CN107555867A - A kind of lightweight high rigidity porcelain tendre ornament materials and preparation method thereof - Google Patents
A kind of lightweight high rigidity porcelain tendre ornament materials and preparation method thereof Download PDFInfo
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- CN107555867A CN107555867A CN201710764536.4A CN201710764536A CN107555867A CN 107555867 A CN107555867 A CN 107555867A CN 201710764536 A CN201710764536 A CN 201710764536A CN 107555867 A CN107555867 A CN 107555867A
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Abstract
A kind of lightweight high rigidity porcelain tendre ornament materials, the lightweight high rigidity porcelain tendre ornament materials is made up of for two layers top layer and bottom, wherein, top layer is by floating bead, coupling agent, silicone acrylic emulsion, cement and inorganic pigment composition, bottom is by cement, quartz sand, silicone acrylic emulsion, flyash forms, the porcelain tendre material prepared by the present invention has the performance of light high rigidity relative to common porcelain tendre material, wherein quality, which mitigates, can reach 20% or so, and hardness improves 1 grade, in addition, wearability and fracture strength are also similar with porcelain tendre material of the prior art, preferable usage time can be ensured.
Description
Technical field
The invention belongs to architectural decoration material field, is related to a kind of preparation method of lightweight high rigidity porcelain tendre ornament materials.
Background technology
Porcelain tendre is a kind of novel flexible planar ornament materials, with aqueous polymer emulsion and cement, soil, quartz sand or ore deposit
The inorganic matters such as powder are obtained by processing and forming, are a kind of ecological, environmental protective construction materials.Porcelain tendre is exactly like ceramics in appearance, but lacks and pass
Ice-cold, heavy, the frangible texture of system ceramic material, there is light matter and thin body, hydrophobic permeable, color and luster is natural, decorative pattern is various and flexible
And the features such as high resilience, and easily cut, paste, cost is low, and construction is convenient, is built suitable for exterior wall, interior wall and ground etc.
Finishing, live and work environment that is greatly abundant and having beautified people.
With the development of technology, it is various, rich and varied that people develop the species such as imitative stone material, leather texture imitation, imitation wood line in succession
Porcelain tendre, these porcelain tendre materials meet building back to nature requirement.As the improvement of people's living standards, people are to life cycle
The requirement more and more higher in border, such as eliminate peculiar smell, bacteriostasis antibiosis, snugness etc. and require.In addition, the porcelain tendre material that surface is smooth,
Its good hand touch, seem in decoration more added with class.There are many researchs to porcelain tendre in the prior art, but it is few right
The multi-functional and excellent mechanical performance of porcelain tendre material is reported.And in real life, many ornament materials are very heavy,
Such as ceramic tile, marble, for these ornament materials in artificial, metope is very high to artificial requirement when being bonded, and when processing
It is easily damaged, in fitting, due in quality, easily being come off by self gravitation and with metope, potential safety hazard be present.
In existing disclosed document, there are many researchs to disclose the research to light building material, but as porcelain tendre field
Lighting and the research of high rigidity are relatively fewer, and this is primarily due to porcelain tendre material for traditional ornament materials,
There is the light characteristic of a quality in itself, this contains large amount of organic, this kind of material energy in raw material mainly due to porcelain tendre
Enough obvious mitigation quality, therefore, few people pay close attention to the research to porcelain tendre material lighting.
Floating bead is a kind of fly ash hollow ball that can be bubbled through the water column, and in canescence, wall is thin hollow, very light in weight, and particle diameter is about
0.1 millimeter, surface-closed and it is smooth, thermal conductivity is small, and refractory temperature is high, is excellent heat insulating refractory material, is widely used in lightweight
In terms of the production of castable and oil drilling.The chemical analysis of floating bead has particle based on silica and alundum (Al2O3)
The multifrequency natures such as carefully, hollow, light, high intensity, wear-resisting, high temperature resistant, insulation insulation, flame-resistant insulation, are to be widely used in fire resisting
One of raw material of industry.
Flyash outward appearance changes similar to cement, color in milky between grey black.Fly ash grain is in porous type honeybee
Nest shape tissue, specific surface area is larger, has higher adsorption activity, the particle size range of particle is 0.5~300 μm.And Zhu Bi
With loose structure, porosity is up to 50% -80%, there is very strong water imbibition.
