CN106495613B - A kind of heat preservation decoration integrative tapestry brick and preparation method thereof - Google Patents
A kind of heat preservation decoration integrative tapestry brick and preparation method thereof Download PDFInfo
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- CN106495613B CN106495613B CN201610959101.0A CN201610959101A CN106495613B CN 106495613 B CN106495613 B CN 106495613B CN 201610959101 A CN201610959101 A CN 201610959101A CN 106495613 B CN106495613 B CN 106495613B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/141—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of heat preservation decoration integrative flexible clay facing tiles and preparation method thereof, and the invention belongs to new decorative material for building fields, it includes porcelain tendre finish coat and insulating layer.The porcelain tendre finish coat includes the component of following parts by weight: 8~15 parts of lotion, 15~25 parts of miberal powder, 5~15 parts of cement, 40~60 parts of quartz sand, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water;The insulating layer is by the component of the following parts by weight containing glass fiber reticular cloth: 8~15 parts of lotion, 15~25 parts of miberal powder, 15~25 parts of cement, 20~50 parts of thermal insulation material, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water.Porcelain tendre finish coat hydrophobicity is strong, resistance to soiling is good, and porcelain tendre finish coat connects into an entirety by grout material with heat preservation interlayer, and heat preservation decoration integrative tapestry brick is light, has decoration and heat insulation function, is a kind of insulation and decoration construction material of excellent combination property.
Description
Technical field
The present invention relates to new decorative material for building technical field more particularly to a kind of heat preservation decoration integrative tapestry brick and
Preparation method.
Background technique
Flexible clay facing tile, also known as bright and beautiful clay (brocade: rich in color, clay: fine and glossy clay).It is with color modified inorganic mineral powder
Material is primary raw material, adds a small amount of water soluble polymer, flexible light by having made of specific technique
Matter building decoration, this respect are different from porcelain tendre, are the alternative materials of ideal traditional decoration building materials porcelain face brick, are suitable for coagulation
The energy conservation of the various newly-built walls such as soil, building block, external thermal insulation system and existing building is transformed with facing.
Flexible clay facing tile can be combined with the various External Thermal Insulation Technology for External used on the market at present, without changing exterior wall
The original technology way of external thermal insulation is directly pasted in outer thermal-insulating and anti-cracking protective layer.Compared to traditional porcelain face brick outer heat preservation system
Way, flexible clay facing tile have three advantages:
First is that safe and reliable from heavy and light, system, avoid due to porcelain face brick and the warm and humid shear stress of protective facing it is big and
The risk fallen;
Second is that steam permeability is extremely strong, waterproofness is again splendid, had not only overcome rainwater and has penetrated into exterior insulation within the walls, but also has prevented
Freeze thawing damage occurs for condensed water;
Third is that the arrangement of reinforcement quantity of structure foundation wall can be reduced, exterior insulation way is simplified, simplifies surface brick adherence process, not only
50% or more work efficiency can be improved, and comprehensive cost reduces by 30% or more, remarkable in economical benefits.
Compared to other same type of material, flexible clay facing tile has two big advantages: first is that water repellent and steam permeability are good, generically
It says, is exactly liquid water into not going, vaporous water can come out, it can be ensured that entire wall has respiratory.Second is that at flexible clay facing tile
Glue is not returned under hot environment, does not return white after brew 96 hours in 85 DEG C or more of hot water and can still be restored to the original state, automatically cleaning
Ability is strong, and the punching of wind water can be bright and clean as fresh.
Patent 201310143356.6 discloses a kind of flexible clay facing tile, is made of the material that following weight parts match, water
Mud 35-45, flyash 5-10, fineness are 60 mesh or so quartz sand 20-30, and fineness is 100 mesh or so quartz sand 5-15, wood
Matter cellulose 1-3, silicon powder 1-5, talcum powder 3-8, calcium oxide 1-5, sodium metasilicate 1-3 press down alkaline agent 0.5-1, acrylic acid
Rubber powder 2-3, iron oxide pigment 2-5.Add water 28 by every 100 parts by weight after material in above-mentioned formula is mixed, usually spends
Powder is put into water, slurry is broken into high-speed mixer, by about three kilograms of every square of materials, first by 2/3rds by ionized water
Slurry uniformly scratch on mold, spread at least one layer of 4# alkali resistant glass fibre open weave cloth, then by remaining one third slurry
On uniform blade coating, finally remove scratch with row brush.
