CN106495636A - A kind of tailing foam mortar of underground mine exploitation filling - Google Patents

A kind of tailing foam mortar of underground mine exploitation filling Download PDF

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Publication number
CN106495636A
CN106495636A CN201610978396.6A CN201610978396A CN106495636A CN 106495636 A CN106495636 A CN 106495636A CN 201610978396 A CN201610978396 A CN 201610978396A CN 106495636 A CN106495636 A CN 106495636A
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CN
China
Prior art keywords
tailing
cement
filling
mortar
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610978396.6A
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Chinese (zh)
Inventor
王小敏
江峰
江一峰
张传信
王浩
毛宏宇
胡润芥
龚平玲
秦桂云
李祯
杨蔡君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huawei National Engineering Research Center of High Efficient Cyclic and Utilization of Metallic Mineral Resources Co Ltd
Sinosteel Maanshan General Institute of Mining Research Co Ltd
Original Assignee
Huawei National Engineering Research Center of High Efficient Cyclic and Utilization of Metallic Mineral Resources Co Ltd
Sinosteel Maanshan General Institute of Mining Research Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huawei National Engineering Research Center of High Efficient Cyclic and Utilization of Metallic Mineral Resources Co Ltd, Sinosteel Maanshan General Institute of Mining Research Co Ltd filed Critical Huawei National Engineering Research Center of High Efficient Cyclic and Utilization of Metallic Mineral Resources Co Ltd
Priority to CN201610978396.6A priority Critical patent/CN106495636A/en
Publication of CN106495636A publication Critical patent/CN106495636A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/141Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing dihydrated gypsum before the final hardening step, e.g. forming a dihydrated gypsum product followed by a de- and rehydration step
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of tailing foam mortar of underground mine exploitation filling, it is to be prepared from by the foam that foaming agent is formed through stirring mixing, injection by cement, mine tailing, quick lime, alumina cement, gypsum, water, total amount is by each component weight/mass percentage composition of 100% timing:Portland cement 8~14%, mine tailing 50~64%, foaming agent 0.8~1.3%, quick lime 0.7~1.4%, alumina cement 0.7~1.4%, gypsum 0.7~1.4%, water 24~34%.Tailing foam mortar, has water-retaining property strong than ordinary mortar obturation, and mobility is strong, light weight, low cost, connects the good advantage of top effect, and raw material is simple, easy to make, can be widely used for the filling field in vast mining area.

