquid left after gas-liquid separation, is flowed by being connected to valve 114
Catalyst catalytic mixing device 110 recycles.
The technical personnel in the technical field can readily realize the present invention with the above specific embodiments,.But it answers
Work as understanding, the present invention is not limited to above-mentioned several specific implementation modes.On the basis of the disclosed embodiments, the technology
The technical staff in field can arbitrarily combine different technical features, to realize different technical solutions.
Claims (8)
1. a kind of Hydrogen Energy air mixture production equipment, including the catalysis of electrolytic cell, heat exchanger, level-one gas-liquid separation device, catalyst
Mixing arrangement, two level gas-liquid separation device and gas surge tank, which is characterized in that the water inlet of the level-one gas-liquid separation device
Mouth is connected to by pipeline with water level regulation water tank, and the air inlet of level-one gas-liquid separation device is connected to by pipeline with heat exchanger,
The hydrogen and oxygen gas mixture outlet that the air inlet of heat exchanger passes through pipeline and electrolytic cell；The level-one gas-liquid separation device
Outlet be connected to catalyst catalytic mixing device by pipeline, the top exit of catalyst catalytic mixing device passes through pipeline and two level
Gas-liquid separation device is connected to, and the top gas outlet of two level gas-liquid separation device is connected to by pipeline with gas buffer tank, and gas is slow
The gas outlet for rushing tank is connected to industrial combustion gas boiler by gas pipeline；
The water inlet of the heat exchanger is connected to by pipeline with cooling water tank, and the cooling water inlet of cooling water tank passes through pipeline
It is connected to the cooling water outlet of heat exchanger；
The electrolytic cell includes negative electrode end plate, positive electrode end plate, electrolytic zinc-coated steel sheet and insulative pin, the negative electrode end plate with
Negative electrode connects, and positive electrode end plate is connect with positive electrode；It is connected with more between the negative electrode end plate and positive electrode end plate
The insulative pin being mutually parallel uniformly is configured with multiple electrolytic zinc-coated steel sheets in insulative pin；Configured with electricity on the positive electrode end plate
Liquid import is solved, electrolyte outlet is configured on negative electrode end plate；
The catalyst catalytic mixing device includes shell, and the top of shell is configured with gas outlet, and the bottom of shell is configured with extremely
Lack a catalyst adding mouth, taper aeration board, the aeration board are configured in the lower part of the housing inner cavity above catalyst adding mouth
On be uniformly provided with multiple solarization air caps.
2. a kind of Hydrogen Energy air mixture production equipment according to claim 1, which is characterized in that the level-one gas-liquid point
It is connected to at least one heat exchanger by pipeline from the air inlet of device；When there are two or when more than two heat exchangers,
Cooling water outlet between two or more heat exchangers is connected to cooling water inlet by pipeline, each heat exchanger
Air inlet be connected to an electrolytic cell by pipeline.
3. a kind of Hydrogen Energy air mixture production equipment according to claim 1, which is characterized in that the water level regulation water
Water level regulation controller and water level regulation pump are installed on the water inlet line of case；
Electrolyte circulating pump is installed on the pipeline that the heat exchanger is connected to electrolytic cell；
Cooling water circulating pump is installed on the pipeline that the heat exchanger is connected to cooling water tank；
The bottom liquid outlet of the two level gas-liquid separation device is connected to by reflux line with catalyst catalytic mixing device, described
Reflux line on connection valve is installed；The bottom of the catalyst catalytic mixing device is equipped with catalyst adding mouth；
Spark arrester is installed on the gas pipeline of the gas buffer tank connection.
4. a kind of Hydrogen Energy air mixture production equipment according to claim 1, which is characterized in that the insulative pin
Both ends are linked together with negative electrode end plate, positive electrode end plate respectively by nut.
