CN106497188A - A kind of preparation method of strong attached type steel structure anti-corrosion paint - Google Patents
A kind of preparation method of strong attached type steel structure anti-corrosion paint Download PDFInfo
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- CN106497188A CN106497188A CN201610923002.7A CN201610923002A CN106497188A CN 106497188 A CN106497188 A CN 106497188A CN 201610923002 A CN201610923002 A CN 201610923002A CN 106497188 A CN106497188 A CN 106497188A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of preparation method of strong attached type steel structure anti-corrosion paint, belongs to anticorrosive paint technology field.The present invention is with parthenocissuss sucker as raw material, milled and collected powder, mix with absolute ethyl alcohol and stirring and must extract concentrated solution, tannic acid is separately added into again, phospholipid, chloroform is placed in beaker, stirring mixing, standing cooling is milled and is prepared into composite modified granule, subsequently distinguish anhydride maleique in proportion, titanium dioxide, aluminium triphosphate etc. is placed in the beaker of deionized water, stirring mixes and stands, a kind of strong attached type steel structure anti-corrosion paint can be prepared into, the present invention is by having a small amount of alduronic acid with negative charge in parthenocissuss sucker polysaccharide in parthenocissuss extracting solution, it is combined with coating, mutually wound by molecule, form irregular aggregation, strengthen the adhesive property between coating and matrix, ink is made effectively to adhere in film surface, make coating that there is higher corrosion resistance and adhesive force, antiseptic property is excellent.
Description
Technical field
The invention discloses a kind of preparation method of strong attached type steel structure anti-corrosion paint, belongs to anticorrosive paint technology neck
Domain.
Background technology
Steel construction is widely used in building engineering field with its unique superiority, particularly high level, Super High, light section
Structure, large-span space structure etc., major advantage are that speed of application fast, energy-conserving and environment-protective, overall economics index are good, building is made
Type is attractive in appearance, anti-seismic performance is good etc., it is contemplated that by 2015, the steel using amount of national construction steel structure was up to the 6% of steel total amount,
Target in terms of structural steel is high-rise building steel structure slab, cold-rolled forming section Aldecor, aluminum-zinc alloy thin plate
Deng all domestic, structural steel stability is higher;Architectural shape is complete in specifications, and Aldecor kind for building increases
Plus, weathering steel, refractory steel, low yield strength ratio steel etc. can be supplied, although steel construction there are many advantages, is also encountered in the application
The Anticorrosion of some problems, mainly steel construction.
Anticorrosive coating system generally comprises priming paint, intermediate coat, finish paint, and priming paint is more containing powder, and base material is few, and film forming is coarse,
Strong with steel adhesion, good with finish paint associativity, then base material is more for finish paint, and film forming is glossy, can protect priming paint not by atmospheric corrosion,
And can have whether compatible problem between weathering resistance, but different coating, need to consider theirs when in front and back from different coating
The compatibility.The resistant to water penetration of steel structure anti-corrosion coating is poor in the market, and paint adhesion is not strong, has a strong impact on film
Corrosion Protection.Therefore, the present invention prepares a kind of both waterproof, and antiseptic power is by force, increases the service life, with good
Application prospect.
Content of the invention
The technical problem to be solved:Resistant to water penetration for existing steel structure anti-corrosion paint is poor, coating
Adhesive force is not strong, and has a strong impact on the problem of the Corrosion Protection of film, there is provided a kind of strong attached type anticorrosion of steel structure is applied
The preparation method of material, the present invention are milled and are collected powder, mixed with absolute ethyl alcohol and stirring with parthenocissuss sucker as raw material
Concentrated solution is extracted, then is separately added into tannic acid, phospholipid, chloroform and is placed in beaker, stirring mixing stands cooling and mills preparation
Composite modified granule is obtained, subsequently anhydride maleique, titanium dioxide, aluminium triphosphate etc. are placed in the beaker of deionized water in proportion respectively
In, stirring mixes and stands, you can be prepared into a kind of strong attached type steel structure anti-corrosion paint, and the present invention is carried by parthenocissuss sucker