Description

A kind of tailing foam mortar of underground mine exploitation filling
Technical field
The present invention relates to a kind of foam mortar, is used for filling in mine more particularly, to a kind of, with mine tailing as primary raw material Foam mortar, not only can be widely used in filling in mine mining technique, it may also be used for municipal administration, processing and construction of construction material etc. Field.
Background technology
Foam mortar is, with physical method, foaming agent water solution is prepared into foam, and key component includes that cement base coagulates material Material, water and optional component are gathered materials, admixture, additive are mixed according to the ratio of certain ratio, and made through physical chemistry A kind of light material formed with hardening.
At present both at home and abroad the filler of filling in mine many using tailings, gather materials, the aggregate such as rubble, add a certain proportion of Cementing material, such as cement, flyash, steel quarrel etc., stir to form certain density filling slurry or lotion together with water, to flow automatically Or the form of pump pressure is transported to stope, but all there is the defect of itself to some extent.Gravity flow tailings filling body is by deadweight No pressure conveying is carried out by pipeline, the subject matter of the filling process is that filling pipe abrasion is big, filling slurry is susceptible to isolation, The problems such as layering, make that strength of filling mass is low, change is big, often can not meet the strength of filling mass of stope design;Meanwhile, filling is adopted Field produces substantial amounts of bleed (including flushing pipe water), not only pollutes stope environment, and makes Tight filling bad, reduces Filling effect.High dense fill (lotion) can reduce filling stope water pollution, and with preferable Tight filling, but paste body filling is deposited In two problems:One be paste body filling be pump pressure conveying, need to introduce a set of pump pressure conveying equipment, system process is complicated, expense Higher;Two is that pumping lotion plugging phenomenon often occurs.Plugging processes very difficult once occur to which, not only affects normal Filling process, and process plugging to pay hardships work and great number cost.
In recent years, people increasingly pay attention to the improvement to method of mining by the way of filling filling process, and foam mortar filling body technique is just It is one of which.Foam mortar obturation be by concrete, gather materials (including thin Gobi aggregate, thin river sand, rod milling sand, flyash, Tailings etc.), water, foaming agent formed foam carry out being well mixed stirring, Jing Guoyi with appropriate additive in certain proportion The physics chemical action of section time, formed after dry hardening to be drained off containing certain ratio space, with some strength Filling new material.《Metal mine》In " Research on Application Value of foam mortar obturation " text that 10th phase in 2013 delivers, In order to obtain more preferable filling effect and cost-effective, can only be improved from filler.Through many-sided contrast, And other mine experiences are used for reference, here selects foam mortar as filler.Selected material be cement, natural sand, water, Foaming agent etc..The expense that the expense filled by foam mortar is filled with conventional slurry is compared, it can be seen that foam is filled Technology has very high economic benefit.But the material selected in this article is cement, natural sand, cost times is so higher, simply than normal Rule mortar carries out filling economical.
Content of the invention
The purpose of the present invention is aiming at the problem of the problems referred to above of prior art presence, and provide a kind of raw material simple, The tailing foam mortar of underground mine exploitation filling easy to make, with low cost.
For realizing that the above-mentioned purpose of the present invention, a kind of tailing foam mortar of underground mine exploitation filling of the invention are adopted Technical scheme below:
A kind of tailing foam mortar of underground mine exploitation filling of the present invention is by cement, mine tailing, quick lime, high alumina water Mud, gypsum, water are prepared from by the foam that foaming agent is formed through stirring mixing, injection, each component of the total amount by 100% timing Weight/mass percentage composition is:
Each component weight/mass percentage composition is preferably:
Each component weight/mass percentage composition is more preferably:
Described Portland cement is greater than or equal to P.O32.5 Portland cements.
The granularity of the mine tailing is 0.074~3mm grain size contents 90%, and wherein 0.1~3mm grain size contents 60% are Preferably;In order to improve obturation compression strength, described mine tailing particle size range accounts for more than 90% with 0.25~3mm and is preferred.
Described quick lime be CaO content 85%, and quick lime through levigate to granularity be -0.074mm contents 90%, It is preferred with -0.074mm contents 95%.
It is raw material that the alumina cement is bauxite and lime, prepares by a certain percentage, through calcining, levigate obtained one Plant the hydraulic cementing materials with aluminate as main mineral constituent.
Described gypsum is gypsum, and main component is CaSO4·2H2O.
Described foaming agent is vegetalitas macromolecule foaming agent.Such as the limited public affairs of Thailand of Linyi City Hedong District section energy-saving building material machinery The vegetalitas macromolecule foaming agent of department's production, the foaming agent import high-quality natural plants macromolecular material is raw material, through one is The complicated chemical reaction of row is generated, and product is in lurid pure transparent oily liquid, nontoxic, tasteless, nothing insensitive to hard water Sediment, pH value are close to neutrality, to cement and metal non-corrosiveness, do not produce pollution to environment.Other manufacturer productions can also be used Vegetalitas cement blowing agent, such as Thailand of section cement plant foaming agent.
Described water is common running water or mine water, ore dressing recirculated water.
Described tailing foam method for preparing mortar is:By Portland cement, mine tailing, quick lime, alumina cement, stone Cream, water sequentially add mechanical agitation uniformly, then introduce a foam into mortar, and mechanical agitation is uniform.
Vegetalitas macromolecule foaming agent of the present invention, by the method for compressed air, makes foaming agent solution and quilt The air of compression makes mixture pass through a special foaming cylinder, most in the indoor mixing of mixing then under compressed air effect End form is introduced in mortar into foam.
Compared with prior art, a kind of advantage of the tailing foam mortar of underground mine exploitation filling of the invention exists In:
(1) in the foam mortar by mine tailing for main component of the present invention, the utilization rate of mine tailing has reached more than 50%, And at present existing filler many using tailings, gather materials, the aggregate such as rubble, therefore foam mortar of the invention is with low cost, In filling construction, economic benefit can be increased substantially.