Patent 201310143356.6 discloses a kind of flexible clay facing tile, is made of the material that following weight parts match, water
Mud 35-45, flyash 5-10, fineness are 60 mesh or so quartz sand 20-30, and fineness is 100 mesh or so quartz sand 5-15, wood
Matter cellulose 1-3, silicon powder 1-5, talcum powder 3-8, calcium oxide 1-5, sodium metasilicate 1-3 press down alkaline agent 0.5-1, acrylic acid
Rubber powder 2-3, iron oxide pigment 2-5.Add water 28 by every 100 parts by weight after material in above-mentioned formula is mixed, usually spends
Powder is put into water, slurry is broken into high-speed mixer, by about three kilograms of every square of materials, first by 2/3rds by ionized water
Slurry uniformly scratch on mold, spread at least one layer of 4# alkali resistant glass fibre open weave cloth, then by remaining one third slurry
On uniform blade coating, finally remove scratch with row brush.
Patent 201410639871.8 discloses one kind can substitute ceramic tile applied to architecture inside and outside decoration use extensively
Colour tapestry brick, the flexibility colored finish brick include components by weight percent be polymer emulsion 10-20%, curing agent 1-2%, increase
Agent 1.5-2.5%, thickener 0.2-0.5%, colorful quartz sands 60-75% and water 12-14% is moulded to be mixed, criticize through raw material
It scrapes molding, cutting, dried at 45-90 DEG C, wherein polymer emulsion is pure-acrylic emulsion or silicone acrylic emulsion, and curing agent is first
Phenylene diisocyanate, methyl diphenylene diisocyanate or aliphatic poly cyanate, thickener are cellulose ethers or polyurethane
Class thickener, colorful quartz sands are natural colorful mineral through the colorful quartz sands broken, fineness made of screening is 140-40 mesh.
Colored flexible clay facing tile of the invention has many advantages, such as that simple, low in cost, the rich in color, water resistance of formula and flexibility are good,
It is a kind of ideal material for substituting ceramic tile and being applied to architecture inside and outside decoration.
But above-mentioned flexible clay facing tile is all single face brick, and it is all undesirable in terms of wall insulation performance, actually answering
Insulating layer, one side complex procedures, another aspect higher cost are also individually laid in.
Summary of the invention
In order to solve deficiency existing for existing building decoration materials, it is an object of that present invention to provide a kind of novel heat preservations
Decoration integrated flexible clay facing tile and preparation method thereof.
The technical solution adopted by the present invention is that:
Heat preservation decoration integrative flexible clay facing tile of the invention is made of porcelain tendre finish coat and insulating layer, the porcelain tendre
Finish coat is grouped as by the group of following parts by weight: 8~15 parts of lotion, 15~25 parts of miberal powder, 5~15 parts of cement, quartz sand 40
~60 parts, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water;The insulating layer is by containing glass fiber net
The group of the following parts by weight of lattice cloth is grouped as: 8~15 parts of lotion, 15~25 parts of miberal powder, 15~25 parts of cement, thermal insulation material 20~
50 parts, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water.
It is preferred that: heat preservation decoration integrative flexible clay facing tile of the invention is made of porcelain tendre finish coat and insulating layer, described
Porcelain tendre finish coat be to be grouped as by the group of following parts by weight: 10 parts of lotion, 20 parts of miberal powder, 10 parts of cement, 50 parts of quartz sand, resistance
10 parts of agent of combustion, 1 part of inorganic pigment and 20 parts of water;The insulating layer is by the component of the following parts by weight containing glass fiber reticular cloth
Composition: 10 parts of lotion, 20 parts of miberal powder, 20 parts of cement, 35 parts of thermal insulation material, 10 parts of fire retardant, 1 part of inorganic pigment and 20 parts of water.
The lotion be organosilicon modified acrylic ester elastic emulsion, solid content 50%, glass transition temperature be-
5~25 DEG C.
The miberal powder is one of kaolin, volcanic ash, flyash or calcium powder.
The cement is one of the white portland cement marked as 325,425,525 or 625.
The quartz sand, partial size are 50~400 mesh.
The fire retardant is one of antimony oxide, melamine and ammonium polyphosphate.
The inorganic pigment is carbon black, titanium white, titan yellow, iron oxide red, iron oxide yellow, barba hispanica, cadmium red, one in cadmium yellow
Kind or two kinds.
The glass fiber reticular cloth is the glass fiber reticular cloth handled through fire retardant.
The thermal insulation material is haydite, expanded perlite granule, hard polyurethane foam particle and polystyrene foam
One of particle.