Liquid is taken, due to having a small amount of alduronic acid with negative charge in parthenocissuss sucker polysaccharide in parthenocissuss extracting solution, is carried out with coating
Compound, mutually wound by molecule, form irregular aggregation, strengthened the adhesive property between coating and matrix, make ink
Effectively adhere in film surface, make coating that there is higher corrosion resistance and adhesive force, preparation method of the present invention is simple, convenient
Implement.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1)Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, by which
It is placed in mortar and mills and sieve, collects and dry parthenocissuss sucker powder in mass ratio 1:10, by itself and absolute ethyl alcohol and stirring
Mixing, is heated to the 1~2h that flows back;
(2)After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 45~50 DEG C is collected drying crystalline and pressed
Mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 6~8h at room temperature, then water-bath at 45~50 DEG C
25~30min of heating, filters and collects filtrate, and at 45~50 DEG C, rotation evaporation and concentration is prepared into and is climbed the mountain to the 1/6 of original volume
Brave sucker extracts concentrated solution, standby;
(3)Score another name 10~15 parts of tannic acid of amount, 10~15 parts of phospholipid, 35~40 parts of chloroform are placed in burning by weight
In cup, stirring mixing is placed in 1~2h of heating in water bath at 45~50 DEG C, subsequently stands and is cooled to room temperature, in 2500~3000r/
10~15min of centrifugation under min, collects lower sediment and is placed in drying 6~8h at 45~50 DEG C, mill and be prepared into compound changing
Property granule;
(4)Count by weight, weigh 15~20 parts of maleic anhydrides, 1~2 part of titanium dioxide, 10~15 parts of trimerization phosphorus respectively
Sour aluminum, 15~20 parts of epoxy resin E-51,5~8 parts of steps(2)The parthenocissuss sucker of preparation extract concentrated solution, 3~5 parts above-mentioned
The composite modified granule and 45~50 parts of deionized waters for preparing is placed in beaker, and stirring mixes and stands 1~2h, you can be prepared into
A kind of strong attached type steel structure anti-corrosion paint.
The present invention application process be:From steel substrate as ground, carried out eliminating rust, after oil removing surface treatment,
The strong attached type steel structure anti-corrosion paint of gained of the present invention is squeegeed onto, thickness is 150~200 μm, and relative humidity 75%~85% is applied
Layer is general to be brushed 4~5 times, must not be drenched with rain after application within 4h.After testing, on steel substrate, appearance of film is smooth, with excellent
Corrosion resistance and adhesive force, and stability can continue 12~15 months.
The invention has the beneficial effects as follows:
(1)Preparation method of the present invention is simple, and construction effect is good, and gained coating adhesion is high, and effect duration is longer, and antiseptic property is good
Good, cost is substantially less than import coating, solves the problems, such as that import coating is with high costs;
(2)A kind of strong attached type steel structure anti-corrosion paint of gained of the present invention, the paint solidification effect and film-formation result good, and corrosion resistant
Corrosion, resistance to soiling, chemical resistance are improved, with higher economic and social benefit.
Specific embodiment
Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, by which
It is placed in mortar and mills and sieve, collects and dry parthenocissuss sucker powder in mass ratio 1:10, by itself and absolute ethyl alcohol and stirring
Mixing, is heated to the 1~2h that flows back;After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 45~50 DEG C is received
Collection drying crystalline in mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 6~8h at room temperature, then
25~30min of heating in water bath at 45~50 DEG C, filters and collects filtrate, and at 45~50 DEG C, rotation evaporation and concentration is to original volume
1/6, it is prepared into parthenocissuss sucker and extracts concentrated solution, by weight score another name 10~15 parts of tannic acid of amount, 10~15 parts of phosphorus
Fat, 35~40 parts of chloroform are placed in beaker, and stirring mixing is placed in 1~2h of heating in water bath at 45~50 DEG C, subsequently stands
Room temperature is cooled to, 10~15min of centrifugation under 2500~3000r/min collects lower sediment and is placed at 45~50 DEG C
6~8h is dried, is milled and is prepared into composite modified granule;Count by weight, weigh respectively 15~20 parts of maleic anhydrides, 1
~2 parts of titanium dioxides, 10~15 parts of aluminium triphosphates, 15~20 parts of epoxy resin E-51,5~8 parts of steps(2)The parthenocissuss of preparation
Sucker extracts concentrated solution, the composite modified granule of 3~5 parts of above-mentioned preparations and 45~50 parts of deionized waters and is placed in beaker, stirs
Mix and stand 1~2h, you can be prepared into a kind of strong attached type steel structure anti-corrosion paint.