Current porcelain tendre material on the market is rare to be concerned about lighting processing, and the present invention will select two kinds of floating bead and flyash
Material, both materials belong to flyash, and its porosity is high, slim and graceful relative to traditional building material quality, while two kinds of things
Compatibility is preferable between matter, and the mechanical property of porcelain tendre material can be prepared and can also be improved.
The content of the invention
In order to solve problems of the prior art, a kind of lightweight high rigidity porcelain tendre ornament materials is prepared, makes the material
Expect light weight, while there is preferable hardness and excellent fire resistance, the present invention uses following methods.
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 10-20, cement 5-10 parts, coupling agent 3-8, inorganic pigment 0-3 parts add
Enter into kneader and be well mixed, obtain top layer powder.
Step (2) prepares bottom powder：Take cement 5-30 parts, quartz sand 5-15 parts, flyash 10-20 parts, coupling agent 1-3
Part is added in kneader and is well mixed, and obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 10-20 part silicone acrylic emulsions, added
Enter 5-30 part water, stir, obtain overlay mixture material；The second mixed powder that step (2) obtains is added to 10-20 parts silicon third
In emulsion, 5-30 part water is added, stirring, obtains bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4-1/2 of mould total amount, is dried
3-7 minutes, overlay mixture material is poured into, fills up mould.
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
In order to ensure that porcelain tendre texture material is slim and graceful, avoid as the heaviness of the decorative bricks such as ceramic tile, and reduce subsequent decorations material
Material comes off, and the present invention has selected primary raw material of the floating bead of lightweight high rigidity as porcelain tendre material.In being designed in whole brick face,
In order to ensure light quality, the thickness on top layer is set into the thickness more than bottom.But using floating bead to be soft made of primary raw material
Ceramic material, its in work progress its due to its surface it is relatively smooth, be unfavorable for and metope paste, therefore, lightweight of the invention
High rigidity porcelain tendre ornament materials is designed as two layers.Because the cost of floating bead is high relative to raw materials such as quartz sands, bottom selects again for we
Select and used flyash to replace quartz sand, such benefit can improve the degree of roughness of bottom, it is possible to increase top layer and bottom
Between adhesive strength, and the sticking strength between porcelain tendre material and metope.In addition, the chemical composition and floating bead of flyash
It is similar so that superficial layer and bottom are more prone to adhesion, and adhesion intensity is high.In addition for flyash, because it is also deposited
In more hole, therefore, using coal ash instead quartz sand, it can further mitigate the quality of porcelain tendre material.
For the specification of floating bead, for the ease of the requirement of lightweight and high rigidity, the density of floating bead is less than 500Kg/m3。
Because the porcelain tendre material of the present invention is materials at two layers, therefore it is to be ensured that the cross-linking effect between materials at two layers, because
This, in the baking step of first layer, it is impossible to drying completely so that bottom, which is deposited, not to be fully cured so that between bottom and top layer
Crosslinking can be mutually mixed, improves the intensity of porcelain tendre material.
Because floating bead is a kind of inorganic material, its quality is light and hardness is high, during as top layer, in order to prevent porcelain tendre material
Top layer floating bead is come off, and we add the use of coupling agent, and coupling agent is crosslinked without generation between enabling to silicone acrylic emulsion,
And floating bead can also be modified to a certain extent, while coupling agent can crosslink with the reacted product of cement hydration, because
This, coupling agent enables to crosslink between the product and silicone acrylic emulsion that floating bead, cement hydration are reacted, and then improves lightweight
The stability and high rigidity of porcelain tendre material.Due to crosslinking between floating bead and cement, silicone acrylic emulsion, therefore be prepared
The wearability of porcelain tendre material is improved significantly, and service life extends.
The lightweight high rigidity porcelain tendre ornament materials that the present invention prepares, it has, and quality is light, hardness height and high fire-retardance
Performance, meanwhile, the adhesive property in work progress between metope is high, difficult for drop-off, and the floating bead attachment of superficial layer is stable, resistance to
Mill property is high, service life length.
Brief description of the drawings
Fig. 1：Lightweight high rigidity porcelain tendre ornament materials schematic diagram
Wherein, 1, top layer；2nd, bottom.
Embodiment
Below in conjunction with embodiment, technical scheme is further described.