Specific step is as follows for the preparation method of heat preservation decoration integrative flexible clay facing tile of the invention:
(1) preparation of porcelain tendre finish coat:
Miberal powder, cement and quartz sand are weighed by weight, is added in kneader, are uniformly mixed, are obtained mixed powder;By weight
Amount part weighs lotion, fire retardant, inorganic pigment and water, is added in stirred tank, stirs evenly, obtains mixed emulsion;It again will mixing
Powder is added in mixed emulsion, is sufficiently stirred, and slurry is obtained;Finally slurry is poured into mold, is done in 40~90 DEG C of baking ovens
Dry 1~3h obtains porcelain tendre finish coat;
(2) preparation of heat preservation decoration integrative tapestry brick:
Miberal powder, cement and thermal insulation material are weighed by weight, is added in kneader, are uniformly mixed, are obtained mixed powder;It presses
Parts by weight weigh lotion, fire retardant, inorganic pigment and water, are added in stirred tank, stir evenly, and obtain mixed emulsion;It will mix again
It closes powder to be added in mixed emulsion, is sufficiently stirred, obtains slurry;Slurry is finally poured into the porcelain tendre decorative layer that step (1) obtains
Surface, after laying grid cloth, dry 2~6h in 40~90 DEG C of baking ovens, it is dried after demoulding, obtain heat preservation decoration integrative decorations
Face brick.
The preparation method of heat preservation decoration integrative flexible clay facing tile of the invention includes slurry preparation, porcelain tendre finish coat and guarantor
Warm formable layer.Preparation method of the invention is simple, energy conservation and environmental protection.Porcelain tendre finish coat hydrophobicity is strong, resistance to soiling is good, porcelain tendre finish coat
One entirety is connected by grout material with heat preservation interlayer, heat preservation decoration integrative tapestry brick is light, has decoration and heat preservation function
Can, it is a kind of insulation and decoration construction material of excellent combination property.
The positive effect of the present invention is as follows:
1. the porcelain tendre finish coat being prepared using organosilicon modified acrylic ester elastic emulsion have good pollution resistance,
Waterproofness and weatherability;Heat preservation decoration integrative flexible clay facing tile antidetonation, cracking resistance and good freeze-thaw resistance are assigned simultaneously;
2. kaolin, volcanic ash and flyash are not only used as powder stuffing, and generated in cement hydration process
Hydraulicity gel rubber material can be formed under the excitation of calcium hydroxide, improve the strong of heat preservation decoration integrative flexible clay facing tile
Degree;
3. heat preservation decoration integrative flexible clay facing tile good flame resistance, meets the environmental requirement of halogen-free flameproof, reach fire retardant etc.
Grade;
4. the porcelain tendre decorative layer of heat preservation decoration integrative flexible clay facing tile and heat preservation interlayer pass through in porcelain tendre layer and insulating layer
Lotion, miberal powder and cement realize effectively bonding, to form a complete body, the construction of heat preservation decoration integrative flexible clay facing tile
Simply, at low cost;
5. flame-proof glass fibre grid cloth improves the intensity of insulating layer as reinforcing material, and then improves heat insulation decoration integrated
The intensity for changing flexible clay facing tile entirety, improves its safety in utilization;
6. heat preservation decoration integrative flexible clay facing tile compared with conventional vacuum integrated board, has the advantages that light, body is thin, whole
Body weight can reduce more than half, and thermal coefficient is lower than 0.1W/m.K, compound insulating material requirement.
Specific embodiment
The following examples are a further detailed description of the invention.
Embodiment 1
The preparation method of heat preservation decoration integrative flexible clay facing tile of the invention, the specific steps are as follows:
(1) preparation of porcelain tendre finish coat:
40 parts of 20 parts of kaolin, 8 parts of 325 white portland cement and 50 mesh quartz sands are weighed by weight, are added to kneading
In machine, it is uniformly mixed, obtains mixed powder;The organosilicon-modified acrylic that glass transition temperature is -5 DEG C is weighed by weight
10 parts of ester lotion, 5 parts of antimony oxide, 1 part of titan yellow and 15 parts of water, are added in stirred tank, stir evenly, obtain mixed emulsion;
Mixed powder is added in mixed emulsion again, is sufficiently stirred, slurry is obtained;Finally slurry is poured into mold, in 40 DEG C of baking ovens
Middle dry 3h, obtains porcelain tendre finish coat;
(2) preparation of heat preservation decoration integrative flexible clay facing tile:
20 parts of kaolin, 15 parts of 325 white portland cement and 40 parts of expanded perlite granule are weighed by weight, are added to
In kneader, it is uniformly mixed, obtains mixed powder;Organic-silicon-modified third that glass transition temperature is -5 DEG C is weighed by weight
10 parts of olefin(e) acid ester lotion, 5 parts of antimony oxide, 1 part of titan yellow and 15 parts of water, are added in stirred tank, stir evenly, and obtain mixing cream
Liquid;Mixed powder is added in mixed emulsion again, is sufficiently stirred, slurry is obtained;Finally by slurry pour into step (1) obtain it is soft
Porcelain decor surface, one layer of laying after the processed glass fiber reticular cloth of fire retardant, is dried 6h, after dried in 70 DEG C of baking ovens
Demoulding, obtains heat preservation decoration integrative flexible clay facing tile.