Example 1
Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, be placed on
Mill in mortar and sieve, collect and dry parthenocissuss sucker powder in mass ratio 1:10, which is mixed with absolute ethyl alcohol and stirring,
It is heated to the 1h that flows back;After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 45 DEG C collects drying crystalline simultaneously
In mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 6h at room temperature, then heating in water bath at 45 DEG C
25min, filters and collects filtrate, and at 45 DEG C, rotation evaporation and concentration is prepared into the extraction of parthenocissuss sucker dense to the 1/6 of original volume
Contracting liquid, by weight score another name 10 parts of tannic acid of amount, 10 parts of phospholipid, 35 parts of chloroform are placed in beaker, stirring mixing
Heating in water bath 1h at 45 DEG C is placed in, is subsequently stood and is cooled to room temperature, centrifugation 10min under 2500r/min collects lower floor
Precipitation is placed in drying 6h at 45 DEG C, mills and is prepared into composite modified granule;Count by weight, weigh 15 parts of maleics respectively
Dicarboxylic anhydride, 1 part of titanium dioxide, 10 parts of aluminium triphosphates, 15 parts of epoxy resin E-51, parthenocissuss suckers of 5 parts of preparations extract concentration
Liquid, the composite modified granule of 3 parts of above-mentioned preparations and 45 parts of deionized waters are placed in beaker, and stirring mixes and stands 1h, you can system
A kind of standby strong attached type steel structure anti-corrosion paint.
From steel substrate as ground, carried out eliminating rust, after oil removing surface treatment, be squeegeed onto gained of the present invention strong
Attached type steel structure anti-corrosion paint, thickness are 150 μm, and relative humidity 75%, coating typically brush 4 times, after application within 4h not
Must drench with rain.After testing, on steel substrate, appearance of film is smooth, and with excellent anticorrosive and adhesive force, and stability can be with
Continue 12 months.
Example 2
Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, be placed on
Mill in mortar and sieve, collect and dry parthenocissuss sucker powder in mass ratio 1:10, which is mixed with absolute ethyl alcohol and stirring,
It is heated to the 2h that flows back;After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 50 DEG C collects drying crystalline simultaneously
In mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 8h at room temperature, then heating in water bath at 50 DEG C
30min, filters and collects filtrate, and at 50 DEG C, rotation evaporation and concentration is prepared into the extraction of parthenocissuss sucker dense to the 1/6 of original volume
Contracting liquid, by weight score another name 15 parts of tannic acid of amount, 15 parts of phospholipid, 40 parts of chloroform are placed in beaker, stirring mixing
Heating in water bath 2h at 50 DEG C is placed in, is subsequently stood and is cooled to room temperature, centrifugation 15min under 3000r/min collects lower floor
Precipitation is placed in drying 8h at 50 DEG C, mills and is prepared into composite modified granule;Count by weight, weigh 20 parts of maleics respectively
Dicarboxylic anhydride, 2 parts of titanium dioxides, 15 parts of aluminium triphosphates, 20 parts of epoxy resin E-51, parthenocissuss suckers of 8 parts of preparations extract concentration
Liquid, the composite modified granule of 5 parts of above-mentioned preparations and 50 parts of deionized waters are placed in beaker, and stirring mixes and stands 2h, you can system
A kind of standby strong attached type steel structure anti-corrosion paint.
From steel substrate as ground, carried out eliminating rust, after oil removing surface treatment, be squeegeed onto gained of the present invention strong
Attached type steel structure anti-corrosion paint, thickness are 200 μm, and relative humidity 85%, coating are typically brushed 5 times, must not within 4h after application
Drench with rain.After testing, on steel substrate, appearance of film is smooth, and with excellent anticorrosive and adhesive force, and stability can be held
Continuous 15 months.
Example 3
Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, be placed on
Mill in mortar and sieve, collect and dry parthenocissuss sucker powder in mass ratio 1:10, which is mixed with absolute ethyl alcohol and stirring,
It is heated to the 2h that flows back;After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 48 DEG C collects drying crystalline simultaneously
In mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 7h at room temperature, then heating in water bath at 48 DEG C
28min, filters and collects filtrate, and at 48 DEG C, rotation evaporation and concentration is prepared into the extraction of parthenocissuss sucker dense to the 1/6 of original volume
Contracting liquid, by weight score another name 13 parts of tannic acid of amount, 13 parts of phospholipid, 38 parts of chloroform are placed in beaker, stirring mixing
Heating in water bath 2h at 48 DEG C is placed in, is subsequently stood and is cooled to room temperature, centrifugation 13min under 2800r/min collects lower floor
Precipitation is placed in drying 7h at 48 DEG C, mills and is prepared into composite modified granule;Count by weight, weigh 18 parts of maleics respectively
Dicarboxylic anhydride, 2 parts of titanium dioxides, 13 parts of aluminium triphosphates, 18 parts of epoxy resin E-51, parthenocissuss suckers of 7 part of 4 preparation extract concentration
Liquid, the composite modified granule of 4 parts of above-mentioned preparations and 48 parts of deionized waters are placed in beaker, and stirring mixes and stands 2h, you can system
A kind of standby strong attached type steel structure anti-corrosion paint.