Embodiment 1
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,10 parts of cement, coupling agent 8,1 part of inorganic pigment is added to kneader
In be well mixed, obtain top layer powder.Floating bead density is 450kg/m3。
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 20 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4 of mould total amount, dries 5 points
Clock, overlay mixture material is poured into, fills up mould.Floating bead density is 450kg/m3。
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Embodiment 2
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,10 parts of cement, coupling agent 8,1 part of inorganic pigment is added to kneader
In be well mixed, obtain top layer powder.
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 20 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/2 of mould total amount, dries 5 points
Clock, overlay mixture material is poured into, fills up mould.
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Embodiment 3
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,5 parts of cement, coupling agent 8,1 part of inorganic pigment is added to kneader
In be well mixed, obtain top layer powder.Floating bead density is 450kg/m3。
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 10 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4 of mould total amount, dries 5 points
Clock, overlay mixture material is poured into, fills up mould.
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Embodiment 4
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Floating bead 20 is taken, 10 parts of cement, coupling agent 8, is added in kneader and is well mixed,
Obtain top layer powder.Floating bead density is 450kg/m3。
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 20 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4 of mould total amount, dries 20 points
Clock, overlay mixture material is poured into, fills up mould.
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Embodiment 5
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,10 parts of cement, coupling agent 5,1 part of inorganic pigment is added to kneader
In be well mixed, obtain top layer powder.Floating bead density is 450kg/m3。
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 20 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4 of mould total amount, dries 5 points
Clock, overlay mixture material is poured into, fills up mould.
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Embodiment 6
A kind of preparation method of lightweight high rigidity porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,10 parts of cement, coupling agent 8,1 part of inorganic pigment is added to kneader
In be well mixed, obtain top layer powder.Floating bead density is 750kg/m3。
Step (2) prepares bottom powder：10 parts of cement, 10 parts of quartz sand, 20 parts of flyash are taken, 2 parts of coupling agent is added to
It is well mixed in kneader, obtains bottom powder.
Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 20 parts of silicone acrylic emulsions,
10 parts of water are added, stirring, obtain bottom mixed material；
Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4 of mould total amount, dries 5 points
Clock, overlay mixture material is poured into, fills up mould.Floating bead density is 450kg/m3。
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Comparative example 1
A kind of preparation method of porcelain tendre ornament materials, it is characterised in that comprise the following steps：A kind of porcelain tendre ornament materials
Preparation method, it is characterised in that comprise the following steps：
Step (1), take 20 parts of silicone acrylic emulsion, inorganic pigment 2 to be added in stirred tank, stir, obtain mixed emulsion material.
Step (2), 10 parts of cement, 20 parts of quartz sand, 2 parts of coupling agent are added in kneader and are well mixed, mixed
Powder.
In step (3), the mixed emulsion material obtained during obtained mixed powder is added to, 10 parts of water are added, is put into and stirs
Mix in machine and stir, obtain mixed material；
Step (4), mixed material poured into mould；
Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain porcelain tendre ornament materials.
Comparative example 2
A kind of preparation method of porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take floating bead 20,10 parts of cement, coupling agent 5,1 part of inorganic pigment is added to kneader
In be well mixed, obtain powder.
Step (2) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain mixed material；
Step (3) molding, mixed material is poured into mould, fills up mould.
Step (4), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Comparative example 3
A kind of preparation method of porcelain tendre ornament materials, it is characterised in that comprise the following steps：
Step (1) prepares top layer powder：Take 10 parts of quartz sand, flyash 20,10 parts of cement, coupling agent 5, inorganic pigment 1
Part is added in kneader and is well mixed, and obtains powder.
Step (2) preparating mixture material：The top layer powder that step (1) obtains is added in 20 parts of silicone acrylic emulsions, added
10 parts of water, stirring, obtain mixed material；
Step (3) molding, mixed material is poured into mould, fills up mould.
Step (4), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre decoration material
Material.
Performance test methods：
Measuring mechanical property：The product that embodiment 1-4 and comparative example 1-3 is obtained carries out performance test, is surveyed using intensity
Equipment test fracture strength is tried, porcelain tendre density of material is tested using density tester.
Using the hardness of Mohs' hardness method measurement porcelain tendre.
Anti-wear performance is tested, and selects wire brush, under the conditions of certain pressure, porcelain tendre material surface is rubbed back and forth,
The mass change ratio of porcelain tendre material is measured, judges its anti-wear performance, wherein mass change ratio is bigger, and wearability is poorer.