Embodiment 2-6
Composition of raw materials and the technological parameter of preparation are as shown in table 1, and specific the preparation method is the same as that of Example 1.
Table 1
Sample obtained by above-described embodiment is surveyed according to GB/T3810.13-2006 test pollution resistance, GB/8624-2006 respectively
Try anti-flammability, GB/T3810.12-2006 test freeze-thaw resistance, GB/T1865-1997 test resistance to ag(e)ing and GB/T10294-
2008 test thermal coefficients.
Table 2
As can be seen from Table 2, the heat preservation decoration integrative flexible clay facing tile that the present invention is prepared has excellent anti-pollution
Property, freeze-thaw resistance, anti-flammability and ageing-resistant performance, thermal coefficient is lower than 0.1W/m.K, meets the requirement of thermal insulation decorative material.This
The weight for inventing the heat preservation decoration integrative flexible clay facing tile being prepared is light compared with conventional vacuum ornament materials, easy for installation, at
This low, energy conservation and environmental protection, is a kind of environmentally protective thermal insulation decorative material.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. a kind of heat preservation decoration integrative flexible clay facing tile, it is characterised in that: it is made of porcelain tendre finish coat and insulating layer, institute
The porcelain tendre finish coat stated is grouped as by the group of following parts by weight: 8~15 parts of lotion, 15~25 parts of miberal powder, 5~15 parts of cement,
40~60 parts of quartz sand, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water;The insulating layer is by containing
There is the group of the following parts by weight of glass fiber reticular cloth to be grouped as: 8~15 parts of lotion, 15~25 parts of miberal powder, 15~25 parts of cement, heat preservation
20~50 parts of material, 5~15 parts of fire retardant, 0.5~2 part of inorganic pigment and 10~25 parts of water;
Specific step is as follows for the heat preservation decoration integrative flexible clay facing tile preparation method:
(1) preparation of porcelain tendre finish coat:
Miberal powder, cement and quartz sand are weighed by weight, is added in kneader, are uniformly mixed, are obtained mixed powder;By weight
Lotion, fire retardant, inorganic pigment and water are weighed, is added in stirred tank, is stirred evenly, mixed emulsion is obtained;Again by mixed powder
It is added in mixed emulsion, is sufficiently stirred, obtain slurry;Finally slurry is poured into mold, dry 1 in 40~90 DEG C of baking ovens~
3h obtains porcelain tendre finish coat;
(2) preparation of heat preservation decoration integrative tapestry brick:
Miberal powder, cement and thermal insulation material are weighed by weight, is added in kneader, are uniformly mixed, are obtained mixed powder;By weight
Part weighs lotion, fire retardant, inorganic pigment and water, is added in stirred tank, stirs evenly, obtains mixed emulsion;Again by mixed powder
Material is added in mixed emulsion, is sufficiently stirred, is obtained slurry;Slurry is finally poured into the porcelain tendre decor surface that step (1) obtains,
After laying grid cloth, dry 2~6h in 40~90 DEG C of baking ovens demoulds after dried, obtains heat preservation decoration integrative tapestry brick;
The thermal insulation material is haydite, expanded perlite granule, hard polyurethane foam particle and polystyrene foam particles
One of.
2. heat preservation decoration integrative flexible clay facing tile as described in claim 1, it is characterised in that: it be by porcelain tendre finish coat and
Insulating layer composition, the porcelain tendre finish coat is grouped as by the group of following parts by weight: 10 parts of lotion, 20 parts of miberal powder, cement 10
Part, 50 parts of quartz sand, 10 parts of fire retardant, 1 part of inorganic pigment and 20 parts of water;The insulating layer is by containing glass fiber reticular cloth
The group of following parts by weight is grouped as: 10 parts of lotion, 20 parts of miberal powder, 20 parts of cement, 35 parts of thermal insulation material, 10 parts of fire retardant, inorganic
1 part of pigment and 20 parts of water.
3. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the lotion is to have
Machine fluorine-silicon modified acrylic ester elastomer lotion, solid content 50%, glass transition temperature are -5~25 DEG C.
4. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the miberal powder is height
One of ridge soil, volcanic ash, flyash or calcium powder.
5. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the cement is mark
Number be 325,425,525 or 625 one of white portland cement.
6. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the quartz sand,
Partial size is 50~400 mesh.
7. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the fire retardant is
One of antimony oxide, melamine and ammonium polyphosphate;The inorganic pigment is carbon black, titanium white, titan yellow, iron oxide
One or both of red, iron oxide yellow, barba hispanica, cadmium red, cadmium yellow.
8. heat preservation decoration integrative flexible clay facing tile as claimed in claim 1 or 2, it is characterised in that: the fiberglass mesh
Cloth is the glass fiber reticular cloth handled through fire retardant.
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