(2) in the foam mortar by mine tailing for main component of the present invention, due to introducing foam, therefore make it have Flow well, pipeline is not blocked in pipeline.At present in the course of conveying of filler, the blocking and abrasion of pipeline Problem is not also solved well, and the foam in foam mortar has lubrication well and drag reduction to act on, and can improve well Transport condition.
(3) in the foam mortar in the present invention by mine tailing for main component, with good education resistance.Conventional filling material In material stowing operation, usually segregation phenomenon can occur, not only result in water pollution, and after causing filler hardening intensity is not Enough uniform, affect filling effect.And the education resistance of tailing foam mortar can make filling even intensity, it is to avoid water pollution stope ring Border.
(4) in the foam mortar in the present invention by mine tailing for main component, with higher concentration and education resistance, therefore Its connect top effect better than conventional filler, almost 100%.
Specific embodiment
For preferably describing the present invention, with reference to embodiment, filling is exploited with a kind of underground mine to the present invention Tailing foam mortar is described in further details.But the invention is not limited in embodiment.
Embodiment 1
A kind of tailing foam mortar for underground filling of the present invention, including Portland cement, mine tailing, quick lime, Alumina cement, gypsum, foaming agent and water, weigh 12.4% Portland cement, 50% iron ore tail by weight percentage Sand, 1.24% quick lime, 1.24% alumina cement, 1.24% gypsum, 0.8% foaming agent and 33.4% water.
Described tailings be iron tailings sand, 0.1~3mm grain size contents 60%, in mine tailing containing S amount, containing soil amount difference little In 1% and 3%.
In described Binder Materials, cement is conch P.O32.5 Portland cements, and specific surface area is 350m2/kg; It is 85% that quick lime is CaO content, and quick lime is 95% through the levigate content to -200 mesh;Alumina cement main component is aluminium Hydrochlorate;Gypsum is gypsum, and main component is CaSO4·2H2O.
Foaming agent is vegetalitas macromolecule foaming agent, and coefficient of foaming is 40 times.
After tailings is weighed by corresponding proportioning to cement, quick lime, alumina cement, gypsum and water, it is placed in agitator and stirs 2min is mixed, then foam is added in last mortar, stirred 1 minute, be allowed to be sufficiently mixed uniform, the foam mortar material for being formed, note Enter and vibrate 1 minute on a vibration table, with mould test block in the curing box maintenance 24h that temperature is 25 DEG C, humidity is 90%, Maintenance can be used with regard to collapsible die, maintenance after 24~48 hours for 3 days.
Compressive strength test is carried out to foam mortar of the present invention, from the foam mortar that is matched somebody with somebody, the test block made is carried out many Secondary repeat to test, according to《Building mortar basic performance tests method standard》Code, with pressure testing machine press mortar specimen, with Loading speed should be 0.25KN each second~1.5KN and continuously press, until destruction, records pressure, it is anti-that bearing capacity meets filling Pressure request.
Embodiment 2
A kind of tailing foam mortar for underground filling of the present invention, including Portland cement, mine tailing, quick lime, Alumina cement, gypsum, foaming agent and water, weigh 9% Portland cement, 53.7% iron ore tail by weight percentage Sand, 0.9% quick lime, 0.9% alumina cement, 0.9% gypsum, 0.9% foaming agent and 33.8% water.According to upper State mass percent to sequentially add, the tailing foam mortar to the present invention that mixing machinery stirs.Wherein each component Specification and producer's model are with embodiment 1.
Implement the method for inspection with embodiment 1, in the present embodiment, change the ratio of cement and mine tailing, as a result find resistance to compression Intensity substantially reduces, but can meet invention effect.
Embodiment 3
A kind of tailing foam mortar for underground filling of the present invention, including Portland cement, mine tailing, quick lime, Alumina cement, gypsum, foaming agent and water, weigh 13.3% Portland cement, 53.3% iron ore by weight percentage Tailings, 1.3% quick lime, 1.3% alumina cement, 1.3% gypsum, 0.9% foaming agent and 28.6% water.According to Above-mentioned mass percent is sequentially added, the tailing foam mortar to the present invention that mixing machinery stirs.Wherein each group Divider lattice and producer's model are with embodiment 1.
Implement the method for inspection with embodiment 1, in the present embodiment, change cement and mine tailing mass concentration, keep cement-sand ratio Constant, as a result find that compression strength is significantly improved.
Embodiment 4
A kind of tailing foam mortar for underground filling of the present invention, including Portland cement, mine tailing, quick lime, Alumina cement, gypsum, foaming agent and water, weigh 13.3% Portland cement, 53.4% iron ore by weight percentage Tailings, 1.3% quick lime, 1.3% alumina cement, 1.3% gypsum, 0.7% foaming agent and 28.6% water.According to Said ratio is sequentially added, the tailing foam mortar to the present invention that mixing machinery stirs.Wherein each component specification With producer model with embodiment 1.
Implement the method for inspection with embodiment 1, in the present embodiment, it is consistent with the mass percent of mine tailing to maintain cement, The foaming agent mass percent being introduced in mortar is changed, as a result finds that compression strength is gradually dropped with the rising of bubble rate Low.
Embodiment 5-12
Described tailings be iron ore mine, -0.074mm grain size contents in material<30%, wherein 0.1~3mm grade contains Amount 60%, in mine tailing, the amount containing S is less than 1%.
In described Binder Materials, cement is conch P.O32.5 Portland cements, and specific surface area is 350m2/kg; It is 85% that quick lime is CaO content, and quick lime is 90%~98% through the levigate content to -200 mesh;Alumina cement mainly into It is divided into aluminate;Gypsum is gypsum, and main component is CaSO4·2H2O.
Foaming agent is vegetalitas macromolecule foaming agent, and coefficient of foaming is 40 times.
Each component weight/mass percentage composition (%) in 1 embodiment 5-12 of table
Above-described embodiment 5-12, equally presses mortar specimen using pressure testing machine, should be each second with loading speed 0.25KN~1.5KN continuously presses, until destruction, records pressure, bearing capacity all meets filling pouring.
The present invention has also carried out commerical test checking to embodiment 6, embodiment 7, embodiment 8, and commerical test is in certain underground Carry out in the mining with stowing of iron ore mine.The tailing foam slurry placement commercial test results of 3 months show, using iron ore mine foam Mortar is filled, 7 days, the compression strength of 28 days respectively reach 1.8~2.0MPa, 3.2~3.5MPa, connect top rate and be up to 100%, fully meet iron ore mine Underground filler intensity requirement;And filling cost is greatly lowered, than adopting ordinary cement Slurry placement reduces more than 40%, than regular-type foam mortar (with natural sand as primary raw material) filling cost reduce by 22% with On, achieve extraordinary technology, economic indicator.