From steel substrate as ground, carried out eliminating rust, after oil removing surface treatment, be squeegeed onto gained of the present invention strong
Attached type steel structure anti-corrosion paint, thickness are 180 μm, and relative humidity 80%, coating are typically brushed 5 times, must not within 4h after application
Drench with rain.After testing, on steel substrate, appearance of film is smooth, and with excellent anticorrosive and adhesive force, and stability can be held
Continuous 14 months.
Claims (1)
1. a kind of preparation method of strong attached type steel structure anti-corrosion paint, it is characterised in that concrete preparation process is:
(1)Fresh parthenocissuss sucker is chosen, its surface silt is cleaned and is dried naturally, collected and dry parthenocissuss sucker, by which
It is placed in mortar and mills and sieve, collects and dry parthenocissuss sucker powder in mass ratio 1:10, by itself and absolute ethyl alcohol and stirring
Mixing, is heated to the 1~2h that flows back;
(2)After the completion of waiting to flow back, filter and collect filtrate, rotary evaporated to dryness at 45~50 DEG C is collected drying crystalline and pressed
Mass ratio 1:8, drying crystalline is mixed with deionized water stirring, after standing 6~8h at room temperature, then water-bath at 45~50 DEG C
25~30min of heating, filters and collects filtrate, and at 45~50 DEG C, rotation evaporation and concentration is prepared into and is climbed the mountain to the 1/6 of original volume
Brave sucker extracts concentrated solution, standby;
(3)Score another name 10~15 parts of tannic acid of amount, 10~15 parts of phospholipid, 35~40 parts of chloroform are placed in burning by weight
In cup, stirring mixing is placed in 1~2h of heating in water bath at 45~50 DEG C, subsequently stands and is cooled to room temperature, in 2500~3000r/
10~15min of centrifugation under min, collects lower sediment and is placed in drying 6~8h at 45~50 DEG C, mill and be prepared into compound changing
Property granule;
(4)Count by weight, weigh 15~20 parts of maleic anhydrides, 1~2 part of titanium dioxide, 10~15 parts of trimerization phosphorus respectively
Sour aluminum, 15~20 parts of epoxy resin E-51,5~8 parts of steps(2)The parthenocissuss sucker of preparation extract concentrated solution, 3~5 parts above-mentioned
The composite modified granule and 45~50 parts of deionized waters for preparing is placed in beaker, and stirring mixes and stands 1~2h, you can be prepared into
A kind of strong attached type steel structure anti-corrosion paint.
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CN201610923002.7A CN106497188A (en) | 2016-10-29 | 2016-10-29 | A kind of preparation method of strong attached type steel structure anti-corrosion paint |
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CN201610923002.7A CN106497188A (en) | 2016-10-29 | 2016-10-29 | A kind of preparation method of strong attached type steel structure anti-corrosion paint |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101701126A (en) * | 2009-11-13 | 2010-05-05 | 中国电力科学研究院 | Aqueous rusty anti-corrosion paint and preparation method thereof |
CN102031053A (en) * | 2010-12-21 | 2011-04-27 | 中国电力科学研究院 | Anti-corrosion coating for surface of steel structure and preparation method thereof |
CN104371507A (en) * | 2014-08-13 | 2015-02-25 | 山东奔腾漆业股份有限公司 | High performance water-based industrial anti-corrosion coating and preparation method thereof |
CN104640461A (en) * | 2012-08-09 | 2015-05-20 | 雀巢产品技术援助有限公司 | Anthocyanin colouring composition |
CN105062413A (en) * | 2015-09-11 | 2015-11-18 | 江苏振宇环保科技有限公司 | Preparation method for parthenocissus tricuspidata sucker polysaccharide biological adhesive |
-
2016
- 2016-10-29 CN CN201610923002.7A patent/CN106497188A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101701126A (en) * | 2009-11-13 | 2010-05-05 | 中国电力科学研究院 | Aqueous rusty anti-corrosion paint and preparation method thereof |
CN102031053A (en) * | 2010-12-21 | 2011-04-27 | 中国电力科学研究院 | Anti-corrosion coating for surface of steel structure and preparation method thereof |
CN104640461A (en) * | 2012-08-09 | 2015-05-20 | 雀巢产品技术援助有限公司 | Anthocyanin colouring composition |
CN104371507A (en) * | 2014-08-13 | 2015-02-25 | 山东奔腾漆业股份有限公司 | High performance water-based industrial anti-corrosion coating and preparation method thereof |
CN105062413A (en) * | 2015-09-11 | 2015-11-18 | 江苏振宇环保科技有限公司 | Preparation method for parthenocissus tricuspidata sucker polysaccharide biological adhesive |
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Application publication date: 20170315 |