Table 1 represents the mechanical performance of porcelain tendre material and apparent state
The mechanical performance and apparent state of the porcelain tendre material of table 1
Can be seen that from the comparing result of comparative example and embodiment can prepare relative to common porcelain tendre material in the present invention
Performance of the material with light high rigidity, wherein quality, which mitigate, can reach 20% or so (embodiment is compared with comparative example 1), and hardness
1 grade is improved, in addition, wearability and fracture strength are also similar with porcelain tendre material of the prior art, it is ensured that preferably
Usage time.
Claims (7)
- A kind of 1. lightweight high rigidity porcelain tendre ornament materials, it is characterised in that；The lightweight high rigidity porcelain tendre ornament materials by top layer and Bottom forms for two layers, wherein, top layer is made up of floating bead, coupling agent, silicone acrylic emulsion, cement and inorganic pigment, and bottom is by cement, stone Sand, silicone acrylic emulsion, flyash composition.
- 2. a kind of lightweight high rigidity porcelain tendre ornament materials as claimed in claim 1, it is characterised in that calculated according to mass parts, table Layer is by floating bead 10-20 parts, coupling agent 3-8 parts, silicone acrylic emulsion 10-20 parts, cement 5-10 parts, inorganic pigment 0-3 parts composition, bottom For cement 5-30 parts, quartz sand 5-15 parts, flyash 10-20 parts, coupling agent 1-3 parts, silicone acrylic emulsion 10-20 parts.
- 3. a kind of lightweight high rigidity porcelain tendre ornament materials as described in claim any one of 1-2, skin depth is underlayer thickness More than one times.
- 4. a kind of preparation method of lightweight high rigidity porcelain tendre ornament materials as described in claim any one of 1-3, its feature exist In：Step (1) prepares top layer powder：Floating bead 10-20 is taken, cement 5-10 parts, coupling agent 3-8, inorganic pigment 0-3 parts, which are added to, pinches It is well mixed in conjunction machine, obtains top layer powder；Step (2) prepares bottom powder：Cement 5-30 parts, quartz sand 5-15 parts, flyash 10-20 parts are taken, coupling agent 1-3 parts add Enter into kneader and be well mixed, obtain bottom powder；Step (3) preparating mixture material：The top layer powder that step (1) obtains is added in 10-20 part silicone acrylic emulsions, stirred, Obtain overlay mixture material；The second mixed powder that step (2) obtains is added in 10-20 part silicone acrylic emulsions, stirs, obtains Bottom mixed material；Step (4) molding, bottom mixed material is poured into mould, and pouring volume is the 1/4-1/2 of mould total amount, dries 3-7 Minute, overlay mixture material is poured into, fills up mould；Step (5), mould is sent into baking oven, solidified, is molded, dried, the demoulding, obtain lightweight high rigidity porcelain tendre ornament materials.
- A kind of 5. preparation method of lightweight high rigidity porcelain tendre ornament materials as described in any one of claim 4, it is characterised in that： With the product obtained after floating bead and cement hydration reaction coupled action can occur for coupling agent.
- A kind of 6. preparation method of lightweight high rigidity porcelain tendre ornament materials as described in any one of claim 4, it is characterised in that： The density of the floating bead is less than 500Kg/m3。
- 7. a kind of preparation method of lightweight high rigidity porcelain tendre ornament materials as described in any one of claim 4, in step (5) The condition of solidification is to solidify 10-20 minutes at 110-130 DEG C.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108863231A (en) * | 2018-07-26 | 2018-11-23 | 万卓（武汉）新材料有限公司 | A kind of waterproof and breathable flexible clay facing tile and preparation method thereof |
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| CN106495613A (en) * | 2016-11-03 | 2017-03-15 | 威骏（湖北）高新实业股份有限公司 | A kind of heat preservation decoration integrative tapestry brick and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108863231A (en) * | 2018-07-26 | 2018-11-23 | 万卓（武汉）新材料有限公司 | A kind of waterproof and breathable flexible clay facing tile and preparation method thereof |
| CN108863231B (en) * | 2018-07-26 | 2021-04-13 | 万卓（武汉）新材料有限公司 | Waterproof breathable flexible facing brick and preparation method thereof |
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