5. a kind of Hydrogen Energy air mixture production equipment according to claim 1, which is characterized in that the electrolytic zinc-coated steel sheet is circle
Shape is uniformly provided with insulative pin corresponding with insulative pin quantity hole on electrolytic zinc-coated steel sheet, and insulative pin runs through insulative pin hole, adjacent
Electrolyte flow hole there are one being opened on circumference where two insulative pin holes；Configured with insulation between two neighboring electrolytic zinc-coated steel sheet
Pad.
6. a kind of Hydrogen Energy air mixture production method, which is characterized in that steps are as follows for this method：
It injects the electrolyte into electrolytic cell and is electrolysed, electrolysate enters heat exchanger, and 15-40 is cooled to through over-heat-exchanger
DEG C, aqueous vapor separation is carried out subsequently into level-one gas-liquid separation device, the mixed gas after aqueous vapor detaches passes through connecting pipe
It is passed through gas catalyst into the catalyst catalytic mixing device for being previously added liquid catalyst, while to catalyst catalytic mixing device,
After catalyst catalytic mixing, mixed gas enters two level gas-liquid separation device by pipeline and carries out gas-liquid separation, after gas-liquid separation
Mixed gas is transported to industrial combustion gas boiler combustion by spark arrester and gas pipeline；
The electrolyte is the KOH solution of mass percent concentration 25%, and the electrolysate is gas-liquid mixture, i.e. hydrogen
The mixture of gas, oxygen, hydrogen ion, hydroxyl ion and electrolyte.
7. a kind of Hydrogen Energy air mixture production method according to claim 6, which is characterized in that the liquid catalyst is
The ethanol solution of 92# gasoline, 95# gasoline or 95% or more mass percent concentration；The gas catalyst is for coal gas or naturally
Gas.
8. a kind of Hydrogen Energy air mixture production method according to claim 6, which is characterized in that match in the electrolytic cell
Multiple electrolytic zinc-coated steel sheets are equipped with, felt pad is configured between adjacent electrolytic zinc-coated steel sheet, the bubble and electrolyte on electrolytic zinc-coated steel sheet mix,
Electrolytic cell is quickly taken out of by electrolyte circulating pump, is detached by entering level-one gas-liquid separation device after heat exchanger, bubble exists
The time adsorbed on electrolytic zinc-coated steel sheet shortens, and will not be accumulated between bubble；Electrolyte is in electrolytic cell, heat exchanger and level-one gas-liquid
It is quickly flowed by electrolyte circulating pump between separator, accelerates the electrolysis of water, while quick separating goes out containing hydroxyl ion
Mixed gas；
The two level gas-liquid separation device carries out the liquid left after gas-liquid separation, mixed by being connected to valve inflow catalyst catalysis
It attaches together and sets recycling.
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| CN111850597B (en) * | 2020-06-15 | 2022-08-05 | 中船(邯郸)派瑞特种气体股份有限公司 | Electrochemical fluorination external circulation electrolysis system |
| CN112206883A (en) * | 2020-09-27 | 2021-01-12 | 广州怡润贸易有限公司 | Paper shredder capable of completely breaking paper and preventing hand from being injured when cleaning |
| CN113341848B (en) * | 2021-07-01 | 2024-03-29 | 白玉林 | Control circuit for generating hydrogen and oxygen in water aqua |
| CN114110574B (en) * | 2021-12-03 | 2024-04-05 | 上海源晗能源技术有限公司 | Nitrogen-insulated combustion and CO of gas boiler 2 Trapping and utilizing process |
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| CN1216184C (en) * | 2001-05-08 | 2005-08-24 | 谢宏凯 | Hydrogen energy generator |
| JP2003328172A (en) * | 2002-05-13 | 2003-11-19 | Toshiba Corp | Hydrogen utilization system |
| CN101928953A (en) * | 2009-10-27 | 2010-12-29 | 上海高企新能源科技有限公司 | Water electrolysis hydrogen producing process by cooling filtering method |
| CN104818496A (en) * | 2014-01-30 | 2015-08-05 | 泱能（厦门）商贸有限公司 | Manufacturing device of oxygen-containing gaseous fuel |
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