Claims (5)

1. the tailing foam mortar that a kind of underground mine exploitation is filled, it is characterised in that be by cement, mine tailing, quick lime, height Aluminium cement, gypsum, water are prepared from by the foam that foaming agent is formed through stirring mixing, injection, and total amount is each by 100% timing Constituent mass percentage composition is:
2. the tailing foam mortar that a kind of underground mine exploitation is filled as claimed in claim 1, it is characterised in that total amount is pressed The each component weight/mass percentage composition of 100% timing is:
3. the tailing foam mortar that a kind of underground mine exploitation is filled as claimed in claim 2, it is characterised in that total amount is pressed The each component weight/mass percentage composition of 100% timing is:
4. the tailing foam mortar that a kind of underground mine exploitation as described in claim 1,2 or 3 is filled, it is characterised in that: Described foaming agent is vegetalitas macromolecule foaming agent;Described Portland cement is common greater than or equal to P.O32.5 Portland cement;The granularity of the mine tailing be 0.074~3mm grain size contents 90%, wherein 0.1~3mm grain size contents 60%;Described quick lime be CaO content 85%, and quick lime through levigate to granularity be -0.074mm contents 90%.
5. the tailing foam mortar that a kind of underground mine exploitation is filled as claimed in claim 4, it is characterised in that:Described Mine tailing be 0.25~3mm grain size contents 90%, quick lime through levigate to granularity be -0.074mm contents 95%.
CN201610978396.6A 2016-11-08 2016-11-08 A kind of tailing foam mortar of underground mine exploitation filling Pending CN106495636A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108530224A (en) * 2018-04-28 2018-09-14 玉门龙川高科技发展有限公司 A kind of organic fertilizer overcoming soil hardening

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723622A (en) * 2008-10-28 2010-06-09 华鑫博越国际土木建筑工程技术(北京)有限公司 Foam tailings cemented filling material and manufacturing method thereof
CN102093009A (en) * 2010-11-26 2011-06-15 北京科技大学 Full-tail paste composite material and preparation method thereof
JP5422301B2 (en) * 2009-08-24 2014-02-19 電気化学工業株式会社 Aerated cement composition
CN104446640A (en) * 2014-12-03 2015-03-25 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 Foam tail mortar and pulping and grouting process thereof
CN104591663A (en) * 2014-11-17 2015-05-06 华唯金属矿产资源高效循环利用国家工程研究中心有限公司 Method for fast preparing mine tailing underground filling material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101723622A (en) * 2008-10-28 2010-06-09 华鑫博越国际土木建筑工程技术(北京)有限公司 Foam tailings cemented filling material and manufacturing method thereof
JP5422301B2 (en) * 2009-08-24 2014-02-19 電気化学工業株式会社 Aerated cement composition
CN102093009A (en) * 2010-11-26 2011-06-15 北京科技大学 Full-tail paste composite material and preparation method thereof
CN104591663A (en) * 2014-11-17 2015-05-06 华唯金属矿产资源高效循环利用国家工程研究中心有限公司 Method for fast preparing mine tailing underground filling material
CN104446640A (en) * 2014-12-03 2015-03-25 深圳市中金岭南有色金属股份有限公司凡口铅锌矿 Foam tail mortar and pulping and grouting process thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108530224A (en) * 2018-04-28 2018-09-14 玉门龙川高科技发展有限公司 A kind of organic fertilizer overcoming soil hardening

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